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1. 发明授权

US4094650A Integrated catalytic gasification process 失效
标题翻译：综合催化气化过程
公开(公告)号：US4094650A
公开(公告)日：1978-06-13
申请号：US740987
申请日：1976-11-11
申请人： Kwang K. Koh , Nicholas C. Nahas , Robert E. Pennington , Lonnie W. Vernon
发明人： Kwang K. Koh , Nicholas C. Nahas , Robert E. Pennington , Lonnie W. Vernon
IPC分类号： C07C1/00 , C10J3/54 , C10G13/30
CPC分类号： C10J3/54 , C07C1/00 , C10J3/482 , C10J2300/093 , C10J2300/0973 , C10J2300/0986 , C10J2300/1853
摘要： Methane and carbon dioxide are produced by reacting steam with a carbonaceous feed material at a reaction temperature between about 1000.degree. F. and about 1500.degree. F. and a reaction pressure in excess of about 100 psia in the presence of a carbon-alkali metal catalyst and equilibrium quantities of added hydrogen and carbon monoxide. The raw product gas withdrawn from the reaction zone is treated for removal of the carbon dioxide, product methane is recovered from the treated gas, and the remaining hydrogen and carbon monoxide can be recycled to supply the added hydrogen and carbon monoxide needed in the reaction zone.
摘要翻译：在碳 - 金属催化剂存在下，反应温度为约1000°F至约1500°F，反应压力超过约100psia，通过使蒸汽与碳质进料反应生成甲烷和二氧化碳。和加入的氢气和一氧化碳的平衡量。处理从反应区抽出的原始产物气体以除去二氧化碳，从处理过的气体中回收产物甲烷，剩余的氢气和一氧化碳可循环使用，以提供反应区所需的加氢和一氧化碳。

2. 发明授权

US3958957A Methane production 失效
标题翻译：甲烷生产
公开(公告)号：US3958957A
公开(公告)日：1976-05-25
申请号：US485041
申请日：1974-07-01
申请人： Kwang K. Koh , Robert E. Pennington , Lonnie W. Vernon , Nicholas C. Nahas
发明人： Kwang K. Koh , Robert E. Pennington , Lonnie W. Vernon , Nicholas C. Nahas
IPC分类号： C07C1/04 , C10J3/54 , C07C9/04
CPC分类号： C10J3/54 , C07C1/0445 , C10J3/482 , C07C2521/18 , C07C2523/04 , C07C2527/055 , C07C2527/232 , C10J2300/0903 , C10J2300/093 , C10J2300/0943 , C10J2300/0973 , C10J2300/0983 , C10J2300/0986 , C10J2300/0993 , C10J2300/1637 , C10J2300/1807 , C10J2300/1853 , C10J2300/1884 , C10J2300/1892 , Y02P20/584
摘要： Methane is produced by contacting a mixture of carbon monoxide or carbon dioxide and hydrogen with a carbon-alkali metal catalyst at a temperature in the range between about 800.degree.F. and about 1500.degree.F. and at a pressure between about atmospheric and about 2000 psig. The catalyst employed may be prepared by heating an intimate mixture of coal, coal char, coke or other carbonaceous solids and an alkali metal salt, hydroxide or similar constituent. Such a catalyst promotes the methanation of carbon monoxide and carbon dioxide and the formation of higher hydrocarbons by the Fischer-Tropsch reaction and at the same time is resistant to high temperature sintering and poisoning by sulfur compounds present in the feed gas. The catalyst can be regenerated if necessary by air oxidation.
摘要翻译：甲烷是通过将一氧化碳或二氧化碳和氢气的混合物与碳 - 碱金属催化剂在约800°F至约1500°F之间的温度下接触并在约大气压至约2000℃的压力下生产的 psig 所使用的催化剂可以通过加热煤，煤焦炭，焦炭或其它含碳固体和碱金属盐，氢氧化物或类似成分的紧密混合物来制备。这样的催化剂促进一氧化碳和二氧化碳的甲烷化和通过费 - 托反应形成高级烃，同时耐高温烧结和在进料气体中存在的硫化合物中毒。如果需要，可以通过空气氧化来再生催化剂。

