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1. 发明申请

US20060094895A1 Process for conducting equilibriun-limited reactions 有权
标题翻译：进行平衡限制反应的方法
公开(公告)号：US20060094895A1
公开(公告)日：2006-05-04
申请号：US10544817
申请日：2004-02-19
申请人： Leah Patterson , Fungau Ho
发明人： Leah Patterson , Fungau Ho
IPC分类号： C07C69/02
CPC分类号： C07B41/12 , C07C67/08 , C07C67/327 , Y02P20/582 , C07C69/54
摘要： This invention relates to a process for conducting equilibrium-limited reactions, such as esterification and alcoholysis reactions, that uses two reaction zones. The first reaction zone operates under reaction conditions that retain at least a portion of the product in a liquid phase, and at least a portion of the liquid from the first reaction zone is introduced into a second reaction zone which operates under conditions sufficient to crack heavies, for example, Michael-addition heavies, formed in or introduced into said second reaction zone and to vaporize at least a portion of the product upon production thereof. Such a process allows for removal of product from the reaction system while catalyst desirably remains in the reaction system.
摘要翻译：本发明涉及一种使用两个反应区进行平衡有限反应的方法，如酯化和醇解反应。第一反应区在反应条件下操作，该反应条件保留产物在液相中的至少一部分，并且来自第一反应区的至少一部分液体被引入第二反应区，其在足以破裂重质的条件下操作例如，形成或引入所述第二反应区的迈克尔加成物重质物，并在其生产时汽化至少一部分产物。这种方法允许从反应体系中除去产物，同时催化剂理想地保留在反应体系中。

2. 发明授权

US06605738B1 Processes for refining butyl acrylate 失效
标题翻译：精制丙烯酸丁酯的方法
公开(公告)号：US06605738B1
公开(公告)日：2003-08-12
申请号：US08859143
申请日：1997-05-20
申请人： Fungau Ho , Vivek Julka
发明人： Fungau Ho , Vivek Julka
IPC分类号： C07C6748
CPC分类号： C07C67/54 , Y02P20/582 , C07C69/54
摘要： Crude butyl acrylate streams, e.g., from the reaction of butanol and acrylic acid, are refined using a splitter distillation column to yield a butyl acrylate- and heavies-containing bottoms fraction and an overhead fraction containing dibutyl ether, butyl acetate, butanol and butyl acrylate. The bottoms fraction is then subjected to separation, e.g., by distillation, to separate heavies from the bottoms fractions and to recover butyl acrylate. A process for the production of butyl acrylate is also disclosed, which process comprises not only the above-mentioned refining steps but also includes the steps of withdrawing from the splitter distillation column the overhead fraction and distilling the overhead fraction to recover a bottoms stream containing butanol and butyl acrylate, at least a portion of which could be recycled for reaction with acrylic acid to make butyl acrylate, and recovering the separated heavies, at least a portion of which could be recycled to a reaction zone for the production of butyl acrylate. At least 10,000 lb(avoir) quantities of a butyl acrylate product comprising at least 99.8 wt % butyl acrylate and containing not more than about 200 ppm butyl ether and not more than about 200 ppm butyl acetate are producible.
摘要翻译：粗丁基丙烯酸酯流，例如从丁醇和丙烯酸的反应中使用分离器蒸馏塔进行精制，得到含丙烯酸丁酯和重质基的塔底馏分和含有二丁基醚，乙酸丁酯，丁醇和丙烯酸丁酯的塔顶馏分。然后将塔底馏分进行分离，例如通过蒸馏分离塔底馏分中的重质物并回收丙烯酸丁酯。还公开了制备丙烯酸丁酯的方法，该方法不仅包括上述精制步骤，而且还包括从分离器蒸馏塔中抽出塔顶馏分并蒸馏塔顶馏分以回收含有丁醇的塔底物流的步骤和丙烯酸丁酯，其至少一部分可以再循环用于与丙烯酸反应以制备丙烯酸丁酯，并回收分离的重质物，其至少一部分可以再循环到用于生产丙烯酸丁酯的反应区中。可生产至少10,000磅（阿维诺）量的包含至少99.8重量％丙烯酸丁酯和不超过约200ppm丁基醚和不超过约200ppm乙酸丁酯的丙烯酸丁酯产物。

