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1. 发明申请

WO2007046611A1 POLYMERIZATION METHODS USING THE CATALYSTS 审中-公开
标题翻译：使用催化剂的聚合方法
公开(公告)号：WO2007046611A1
公开(公告)日：2007-04-26
申请号：PCT/KR2006/004199
申请日：2006-10-17
申请人： LG CHEM, LTD. , CHUNG, Young-Keun , JUNG, Il-Gu , CHUN, Sung-Ho , PARK, Young-Whan , CHOI, Dai-Seung , YOON, Sung-Cheol , LIM, TaeSun , LEE, Jungmin
发明人： CHUNG, Young-Keun , JUNG, Il-Gu , CHUN, Sung-Ho , PARK, Young-Whan , CHOI, Dai-Seung , YOON, Sung-Cheol , LIM, TaeSun , LEE, Jungmin
IPC分类号： C08F132/00 , C08F134/00 , C08F4/00
CPC分类号： C08F4/70 , C08F32/08
摘要： Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer. [M(L1)x(Ll2)y(L3)z]a[Ani]b wherein M is a Group X metal; [M(Li)χ(L'2)y(L3)z] is a cationic complex; Li is an anionic hydrocarbyl-containing ligand; U2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2;2≤x+y+z≤6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.
摘要翻译：提供通过环状烯烃单体的加成聚合制备环状烯烃聚合物的方法，该方法包括使由下述通式1表示的金属催化剂络合物与环状烯烃单体接触。 [式1] [M（L1）x（Ll2）y（L3）z] a [Ani] b其中M是第X族金属; [M（Li）2（L'2）y（L3）z]是阳离子络合物; Li是含阴离子烃基的配体; U2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 = x + y + z = 6; a和b分别是能够与金属M弱配位的阳离子数和阴离子数，并且各自为1-10，其用于满足金属催化剂络合物的净电荷平衡，并且其中对于每个的L1，L2和L3，当多个配体存在于金属催化剂络合物的分子中时，配体可以相同或不同。根据本发明的方法，即使使用含极性官能团的环状烯烃单体，也可以高产率地制造高分子量环状烯烃加成聚合物。使用该方法制备的聚合物显示出良好的热稳定性。

2. 发明申请

WO2007040340A1 CATALYSTS FOR POLYMERIZING CYCLIC OLEFIN 审中-公开
标题翻译：用于聚合环烯烃的催化剂
公开(公告)号：WO2007040340A1
公开(公告)日：2007-04-12
申请号：PCT/KR2006/003987
申请日：2006-10-02
申请人： LG CHEM, LTD. , CHUNG, Young-Keun , JUNG, Il-Gu , CHUN, Sung-Ho , PARK, Young-Whan , YOON, Sung-Cheol , LIM, TaeSun , LEE, Jungmin , CHOI, Dai-Seung
发明人： CHUNG, Young-Keun , JUNG, Il-Gu , CHUN, Sung-Ho , PARK, Young-Whan , YOON, Sung-Cheol , LIM, TaeSun , LEE, Jungmin , CHOI, Dai-Seung
IPC分类号： C07F15/00
CPC分类号： C07F15/006 , C08F4/7034 , C08F4/80
摘要： Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L 1 ) x (L' 2 ) y (L 3 ) z ] a [Ani] b wherein M is a Group X metal; [M(L 1 ) x (L' 2 ) y (L 3 ) z ] is a cationic precatalyst; L 1 is an anionic hydrocarbyl-containing ligand; L' 2 is a neutral ligand; L 3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≤x+y+z≤6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.
摘要翻译：本发明提供一种金属催化剂配合物，其通过以下式1表示的环状烯烃类单体的加成聚合制备环状烯烃系聚合物：[式1] [M（L 1）（L'2 ）（L 3）z _{（L 3）（L 3 >）Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 = X + Y + Z = 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体，因此具有优异的热稳定性和反应性。}

