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    • 2. 发明授权
    • Narrow MWD, compositionally optimized ethylene interpolymer composition, process for making the same and article made therefrom
    • 窄MWD,组分优化的乙烯互聚物组合物,其制备方法和由其制备的制品
    • US06469103B1
    • 2002-10-22
    • US09156948
    • 1998-09-18
    • Pradeep JainLonnie G. HazlittJacquelyn A. deGrootKenneth W. Anderson
    • Pradeep JainLonnie G. HazlittJacquelyn A. deGrootKenneth W. Anderson
    • C08L2306
    • C08L23/0815C08F210/16C08L2205/02C08L2308/00C08L2314/06C08L2666/04C08F210/14C08F2500/03C08F2500/12C08F2500/26C08F2/001
    • The present invention pertains to an ethylene interpolymer composition characterized as having a narrow molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having at least two polymer components, the first component having an ATREF peak temperature, Tpeak1 and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with increased composition density and Mv1/Mv2 is less than or equal to 1.2. The novel composition is further characterized as having a Mw/Mn of less than or equal to 3.3 as determined by gel permeation chromatography, an I10/I2>6.6, and a composition density less than 0.945 gram/cubic centimeter. The novel composition exhibits high, balanced toughness properties, good processibility and surprisingly improved optical properties and is particularly well-suited for use in applications such as lamination films trash can liners and heavy duty shipping bags, especially as a blown film.
    • 本发明涉及具有窄分子量分布(MWD)和优化组合均匀性的乙烯互聚物组合物,制备这种组合物的方法和由这种组合物制成的制造制品。 该新型组合物的特征在于具有至少两种聚合物组分,第一组分具有ATREF峰温度,Tpeak1和粘均分子量Mv1,第二组分具有ATREF峰温度Tpeak2和粘均分子, Mv2,其中Tpeak2和Tpeak1之间的温差随着组成密度的增加而降低,Mv1 / Mv2小于或等于1.2。 该新型组合物的特征还在于通过凝胶渗透色谱法测定的Mw / Mn小于或等于3.3,I10 / I2> 6.6,组成密度小于0.945克/立方厘米。 该新型组合物显示出高的平衡的韧性,良好的加工性和令人惊奇的改进的光学性能,特别适用于诸如层压膜垃圾桶衬里和重型运输袋,特别是作为吹塑薄膜的应用。