3. 发明授权

US08530700B2 Process for producing acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：US08530700B2
公开(公告)日：2013-09-10
申请号：US13469215
申请日：2012-05-11
申请人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
发明人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
IPC分类号： C07C51/42 , C07C51/16
CPC分类号： C07C51/44 , C07C57/04
摘要： The process for the distillation of a gas mixture comprising (meth)acrylic acid obtained from the gas-phase oxidation of at least one (meth)acrylic acid precursors is improved through the use of coupled distillation columns. In a first column, the gaseous mixture is dehydrated while in a second column, the dehydrated gaseous mixture is distilled into product, overhead and bottoms streams.
摘要翻译：通过使用偶联的蒸馏塔，提高了从至少一种（甲基）丙烯酸前体的气相氧化获得的包含（甲基）丙烯酸的气体混合物的蒸馏方法。在第一列中，气态混合物在第二塔中脱水，脱水的气态混合物蒸馏成产物，塔顶馏出物和塔底物流。

4. 发明授权

US06521783B1 Processes for preparing oxygenates 失效
标题翻译：制备含氧化合物的方法
公开(公告)号：US06521783B1
公开(公告)日：2003-02-18
申请号：US09613275
申请日：2000-07-10
申请人： Richard William Wegman , David McNeill Somerville , Barry Brent Fish , Raymond Edwin Rooks , Chinsoo Stephen Lee , Paul Frank Bryan , William J. Bartley , David Michael Anthony Minahan , Fungau Ho
发明人： Richard William Wegman , David McNeill Somerville , Barry Brent Fish , Raymond Edwin Rooks , Chinsoo Stephen Lee , Paul Frank Bryan , William J. Bartley , David Michael Anthony Minahan , Fungau Ho
IPC分类号： C07C6736
CPC分类号： C07C67/36 , C07C29/1512 , C07C29/153 , C07C51/12 , C07C67/37 , Y02P20/582 , C07C53/08 , C07C69/14 , C07C31/04
摘要： This invention relates in part to a processes for the conversion of a feedstock stream comprising carbon monoxide and hydrogen to a product stream comprising at least one of an ester, acid, acid anhydride and mixtures thereof. This invention also relates in part to processes for converting an alcohol and/or ether feedstock to oxygenated products, e.g., esters, acids, acid anhydrides and mixtures thereof. The processes and catalysts are especially suitable for the production of acetic acid and methyl acetate from a synthesis gas feedstock or from an alcohol and/or ether feedstock.
摘要翻译：本发明部分地涉及将包含一氧化碳和氢气的原料流转化成包含酯，酸，酸酐及其混合物中的至少一种的产物流的方法。本发明还部分涉及将醇和/或醚原料转化为含氧产物，例如酯，酸，酸酐及其混合物的方法。方法和催化剂特别适用于从合成气原料或醇和/或醚原料生产乙酸和乙酸甲酯。

5. 发明申请

US20090253934A1 Process for Producing Acrylic Acid 有权
标题翻译：生产丙烯酸的方法
公开(公告)号：US20090253934A1
公开(公告)日：2009-10-08
申请号：US12439620
申请日：2007-08-31
申请人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
发明人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
IPC分类号： C07C51/42
CPC分类号： C07C51/44 , C07C57/04
摘要： The process for the distillation of a gas mixture comprising (meth)acrylic acid obtained from the gas-phase oxidation of at least one (meth)acrylic acid precursors is improved through the use of coupled distillation columns. In a first column, the gaseous mixture is dehydrated while in a second column, the dehydrated gaseous mixture is distilled into product, overhead and bottoms streams.
摘要翻译：通过使用偶联的蒸馏塔，提高了从至少一种（甲基）丙烯酸前体的气相氧化获得的包含（甲基）丙烯酸的气体混合物的蒸馏方法。在第一列中，气态混合物在第二塔中脱水，脱水的气态混合物蒸馏成产物，塔顶馏出物和塔底物流。