3. 发明授权

US5248407A Storage stable polymer modified asphalt paving binder 失效
标题翻译：储存稳定聚合物改性沥青铺路粘合剂
公开(公告)号：US5248407A
公开(公告)日：1993-09-28
申请号：US914073
申请日：1992-07-16
申请人： Jacques G. Bardet , Martin L. Gorbaty , Nicholas C. Nahas
发明人： Jacques G. Bardet , Martin L. Gorbaty , Nicholas C. Nahas
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： Paving binders, especially hot mix paving mixtures, having excellent storage stability, reduced binder runoff, and high temperature viscosity are formed by adding a copolymer of ethylene with an alkyl acrylate or vinyl acetate and a neutralized sulfonated polymer to the asphalt. Preferably, the alkyl acrylate is methyl acrylate and the neutralized sulfonated polymer is a terpolymer of ethylene, propylene, and a diene monomer.

4. 发明授权

US4284416A Integrated coal drying and steam gasification process 失效
标题翻译：综合煤干燥和蒸汽气化过程
公开(公告)号：US4284416A
公开(公告)日：1981-08-18
申请号：US103648
申请日：1979-12-14
申请人： Nicholas C. Nahas
发明人： Nicholas C. Nahas
IPC分类号： C10L9/08 , C10J3/00 , C10J3/54 , C10L5/00
CPC分类号： C10J3/00 , C10J3/54 , C10J2300/0903 , C10J2300/093 , C10J2300/0986 , C10J2300/1807 , Y10S48/07
摘要： Carbonaceous solids slurried in an aqueous solution, which preferably contains catalyst constituents having gasification activity, are dried by contacting the slurry with superheated steam in a fluid bed slurry dryer and the resultant dried solids are subsequently gasified with steam generated in the dryer.
摘要翻译：在优选含有具有气化活性的催化剂组分的水溶液中浆化的碳质固体通过在流化床淤浆干燥器中使浆料与过热蒸汽接触而干燥，然后将所得干燥固体随后在干燥器中产生的蒸汽气化。

5. 发明授权

US4211538A Process for the production of an intermediate Btu gas 失效
标题翻译：生产中间体Btu气体的方法
公开(公告)号：US4211538A
公开(公告)日：1980-07-08
申请号：US920045
申请日：1978-06-28
申请人： James M. Eakman , Nicholas C. Nahas , Charles A. Euker, Jr.
发明人： James M. Eakman , Nicholas C. Nahas , Charles A. Euker, Jr.
IPC分类号： C10J3/54
CPC分类号： C10J3/54 , C10J3/482 , C10J3/723 , C10J3/74 , C10J3/84 , C10K1/003 , C10K1/004 , C10K1/005 , C10K1/101 , C10K1/122 , C10K1/143 , C10K1/146 , C10K1/165 , C10J2300/093 , C10J2300/094 , C10J2300/0943 , C10J2300/0946 , C10J2300/0976 , C10J2300/0996 , C10J2300/1846
摘要： An intermediate Btu gas is produced by reacting steam with a carbonaceous feed material in the presence of a carbon-alkali metal catalyst and substantially equilibrium quantities of added hydrogen and carbon monoxide at a temperature between about 1000.degree. F. and about 1500.degree. F. and a pressure in excess of about 100 psia to produce an effluent or raw product gas consisting essentially of equilibrium quantities, at reaction temperature and pressure, of methane, steam, carbon dioxide, carbon monoxide and hydrogen; recovering at least a portion of the effluent or raw product gas from the gasifier as an intermediate Btu product gas; contacting a carbon-containing material with steam in a steam reforming zone under conditions such that at least a portion of the carbon-containing material reacts with the steam to produce carbon monoxide and hydrogen; and passing the effluent from the reforming zone into the gasifier, thereby supplying the added hydrogen and carbon monoxide required in the gasifier.
摘要翻译：在碳 - 金属催化剂存在下，蒸汽与含碳原料反应生成中间体Btu气体，在大约1000°F至大约1500°F的温度下，基本上平衡量的加氢和一氧化碳，压力超过约100psia，以产生在反应温度和压力下，甲烷，蒸汽，二氧化碳，一氧化碳和氢气基本上由平衡量组成的流出物或原始产品气体; 从作为中间体Btu产物气体的气化器回收至少一部分流出物或原始产物气体; 在含水材料的至少一部分与蒸汽反应产生一氧化碳和氢气的条件下，使含碳材料与蒸汽重整区中的蒸汽接触; 并将来自重整区的流出物送入气化器，由此供应气化器中所需的加氢和一氧化碳。

