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1. 发明授权

US06441087B1 High gloss acrylic coatings with improved impact resistance 失效
标题翻译：高光泽丙烯酸涂料具有改善的抗冲击性
公开(公告)号：US06441087B1
公开(公告)日：2002-08-27
申请号：US09671572
申请日：2000-09-27
申请人： Lichang Zhou , Oliver Wendell Smith , Thomas Clayton Forschner , Wyndham Henry Boon , David Eric Gwyn , Shelby Freland Thames
发明人： Lichang Zhou , Oliver Wendell Smith , Thomas Clayton Forschner , Wyndham Henry Boon , David Eric Gwyn , Shelby Freland Thames
IPC分类号： C08L7500
CPC分类号： C08G18/792 , C08G18/4063 , C08G18/44 , C09D175/04
摘要： Disclosed is an acrylic polyurethane coating composition characterized by improved impact resistance and high gloss and produced by reacting a polyol, optionally a catalyst, and a polyisocyanate crosslinking agent, wherein the polyol is substituted with 2 to 50% by weight of a polytrimethylene carbonate diol or triol.
摘要翻译：公开了一种丙烯酸聚氨酯涂料组合物，其特征在于具有改善的耐冲击性和高光泽度，并且通过使多元醇，任选的催化剂和多异氰酸酯交联剂反应制备，其中多元醇被2-50重量％的聚三亚甲基碳酸酯二醇或三醇

2. 发明授权

US06534178B2 Carboxyl-functional polyester epoxy resin powder coatings based on 1,3-propanediol 失效
标题翻译：基于1,3-丙二醇的羧基官能聚酯环氧树脂粉末涂料
公开(公告)号：US06534178B2
公开(公告)日：2003-03-18
申请号：US09808975
申请日：2001-03-15
申请人： Lichang Zhou , Shelby F. Thames , Oliver Wendell Smith , Wyndham Henry Boon , Thomas Clayton Forschner
发明人： Lichang Zhou , Shelby F. Thames , Oliver Wendell Smith , Wyndham Henry Boon , Thomas Clayton Forschner
IPC分类号： B32B2736
CPC分类号： C08G59/4276 , C09D167/00 , Y10S525/934 , Y10T428/31511 , C08L63/00
摘要： In accordance with the foregoing, the present invention comprises a polyester epoxy resin powder coating exhibiting improved impact resistance and flexibility, without the loss of other key properties and where the 1,3-PDO modified polyester has lower melt viscosity than polyesters made with 100% neopentyl glycol, which is formed by reacting: a) A carboxyl functional polyester resin formed by reacting one or more aliphatic glycols and one or more polycarboxylic acids and/or anhydrides, wherein 5 to 90% (on a molar basis) of the aliphatic glycol is 1,3-propanediol, in the presence of an esterification catalyst and then endcapping the polyester with an endcapping agent to ensure that the polyester has carboxyl chain ends; and b) An epoxy resin crosslinking agent.
摘要翻译：根据上述，本发明包括具有改善的耐冲击性和柔韧性的聚酯环氧树脂粉末涂料，而不损失其它关键性能，并且其中1,3-PDO改性聚酯的熔体粘度低于用100％新戊二醇是通过以下反应而形成的：a）通过一种或多种脂族二醇与一种或多种多元羧酸和/或酸酐反应形成的羧基官能聚酯树脂，其中5至90％（基于摩尔数）的脂族二醇是1,3-丙二醇，在酯化催化剂的存在下，然后用封端剂封端聚酯以确保聚酯具有羧基链端; andb）环氧树脂交联剂。

3. 发明授权

US4016059A Method for curing ink and coating compositions of acrylated epoxidized soybean oil amine compounds 失效
标题翻译：丙烯酸酯化环氧化大豆油胺化合物的油墨和涂料组合物的固化方法
公开(公告)号：US4016059A
公开(公告)日：1977-04-05
申请号：US563132
申请日：1975-03-28
申请人： David John Trecker , George Wayne Borden , Oliver Wendell Smith
发明人： David John Trecker , George Wayne Borden , Oliver Wendell Smith
IPC分类号： C08F220/36 , C09D11/10 , B01J1/10
CPC分类号： C08F220/36 , C09D11/10
摘要： Compositions of amine derivatives of acrylated epoxidized soybean oil, which are the reaction products of an organic amine with the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and an acrylyl compound which are useful as coatings and inks are cured by radiation. The compositions can also contain photosensitizers and/or pigments.
摘要翻译：作为有机胺与环氧化大豆油与丙烯酸或甲基丙烯酸的反应产物和可用作涂料和油墨的丙烯酰基化合物的丙烯酸酯化环氧化大豆油的胺衍生物的组合物通过辐射固化。组合物还可以含有光敏剂和/或颜料。

