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1. 发明授权

US5516932A Halogenated cinnamic acids and esters thereof, processes for the preparation thereof and halogenated aryldiazonium salts 失效
标题翻译：卤化肉桂酸及其酯，其制备方法和卤代芳基重氮盐
公开(公告)号：US5516932A
公开(公告)日：1996-05-14
申请号：US178089
申请日：1994-01-06
申请人： Matthias Beller , Hartmut Fischer , Laurent Weisse , Klaus Forstinger , Ralf Pfirmann , Heinz Strutz
发明人： Matthias Beller , Hartmut Fischer , Laurent Weisse , Klaus Forstinger , Ralf Pfirmann , Heinz Strutz
IPC分类号： B01J23/44 , C07B61/00 , C07C57/60 , C07C67/333 , C07C67/343 , C07C69/65 , C07C245/20 , C07C69/76
CPC分类号： C07C245/20 , C07C57/60 , C07C67/343 , C07C69/65
摘要： The present invention relates to compounds of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and are hydrogen or an alkyl radical having 1 to 18 carbon atoms and optionally containing oxygen, nitrogen or halogen, the radicals X, Y and Z are identical and are a fluorine, bromine or iodine atom or if two of the radicals X, Y or Z are identical or all of the radicals X, Y, Z are different from each other, X, Y and Z are a fluorine, chlorine, bromine or iodine atom. The invention further relates to a process for the preparation of the compounds, by reacting an aryldiazonium salt of the formula ##STR2## in which the radicals X, Y and Z are identical and are a fluorine, bromine or iodine atom or, if two of the radicals X, Y and Z are identical or all of the radicals X, Y, Z are different from each other, X, Y and Z are a fluorine, chlorine, bromine or iodine atom and A.sup.(-) is an anion of an acid having a pK.sub.a
摘要翻译：本发明涉及式（I）的化合物，其中R 1和R 2相同或不同并且是氢或具有1至18个碳原子并且任选地含有氧，氮或卤素的烷基，基团X， Y和Z相同并且是氟，溴或碘原子，或者如果基团X，Y或Z中的两个相同或基团X，Y，Z的全部彼此不同，则X，Y和Z是氟，氯，溴或碘原子。本发明还涉及通过使基团X，Y和Z相同且为氟，溴或碘原子的式（II）的芳基重氮盐与式如果基团X，Y和Z中的两个相同或全部基团X，Y，Z彼此不同，X，Y和Z是氟，氯，溴或碘原子，并且A（ - ）是具有pKa <7的酸的阴离子与式（III）的化合物反应，其中R 1和R 2相同或不同，并且是氢或具有1至18个碳原子的烷基，并且任选地含有氧，氮或卤素，在含钯催化剂的存在下，如果合适，加入碱，和式（II）的芳基重氮盐。

2. 发明授权

US5364983A Process for the preparation of aromatic polyhydroxy compounds 失效
标题翻译：芳香族多羟基化合物的制备方法
公开(公告)号：US5364983A
公开(公告)日：1994-11-15
申请号：US133660
申请日：1993-10-07
申请人： Laurent Weisse , Heinz Strutz
发明人： Laurent Weisse , Heinz Strutz
IPC分类号： B01J31/02 , C07B61/00 , C07C37/56 , C07C39/08 , C07C37/00
CPC分类号： C07C37/56
摘要： The present invention relates to a process for the preparation of aromatic polyhydroxy compounds, by reacting an aromatic hydroxyaldehyde with hydrogen peroxide, with or without the addition of a base, in the presence of a nitrile R--CN, in which R is an alkyl radical having 1 to 4 carbon atoms or a phenyl radical, which is unsubstituted or substituted by one or more alkyl groups.
摘要翻译：本发明涉及一种制备芳族多羟基化合物的方法，其中芳基羟基醛与过氧化氢在碱存在或不加入下，在腈R-CN存在下反应，其中R是烷基具有1至4个碳原子或苯基，其未被取代或被一个或多个烷基取代。