6. 发明授权

US5006608A Catalytic process for oxidative, shear accelerated polymer degradation 失效
标题翻译：氧化，剪切加速聚合物降解的催化过程
公开(公告)号：US5006608A
公开(公告)日：1991-04-09
申请号：US241620
申请日：1988-09-08
申请人： John B. Gardiner , Anthony A. Loffredo , ricardo Bloch , Nicholas C. Nahas , Keith U. Ingold , Theodore V. Kowalchyn
发明人： John B. Gardiner , Anthony A. Loffredo , ricardo Bloch , Nicholas C. Nahas , Keith U. Ingold , Theodore V. Kowalchyn
IPC分类号： C08F8/50 , C10M143/18
CPC分类号： C10M143/18 , B29B7/00 , B29C47/92 , C08F8/50 , B29C2947/92704 , B29C47/0004 , B29C47/38 , B29C47/805 , C08F2800/20 , C08F2810/10 , C10M2205/00 , C10M2205/026 , C10M2205/06 , C10M2205/10
摘要： The molecular weight and the thickening efficiency of primarily oil soluble hydrocarbon polymers, such as hydrogenated random copolymers and block copolymers of styrene-isoprene or styrene-butadiene, polyisobutylene, poly-n-butene, low unsaturation butyl rubbers, low unsaturation EPDM rubbers, preferably ethylene-propylene copolymers, of the type which are to be used as viscosity index improver additives or as precursors for dispersants and multi-functional viscosity improver additives for lubricating oils, are reduced by heating and masticating the polymers in the presence of oxygen or air and in the presence of a transition metal catalyst, preferably in the further presence of a peroxide accelerator.

7. 发明授权

US4260421A Cement production from coal conversion residues 失效
标题翻译：煤转化残渣生产水泥
公开(公告)号：US4260421A
公开(公告)日：1981-04-07
申请号：US41271
申请日：1979-05-18
申请人： Leo D. Brown , James M. Eakman , Nicholas C. Nahas , LeRoy R. Clavenna
发明人： Leo D. Brown , James M. Eakman , Nicholas C. Nahas , LeRoy R. Clavenna
IPC分类号： C04B7/44 , C04B7/24
CPC分类号： C04B7/24 , Y02P40/145
摘要： Cement is produced by feeding residue solids containing carbonaceous material and ash constituents obtained from converting a carbonaceous feed material into liquids and/or gases into a cement-making zone and burning the carbon in the residue solids to supply at least a portion of the energy required to convert the solids into cement.
摘要翻译：通过将含有碳质材料的残余固体和由碳质进料转化成液体和/或气体的灰分组分进料到水泥制造区域中并将残留物中的碳燃烧以提供所需能量的至少一部分来生产水泥将固体转化成水泥。

8. 发明授权

US4057512A Alkali metal catalyst recovery system 失效
标题翻译：碱金属催化剂回收系统
公开(公告)号：US4057512A
公开(公告)日：1977-11-08
申请号：US618292
申请日：1975-09-29
申请人： Charles J. Vadovic , Robert D. Wesselhoft , Nicholas C. Nahas
发明人： Charles J. Vadovic , Robert D. Wesselhoft , Nicholas C. Nahas
IPC分类号： B01J23/92 , C01B33/12 , C01D5/02 , C01F7/34 , C01F7/36 , C05C5/00 , C10J3/54 , C01D13/00
CPC分类号： C10J3/54 , B01J23/92 , C01B33/12 , C01D5/02 , C01F7/34 , C01F7/36 , C05C5/00 , C10J3/482 , C10J2300/093 , C10J2300/0973 , C10J2300/0986 , C10J2300/1853 , Y02P20/52 , Y02P20/584
摘要： In a coal gasification operation or similar process carried out in the presence of an alkali metal-containing catalyst wherein spent solids containing ash and alkali metal catalyst residues are produced, alkali metal constituents are recovered from the spent solids by first removing magnetic constituents from the solids, contacting the solid particles from which magnetic constituents have been separated with an acid solution to extract alkali metal constituents from the solids and produce a spent acid solution enriched in alkali metal salts, raising the pH of the enriched solution sufficiently to precipitate aluminum from the solution as aluminum hydroxide, heating the remaining solution to precipitate silicon compounds, and recovering an enriched alkali metal solution from which aluminum and silicon compounds have been removed. This process permits the effective recovery of alkali metal catalyst constituents, eliminates iron compounds and other inactive constituents which may otherwise tend to build up in the catalyst system, and makes possible the recovery of aluminum as a valuable by-product of the process.
摘要翻译：在生产含有灰分和碱金属催化剂残余物的废固体的碱金属的催化剂存在下进行的煤气化操作或类似方法中，通过首先从固体中除去磁性成分从废固体中回收碱金属成分使已经与磁性组分分离的固体颗粒与酸溶液接触以从固体中提取碱金属成分，并产生富含碱金属盐的废酸溶液，从而使富含溶液的pH充分地从溶液中沉淀出铝作为氢氧化铝，加热剩余的溶液以沉淀硅化合物，并回收已除去铝和硅化合物的富集的碱金属溶液。该方法允许碱金属催化剂组分的有效回收，消除铁化合物和其它可能倾向于在催化剂体系中累积的其它无活性组分，并且使作为该方法有价值的副产物的铝的回收成为可能。

