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1. 发明专利

GB1012644A Urethane polymers and methods of applying compositions containing the polymers 未知
公开(公告)号：GB1012644A
公开(公告)日：1965-12-08
申请号：GB2949062
申请日：1962-07-31
申请人： LANKRO CHEM LTD , EDWIN FENTON CHANDLEY , ERNEST LEVY , ARNOLD JOHN LOWE
发明人： CHANDLEY EDWIN FENTON , LEVY ERNEST , LOWE ARNOLD JOHN
IPC分类号： C08G18/28 , C14C9/00 , C14C11/00
摘要： A polyurethane is prepared by the reaction of a stoichiometric excess of a di- or higher functional organic isocyanate with a mixture of one or more monohydric alcohols and one or more polyoxyalkylene polyols which contain more than two hydroxyl groups. The polyol is preferably a triol and preferably prepared from propylene oxide and a trihydric alcohol, e.g. glycerol, trimethanol propane, hexane triol. The monohydric alcohols may be represented by the formula R(OCnH2n)yOH where R is a hydrocarbon radical, n may be 2, 3 or 4, and y may be 0 or an integer between 1 and 50. Compounds mentioned are the condensation products of ethylene oxide with cetyl-oleyl alcohol and ethylene oxide with nonyl phenol. The isocyanate may be aromatic or aliphatic. The mixture of alcohols may also contain a polyoxyalkylene diol which may be the reaction product of propylene oxide with water or a dihydric alcohol, e.g. propylene glycol and preferably has a M.W. of 1000-3000. The polyurethane may be dissolved in a solvent, e.g. an ester, ketone or hydrocarbon fraction and used for coating leather. Up to 100% of raw oil, e.g. cold test neatsfoot oil or sperm oil may be incorporated in the solution. In Example (1) a mixture of glycerol based polyoxypropylene triol, cetyl-oleyl alcohol and polyoxypropylene diol were reacted with tolylene diisocyanate and the polymer dissolved in Shellsol "A." In other examples, the monohydric alcohols used were (1B) condensate of nonyl phenol and ethylene oxide, (1C) anhydrous butanol, (2) cetyl-oleyl alcohol, (11) a butoxy polyoxypropylene monohydric alcohol.ALSO:A solution of a polyurethane in an aromatic hydrocarbon fraction, ketone or carboxylic ester is applied to leather, said polyurethane having been prepared by reacting a mixture of one or more monohydric alcohols and one or more polyoxyalkylene polyols which contain more than two hydroxyl groups with a stoichiometric excess of a di or higher functional organic isocyanate. The urethane solution may be applied by a paint roller or by spraying or padding. Leathers mentioned are: shoe upper leather, full chrome goatskin, pigskin, sheepskin, upholstery and case leathers. In a typical example (II) a mixture of a polyoxypropylene triol and a butoxy polyoxypropylene monohydric alcohol were reacted with toluene diisocyanate in shellsol "A" and the polymer solution appled by spraying to the grain side of chrome upper shoe leather, the solvent allowed to evaporate and the treated leather finished by coating with a pigment and an acrylic resin emulsion followed by a spray coat of nitrocellulose emulsion and finally by a tinted spray coat of high flash nitrocellulose lacquer.

2. 发明专利

GB989396A Improvements in the manufacture of polyether glycols 未知
公开(公告)号：GB989396A
公开(公告)日：1965-04-14
申请号：GB369263
申请日：1963-01-29
申请人： LANKRO CHEM LTD , ARNOLD JOHN LOWE , EDWIN FENTON CHANDLEY , LELIO MOLINARIO
发明人： LOWE ARNOLD JOHN , CHANDLEY EDWIN FENTON , MOLINARIO LELIO
IPC分类号： C08G65/28 , C08L27/06 , C11D1/72
摘要： Diol compositions are prepared by reacting in the presence of an alkaline catalyst under substantially anhydrous conditions a dihydroxy compound HOCH2RCH2OH wherein R is absent or is a saturated aliphatic diradical, having a molecular weight of less than 140 with between 1 and 4 molar proportions inclusive of 1,2-propylene oxide. Specified dihydroxy compounds are ethylene glycol, diethylene glycol, triethylene glycol, 1,3-propanediol and 1,12-dodecanediol. The catalyst may be sodium or potassium metal or an hydroxide or alkoxide of these metals or potassium carbonate. A temperature of 90-150 DEG C., preferably 100-120 DEG C. may be used. The products may be used in detergent compositions or may be converted into esters, e.g. with butyric, pelargonic or adipic acid, which esters may be used for plasticizing PVC or in hydraulic fluids and synthetic lubricants.ALSO:An aqueous dish-washing composition comprises sodium dodecylbenzenesulphonate, ammonium nonyl polyethen sulphate and a product obtained by reacting diethylene glycol with 4 molar proportions of 1,2-propylene oxide under alkaline, substantially anhydrous conditions.

