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1. 发明申请

WO2005040316A3 ADDITIVE MIXTURE AS COMPONENT OF MINERAL OIL COMPOSITIONS 审中-公开
标题翻译：作为矿物油组合物组分的添加剂混合物
公开(公告)号：WO2005040316A3
公开(公告)日：2005-06-16
申请号：PCT/DE2004002316
申请日：2004-10-15
申请人： LEUNA POLYMER GMBH , TAEUBERT HILTRUD , HAUBOLD WOLFGANG , MEYER TORSTEN , BRAUER ERHARD , KLIMEK IRENE , WENSE DIETRICH VON DER
发明人： TAEUBERT HILTRUD , HAUBOLD WOLFGANG , MEYER TORSTEN , BRAUER ERHARD , KLIMEK IRENE , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22
CPC分类号： C10L10/08 , C10L1/143 , C10L1/146 , C10L1/1817 , C10L1/1905 , C10L1/1915 , C10L1/1973 , C10L1/1983 , C10L1/2364
摘要： The invention relates to an additive mixture as component of mineral oil compositions, comprising as main component and trace proportions of the additive mixture the following additive components a) ethylene vinyl ester copolymers with molecular mass weight averages of 3,000 to 50,000 and an ethylene proportion of 50 to 90 mass %, b) mixed esters of glycerine, in which 50 to 80 mol % of the hydroxy groups are esterified with unsaturated C12-C40 monocarboxylic acids and 20 to 50 mol % of the hydroxy groups are esterified with partially imidated and/or partially esterified maleic acid anhydride copolymers and/or c) partially and/or completely imidated copolymers of maleic acid anhydride and alpha -methylstyrol with molecular mass number averages of 1,500 to 15,000 and at least one terminal group based on dimeric alpha -methylstyrol, and/or d) wax compositions based on natural starting materials of type d1) wax-like oligomeric esters based on glyceryl monostearate and dimeric acids and/or d2) waxy esters with the consistency of vaseline, based on at least two different straight chain and/or branched C14-C36 alcohols and dimeric acids, whereby the content of the additive mixture in the mineral oil is 0.005 to 1 mass % and the mass proportions of the additive components a/b, or a/c, or a/d is 10: 90 to 90: 10 respectively. The mineral oil compositions are suitable as low temperature flow transportable media and as mineral oil fuels with high ease of flow.
摘要翻译：的添加剂混合物作为为主要成分以及少量的添加剂混合物，矿物油的组合物的组分，所述添加剂组分a）含有具有乙烯乙烯酯共聚物Molmassengewichts-向前3000-50000和乙烯含量为50〜90重量％，和b）甘油的Mischester，其中其50〜80摩尔％的不饱和C12-C40单羧酸的羟基和羟基基团的20至50莫洛％的酯化的部分酰亚胺化和/或部分酯化的马来酸酐共聚物，和/或c）部分和/或完全酰亚胺化马来酸酐的共聚物和α-甲基苯乙烯与数均摩尔量为1500至15000和至少一个末端基团基于二聚α-甲基苯乙烯，和/或d）的蜡组合物单硬脂酸酯的基础的类型d1的天然起始原料）蜡样低聚酯基于甘油和二聚酸和 /或d2）蜡酯与凡士林基于至少两个不同的直链和/或支链的C14-C36醇与二聚酸，分别其中添加剂混合物的在矿物油中的〜1质量％的含量为0.005和添加剂组分A / B或A / C或A / d，的质量比Licher一致性 10：90至90：10。矿物油的组合物适合作为在低温下运输的可流动介质，并且作为矿物油燃料具有高润滑性和流动性。