6. 发明授权

US09745244B2 Control of a process for the purification of (meth)acrylic acid using on-line, near IR analysis 有权
公开(公告)号：US09745244B2
公开(公告)日：2017-08-29
申请号：US13121046
申请日：2009-09-18
申请人： Timothy D. Ligon , Olan S. Fruchey , Christopher T. Reeves , Fungau Ho , Roger L. Roundy , William G. Etzkorn , Mahmood N. A. Jawaid , Patrick M. Wiegand
发明人： Timothy D. Ligon , Olan S. Fruchey , Christopher T. Reeves , Fungau Ho , Roger L. Roundy , William G. Etzkorn , Mahmood N. A. Jawaid , Patrick M. Wiegand
IPC分类号： C07C51/44
CPC分类号： C07C51/44 , B01D3/143 , B01D3/36 , B01D3/42 , C07C57/04
摘要： An improved process for the manufacture of technical grade (meth)acrylic acid, e.g., acrylic acid, the process comprising producing a hydrated reaction product from the gas-phase oxidation of at least one (meth)acrylic acid precursor, e.g., propylene, followed by first dehydrating and then concentrating the reaction product, the improvement comprising controlling at least one of the water, acetic acid and (meth)acrylic acid content of the reaction product during the purification of the reaction product using on-line, near IR spectroscopy.

7. 发明申请

US20120226074A1 PROCESS FOR PRODUCING ACRYLIC ACID 有权
标题翻译：生产丙烯酸的方法
公开(公告)号：US20120226074A1
公开(公告)日：2012-09-06
申请号：US13469215
申请日：2012-05-11
申请人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
发明人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
IPC分类号： C07C51/44
CPC分类号： C07C51/44 , C07C57/04
摘要： The process for the distillation of a gas mixture comprising (meth)acrylic acid obtained from the gas-phase oxidation of at least one (meth)acrylic acid precursors is improved through the use of coupled distillation columns. In a first column, the gaseous mixture is dehydrated while in a second column, the dehydrated gaseous mixture is distilled into product, overhead and bottoms streams.
摘要翻译：通过使用偶联的蒸馏塔，提高了从至少一种（甲基）丙烯酸前体的气相氧化获得的包含（甲基）丙烯酸的气体混合物的蒸馏方法。在第一列中，气态混合物在第二塔中脱水，脱水的气态混合物蒸馏成产物，塔顶馏出物和塔底物流。

8. 发明授权

US08242308B2 Process for producing acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：US08242308B2
公开(公告)日：2012-08-14
申请号：US12439620
申请日：2007-08-31
申请人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
发明人： Fungau Ho , Olan S. Fruchey , Roger L. Roundy , William G. Etzkorn , Christopher T. Reeves , Mahmood Jawaid , Edmund J. Yang , Dennis W. Jewell
IPC分类号： C07C51/42
CPC分类号： C07C51/44 , C07C57/04
摘要： The process for the distillation of a gas mixture comprising (meth)acrylic acid obtained from the gas-phase oxidation of at least one (meth)acrylic acid precursors is improved through the use of coupled distillation columns. In a first column, the gaseous mixture is dehydrated while in a second column, the dehydrated gaseous mixture is distilled into product, overhead and bottoms streams.
摘要翻译：通过使用偶联的蒸馏塔，提高了从至少一种（甲基）丙烯酸前体的气相氧化获得的包含（甲基）丙烯酸的气体混合物的蒸馏方法。在第一列中，气态混合物在第二塔中脱水，脱水的气态混合物蒸馏成产物，塔顶馏出物和塔底物流。

