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1. 发明申请

WO2008048052A1 OXYGEN BARRIER FILM AND CONTAINER COMPRISING ETHYLENE-ACRYLATE COPOLYMER 审中-公开
标题翻译：包含乙烯 - 丙烯酸酯共聚物的氧气阻隔膜和容器
公开(公告)号：WO2008048052A1
公开(公告)日：2008-04-24
申请号：PCT/KR2007/005101
申请日：2007-10-18
申请人： LG CHEM, LTD. , SHIN, Bae-kun , LEE, Ki-soo , JEON, Byoung-ho , JUNG, Yoo-young
发明人： SHIN, Bae-kun , LEE, Ki-soo , JEON, Byoung-ho , JUNG, Yoo-young
IPC分类号： C08J5/18
CPC分类号： C08J5/18 , C08J2333/08
摘要： The present invention relates to an oxygen barrier film and container comprising ethylene- acrylate copolymer, more precisely an oxygen barrier film and container comprising ethylene- acrylate based copolymer composed of 10 - 50 mol% of ethylene monomer and 50 - 90 mol% of acrylate based monomer and having the weight average molecular weight of at least 30,000 g/m. The present invention provides an oxygen barrier film and container having excellent mechanical properties including flexibility, stretchability, glass transition temperature, anti- absorptiveness and Rockwell hardness and other characteristics such as oxygen barrier property and transparency as well.
摘要翻译：本发明涉及包含乙烯 - 丙烯酸酯共聚物的阻氧膜和容器，更确切地说，是一种隔氧膜和容器，其包含由10-50mol％乙烯单体和50-90mol％丙烯酸酯基组成的乙烯 - 丙烯酸酯基共聚物单体，其重均分子量至少为30,000g / m 2。本发明提供了具有优异的机械性能的氧阻隔膜和容器，包括柔韧性，拉伸性，玻璃化转变温度，抗吸收性和洛氏硬度以及其它特性，例如氧气阻隔性和透明性。

2. 发明申请

WO2007126263A1 ALKENE-ACRYLATE-NORBORNENE TERPOLYMER AND METHOD FOR PREPARING THE SAME 审中-公开
标题翻译：丙烯酸 - 异戊二烯丙烯酸酯及其制备方法
公开(公告)号：WO2007126263A1
公开(公告)日：2007-11-08
申请号：PCT/KR2007/002083
申请日：2007-04-27
申请人： LG CHEM, LTD. , JUNG, Yoo-young , JEON, Byoung-ho , SHIN, Bae-kun , LEE, Ki-soo
发明人： JUNG, Yoo-young , JEON, Byoung-ho , SHIN, Bae-kun , LEE, Ki-soo
IPC分类号： C08F2/38
CPC分类号： C08F210/18 , C08F220/10 , C08F232/00 , C08F2500/25
摘要： The present invention provides method of preparing alkene-acrylate-norbornene terpolymer by polymerization of a monomer mixture consisting of alkene, acrylate and norbornene by a radical initiator under the presence of a Lewis acid. In the method of preparing the alkene-acrylate-norbornene terpolymer of the present invention, the terpolymer may be prepared in the mild condition of low temperature and low pressure by using the Lewis acid so that the process is simple and the property of the terpolymer may be easily controlled. In addition, the terpolymer prepared by the method includes the ethylene and the norbornene simultaneously so that it has high glass transition temperature, and the brittle property in forming of film is improved.
摘要翻译：本发明提供了在路易斯酸存在下，通过自由基引发剂聚合由烯烃，丙烯酸酯和降冰片烯组成的单体混合物来制备烯烃 - 丙烯酸酯 - 降冰片烯三元共聚物的方法。在制备本发明的烯烃 - 丙烯酸酯 - 降冰片烯三元共聚物的方法中，三元共聚物可以通过使用路易斯酸在低温和低压的温和条件下制备，使得该方法简单，并且三元共聚物的性质可以容易控制。此外，通过该方法制备的三元共聚物同时包括乙烯和降冰片烯，使得其具有高玻璃化转变温度，并且改善了膜形成中的脆性。

3. 发明申请

WO2007105898A1 METHOD FOR PREPARATION OF 1-ALKENE-ACRYLATE BASED COPOLYMER 审中-公开
标题翻译：制备1-丙烯酸丙烯酸酯共聚物的方法
公开(公告)号：WO2007105898A1
公开(公告)日：2007-09-20
申请号：PCT/KR2007/001212
申请日：2007-03-13
申请人： LG CHEM, LTD. , JUNG, Yoo-young , JEON, Byoung-ho , SHIN, Bae-kun , LEE, Ki-soo , HAN, Yong-gyu
发明人： JUNG, Yoo-young , JEON, Byoung-ho , SHIN, Bae-kun , LEE, Ki-soo , HAN, Yong-gyu
IPC分类号： C08F220/10 , C08F210/00 , C08F4/06
CPC分类号： C08F222/10 , C08F210/02 , C08F220/12 , C08F220/14 , C08F220/18 , C08F210/14
摘要： The present invention provides a method for preparation of an 1-alkene-acrylate based copolymer comprising a step of a radical polymerization reaction of 1-alkene and acrylate based monomer under presence of a metal oxide or Lewis acid, and a method for preparation of an alkene-acrylate based copolymer comprising reacting alkene with an acrylate based monomer under presence of a metal oxide. In the method of preparation according to the present invention, the process is simple and properties of the copolymer can be easily controlled by preparing the copolymer in a mild condition of 100°C or less and 200bar or less. In addition, the amount of the polar group of the copolymer prepared by the method is so high that the copolymer can be used for transparent optical products. Since the alkene-acrylate based copolymer prepared by the method is a random copolymer of ethylene and a polar monomer and the amount of the polar group of the polar monomer so high that the crystallinity of the ethylene monomer does not remain in the copolymer, the ethylene- acrylate based copolymer is not affected from a tra nsparency of the polymer and thus may be used for optical products.
摘要翻译：本发明提供一种制备1-烯烃 - 丙烯酸酯基共聚物的方法，其包括在金属氧化物或路易斯酸存在下，1-烯烃和丙烯酸酯类单体的自由基聚合反应的步骤，以及制备烯烃 - 丙烯酸酯基共聚物，其包含在金属氧化物的存在下使烯烃与丙烯酸酯基单体反应。在根据本发明的制备方法中，该方法简单，并且通过在100℃以下且200巴以下的温和条件下制备共聚物可以容易地控制共聚物的性质。此外，通过该方法制备的共聚物的极性基团的量非常高，使得该共聚物可用于透明光学产品。由于通过该方法制备的基于烯烃 - 丙烯酸酯的共聚物是乙烯和极性单体的无规共聚物和极性单体的极性基团的量如此高以至于乙烯单体的结晶度不会残留在共聚物中，所以乙烯丙烯酸酯基共聚物不受聚合物的透明度的影响，因此可用于光学产品。

