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1. 发明授权

US5072016A Mixtures of fluorescent whitening agents 失效
标题翻译：荧光染料的混合物
公开(公告)号：US5072016A
公开(公告)日：1991-12-10
申请号：US581244
申请日：1990-09-07
申请人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
发明人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
IPC分类号： C09B67/22 , D06L3/12
CPC分类号： D06L3/125
摘要： Mixtures of fluorescent whitening agents consisting of 51 to 99% by weight of 1-(4-cyanostyryl)-4-(3'-styryl)benzene, 49 to 1% by weight of 1-(4-cyanostyryl)-4-(2'-cyanostyryl)benzene and 0.5 to 5% by weight of 1,4-bis(cyanostyryl)benzene, a process for the preparation of said mixtures by condensing terephthalaldehyde with a 4-dialkylphosphonomethylbenzonitrile to 4-cyano-4'-formylstilbene, which is further condensed, either direct or after isolation, with a 3- and 2-dialkylphosphonomethylbenzonitrile, the use of these mixtures for whitening polyester fibres, and compositions containing said mixtures for whitening polyester fibres.
摘要翻译：由51〜98.5重量％的1-（4-氰基苯乙烯基）-4-（3'-苯乙烯基）苯组成的荧光增白剂混合物，48.5〜1重量％的1-（4-氰基苯乙烯基）-4-（ 2'-氰基苯乙烯基）苯和0.5至5重量％的1,4-双（氰基苯乙烯基）苯，通过将对苯二甲醛与4-二烷基膦酰基甲基苄腈一起冷凝至4-氰基-4'-甲酰基芪制备所述混合物的方法，其通过3-和2-二烷基膦酰基甲基苄腈直接或分离后进一步缩合，使用这些用于增白聚酯纤维的混合物，以及含有用于增白聚酯纤维的所述混合物的组合物。

2. 发明授权

US4867906A Mixtures of fluorescent whitening agents 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4867906A
公开(公告)日：1989-09-19
申请号：US148453
申请日：1988-01-25
申请人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
发明人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
IPC分类号： C09B67/22 , D06L3/12
CPC分类号： D06L3/125
摘要： Mixtures of fluorescent whitening agents consisting of 51 to 98.5% by weight of 1-(4-cyanostyryl)-4-(3'-styryl)benzene, 48.5 to 1% by weight of 1-(4-cyanostyryl)-4-(2'-cyanostyryl)benzene and 0.5 to 5% by weight of 1,4-bis(cyanostyryl)benzene, a process for the preparation of said mixtures by condensing terephthalaldehyde with a 4-dialkylphosphonomethylbenzonitrile to 4-cyano-4'-formylstilbene, which is further condensed, either direct or after isolation, with a 3- and 2-dialkylphosphonomethylbenzonitrile, the use of these mixtures for whitening polyester fibers, and compositions containing said mixtures for whitening polyester fibers.
摘要翻译：由51〜98.5重量％的1-（4-氰基苯乙烯基）-4-（3'-苯乙烯基）苯组成的荧光增白剂混合物，48.5〜1重量％的1-（4-氰基苯乙烯基）-4-（ 2'-氰基苯乙烯基）苯和0.5至5重量％的1,4-双（氰基苯乙烯基）苯，通过将对苯二甲醛与4-二烷基膦酰基甲基苄腈一起冷凝至4-氰基-4'-甲酰基芪制备所述混合物的方法，其通过3-和2-二烷基膦酰基甲基苄腈直接或分离后进一步缩合，使用这些用于增白聚酯纤维的混合物，以及含有用于增白聚酯纤维的所述混合物的组合物。

3. 发明授权

US4778622A Mixtures of fluorescent whitening agents 失效
公开(公告)号：US4778622A
公开(公告)日：1988-10-18
申请号：US25023
申请日：1987-03-12
申请人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
发明人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
IPC分类号： C09B67/42 , C09B67/22 , D06L3/12 , C09K11/06
CPC分类号： D06L3/125
摘要： Mixtures of fluorescent whitening agents consisting of 51 to 99% by weight of a symmetrically or unsymmetrically substituted first 1,4-bis(cyanostyryl)benzene and 49 to 1% by weight of an unsymmetrically substituted second 1,4-bis(cyanostyryl)benzene that differs from the first, a process for the preparation of said mixtures by condensing terephthalaldehyde with a di(C.sub.1 -C.sub.4) alkylphosphonomethylbenzonitrile to cyano-4-formylstilbene, which is further condensed, either direct or after isolation, with at least one other di(C.sub.1 -C.sub.4)alkylphosphonomethylbenzonitrile, the use of these mixtures for whitening polyester fibres, and compositions containing said mixtures for whitening polyester fibres.