3. 发明申请

WO2007145478A1 METHOD FOR POLYMERIZING CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, OLEFIN POLYMER PRODUCED THEREBY, OPTICAL ANTISOTROPIC FILM COMPRISING THE SAME, AND CATALYST COMPOSITION FOR POLYMERIZING THE CYCLIC OLEFIN 审中-公开
标题翻译：聚合具有极性官能团的环烯烃的方法，生产的烯烃聚合物，包含它们的光学抗反射膜和用于聚合环烯烃的催化剂组合物
公开(公告)号：WO2007145478A1
公开(公告)日：2007-12-21
申请号：PCT/KR2007/002896
申请日：2007-06-15
申请人： LG CHEM, LTD. , CHOI, Dai-Seung , PARK, Young-Whan , CHUN, Sung-Ho , YOON, Sung-Cheol , WON, Young-Chul
发明人： CHOI, Dai-Seung , PARK, Young-Whan , CHUN, Sung-Ho , YOON, Sung-Cheol , WON, Young-Chul
IPC分类号： C08F4/60 , C08F10/00
CPC分类号： C08F32/00
摘要： Disclosed is a method of producing a cyclic olefin polymer having a polar functional group, an olefin polymer produced by using the method, an optical anisotropic film including the olefin polymer, and a catalyst composition for producing the cyclic olefin polymer. In the olefin polymerization method and the catalyst composition for polymerization, since deactivation of the catalyst due to polar functional groups of monomers is capable of being suppressed, it is possible to produce polyolefins having a high molecular weight at high polymerization yield during polyolefin polymerization. Furthermore, the cyclic olefin having the polar functional groups has excellent polymerization reactivity and the activity of the catalyst composition including the same is maintained under a variable polymerization condition. Accordingly, the present invention is very useful for a mass-production process.
摘要翻译：公开了一种制备具有极性官能团的环烯烃聚合物，使用该方法制备的烯烃聚合物，包含烯烃聚合物的光学各向异性膜和用于制备环烯烃聚合物的催化剂组合物的方法。在烯烃聚合方法和聚合用催化剂组合物中，由于能够抑制由于单体的极性官能团导致的催化剂的失活，因此可以在聚烯烃聚合期间以高聚合率产生高分子量聚烯烃。此外，具有极性官能团的环状烯烃具有优异的聚合反应性，并且包含其的催化剂组合物的活性在可变的聚合条件下保持。因此，本发明对于批量生产方法是非常有用的。

4. 发明申请

WO2007145478A9 METHOD FOR POLYMERIZING CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, OLEFIN POLYMER PRODUCED THEREBY, OPTICAL ANTISOTROPIC FILM COMPRISING THE SAME, AND CATALYST COMPOSITION FOR POLYMERIZING THE CYCLIC OLEFIN 审中-公开
公开(公告)号：WO2007145478A9
公开(公告)日：2007-12-21
申请号：PCT/KR2007/002896
申请日：2007-06-15
申请人： LG CHEM, LTD. , CHOI, Dai-Seung , PARK, Young-Whan , CHUN, Sung-Ho , YOON, Sung-Cheol , WON, Young-Chul
发明人： CHOI, Dai-Seung , PARK, Young-Whan , CHUN, Sung-Ho , YOON, Sung-Cheol , WON, Young-Chul
IPC分类号： C08F4/60 , C08F10/00
摘要： Disclosed is a method of producing a cyclic olefin polymer having a polar functional group, an olefin polymer produced by using the method, an optical anisotropic film including the olefin polymer, and a catalyst composition for producing the cyclic olefin polymer. In the olefin polymerization method and the catalyst composition for polymerization, since deactivation of the catalyst due to polar functional groups of monomers is capable of being suppressed, it is possible to produce polyolefins having a high molecular weight at high polymerization yield during polyolefin polymerization. Furthermore, the cyclic olefin having the polar functional groups has excellent polymerization reactivity and the activity of the catalyst composition including the same is maintained under a variable polymerization condition. Accordingly, the present invention is very useful for a mass-production process.