4. 发明申请

WO2008062958A1 SYNTHESIS METHOD OF METAL CYCLOPENTADIENIDE IN BULK 审中-公开
标题翻译：金属环己二烯在块体中的合成方法
公开(公告)号：WO2008062958A1
公开(公告)日：2008-05-29
申请号：PCT/KR2007/005511
申请日：2007-11-02
申请人： LG CHEM, LTD. , HAN, Yong-gyu , LEE, Ki-soo , KWON, Heon-yong , PARK, Jong-sang , MAGGIAROSA, Nicola
发明人： HAN, Yong-gyu , LEE, Ki-soo , KWON, Heon-yong , PARK, Jong-sang , MAGGIAROSA, Nicola
IPC分类号： C07F1/00
CPC分类号： C07F17/00 , C07F1/00 , C07F1/04
摘要： The present invention relates to a synthesis method of metal cyclopentadienide by direct reaction of dicyclopentadiene with a group 1 metal in the presence of an aprotic solvent. Unlike the conventional method depending on retro Diels -Alder reaction of dicyclopentadiene to generate indirectly cyclopentadiene, the method of the present invention favors generation of cy- clopentadiene and metal cyclopentadienide as well by adding dicyclopentadiene directly when the reaction temperature reaches to the boiling point of a reaction solvent.
摘要翻译：本发明涉及金属环戊二烯的合成方法，其通过在非质子溶剂的存在下二环戊二烯与1族金属直接反应。与常规方法不同，根据二环戊二烯的复古Diels-Alder反应产生间接的环戊二烯，本发明的方法也有利于在反应温度达到沸点时直接加入二环戊二烯，环戊二烯和金属环戊二烯反应溶剂。

5. 发明授权

EP1994067B1 METHOD FOR PREPARATION OF 1-ALKENE-ACRYLATE BASED COPOLYMER 有权
标题翻译：用于生产共聚物基于1- ALKEN-ACRYLATE
公开(公告)号：EP1994067B1
公开(公告)日：2013-01-09
申请号：EP07715608.1
申请日：2007-03-13
申请人： LG Chem, Ltd.
发明人： JUNG, Yoo-young , JEON, Byoung-ho , SHIN, Bae-kun , LEE, Ki-soo , HAN, Yong-gyu
IPC分类号： C08F220/10 , C08F210/00 , C08F4/06
CPC分类号： C08F222/10 , C08F210/02 , C08F220/12 , C08F220/14 , C08F220/18 , C08F210/14

6. 发明公开

EP1994067A1 METHOD FOR PREPARATION OF 1-ALKENE-ACRYLATE BASED COPOLYMER 有权
标题翻译：用于生产共聚物基于1- ALKEN-ACRYLATE
公开(公告)号：EP1994067A1
公开(公告)日：2008-11-26
申请号：EP07715608.1
申请日：2007-03-13
申请人： LG Chem, Ltd.
发明人： JUNG, Yoo-young , JEON, Byoung-ho , SHIN, Bae-kun , LEE, Ki-soo , HAN, Yong-gyu
IPC分类号： C08F220/10 , C08F210/00 , C08F4/06
CPC分类号： C08F222/10 , C08F210/02 , C08F220/12 , C08F220/14 , C08F220/18 , C08F210/14
摘要： The present invention provides a method for preparation of an 1-alkene-acrylate based copolymer comprising a step of a radical polymerization reaction of 1-alkene and acrylate based monomer under presence of a metal oxide or Lewis acid, and a method for preparation of an alkene-acrylate based copolymer comprising reacting alkene with an acrylate based monomer under presence of a metal oxide. In the method of preparation according to the present invention, the process is simple and properties of the copolymer can be easily controlled by preparing the copolymer in a mild condition of 100°C or less and 200bar or less. In addition, the amount of the polar group of the copolymer prepared by the method is so high that the copolymer can be used for transparent optical products. Since the alkene-acrylate based copolymer prepared by the method is a random copolymer of ethylene and a polar monomer and the amount of the polar group of the polar monomer so high that the crystallinity of the ethylene monomer does not remain in the copolymer, the ethylene- acrylate based copolymer is not affected from a tra nsparency of the polymer and thus may be used for optical products.

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