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    • 2. 发明授权
    • Combination soap bar composition containing monoglyceride sulfonate and its manufacturing method
    • 含有单酸甘油酯磺酸盐的组合皂条组合物及其制备方法
    • US06599869B2
    • 2003-07-29
    • US10114412
    • 2002-04-02
    • Je-Kwon GooYoung-Ho ChoiMoon-Jeong RangTae-Seong KimTae-Kyung HuhJung-Jin ChoiHo-Jeong Ahn
    • Je-Kwon GooYoung-Ho ChoiMoon-Jeong RangTae-Seong KimTae-Kyung HuhJung-Jin ChoiHo-Jeong Ahn
    • A61K750
    • C11D17/006C11D1/123C11D1/126C11D1/28C11D1/29C11D10/042
    • The present invention relates to a combination soap bar composition containing monoglyceride sulfonates and a method for manufacturing the same. A combination bar composition containing monoglyceride sulfonates of the present invention comprises fatty acid based toilet bars and monoglyceride sulfonates of the following General Formula 1: where R is an alkyl having 7 to 21 carbon atoms, and M is sodium, potassium, triethanolamine, or ammonium. A combination bar composition containing monoglyceride sulfonates of the present invention has good general physical properties such as soap softness, etc. and very good moisturization properties and feel during usage even after repeated uses. Furthermore, a combination liquid phase solution is manufactured by adding chloro sulfonates to a liquid phase soap which is produced from fatty acids, with the above combined liquid phase solution agitated, dried, and passed through soap manufacturing equipment in order to manufacture a combination soap bar containing monoglyceride sulfonates of the present invention. A method for manufacturing a combination bar containing monoglyceride sulfonates of the present invention involves a simple and economical manufacturing process. The quality of soap manufactured by the above method is equal to or higher than soap manufactured in a milling or slurry process after synthesizing monoglyceride.
    • 本发明涉及含有单酸甘油酯磺酸盐的组合皂条组合物及其制造方法。 含有本发明单酸甘油酯磺酸盐的组合棒组合物包含以下通式1的脂肪酸基马桶和单酸甘油酯磺酸盐:其中R是具有7-21个碳原子的烷基,M是钠,钾,三乙醇胺或铵 含有本发明的单酸甘油酯磺酸盐的组合棒组合物具有良好的一般物理性质如皂柔软度等,甚至在重复使用后使用时具有非常好的保湿性和使用感。另外,通过加入氯 将磺酸盐转化成由脂肪酸生产的液相皂,将上述组合的液相溶液搅拌,干燥并通过肥皂制造设备,以制备含有本发明的单酸甘油酯磺酸盐的组合皂条。 本发明的含有单酸甘油酯磺酸盐的组合棒的制造方法涉及简单且经济的制造方法。 通过上述方法制造的肥皂的质量等于或高于在合成甘油单酯之后在研磨或淤浆方法中制造的皂。
    • 3. 发明授权
    • Preparation of cationic surfactants containing ester group in molecules
    • 在分子中制备含酯基的阳离子表面活性剂
    • US06414170B1
    • 2002-07-02
    • US09744349
    • 2001-01-23
    • Dong-Il KimJeong-Wook HaTae-Seong KimMoon-Jeong Rang
    • Dong-Il KimJeong-Wook HaTae-Seong KimMoon-Jeong Rang
    • C07C23100
    • C07C213/04C07C219/06
    • The present invention relates to a method for preparing a cationic surfactant in which physical chemical characteristics such as softness, antistatic properties, etc. as well as biodegradability are quite excellent due to having an ester group and a hydrophilic hydroxyl group in its molecules. A cationic surfactant of the present invention is prepared by reacting tertiary amine drivatives, fatty acid, and epihalohydrin, and prepared simply by reacting esterification and quaternary reactions in one step with a high yield. The above cationic surfactant is a high grade alkyl quaternary ammonium compound as represented in General Formula (1), wherein R1 is a C1-C4 alkyl group; R2 is a C7-C21 linear or branched alkyl or alkenyl group; A is OCOR3, NHCOR3 or OH; R3 is a C7-C21 linear or branched alkyl or alkenyl group; X is a halogen atom; and n is an integral number from 2 to 6.
    • 本发明涉及一种阳离子表面活性剂的制备方法,其中由于在其分子中具有酯基和亲水性羟基,其物理化学特性如柔软性,抗静电性等以及生物降解性都非常优异。 本发明的阳离子表面活性剂是通过叔胺驱动剂,脂肪酸和表卤代醇反应制备的,并且通过酯化反应和季铵反应在一步中以高产率进行反应来制备。 上述阳离子表面活性剂是通式(1)表示的高级烷基季铵化合物,其中R1是C1-C4烷基; R2是C7-C21直链或支链烷基或烯基; A为OCOR 3,NHCOR 3或OH; R3是C7-C21直链或支链烷基或链烯基; X是卤原子; n为2〜6的整数。