5. 发明申请

WO2006004376A9 METHOD OF PRODUCING CYCLIC OLEFIN POLYMERS HAVING POLAR FUNCTIONAL GROUPS, OLEFIN POLYMER PRODUCED USING THE METHOD AND OPTICAL ANISOTROPIC FILM COMPRISING THE SAME 审中-公开
公开(公告)号：WO2006004376A9
公开(公告)日：2006-01-12
申请号：PCT/KR2005/002149
申请日：2005-07-05
申请人： LG CHEM. LTD. , YOON, Sung-Cheol , WON, Young-Chul , PARK, Young-Whan , CHUN, Sung-Ho , CHOI, Dai-Seung , KIM, Won-Kook , LIM, Tae-Sun , KIM, Heon , LEE, Jung-Min , PAIK, Kyung-Lim
发明人： YOON, Sung-Cheol , WON, Young-Chul , PARK, Young-Whan , CHUN, Sung-Ho , CHOI, Dai-Seung , KIM, Won-Kook , LIM, Tae-Sun , KIM, Heon , LEE, Jung-Min , PAIK, Kyung-Lim
IPC分类号： C08F12/32 , C08F2/38 , C08F32/00 , C08F4/80
摘要： A method of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups, moisture and oxygen is provided. A ccording to the olefin polymerization method, deactivation of a catalyst due to polar functional groups of monomers can be prevented, and thus a polyolefin having a high molecular weight can be prepared with a high yield, and the ratio of catalyst to monomer can be less than 1/5000 due to good activity of the catalyst, and thus removal of catalyst residues is not required.

6. 发明申请

WO2008056938A1 METHOD FOR REMOVING CATALYST RESIDUES FROM POLYMER SOLUTION AND POLYMERS PURIFIED BY THE METHOD 审中-公开
标题翻译：从聚合物溶液中除去催化剂残留物的方法和由该方法纯化的聚合物
公开(公告)号：WO2008056938A1
公开(公告)日：2008-05-15
申请号：PCT/KR2007/005596
申请日：2007-11-07
申请人： LG CHEM, LTD. , YOON, Sung-Cheol , JUNG, Hye-Young , CHUN, Sung-Ho
发明人： YOON, Sung-Cheol , JUNG, Hye-Young , CHUN, Sung-Ho
IPC分类号： C08G18/82
CPC分类号： C08F6/02
摘要： Disclosed is a method for removing a metallic compound catalyst residue from a polymer solution which is prepared in the presence of a catalyst containing metal of Group 10 using a thiourea compound, a polymer from which the metallic compound catalyst residue is removed using the method, and a film produced using the method.
摘要翻译：公开了一种从使用硫脲化合物的含有第10族金属的催化剂存在下制备的聚合物溶液中除去金属化合物催化剂残留物的方法，使用该方法除去金属化合物催化剂残余物的聚合物，以及使用该方法生产的薄膜。

7. 发明申请

WO2004049011A2 NEGATIVE C-PLATE TYPE OPTICAL ANISOTROPIC FILM COMPRISING POLY CYCLOOLEFIN AND METHOD FOR PREPARING THE SAME 审中-公开
标题翻译：包含聚环烯烃的负C片型光学各向异性膜及其制备方法
公开(公告)号：WO2004049011A2
公开(公告)日：2004-06-10
申请号：PCT/KR2003/002493
申请日：2003-11-19
申请人： LG CHEM, LTD. , KIM, Won-Kook , CHUN, Sung-Ho , YOON, Sung-Cheol , LIM, Tae-Sun , KIM, Heon , LEE, Jung-Min , YU, Jeong-Su
发明人： KIM, Won-Kook , CHUN, Sung-Ho , YOON, Sung-Cheol , LIM, Tae-Sun , KIM, Heon , LEE, Jung-Min , YU, Jeong-Su
IPC分类号： G02B
CPC分类号： C08J5/18 , C08J2365/00 , G02B5/3083 , G02F1/133634 , Y10T428/1036 , Y10T428/105
摘要： The present invention provides a negative C-plate type optical anisotropic film having negative birefringence along the thickness direction. In particular, the present invention provides a film comprising cycloolefin addition polymer, which is prepared by addition polymerizing norbornene-based monomers, a method for preparing the same, and a liquid crystal display comprising the same. The film of the present invention can be used for optical compensation films of a variety of LCD (liquid crystal display) modes because the refractive index along the thickness direction can be controlled by the kind and amount of functional groups introduced to the cycloolefin addition polymer.
摘要翻译：本发明提供沿着厚度方向具有负双折射的负C-板型光学各向异性膜。特别是，本发明提供一种包含通过加成聚合降冰片烯类单体制备的环烯烃加成聚合物的薄膜，其制备方法以及包含该薄膜的液晶显示器。本发明的膜可以用于各种LCD（液晶显示器）模式的光学补偿膜，因为沿厚度方向的折射率可以通过引入环烯烃加成聚合物的官能团的种类和数量来控制。