9. 发明申请

US20110172462A1 CONTROL OF A PROCESS FOR THE PURIFICATION OF (METH)ACRYLIC ACID USING ON-LINE, NEAR IR ANALYSIS 有权
标题翻译：使用在线，近红外分析纯化（甲基）丙烯酸的方法的控制
公开(公告)号：US20110172462A1
公开(公告)日：2011-07-14
申请号：US13121046
申请日：2009-09-18
申请人： Timothy D. Ligon , Olan S. Fruchey , Christopher Reeves , Fungau Ho , Roger L. Roundy , William G. Etzkorn , Mahmood N. A. Jawaid , Patrick M. Wiegand
发明人： Timothy D. Ligon , Olan S. Fruchey , Christopher Reeves , Fungau Ho , Roger L. Roundy , William G. Etzkorn , Mahmood N. A. Jawaid , Patrick M. Wiegand
IPC分类号： C07C57/07 , C07C57/04 , B01D3/00
CPC分类号： C07C51/44 , B01D3/143 , B01D3/36 , B01D3/42 , C07C57/04
摘要： An improved process for the manufacture of technical grade (meth)acrylic acid, e.g., acrylic acid, the process comprising producing a hydrated reaction product from the gas-phase oxidation of at least one (meth)acrylic acid precursor, e.g., propylene, followed by first dehydrating and then concentrating the reaction product, the improvement comprising controlling at least one of the water, acetic acid and (meth)acrylic acid content of the reaction product during the purification of the reaction product using on-line, near IR spectroscopy.
摘要翻译：用于制造工业级（甲基）丙烯酸（例如丙烯酸）的改进方法，该方法包括从至少一种（甲基）丙烯酸前体（例如丙烯）的气相氧化产生水合反应产物，随后通过首先使反应产物脱水然后浓缩反应产物，其改进包括使用在线近红外光谱法，在反应产物的纯化期间控制反应产物的水，乙酸和（甲基）丙烯酸含量中的至少一种。

10. 发明申请

US20100292501A1 PROCESS FOR RECOVERING SULFONIC ACID CATALYST AND NOBLE PRODUCTS FROM ACRYLATE HEAVY ENDS 审中-公开
标题翻译：从丙烯酸酯重结晶中回收硫酸催化剂和产品的方法
公开(公告)号：US20100292501A1
公开(公告)日：2010-11-18
申请号：US12812641
申请日：2008-12-29
申请人： Mahmood N. A. Jawaid , Olan S. Fruchey , William C. Brooks , Fungau Ho
发明人： Mahmood N. A. Jawaid , Olan S. Fruchey , William C. Brooks , Fungau Ho
IPC分类号： C07C69/00 , C07C315/00 , C07C57/02
CPC分类号： C07C51/44 , C07C67/08 , C07C67/327 , C07C303/44 , C07C57/04 , C07C69/54 , C07C309/04 , C07C309/06 , C07C309/29 , C07C309/30
摘要： Sulfonic acid catalyst, e.g., methanesulfonic acid (MSA), and noble products, e.g., acrylic acid, butanol and butyl acrylatε, are recovered from acrylate reactor blowdown. The blowndown comprises, among oilier things, the Michael ad ducts of the sulfonic acid and acrylate esters. The blowdown is mixed with water, subjected to conditions sufficient to crack or hydrolyze the Michael addνcts into their constituent parts. These cracking conditions are also sufficient to allow the recovery of the sulfonic acid and constituent parts, as well as other light components of the heavy ends, e.g., unreacted acrylic acid and butanol,
摘要翻译：从丙烯酸酯反应器排污回收磺酸催化剂，例如甲磺酸（MSA）和贵重产物，例如丙烯酸，丁醇和丙烯酸丁酯。在较大的物质之间，吹塑包括磺酸和丙烯酸酯的迈克尔导管。排污与水混合，经受足够的条件使迈克尔添加剂裂化或水解成其组成部分。这些裂解条件也足以使磺酸和组分部分以及重馏分的其它轻组分例如未反应的丙烯酸和丁醇回收，

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