4. 发明授权

US4891153A Mixtures of fluorescent whitening agents 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4891153A
公开(公告)日：1990-01-02
申请号：US228643
申请日：1988-08-05
申请人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
发明人： Leonardo Guglielmetti , Hans R. Meyer , Dieter Reinehr , Kurt Weber
IPC分类号： C09B67/42 , C09B67/22 , D06L3/12
CPC分类号： D06L3/125
摘要： Mixtures of fluorescent whitening agents consisting of 51 to 99% by weight of a symmetrically or unsymmetrically substituted first 1,4-bis(cyanostyryl)benzene and 49 to 1% by weight of an unsymmetrically substituted second 1,4-bis(cyanostyryl)benzene that differs from the first, a process for the preparation of said mixtures by condensing terephthalaldehyde with a di(C.sub.1 -C.sub.4)alkylphosphonomethylbenzonitrile to cyano-4-formylstilbene, which is further condensed, either direct or after isolation, with at least one other di(C.sub.1 -C.sub.4)alkylphosphonomethylbenzonitrile, the use of these mixtures for whitening polyester fibres, and compositions containing said mixtures for whitening polyester fibres.
摘要翻译：由对称或不对称取代的第一1,4-双（氰基苯乙烯基）苯和49至1重量％的不对称取代的第二1,4-双（氰基苯乙烯基）苯的51至99重量％的荧光增白剂混合物其与第一种不同之处在于，通过将对苯二甲醛与二（C 1 -C 4）烷基膦酰基甲基苄腈缩合成氰基-4-甲酰基茋而制备所述混合物的方法，其直接或分离后与至少一种其它二（C1-C4）烷基膦酰基甲基苄腈，使用这些用于增白聚酯纤维的混合物，以及含有用于增白聚酯纤维的所述混合物的组合物。

5. 发明授权

US5152922A 1,4-distyrylbenzene compounds and mixtures thereof with other 1,4-distyrybenzene compounds 失效
标题翻译： 1,4-二氨基苯乙烯化合物及其与1,4-二氨基苯酚化合物的混合物
公开(公告)号：US5152922A
公开(公告)日：1992-10-06
申请号：US671178
申请日：1991-03-15
申请人： Hans R. Meyer , Leonardo Guglielmetti
发明人： Hans R. Meyer , Leonardo Guglielmetti
IPC分类号： C07C45/68 , C07C47/55 , C07C317/14 , C09K11/06 , D06L3/12
CPC分类号： C07C317/00 , C07C45/68 , C07C47/55 , D06L3/125
摘要： Novel 1,4-distyrylbenzene compounds of the formula ##STR1## and mixtures thereof with compounds of the formulae ##STR2## and/or ##STR3## in which R.sub.1 is C.sub.1 -C.sub.4 -alkyl or phenyl, R.sub.2 is cyano, COOC.sub.1 -C.sub.4 -alkyl or chlorine and R.sub.3 is hydrogen or chlorine, agents for the fluorescent brightening of polyester fibers and a process for the preparation of the compounds of the formula 1 or mixtures thereof with compounds of the formulae 2 and/or 3 and also novel aldehydes which can be isolated as intermediates.
摘要翻译：式（1）的新型1,4-二苯乙烯基苯化合物及其与下式的化合物（IMAGE）（2）和/或其中R 1为C 1 -C 4烷基的化合物的混合物，烷基或苯基，R2是氰基，COOC1-C4-烷基或氯，R3是氢或氯，聚酯纤维的荧光增白剂和制备式1化合物的方法或其与式2和/或3以及可以作为中间体分离的新型醛。