8. 发明申请

WO2004007564A1 METHOD FOR PREPARING NORBORNENE BASED ADDITION POLYMER CONTAINING ESTER OR ACETYL FUNCTIONAL GROUP 审中-公开
标题翻译：用于制备含有异丁烯基官能团的基于诺酮基的添加剂聚合物的方法
公开(公告)号：WO2004007564A1
公开(公告)日：2004-01-22
申请号：PCT/KR2003/001350
申请日：2003-07-07
申请人： LG CHEM, LTD. , CHUN, Sung-Ho , KIM, Won-Kook , YOON, Sung-Cheol , LIM, Tae-Sun , KIM, Heon , KIM, Kyoung-Hoon
发明人： CHUN, Sung-Ho , KIM, Won-Kook , YOON, Sung-Cheol , LIM, Tae-Sun , KIM, Heon , KIM, Kyoung-Hoon
IPC分类号： C08F4/80
CPC分类号： C08G61/08 , C08F4/7027 , C08F32/08 , C08F132/08 , C08F2410/01 , C08G61/06 , G02F1/136227
摘要： The present invention relates to a method for preparing a cyclic olefin polymer by addition polymerization, and more particularly to a method for preparing a norbornene-based addition polymer, which comprises a step of contacting a norbornene-based monomer having an ester or acetyl group with a catalyst system comprising: a Group X transition metal compound; a compound comprising a neutral Group XV electron donor ligand having a cone angle of at least 160°; and a salt capable of offering an anion that can be weakly coordinated to the transition metal, in solvent. The norbornene-based addition polymer having an ester or acetyl group according to the present invention is transparent, has superior adhesivity and a low dielectric constant, and it generates no byproducts when attached to metal. Therefore, it can be used as an optical film, a retardation film, a protection film for a polarizer, POFs (plastic optical fiber), PCBs (printed circuit board), or insulators of electronic devices.
摘要翻译：本发明涉及通过加成聚合制备环烯烃聚合物的方法，更具体地说涉及一种制备降冰片烯系加成聚合物的方法，该方法包括使具有酯或乙酰基的降冰片烯系单体与一种催化剂体系，包括：第X族过渡金属化合物; 包含具有至少160°的锥角的中性第XV族电子供体配体的化合物; 以及能够在溶剂中提供能够与过渡金属配位的阴离子的盐。具有根据本发明的酯或乙酰基的降冰片烯系加成聚合物是透明的，具有优异的粘附性和低介电常数，并且当附着于金属时不产生副产物。因此，它可以用作光学膜，延迟膜，偏振器用保护膜，POF（塑料光纤），PCB（印刷电路板）或电子器件的绝缘体。