4. 发明授权

US3943082A Thermosetting powder coatings 失效
标题翻译：热固性粉末涂料
公开(公告)号：US3943082A
公开(公告)日：1976-03-09
申请号：US529524
申请日：1974-12-04
申请人： Oliver Wendell Smith , Joseph Victor Koleske
发明人： Oliver Wendell Smith , Joseph Victor Koleske
IPC分类号： C08L27/00 , B29C37/00 , C08K5/1515 , C08L63/00 , C08L67/00 , C09D5/03 , C09D5/46 , C09D127/06 , C08K5/15 , C08L63/02 , C08L91/00
CPC分类号： B29C37/0067 , C09D127/06 , C08L63/00 , Y10S524/904 , Y10T428/31529 , Y10T428/31935
摘要： Powder coating compositions of copolymers of vinyl chloride and a glycidyl acrylyl compound containing a crosslinker for the oxirane groups of the acrylyl compound and the epoxy resin and a minor amount of a plasticizing epoxy resin have been produced having improved flow properties.
摘要翻译：已经制备了具有改进的流动性质的氯乙烯和含有丙烯酰基化合物和环氧树脂的环氧乙烷基团的交联剂和少量增塑环氧树脂的缩水甘油基丙烯酰基化合物的共聚物的粉末涂料组合物。

5. 发明授权

US4119593A Polyepoxide high solids coatings 失效
标题翻译：聚环氧化物高固体涂料
公开(公告)号：US4119593A
公开(公告)日：1978-10-10
申请号：US798185
申请日：1977-05-18
申请人： Oliver Wendell Smith , Joseph Victor Koleske
发明人： Oliver Wendell Smith , Joseph Victor Koleske
IPC分类号： C08G59/00 , C08G59/16 , C08G59/20 , C08G59/42 , C08G59/68 , C09D163/00 , C09D3/58
CPC分类号： C08G59/42 , C08G59/681 , C09D163/00
摘要： High solids, low energy cure coating compositions of aliphatic polyepoxides, monocarboxylic acid compounds as initiator and stannous salts as catalysts.
摘要翻译：脂肪族聚环氧化物，一元羧酸化合物作为引发剂的高固体，低能量固化涂料组合物和作为催化剂的亚锡盐。

6. 发明授权

US4003868A Ink or coating compositions of low volatility 失效
标题翻译：低挥发性油墨或涂料组合物
公开(公告)号：US4003868A
公开(公告)日：1977-01-18
申请号：US571786
申请日：1975-04-25
申请人： Oliver Wendell Smith , Charles Hobert Carder , David John Trecker
发明人： Oliver Wendell Smith , Charles Hobert Carder , David John Trecker
IPC分类号： B05D3/02 , B05D3/06 , C09D4/00 , C09D11/10 , C09D3/52 , C09D3/58 , C09D3/81
CPC分类号： B05D3/067 , B05D3/0209 , B05D3/068 , C09D11/101 , C09D4/00 , Y10S522/909
摘要： Liquid ink or coating compositions that can be cured by thermal treatment or by a combination of ionizing or non-ionizing radiation and a thermal treatment are disclosed. The components are all essentially non-volatile during cure and the compositions have high viscosities making them eminently suitable for printing applications.
摘要翻译：公开了可以通过热处理或通过电离或非电离辐射和热处理的组合固化的液体油墨或涂料组合物。组分在固化期间基本上都是非挥发性的，并且组合物具有高粘度，使得它们非常适用于印刷应用。

7. 发明授权

US3931071A Compositions of acrylated epoxidized soybean oil amine compounds useful as inks and coatings 失效
标题翻译：丙烯酸环氧化大豆油组合物作为油墨和涂料有用的组合物
公开(公告)号：US3931071A
公开(公告)日：1976-01-06
申请号：US476054
申请日：1974-06-03
申请人： David John Trecker , George Wayne Borden , Oliver Wendell Smith
发明人： David John Trecker , George Wayne Borden , Oliver Wendell Smith
IPC分类号： C08F220/36 , C09D11/10 , C08F19/14
CPC分类号： C09D11/101 , C08F220/36
摘要： Compositions of amine derivatives of acrylated epoxidized soybean oil, which are the reaction products of an organic amine with the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and an acrylyl compound are useful as coatings and inks; photosensitizers and/or pigments can optionally be present. The compositions can be cured by radiation.