6. 发明授权

US5001253A Fluorescent brighteners consisting of bis-styrylbenzene compounds, a process for their preparation and their use 失效
标题翻译：由双苯乙烯基苯化合物组成的荧光增白剂，其制备方法及其用途
公开(公告)号：US5001253A
公开(公告)日：1991-03-19
申请号：US520843
申请日：1990-05-10
申请人： Leonardo Guglielmetti
发明人： Leonardo Guglielmetti
IPC分类号： C09B57/00 , C11D3/42 , D06L3/12
CPC分类号： D06L3/125
摘要： A fluorescent brightener is proposed which consists of 51-99% of an unsymmetrically substituted compound of the formula ##STR1## in which R and R.sub.1 are identical or different and, if R and R.sub.1 are identical, R.sub.1 must occupy a position in the phenyl ring to which it is bonded which differs from the position occupied by R in its phenyl ring, and in which R and R.sub.1 independently of one another are CN or a corboxylic acid ester group, and 49-1% of a symmetrically substituted compound of the formula ##STR2## in which R is as defined above and the two R's are bonded to identical positions in their phenyl rings, as are also agents which contain these fluorescent brighteners and the use of these fluorescent brighteners for the fluorescent brightening of, in particular, textile materials, preferably made of polyester. The said fluorescent brighteners are prepared by reacting terephthaladehyde preferably with a correspondingly substituted benzylphosphonate and further reacting the resulting mixture of a correspondingly substituted 4-stilbene aldehyde and a symmetrical p-bis-styrylbenzene with a benzylphosphonate which differs from the benzylphosphonate first used.
摘要翻译：提出了一种荧光增白剂，其由51-99％的不对称取代的式（1）化合物组成，其中R和R 1相同或不同，并且如果R和R 1相同，则R1必须占据与苯基环中R所占的位置不同的苯环，其中R和R 1彼此独立地为CN或羧酸酯基，和49-1％的对称取代的化合物其中R如上定义并且两个R在其苯环中的相同位置键合，其中R是如上定义的，以及含有这些荧光增白剂的试剂和使用这些荧光增白剂进行荧光增白特别是纺织材料，优选由聚合物制成。所述荧光增白剂通过使对苯二甲醛优选与相应取代的苄基膦酸酯反应制备，并进一步使得到的相应取代的4-芪和对称的对双对苯乙烯基苯的混合物与首先使用的苄基膦酸盐不同的苄基膦酸酯反应。

7. 发明授权

US4011261A Process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds and new 1,4-disubstituted bicyclic compounds 失效
标题翻译： 1,4-取代的双环或三聚化合物和新的1,4-取代双环化合物的制备方法
公开(公告)号：US4011261A
公开(公告)日：1977-03-08
申请号：US629180
申请日：1975-11-05
申请人： Leonardo Guglielmetti
发明人： Leonardo Guglielmetti
IPC分类号： C07C255/52 , C07C51/08 , C07C63/38
CPC分类号： C07C255/52 , C07C2103/24
摘要： The present invention provides a new process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds by reacting a 1,2-bis-cyanomethyl-benzene or 2,3-bis-cyanomethyl-naphthalene with glyoxal in the presence of a base and a solvent as well as new 1,4-disubstituted bicyclic compounds.

8. 发明授权

US4785128A Process for the preparation of bis-styrylbenzenes 失效
标题翻译：双苯乙烯基苯的制备方法
公开(公告)号：US4785128A
公开(公告)日：1988-11-15
申请号：US474731
申请日：1983-03-18
申请人： Leonardo Guglielmetti
发明人： Leonardo Guglielmetti
IPC分类号： C09B57/00 , C11D3/42 , D06L3/12 , C07C121/64
CPC分类号： D06L3/125
摘要： A fluorescent brightener is proposed which consists of 51-99% of an unsymmetrically substituted compound of the formula ##STR1## in which R and R.sub.1 are identical or different and, if R and R.sub.1 are identical, R.sub.1 must occupy a position in the phenyl ring to which it is bonded which differs from the position occupied by R in its phenyl ring, and in which R and R.sub.1 independently of one another are CN or a carboxylic acid ester group, and 49-1% of a symmetrically substituted compound of the formula ##STR2## in which R is as defined above and the two R's are bonded to identical positions in their phenyl rings, as are also agents which contain these fluorescent brighteners and the use of these fluorescent brighteners for the fluorescent brightening of, in particular, textile materials, preferably made of polymer. The said fluorescent brighteners are prepared by reacting terephthalaldehyde preferably with a correspondingly substituted benzylphosphonate and further reacting the resulting mixture of a correspondingly substituted 4-stilbene aldehyde and a symmetrical p-bis-styrylbenzene with a benzylphosphonate which differs from the benzylphosphonate first used.
摘要翻译：提出了一种荧光增白剂，其由51-99％的不对称取代的式（1）化合物组成，其中R和R 1相同或不同，并且如果R和R 1相同，则R1必须占据与苯基环中R所占的位置不同的苯环，其中R和R 1彼此独立地为CN或羧酸酯基，和49-1％的对称取代的化合物其中R如上定义并且两个R在其苯环中的相同位置键合，其中R是如上定义的，以及含有这些荧光增白剂的试剂和使用这些荧光增白剂进行荧光增白特别是纺织材料，优选由聚合物制成。所述荧光增白剂通过使对苯二甲醛优选与相应取代的苄基膦酸酯反应制备，并进一步使得到的相应取代的4-芪和对称的对双对苯乙烯基苯的混合物与首先使用的苄基膦酸盐不同的苄基膦酸酯反应。