9. 发明申请

WO2004050726A1 METHOD FOR POLYMERIZING CYCLOOLEFIN POLYMER CONTAINING POLAR FUNCTIONAL GROUPS AND ELECTRONIC DEVICES EMPLOYING THE POLYMERIZED CYCLOOLEFINS 审中-公开
标题翻译：聚合含有极性官能团的环烯烃聚合物的方法和使用聚合的环烯烃的电子器件
公开(公告)号：WO2004050726A1
公开(公告)日：2004-06-17
申请号：PCT/KR2003/002634
申请日：2003-12-03
申请人： LG CHEM, LTD. , YOON, Sung-Cheol , CHUN, Sung-Ho , KIM, Won-Kook , LIM, Tae-Sun , KIM, Heon , LEE, Jung-Min
发明人： YOON, Sung-Cheol , CHUN, Sung-Ho , KIM, Won-Kook , LIM, Tae-Sun , KIM, Heon , LEE, Jung-Min
IPC分类号： C08F32/00
CPC分类号： C08F4/70 , C08F32/00 , C08F232/08 , C08G61/06 , C08G61/08 , C09K19/38 , Y10T428/1036
摘要： Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200 °C, the total amount of the organic solvent being 50-800 % by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.
摘要翻译：公开了一种制备含有极性官能团的环烯烃聚合物的方法，包括：制备催化剂混合物，其包括i）预催化剂，其含有具有与金属键合的含氧离子的配体的第10族过渡金属; ii）第一助催化剂，其是含有第15族元素的有机化合物; 和iii）能够提供阴离子并与预催化剂的金属弱配位的第二助催化剂; 将含有极性官能团的降冰片烯系化合物的单体溶液在有机溶剂和催化剂混合物的存在下，在80〜200℃的温度下进行加成聚合反应，基于单体溶液中所含的单体的总重量为50-800重量％，聚合物的产物收率基于单体的总重量为50重量％以上。

10. 发明申请

WO2008069569A1 APPARATUS AND METHOD FOR RECOVERING POLYMER 审中-公开
标题翻译：用于回收聚合物的装置和方法
公开(公告)号：WO2008069569A1
公开(公告)日：2008-06-12
申请号：PCT/KR2007/006279
申请日：2007-12-05
申请人： LG CHEM, LTD. , HONG, Sung-Don , LEE, In-Su , LEE, Jong-Ku , CHUN, Sung-Ho , PARK, Seung-Young , YOON, Sung-Cheol
发明人： HONG, Sung-Don , LEE, In-Su , LEE, Jong-Ku , CHUN, Sung-Ho , PARK, Seung-Young , YOON, Sung-Cheol
IPC分类号： C08J11/00
CPC分类号： C08J3/12 , C08J11/04 , C08J2333/14 , C08J2365/00 , Y02P20/143 , Y02W30/70
摘要： The present invention provides an apparatus for recovering a polymer from polymer solution, and a method of recovering a polymer using the apparatus. The apparatus includes a polymer solution-storage tank for storing a polymer solution; a polymer solution feeding pump for pumping the polymer solution from the polymer solution storage tank; an antisolvent storage tank for storing an antisolvent; an antisolvent feeding pump for pumping the antisolvent from the antisolvent storage tank; a reaction chamber to which the polymer solution pumped by the polymer solution feeding pump and the antisolvent pumped by the antisolvent feeding pump are supplied; a high-speed mixer that is rotated in the reaction chamber at a speed range of 1000 to 30000 rpm, mixes the polymer solution with the antisolvent under a shearing force cor¬ responding to a tip speed of 5 to 30 m/sec, and precipitates a polymer; and a precipitate storage tank for storing the precipitation mixture of the polymer and the solvent/antisolvent.
摘要翻译：本发明提供了一种从聚合物溶液中回收聚合物的装置，以及使用该装置回收聚合物的方法。该装置包括用于储存聚合物溶液的聚合物溶液 - 储存罐; 用于从聚合物溶液储罐泵送聚合物溶液的聚合物溶液进料泵; 用于储存抗溶剂的抗溶剂储罐; 用于从抗溶剂储罐泵出抗溶剂的反溶剂供给泵; 提供由聚合物溶液供给泵泵送的聚合物溶液和由反溶剂供给泵泵送的反溶剂的反应室; 在1000〜30000rpm的转速范围内在反应室内旋转的高速混合机，在与5〜30m /秒的叶尖速度相对应的剪切力下将聚合物溶液与抗溶剂混合，聚合物以及用于储存聚合物和溶剂/反溶剂的沉淀混合物的沉淀储存罐。

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