3. 发明授权

US5329050A Process for the preparation of substituted indanones, and their use 失效
标题翻译：制备取代茚满酮的方法及其用途
公开(公告)号：US5329050A
公开(公告)日：1994-07-12
申请号：US53835
申请日：1993-04-27
申请人： Laurent Weisse , Jurgen Rohrmann , Frank Kuber , Heinz Strutz
发明人： Laurent Weisse , Jurgen Rohrmann , Frank Kuber , Heinz Strutz
IPC分类号： C07F7/08 , C07C45/45 , C07C45/46 , C07C49/665 , C07C49/67 , C07C49/675 , C07C49/753 , C07J11/00
CPC分类号： C07C45/46 , C07C49/665 , C07C49/67 , C07C49/675 , C07J11/00
摘要： 1-Indanones of the formula IV or IVa ##STR1## in which R.sup.1 and R.sup.7 are preferably hydrogen or alkyl, or adjacent radicals R.sup.1 to R.sup.4 form a ring, are obtained in a one-step reaction by reacting a compound I ##STR2## with a compound of the formula II or a compound III ##STR3## in liquid hydrogen fluoride.
摘要翻译：其中R1和R7优选为氢或烷基或相邻基团R1至R4形成环的式IV或IVa的化合物（IVa）（IVa）在一步反应中获得通过使化合物I（I）与式II化合物或化合物III（II）化合物（III）在液体氟化氢中反应。

4. 发明授权

US5395978A Process for selective preparation of hydroxybenzaldehydes 失效
标题翻译：选择性制备羟基苯甲醛的方法
公开(公告)号：US5395978A
公开(公告)日：1995-03-07
申请号：US154255
申请日：1993-11-18
申请人： Laurent Weisse , Robert Neunteufel , Heinz Strutz
发明人： Laurent Weisse , Robert Neunteufel , Heinz Strutz
IPC分类号： C07B61/00 , C07C45/49 , C07C47/565 , C07C47/57
CPC分类号： C07C47/565 , C07C45/49 , C07C47/57
摘要： Process for preparing hydroxybenzaldehydes of the formula (1) ##STR1## in which R.sup.1 -R.sup.4 are hydrogen, fluorine, chlorine, bromine, alkyl, alkoxy, phenyl, naphthyl, phenylalkyl, naphthylalkyl, phenoxy or saturated or unsaturated cyclopentane or cyclohexane radicals, and R.sup.1 -R.sup.4 may with the hydroxybenzene ring carbon atoms on which they are located form 1 or 2 saturated or unsaturated isocyclic or heterocyclic rings, by admixing 1 mol of a phenol of the formula (2) ##STR2## in which R.sup.1 -R.sup.4 have the stated meanings, in a pressure vessel with from 5 to 100 mol of hydrogen fluoride and from 0.5+x to 1.5+x mol of boron trifluoride, where x is the number of oxygen atoms contained in the starting compound (formula (2)), setting the mixture to from -10.sup..degree. to 100.degree. C. and then passing carbon monoxide into this mixture until a pressure of from 10 to 150 bar is reached and allowing the mixture to react at the desired pressure reached.
摘要翻译：制备式（1）的羟基苯甲醛的方法其中R 1 -R 4是氢，氟，氯，溴，烷基，烷氧基，苯基，萘基，苯基烷基，萘基烷基，苯氧基或饱和或不饱和环戊烷或环己烷自由基和R1-R4可以与它们所位于的羟基苯环碳原子一起形成1或2个饱和或不饱和的环或杂环，通过将1mol式（2）的苯酚（2）在在具有5至100摩尔氟化氢和0.5 + x至1.5 + x摩尔三氟化硼的压力容器中，R1-R4具有所述含义，其中x为起始化合物中所含的氧原子数（式（2）），将混合物置于-10℃至100℃，然后将一氧化碳通入该混合物中直至达到10至150巴的压力，并使混合物在达到的所需压力下反应。