9. 发明授权

US4719051A Process for the preparation of 4,4'-dinitrostilbene-2,2'-disulfonic acid and its salts 失效
标题翻译：制备4,4'-二硝基二茋-2,2'-二磺酸及其盐的方法
公开(公告)号：US4719051A
公开(公告)日：1988-01-12
申请号：US896561
申请日：1986-08-13
申请人： Leonardo Guglielmetti
发明人： Leonardo Guglielmetti
IPC分类号： C09B57/00 , B01J23/00 , B01J23/34 , B01J27/00 , B01J31/00 , B01J31/04 , B01J31/22 , C07B61/00 , C07C20060101 , C07C15/52 , C07C67/00 , C07C301/00 , C07C303/22 , C07C303/32 , C07C309/40 , C07C309/46 , C09B20060101 , C09B23/10 , C09B23/14 , C09B31/047 , D06L3/12 , C07C143/24
CPC分类号： C07C309/00
摘要： A process for the preparation of 4,4'-dinitrostilbene-2,2'-disulfonic acid and its salts, of the formula ##STR1## in which M is hydrogen or an alkali metal cation, by oxidation of 4-nitrotoluene-2-sulfonic acid in organic solvents, and also the reduction of the resulting acid or salt, without isolation, to give 4,4'-diamino- or (4-amino-4'-nitro)-stilbene-2,2'-disulfonic acid or salts thereof.
摘要翻译：通过氧化4-硝基甲苯-2-磺酸的方法制备式“IMAGE”的4,4'-二硝基二苯乙烯-2,2'-二磺酸及其盐，其中M为氢或碱金属阳离子，磺酸在有机溶剂中的溶解，还可以不分离而还原得到的酸或盐，得到4,4'-二氨基 - 或（4-氨基-4'-硝基） - 芪-2,2'-二磺酸或其盐。

10. 发明授权

US4249022A Process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds and new 1,4-disubstituted bicyclic compounds 失效
标题翻译：用于制备1,4-二取代的双环或三环化合物和新的1,4-二取代的双环化合物的方法
公开(公告)号：US4249022A
公开(公告)日：1981-02-03
申请号：US060089
申请日：1979-07-23
申请人： Leonardo Guglielmetti
发明人： Leonardo Guglielmetti
IPC分类号： C07C253/30 , C07C51/00 , C07C51/10 , C07C63/38 , C07C63/46 , C07C67/00 , C07C253/00 , C07C255/33 , C07C255/35 , C07C255/37 , C07C255/52 , C07C255/62 , C07C301/00 , C07C309/58 , C07C311/39 , C07C313/00 , C07C315/04 , C07C317/44 , C07C317/46
CPC分类号： C07C63/38 , C07C255/52 , C07C2103/24
摘要： The present invention provides a new process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds by reacting a 1,2-bis-cyanomethyl-benzene or 2,3-bis-cyanomethyl-naphthalene with glyoxal in the presence of a base and a solvent as well as new 1,4-disubstituted bicyclic compounds.
摘要翻译：本发明提供了通过在碱的存在下使1,2-双氰基甲基 - 苯或2,3-双 - 氰基甲基 - 萘与乙二醛反应制备1,4-二取代的双环或三环化合物的新方法和溶剂以及新的1,4-二取代的双环化合物。

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