2. 发明专利

CA2542812C ADDITIVE MIXTURE AS COMPONENT OF MINERAL OIL COMPOSITIONS 未知
公开(公告)号：CA2542812C
公开(公告)日：2010-02-16
申请号：CA2542812
申请日：2004-10-15
申请人： LEUNA POLYMER GMBH
发明人： TAEUBERT HILTRUD , HAUBOLD WOLFGANG , MEYER TORSTEN , BRAUER ERHARD , KLIMEK IRENE , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22
摘要： The invention relates to an additive mixture as component of mineral oil compositions, comprising as main component and trace proportions of the additive mixture the following additive components a) ethylene vinyl ester copolymers with molecular mass weight averages of 3,000 to 50,000 and an ethylene proportion of 50 to 90 mass %, b) mixed esters of glycerine, in which 50 to 80 mol % of the hydroxy groups are esterified with unsaturated C12-C40 monocarboxylic acids and 20 to 50 mol % of the hydroxy groups are esterified with partially imidated and/or partially esterified maleic acid anhydride copolymers and/or c) partially and/or completely imidated copolymers of maleic acid anhydride and .alpha.-methylstyrol with molecular mass number averages of 1,500 to 15,000 and at least one terminal group based on dimeric .alpha.-methylstyrol, and/or d) wax compositions based on natural starting materials of type d1) wax-like oligomeric esters based on glyceryl monostearate and dimeric acids and/or d2) waxy esters with the consistency of vaseline, based on at least two different straight chain and/or branched C14-C36 alcohols and dimeric acids, whereby the content of the additive mixture in the mineral oil is 0.005 to 1 mass % and the mass proportions of the additive components a/b, or a/c, or a/d is 10: 90 to 90: 10 respectively. The mineral oil compositions are suitable as low temperature flow transportable media and as mineral oil fuels with high ease of flow.

3. 发明专利

DE10349859B4 未知
公开(公告)号：DE10349859B4
公开(公告)日：2006-12-07
申请号：DE10349859
申请日：2003-10-22
申请人： LEUNA POLYMER GMBH
发明人： TAEUBERT HILTRUD , HAUBOLD WOLFGANG , KLIMEK IRENE , MEYER TORSTEN , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22

4. 发明专利

DE10349865A1 Additive mixture for mineral oil products comprises a modified ethylene/vinyl ester copolymer together with an alkoxylated monocarboxylic acid and/or an imidated anhydride copolymer 未知
公开(公告)号：DE10349865A1
公开(公告)日：2005-06-16
申请号：DE10349865
申请日：2003-10-22
申请人： LEUNA POLYMER GMBH
发明人： TAEUBERT HILTRUD , HAUBOLD WOLFGANG , MEYER TORSTEN , BRAUER ERHARD , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22
摘要： Additive mixture for mineral oil products comprises an ethylene/vinyl ester copolymer (I) modified with polar groups and having a molecular weight of 3000-50000 and an ethylene content of 50-90 wt.% together with a C2-C6 alkoxylated C12-C40 monocarboxylic acid (II) and/or an imidated copolymer (III) of an unsaturated C4-C20 dicarboxylic anhydride and a vinylaromatic and/or C2-C36 alpha -olefin. Additive mixture for use in mineral oil products in an amount of 0.005-1 wt.% comprises an ethylene/vinyl ester copolymer (I) modified with polar groups and having a molecular weight of 3000-50000 and an ethylene content of 50-90 wt.% together with a C2-C6 alkoxylated C12-C40 monocarboxylic acid (II) and/or an imidated copolymer (III) of an unsaturated C4-C20 dicarboxylic anhydride and a vinylaromatic and/or C2-C36 alpha -olefin. The weight ratio of (I) to (II), (III) or (II)+(III) is 10:90 to 90:10. Independent claims are also included for: (1) mineral oil product as above in which the mineral oil is crude oil or a middle distillate fuel oil with a sulfur content below 0.05 wt.%; (2) producing a mineral oil product by preparing a solution containing 1-60 wt.% of an additive mixture as above in a middle distillate oil at 20-90[deg]C and homogenizing the solution with a mineral oil, where other additives are added to the solution or mineral oil in an amount of 0-200% by weight of the additive mixture.