5. 发明授权

US5360936A Process for the preparation of substituted indanones 失效
标题翻译：制备取代茚满酮的方法
公开(公告)号：US5360936A
公开(公告)日：1994-11-01
申请号：US120104
申请日：1993-09-10
申请人： Laurent Weisse , Heinz Strutz
发明人： Laurent Weisse , Heinz Strutz
IPC分类号： C07B61/00 , C07C45/46 , C07C49/67 , C07C49/675 , C07C49/683 , C07C49/697 , C07C45/45
CPC分类号： C07C49/697 , C07C45/46 , C07C49/67 , C07C49/675 , C07C49/683
摘要： 1-Indanones of the formula IV or IVa ##STR1## in which R.sup.1 to R.sup.7 are preferably hydrogen or alkyl, or adjacent radicals R.sup.1 to R.sup.4 form a ring, are obtained in a one-step reaction by reacting a compound I ##STR2## with a compound of the formula II ##STR3## or with a compound of the formula (III) ##STR4## in anhydrous hydrogen fluoride and with boron trifluoride.
摘要翻译：其中R 1至R 7优选为氢或烷基或相邻基团R 1至R 4形成环的式IV或IVa的化合物（IVa）（IVa）在一步反应中获得通过使化合物I（I）与式II（II）化合物或式（III）化合物（III）在无水氟化氢和三氟化硼中反应。

6. 发明授权

US5329049A Process for the preparation of substituted indanones 失效
标题翻译：制备取代茚满酮的方法
公开(公告)号：US5329049A
公开(公告)日：1994-07-12
申请号：US53716
申请日：1993-04-27
申请人： Laurent Weisse , Heinz Strutz
发明人： Laurent Weisse , Heinz Strutz
IPC分类号： C07C45/45 , C07C45/46 , C07C49/67
CPC分类号： C07C49/67 , C07C45/46
摘要： 1-Indanones of the formula III or IIIa ##STR1## in which R.sup.1 to R.sup.7 are preferably hydrogen or alkyl, or adjacent radicals R.sup.1 to R.sup.4 form a ring, are obtained in a one-step reaction by reacting a compound I ##STR2## with a compound of the formula II ##STR3## in liquid hydrogen fluoride.
摘要翻译：其中R 1至R 7优选为氢或烷基或相邻基团R 1至R 4形成环的式III或IIIa（IIIa）（IIIa）（IIIa）的1-茚满酮在一步反应中获得通过使化合物I（I）与式II的化合物（II）在液体氟化氢中反应。

7. 发明授权

US08664444B2 Method for producing primary aliphatic amines from aldehydes 有权
标题翻译：从醛生产伯脂肪族胺的方法
公开(公告)号：US08664444B2
公开(公告)日：2014-03-04
申请号：US13817155
申请日：2011-08-18
申请人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
发明人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
IPC分类号： C07C209/26
CPC分类号： C07B43/04 , B01J21/08 , B01J23/40 , B01J23/70 , B01J23/866 , C07C209/26 , C07C211/07
摘要： A continuous process for producing primary aliphatic amines having 9 to 18 carbon atoms by reaction of corresponding aliphatic aldehydes with ammonia and hydrogen in the presence of a hydrogenation catalyst in the liquid phase, characterized in that the reaction is carried out solventlessly at a molar ratio of aliphatic aldehyde:ammonia of at least 1:30, at a temperature of 100 to 200° C. and at a pressure of 6 to 11 MPa.
摘要翻译：在液相中在氢化催化剂存在下，通过相应的脂族醛与氨和氢的反应制备具有9至18个碳原子的伯脂肪族胺的连续方法，其特征在于该反应以脂肪醛：氨至少1:30，温度为100〜200℃，压力为6〜11MPa。

8. 发明申请

US20130131391A1 Method for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the side-streams in trimethylolpropane production 有权
公开(公告)号：US20130131391A1
公开(公告)日：2013-05-23
申请号：US13810723
申请日：2011-07-28
申请人： Thorsten Kreickmann , Guido D. Frey , Norman Nowotny , Heinz Strutz
发明人： Thorsten Kreickmann , Guido D. Frey , Norman Nowotny , Heinz Strutz
IPC分类号： C07C29/74 , C07C41/34
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.

