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    • 6. 发明授权
    • Non-adiabatic olefin solution polymerization
    • 非绝热烯烃溶液聚合
    • US5977251A
    • 1999-11-02
    • US831172
    • 1997-04-01
    • Che I. KaoR. Bruce CombsGary A. CampDavid A. EversdykPradeep JainGreg A. WinterJeff H. Stultz
    • Che I. KaoR. Bruce CombsGary A. CampDavid A. EversdykPradeep JainGreg A. WinterJeff H. Stultz
    • B01J19/24C08F2/06C08F10/00C08F210/16
    • C08F10/00B01J19/2435B01J19/245B01J19/2465B01J2219/00085B01J2219/00103B01J2219/00159B01J2219/00162B01J2219/00168B01J2219/00765C08F210/16Y02P20/584Y10S526/905
    • A solution polymerization system for polymerizing a olefin monomer by reacting the monomer with catalyst and solvent has been invented. The system in one aspect including a flow loop with a product polymer outlet, the flow loop forming a recycling reactor, a catalyst inlet on the flow loop through which catalyst and solvent flow into the flow loop, a monomer inlet on the flow loop through which monomer and solvent flow into the flow loop and, with the catalyst, form a reactant materials stream, a first heat exchanger on the flow loop for receiving the reactant materials stream and any formed polymer and for removing heat of reaction or polymerization from the flow loop, and pump apparatus for pumping the reactant materials stream and formed polymer in the flow loop and from the first heat exchanger to the product polymer outlet. In one aspect, the system includes at least one additional heat exchanger on the flow loop for receiving the reactant materials stream and formed polymer and for removing heat of reaction or polymerization from the flow loop, the pump apparatus pumping formed polymer and remaining reactant materials to the product polymer outlet, and a portion of the formed polymer and remaining reactant materials flowing out from the product polymer outlet and the remainder recycling through the flow loop. In one aspect systems and methods according to the present invention are used to make polyethylene.
    • 已经发明了通过使单体与催化剂和溶剂反应来使烯烃单体聚合的溶液聚合体系。 该系统在一个方面包括具有产物聚合物出口的流动回路,形成循环反应器的流动回路,流动回路上的催化剂入口,催化剂和溶剂通过该回路进入流动回路,流动回路上的单体入口, 单体和溶剂流入流动回路,并且与催化剂形成反应物料流,流动回路上用于接收反应物料流和任何形成的聚合物的第一热交换器,以及用于从流动回路除去反应或聚合的热量 以及泵装置,用于将反应物料流和形成的聚合物泵送在流动回路中并从第一热交换器泵送到产物聚合物出口。 在一个方面,该系统在流动回路上包括至少一个额外的热交换器,用于接收反应物料流和形成的聚合物,并用于从流动回路除去反应或聚合的热量,泵设备将形成的聚合物和剩余的反应物材料泵送到 产物聚合物出口,以及形成的聚合物的一部分和剩余的反应物料从产物聚合物出口流出,其余反应物质通过流动回路循环。 一方面,根据本发明的系统和方法用于制备聚乙烯。