9. 发明授权

US06776607B2 Process for minimizing afterburn in a FCC regenerator 失效
标题翻译：在FCC再生器中最小化后燃烧的方法
公开(公告)号：US06776607B2
公开(公告)日：2004-08-17
申请号：US09892382
申请日：2001-06-26
申请人： Nicholas C. Nahas , Richard E. Walter , Dean C. Draemel , Bruce J. Artuso
发明人： Nicholas C. Nahas , Richard E. Walter , Dean C. Draemel , Bruce J. Artuso
IPC分类号： F23J1500
CPC分类号： C10G11/182 , B01J38/14 , B01J38/16 , B01J38/20
摘要： The invention relates to a process and apparatus for controlling afterburning in the regenerator of a FCC unit. The process and apparatus inject steam into the dilute phase within a regenerator to promote combustion of carbon monoxide before it enters the regenerator cyclones, plenum, or flue gas transfer lines.
摘要翻译：本发明涉及用于控制FCC单元的再生器中的后燃烧的方法和装置。该方法和装置将蒸汽注入到再生器内的稀相中，以在一氧化碳进入再生器旋风分离器，增压室或烟道气输送管线之前促进一氧化碳的燃烧。

10. 发明授权

US5549744A Pavement Binder 失效
标题翻译：路面粘合剂
公开(公告)号：US5549744A
公开(公告)日：1996-08-27
申请号：US525898
申请日：1995-09-08
申请人： Olga Puzic , Larry J. Evers , Kenneth E. Williamson , Martin L. Gorbaty , Nicholas C. Nahas
发明人： Olga Puzic , Larry J. Evers , Kenneth E. Williamson , Martin L. Gorbaty , Nicholas C. Nahas
IPC分类号： C08L95/00 , E01C7/26 , C09D195/00
CPC分类号： E01C7/267 , C08L95/00 , E01C7/265
摘要： The present invention provides for a method of making storage stable road paving binders by blending a minor amount of a polymer having at least one diene monomer with a major amount of asphalt containing at least 0.3% by weight of total nitrogen at an elevated temperature such that the components are sufficiently fluid to blend; treating the asphalt-polymer blend using not more than 250 meq of a sulfonating agent per 100 g of asphalt-polymer blend to introduce the corresponding acid functionality into the blend; maintaining the sulfonated asphalt-polymer blend at a sufficiently elevated temperature and stripping the sulfonated blend with sufficient chemically unreactive gas to remove a major fraction of the acid functionality introduced by sulfonation. The invention also provides for the compositions made by the process. These are useful as binders in road paving applications.
摘要翻译：本发明提供一种通过将少量具有至少一种二烯单体的聚合物与主要含量为总氮至少0.3重量％的沥青在升高的温度下混合来制备储存稳定的铺路粘合剂的方法，使得组分充分流体混合; 使用每100g沥青聚合物共混物不超过250meq的磺化剂处理沥青聚合物共混物以将相应的酸官能团引入到共混物中; 在充分升高的温度下保持磺化沥青聚合物共混物，并用足够的化学反应性气体汽提磺化的共混物，以除去通过磺化引入的大部分酸性官能团。本发明还提供了通过该方法制备的组合物。这些作为道路铺路应用中的粘合剂是有用的。

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