9. 发明申请

US20130116467A1 Process for Aftertreating Polyolesters 有权
标题翻译：后置聚酯的工艺
公开(公告)号：US20130116467A1
公开(公告)日：2013-05-09
申请号：US13805693
申请日：2011-06-29
申请人： Guido D. Frey , Heyko Jürgen Schultz , Heinz Strutz
发明人： Guido D. Frey , Heyko Jürgen Schultz , Heinz Strutz
IPC分类号： C07C67/48
CPC分类号： C07C67/60 , C07C69/28
摘要： A process for aftertreatment of polyol esters prepared by reacting polyols of the general formula H—(—O—[—CR1R2—]m—)o—OH in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, or a hydroxyalkyl radical having 1 to 5 carbon atoms, m is an integer of 1 to 10, o is an integer of 2 to 15, with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the presence of an adsorbent and in the presence of metal compounds selected from the group of titanium compounds, zirconium compounds, tin compounds, zinc compounds, iron compounds and aluminium compounds as a catalyst while removing the water formed and subsequently treating with steam, characterized in that the polyol ester obtained is aftertreated first with an oxidizing or reducing compound and immediately thereafter with steam at a temperature of 150 to 250° C. and over a period of 0.5 to 5 hours.
摘要翻译：一种通过使通式为H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH的多元醇反应制备的多元醇酯的方法，其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基原子或具有1至5个碳原子的羟烷基，m是1至10的整数，o是2至15的整数，在吸附剂存在下具有3至20个碳原子的直链或支链脂肪族单羧酸在选择钛化合物，锆化合物，锡化合物，锌化合物，铁化合物和铝化合物作为催化剂的金属化合物的存在下，同时除去形成的水并随后用蒸汽处理，其特征在于获得的多元醇酯首先用氧化或还原化合物进行后处理，然后立即用蒸汽在150至250℃的温度和0.5至5小时的时间内进行处理。

10. 发明授权

US08357824B2 Process for preparing neopentyl glycol by cracking high boilers occurring in the production process 有权
标题翻译：通过裂解在生产过程中发生的高锅炉来制备新戊二醇的方法
公开(公告)号：US08357824B2
公开(公告)日：2013-01-22
申请号：US12737388
申请日：2009-06-25
申请人： Rolf-Peter Schulz , Horst Scholz , Thomas Hupperich , Peter Heymanns , Tonia Weber , Alexander Kaufmann , Kurt Schalapski , Heinz Strutz
发明人： Rolf-Peter Schulz , Horst Scholz , Thomas Hupperich , Peter Heymanns , Tonia Weber , Alexander Kaufmann , Kurt Schalapski , Heinz Strutz
IPC分类号： C07C31/18
CPC分类号： C07C29/132 , C07C29/149 , C07C31/20
摘要： The present invention relates to a process for obtaining neopentyl glycol by hydrogenating cracking of high-boilers occurring in the production process in the presence of copper-chromite catalysts. The hydrogenating cracking proceeds in the absence of solvent at a temperature of 140 to 220° C. and at pressures of 7 to 28 MPa.
摘要翻译：本发明涉及通过在亚铬酸铜催化剂的存在下，在生产过程中发生的高锅炉的氢化氢化获得新戊二醇的方法。在不存在溶剂的情况下，在140〜220℃的温度和7〜28MPa的压力下进行氢化裂化。

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