3. 发明授权

US3520835A Polyurethane foams and their method of preparation using stannous salts of aliphatic acids and beta-hydroxy amines as catalysts 失效
标题翻译：聚氨酯泡沫塑料及其制备方法，使用作为催化剂的脂肪酸和β-羟基苯胺的稳定性
公开(公告)号：US3520835A
公开(公告)日：1970-07-21
申请号：US43667465
申请日：1965-03-02
申请人： LANKRO CHEM LTD
发明人： CHANDLEY EDWIN FENTON , LEIGH HUGH WALLIS , LOWE ARNOLD JOHN
IPC分类号： C08G18/16 , C08G18/18 , C08G18/28 , C08G18/48 , C08G22/46 , C08G22/34
CPC分类号： C08G18/48 , C08G18/165 , C08G18/1825 , C08G18/2875

4. 发明专利

DE1203242B 未知
公开(公告)号：DE1203242B
公开(公告)日：1965-10-21
申请号：DEL0046886
申请日：1964-01-27
申请人： LANKRO CHEM LTD
发明人： LOWE ARNOLD JOHN , CHANDLEY EDWIN FENTON , MOLINARIO LELIO
IPC分类号： C08G65/28 , C08L27/06 , C11D1/72

5. 发明专利

GB1091483A Improvements in or relating to the production of hydroxy alkoxy alkyl phosphites 未知
公开(公告)号：GB1091483A
公开(公告)日：1967-11-15
申请号：GB3855563
申请日：1963-10-01
申请人： LANKRO CHEM LTD
发明人： LOWE ARNOLD JOHN , CHANDLEY EDWIN FENTON , DYKE RAYMOND
IPC分类号： C07F9/141 , C08G18/38 , C08G18/50
摘要： Polyether based polyurethane foams are prepared by reacting a polyfunctional organic isocyanate or isothiocyanate of the formula R1(NCX)n+1 where R1 is an organic radical, X is O or S and n is a positive integer with a polyhydroxy polyoxyalkylene glycol ether containing two or more hydroxy groups and water in the presence of a catalyst, e.g. a tin compound or a tertiary amine, together with a foam stabilizer and a phosphite of the general formula where (a+b) has an average value of between one and four and b may be zero, and R is non-existent or is a saturated aliphatic diradical having a molecular weight of less than 140 (see Division C2). All or part of the water may be replaced by a blowing agent. Preferred polyhydroxy polyoxyalkylene glycol ethers are polyoxyalkylene diols of molecular weight 1000 to 3000 and polyoxyalkylene triols of molecular weight 1000 to 6000, also tri- or higher hydroxy polyoxyalkylene glycol ethers with molecular weights between 500 and 1200 and mixtures thereof. The organic polyisocyanate or isothiocyanate may be aliphatic, aromatic or cyclo-aliphatic and may contain substituent groups. The preferred compounds are those containing 2 to 6 isocyanate or isothiocyanate groups such as polymethylene diisocyanate and diisothiocyanate; hexamethylene diisocyanate; xylene diisocyanate; 1-methyl-2:4-phenylene diisocyanate; 1-methyl 2:6-phenylene diisocyanate; 4,41-diisocyanato-diphenyl methane, tolylene diisocyanate containing about 80% of tolylene-2:4-diisocyanate and 20% tolyene-2:6-diisocyanate and isocyantaes of the formula where q is from 0 to 3. Auxiliary blowing agents specified are halogenated hydrocarbons such as trichlorofluoromethane, dichlorodifluoromethane or methylene dichloride. The preferred phosphites for use in production of (1) flexible polyether-based polyurethane foams are those with molecular weight in the range 600 to 1200; and for (2) flame-retarded rigid polyurethane foams, those with molecular weights in the range 400 to 650. The degree of flame-retardancy of the foams may be enhanced by incorporation of conventional flame-retardants such as tris-(2:3-dibromopropyl) phosphatesALSO:The invention comprises phosphites of the general formula in which (a + b) has an average value of between one and four, and b may be zero, and R is non-existent or is a saturated aliphatic diradical having a molecular weight of less than 140. They may be obtained by transesterifying a tri-aryl phosphite, a tri-alkyl phosphite, a di-alkyl aryl phosphite or a di-aryl alkyl phosphite, with a reaction product of 1 : 2-propylene oxide and a saturated aliphatic dihydroxy organic compound, the said reaction product having an average molecular weight of between 100 and 500 and a structure Preferred products for reaction with the phosphite esters are those obtained from the reaction of one two moles of 1 : 2-propylene oxide with ethylene glycol or diethylene glycol. Specified transesterification catalysts are CH3OK, NaOH, K2CO3 and C6H5ONa. Also, diphenyl hydrogen phosphite, H3PO3 and diethyl hydrogen phosphite may be used as catalysts. The products may be used in the production of polyurethane foams (see Division C3). Examples are given for the production of the phosphites.

6. 发明专利

DE1233133B 未知
公开(公告)号：DE1233133B
公开(公告)日：1967-01-26
申请号：DEL0048350
申请日：1964-07-22
申请人： LANKRO CHEM LTD , THEODORE GOLDSCHMIDT A G
发明人： CHANDLEY EDWIN FENTON , LOWE ARNOLD JOHN , ROSSMY GERD RICHARD
IPC分类号： C08G18/16 , C08J9/00 , C08G22/46

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