5. 发明专利

CA2542812A1 ADDITIVE MIXTURE AS COMPONENT OF MINERAL OIL COMPOSITIONS 未知
公开(公告)号：CA2542812A1
公开(公告)日：2005-05-06
申请号：CA2542812
申请日：2004-10-15
申请人： LEUNA POLYMER GMBH
发明人： WENSE DIETRICH VON DER , KLIMEK IRENE , BRAUER ERHARD , MEYER TORSTEN , HAUBOLD WOLFGANG , TAEUBERT HILTRUD
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22
摘要： An additive mixture as component of compositions of mineral oil as the main component and trace portions of an additive mixture contains the additive components a) ethylene-vinylester copolymers with molecular mass weight averages from 3000 to 50000 and an ethylene proportion of 50 to 90 mass %, and b) mixed esters of glycerine in which 50 to 80 mol % of the hydroxy groups are esterified with unsaturated C 12 -C 40 monocarboxylic acids and 20 to 50 mol % of the hydroxy groups are esterified with partially imidated and/or partially esterified maleic anhydride copolymers, and/or c) partially and/or completely imidated copolymers consisting of maleic anhydride and alpha-methylstyrene with molecular mass number averages from 1500 to 15000 and at least one terminal group based on dimeric alpha-methyl styrene, and/or d) wax compositions based on natural starting materials of type d1) wax-like oligomeric esters based on glyceryl monostearate and dimeric acid and/or d2) wax esters with vaseline-like consistency, based on at least two different straight-chain and/or branched C 14 -C 36 -alcohols and dimeric acid whereby the content of the additive mixture in the mineral oil is 0.005 to 1 mass % and the mass proportion of the additive components a/b or a/c or a/d is in the range from 10:90 to 90:10, respectively. The mineral oil compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.

6. 发明专利

EA011632B1 КОМПОЗИЦИЯ МИНЕРАЛЬНОГО НЕФТЕТОПЛИВА, СОДЕРЖАЩАЯ СМЕСЬ ПРИСАДОК, СПОСОБ ЕЕ ПОЛУЧЕНИЯ И ЕЕ ПРИМЕНЕНИЕ 未知
公开(公告)号：EA011632B1
公开(公告)日：2009-04-28
申请号：EA200600809
申请日：2004-10-15
申请人： LEUNA POLYMER GMBH
发明人： TAUBERT HILTRUD , HAUBOLD WOLFGANG , MEYER TORSTEN , BRAUER ERHARD , KLIMEK IRENE , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22
摘要： Присадочнаясмеськаккомпоненткомпозицийминеральногонефтетопливав качествеосновногокомпонентаи следовыхколичествсмесиприсадоксодержитследующиекомпонентыприсадок:a) сополимерыэтиленаи сложноговиниловогоэфирасосреднемассовоймолекулярноймассойот 3000 до 50000 ипропорциейэтилена 50-90 мас.%; иb) смешанныесложныеэфирыглицерина, где 50-80 мол.% гидроксильныхгрупппроэтерифицированоненасыщеннымиС-Смонокарбоновымикислотамии 20-50 мол.% гидроксильныхгрупппроэтерифицированочастичноимидированнымии/иличастичноэтерифицированнымисополимерамималеиновогоангидрида; и/илиc) частичнои/илиполностьюимидированныесополимерымалеиновогоангидридаи α-метилстироласосреднечисловоймолекулярноймассойот 1500 до 15000 ипоменьшеймереоднойконцевойгруппойнаосноведимерногоα-метилстирола; и/илиd) восковыекомпозициинаосновеприродныхнатуральныхматериаловтипаd1) воскоподобныхолигомерныхсложныхэфировнаосновеглицерилмоностеаратаи димернойкислотыи/илиd2) восковыхсложныхэфировс вазелиноподобнойконсистенциейнаосновепоменьшеймередвухразличныхлинейныхи/илиразветвленныхС-С-спиртови димерныхкислот,посредствомчегосодержаниесмесиприсадокв минеральномнефтетопливесоставляет 0,005-1 мас.% имассоваяпропорциякомпонентовприсадока/b, а/сили a/d находитсяв интервалеот 10:90 до 90:10, соответственно.Композиции, содержащиеминеральноенефтетопливоявляютсяподходящимив качестветекучейсреды, транспортируемойпринизкихтемпературах, ив качествеминеральногонефтетопливас высокойсмазывающейспособностьюи текучестью.