8. 发明授权

US4102942A Compositions of high solids content comprising carboxylic polymer and aliphatic diepoxide 失效
标题翻译：包含羧酸聚合物和脂族二环氧化物的高固含量组合物
公开(公告)号：US4102942A
公开(公告)日：1978-07-25
申请号：US709816
申请日：1976-07-29
申请人： Oliver Wendell Smith , Robert Arthur Taller , Joseph Victor Koleske
发明人： Oliver Wendell Smith , Robert Arthur Taller , Joseph Victor Koleske
IPC分类号： C08L33/00 , C08G59/00 , C08G59/42 , C08L33/02 , C08L33/04 , C08L35/00 , C08L63/00 , C09D163/00 , C08L63/10
CPC分类号： C08L33/02 , C08G59/4261 , C08L35/00 , C09D163/00 , C08L63/00 , Y10T428/31511 , Y10T428/31529 , Y10T428/31692 , Y10T428/31699 , Y10T428/31855
摘要： High solids coating or ink compositions comprising blends of low molecular weight acrylic copolymers having pendant carboxyl groups and aliphatic polyepoxides.
摘要翻译：包含具有侧基羧基的低分子量丙烯酸共聚物和脂族聚环氧化物的共混物的高固含量涂料或油墨组合物。

9. 发明授权

US4101603A High solids coating compositions 失效
标题翻译：高固含量涂料组合物
公开(公告)号：US4101603A
公开(公告)日：1978-07-18
申请号：US690185
申请日：1976-05-26
申请人： Oliver Wendell Smith , Joseph Victor Koleske
发明人： Oliver Wendell Smith , Joseph Victor Koleske
IPC分类号： C08G63/12 , C08G63/664 , C09D161/28 , C09D167/04 , C09D175/06 , C08L61/32 , C08L67/04
CPC分类号： C09D167/04 , C08G63/12 , C08G63/664 , C09D161/28 , C09D175/06
摘要： High solids coating compositions comprising a polycaprolactone derivative and a mixture of a methylolated melamine and a low molecular weight polyol; and, optionally, solvent and catalyst. The polycaprolactone derivative used in the coating compositions can be (A) a polycaprolactone polyol; or (B) the reaction product of a polycaprolactone polyol and an anhydride of a polycarboxylic acid; or (C) the reaction product of a polycaprolactone polyol, a polyisocyanate and an anhydride of a polycarboxylic acid; or (D) the reaction product of a polycaprolactone polyol, a diepoxide and an anhydride of a polycarboxylic acid; the polycaprolactone polyol referred to in the above four classes, Types A to D, has an average of at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to about 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride mentioned has at least one intramolecular carboxylic anhydride group. The polycaprolactone derivatives are water insoluble.
摘要翻译：包含聚己内酯衍生物和羟甲基化三聚氰胺与低分子量多元醇的混合物的高固含量涂料组合物; 和任选的溶剂和催化剂。用于涂料组合物的聚己内酯衍生物可以是（A）聚己内酯多元醇; 或（B）聚己内酯多元醇与多元羧酸的酸酐的反应产物; 或（C）聚己内酯多元醇，多异氰酸酯和多元羧酸的酸酐的反应产物; 或（D）聚己内酯多元醇，二环氧化物和多元羧酸的酸酐的反应产物; 上述四类A，D中所述的聚己内酯多元醇在分子中平均具有至少两个羟基，羟值为约15至约600，平均分子量为约290至约 6,000。所述羧酸酐具有至少一个分子内羧酸酐基团。聚己内酯衍生物是水不溶性的。

10. 发明授权

US4096125A Polycaprolactone derivatives and coating compositions thereof 失效
标题翻译：聚己内酯衍生物及其涂料组合物
公开(公告)号：US4096125A
公开(公告)日：1978-06-20
申请号：US690353
申请日：1976-05-26
申请人： Oliver Wendell Smith , Joseph Victor Koleske
发明人： Oliver Wendell Smith , Joseph Victor Koleske
IPC分类号： C08G63/00 , C08G63/08 , C08G63/91 , C09D167/00 , C09D167/04 , C08G63/12 , C08G63/52 , C08G63/68
CPC分类号： C08G63/08 , C09D167/04
摘要： Water insoluble adducts are produced comprising the reaction product of a polycaprolactone polyol and an anhydride of a polycarboxylic acid. The polycaprolactone polyol reacted with the anhydride of the polycarboxylic acid has an average of at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride has at least one intramolecular carboxylic anhydride group. These water insoluble adducts on reaction with an inorganic or organic base produce water soluble, carboxyl modified oligomer addition reaction products which are eminently suitable for the production of aqueous coatings compositions. Exceptionally good coatings compositions are obtained when a crosslinker is present in the coating composition.
摘要翻译：制备包含聚己内酯多元醇与多元羧酸酐的反应产物的水不溶性加合物。与多元羧酸酐反应的聚己内酯多元醇在分子中平均具有至少两个羟基，羟值为约15至600，平均分子量为约290至约6,000。羧酸酐具有至少一个分子内羧酸酐基团。这些与无机或有机碱反应的水不溶性加合物产生水溶性羧基改性低聚物加成反应产物，其特别适用于生产水性涂料组合物。当涂料组合物中存在交联剂时，获得了非常好的涂料组合物。

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