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    • 3. 发明申请
    • METHODS FOR PREPARING OF WEATHERABILITY THERMOPLASTIC RESIN
    • 制备耐候性热塑性树脂的方法
    • WO2003004542A1
    • 2003-01-16
    • PCT/KR2001/002274
    • 2001-12-27
    • LG CHEM, LTD.SHIN, Yang-HyunYOO, Keun-HoonAHN, Tae-BinLEE, Chan-Hong
    • SHIN, Yang-HyunYOO, Keun-HoonAHN, Tae-BinLEE, Chan-Hong
    • C08F265/06
    • C08F265/04C08F285/00C08F212/10
    • The present invention relates to a method for preparing a weatherable thermoplastic resin, and more particularly to a method for preparing a thermoplastic acrylate-styrene-acrylonitrile (ASA) resin having superior weatherability and colorability. In detail, the present invention provides a method comprising the steps of: a) preparing a seed by adding a water-soluble initiator to an aromatic vinyl compound, or to a (meth)acrylic acid alkyl ester, and polymerizing; b) preparing an alkyl acrylate rubber polymer by adding an alkyl acrylate monomer, an emulsifier of pH 3∼-9, and an oil-soluble initiator to the seed, and polymerizing; and c) preparing a thermoplastic resin by adding an aromatic vinyl compound, a vinyl cyanide compound, an emulsifier of pH 9∼-13, and an oil-soluble initiator to the alkyl acrylate rubber polymer, and graft polymerizing.
    • 本发明涉及一种制备耐候性热塑性树脂的方法,更具体地说涉及一种具有优异耐候性和着色性的热塑性丙烯酸酯 - 苯乙烯 - 丙烯腈(ASA)树脂的制备方法。 详细地说,本发明提供了一种方法,包括以下步骤:a)通过向芳族乙烯基化合物或(甲基)丙烯酸烷基酯中加入水溶性引发剂,并聚合而制备种子; b)通过向种子中加入丙烯酸烷基酯单体,pH 3〜9的乳化剂和油溶性引发剂来制备丙烯酸烷基酯橡胶聚合物,并进行聚合; 和c)通过向丙烯酸烷基酯橡胶聚合物中加入芳香族乙烯基化合物,乙烯基氰化合物,pH 9〜13的乳化剂和油溶性引发剂,并进行接枝聚合来制备热塑性树脂。
    • 5. 发明申请
    • THERMOPLASTIC RESIN AND PREPARATION THEREOF
    • 热塑性树脂及其制备方法
    • WO2003044069A1
    • 2003-05-30
    • PCT/KR2002/001884
    • 2002-10-09
    • LG CHEM, LTD.CHAI, Joo-ByungLEE, Chan-HongYANG, Byung-TaeKIM, Kun-Su
    • CHAI, Joo-ByungLEE, Chan-HongYANG, Byung-TaeKIM, Kun-Su
    • C08F279/04
    • C08L25/12C08F279/04C08L55/02C08F2/22C08L2666/24C08L2666/04
    • The present invention relates to ABS thermoplastic resin and preparation thereof, and particularly to a process for preparing an ABS graft copolymer comprising the step of introducing to a) 40 to 80 weight parts of rubber latex comprising i) 10 to 50 weight parts of large diameter polybutadiene rubber latex having a particle diameter of 2500 to 3500 Å, gel contents of 60 to 80%, and a swelling index to 12 to 30, and ii) 50 to 90 weight parts of large diameter rubber latex having a particle diameter of 2500 to 3500 Å, gel contents of 81 to 97%, and a swelling index of 18 to 40, b) 20 to 60 weight parts of a monomer mixture of two or more kinds selected from a group consisting of aromatic vinyl compounds and vinyl cyanide compounds to prepare a graft copolymer, wherein 5 to 30 wt% of the monomer mixture is introduced as a batch and simultaneously 70 to 95 wt% of the monomer mixture is started to be continuously introduced in an emulsified state, and a thermoplastic resin composition using the same. According to the process of the present invention, control of polymerization heat is easy even at high solid contents, and polymerization cohesion contents can be minimized and thus ABS thermoplastic resin having superior impact resistance, gloss, and coloring property can be provided.
    • 本发明涉及ABS热塑性树脂及其制备方法,特别涉及制备ABS接枝共聚物的方法,该方法包括以下步骤:向a)40至80重量份的橡胶胶乳中引入,其包含i)10至50重量份的大直径 粒径为2500〜3500埃的聚丁二烯橡胶胶乳,凝胶含量为60〜80%,溶胀指数为12〜30,ii)50〜90重量份的粒径为2500〜 3500 ANGSTROM,凝胶含量为81〜97%,溶胀指数为18〜40,b)20〜60重量份选自芳族乙烯基化合物和乙烯基氰化合物的两种或更多种的单体混合物, 制备接枝共聚物,其中以批料引入5〜30重量%的单体混合物,同时70-90重量%的单体混合物开始以乳化状态连续引入,热塑性树脂 组合使用相同。 根据本发明的方法,即使在固体含量高的情况下聚合热的控制也容易,聚合内聚物含量可以最小化,因此可以提供具有优异抗冲击性,光泽和着色性能的ABS热塑性树脂。