7. 发明专利

DE10349865B4 未知
公开(公告)号：DE10349865B4
公开(公告)日：2006-11-30
申请号：DE10349865
申请日：2003-10-22
申请人： LEUNA POLYMER GMBH
发明人： TAEUBERT HILTRUD , HAUBOLD WOLFGANG , MEYER TORSTEN , BRAUER ERHARD , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22

8. 发明专利

DE10349859A1 Additive mixture for mineral oil products comprises an ethylene/vinyl ester copolymer together with a mixed glyceride, an imidated anhydride copolymer and/or a waxy ester 未知
公开(公告)号：DE10349859A1
公开(公告)日：2005-06-16
申请号：DE10349859
申请日：2003-10-22
申请人： LEUNA POLYMER GMBH
发明人： TAEUBERT HILTRUD , HAUBOLD WOLFGANG , KLIMEK IRENE , MEYER TORSTEN , WENSE DIETRICH VON DER
IPC分类号： C10L1/14 , C10L1/18 , C10L1/22
摘要： Additive mixture for mineral oil products comprises an ethylene/vinyl ester copolymer (I) together with a mixed ester (II) of glycerol with an unsaturated monocarboxylic acid and a partially imidated and/or esterified maleic anhydride copolymer and/or an imidated copolymer (III) of maleic anhydride and alpha -methylstyrene and/or a waxy oligomeric ester (IVa) based on glycerol monostearate and dimer acids and/or a wax ester (IVb) based on two different alcohols and dimer acids : Additive mixture for use in mineral oil products in an amount of 0.005-1 wt.% comprises an ethylene/vinyl ester copolymer (I) having a molecular weight of 3000-50000 and an ethylene content of 50-90 wt.% together with a mixed ester (II) of glycerol in which 50-80% of the hydroxy groups are esterified with an unsaturated C12-C40 monocarboxylic acid and 20-50% of the hydroxy groups are esterified with a partially imidated and/or esterified maleic anhydride copolymer and/or an imidated copolymer (III) of maleic anhydride and alpha -methylstyrene with a molecular weight of 1500-15000 and at least one terminal group based on dimeric alpha -methylstyrene and/or a waxy oligomeric ester (IVa) based on glycerol monostearate and dimer acids and comprising at least 90 wt.% of structures of formula (A) and/or a wax ester (IVb) with a petrolatum-like consistency based on two different C14-C36 alcohols and dimer acids and comprising at least 80 wt.% of structures of formula (B). The weight ratio of (I) to (II), (III), (IVa) or (IVb) is 10:90 to 90:10. Y(OCHR 1>CH 2OCO(CH 2) aCHR 2>CHR 3>(CH 2) dCO) nOX (A) H 3C(CH 2) iOCO(CH 2) kCHR 4>CHR 5>(CH 2) pCOO(CH 2) sCH 3 (B) R 1>CH 2OCO(CH 2) zCH 3; R 2>(CH 2) bCH 3; R 3>(CH 2) cCH 3; n : 1-20; a+b+c+d : 30; z : 12-20; Y : H or CO(CH 2) dCHR 2>CHR 3>(CH 2) aCOOH; X : H or CH 2CH(OH)CH 2OCO(CH 2) zCH 3; R 4>(CH 2) mCH 3; R 5>(CH 2) nCH 3; i, s : 13-35; k+m+n+p : 30-34. Independent claims are also included for: (1) mineral oil product as above in which the mineral oil is crude oil or a middle distillate fuel oil with a sulfur content below 0.05 wt.%; (2) producing a mineral oil product by preparing a solution containing 1-60 wt.% of an additive mixture as above in a middle distillate oil at 20-90[deg]C and homogenizing the solution with a mineral oil, where other additives are added to the solution or mineral oil in an amount of 0-200% by weight of the additive mixture.

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