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    • 4. 发明授权
    • Process for the manufacturing of zeaxanthin from lutein
    • 用于从叶黄素制造玉米黄质的方法
    • US5780693A
    • 1998-07-14
    • US935262
    • 1997-09-22
    • Kurt BernhardAlfred Giger
    • Kurt BernhardAlfred Giger
    • B01J31/02C07B35/08C07B61/00C07C403/24C09B61/00C07C35/21
    • C07C403/24C09B61/00
    • A process for the conversion of lutein or of its esters into zeaxanthin by base-catalyzed isomerization is disclosed. The process is carried out by heating an optionally pre-treated lutein-containing material in a mixture of an aqueous solution of an alkali hydroxide and either dimethyl sulphoxide or an organic solvent based on saturated aliphatic and/or aromatic hydrocarbons at temperatures in the range from about 50.degree. C. to about 120.degree. C. The process is carried out in the presence of a phase transfer catalyst when an organic solvent based on hydrocarbons is used. Being carotenoids, lutein and zeaxanthin are used correspondingly, especially as pigments for egg yolk, the integuments and the subcutaneous fat of poultry, the flesh and the integuments of fish and crustaceans, as well as foodstuffs. Zeaxanthin is preferably used in many applications, since in comparable dosages it produces a more intensive golden yellow pigmentation than lutein.
    • 公开了通过碱催化的异构化将叶黄素或其酯转化为玉米黄质的方法。 该方法通过在基于饱和脂族和/或芳族烃的饱和脂族和/或芳族烃的碱金属氢氧化物和二甲基亚砜或有机溶剂的水溶液的混合物中加热任选地预处理的含叶黄素的材料来进行, 约50℃至约120℃。当使用基于烃的有机溶剂时,该方法在相转移催化剂存在下进行。 相应地使用类胡萝卜素,叶黄素和玉米黄质,特别是作为蛋黄的颜料,家禽的皮肤和皮下脂肪,鱼和甲壳类动物的肉皮和皮肤以及食品。 玉米黄质优选用于许多应用中,因为在可比较的剂量中,其产生比叶黄素更强烈的金黄色素。
    • 5. 发明申请
    • Colorant for food and pharmaceuticals
    • 食品和药品着色剂
    • US20050008746A1
    • 2005-01-13
    • US10489378
    • 2002-09-04
    • Markus BeckKurt BernhardAlfred GigerBruno Leuenberger
    • Markus BeckKurt BernhardAlfred GigerBruno Leuenberger
    • A23L1/00A23L1/275A61K9/08A61K9/10A61K9/107A61K9/20A61K9/48A61K36/00A61K36/185A61K36/286A61K36/31A61K36/48A61K36/889A61K36/899A61K47/04A61K47/06A61K47/10A61K47/14A61K47/20A61K47/22A61K47/26A61K47/36A61K47/42C07C403/24C09B61/00C09B67/02C09B67/46A23L1/27
    • C09B61/00A23L5/44A61K36/185A61K36/286A61K36/31A61K36/48A61K36/889A61K36/899A61K2300/00
    • The use of α-zeacarotene, β-zeacarotene or a mixture of both as a coloring agent for food or pharmaceutical compositions. For addition to the food or pharmaceutical composition or otherwise incorporation therein during its preparation the zeacarotene (mixture) is generally first formulated to a solid or liquid colorant composition in the form of a stable water-soluble or -dispersible powder, an aqueous colloidal solution or oil-in-water dispersion of such powder, an oil-in-water dispersion of the zeacarotene (mixture), or an oil-soluble dispersion of the zeacarotene (mixture) in a triglyceride. In a solid colorant composition the zeacarotene (mixture) is generally finely dispersed in a matrix or carrier. Such colorant compositions may be prepared by homogenizing, in an aqueous or colloidal solution of a carrier and optionally one or more water-soluble excipients and/or adjuvants, a solution or dispersion of the zeacarotene (mixture) and optionally one or more fat-soluble excipients and/or adjuvants in a triglyceride or an organic solvent, or in a mixture of both triglyceride and organic solvent, and, if required, converting the so obtained dispersion into a solid composition. The colorant compositions, their processes of preparation and the food or pharmaceutical compositions which comprise the zeacarotene (mixture) as the coloring agent are further aspects of this invention.
    • 使用α-zeacarotene,β-zeacarotene或两者的混合物作为食品或药物组合物的着色剂。 为了加入食品或药物组合物或在其制备过程中以其他方式并入其中,将玉米角胡萝卜素(混合物)通常首先以稳定的水溶性或分散性粉末,水性胶体溶液或水溶性溶液的形式配制成固体或液体着色剂组合物 这种粉末的水包油分散体,玉米角胡萝卜素(混合物)的水包油分散体或玉米黄素(混合物)的油溶性分散体在甘油三酯中。 在固体着色剂组合物中,玉米角胡萝卜素(混合物)通常细分散在基质或载体中。 这样的着色剂组合物可以通过在载体和任选的一种或多种水溶性赋形剂和/或佐剂的水溶液或胶体溶液中均匀化,将玉米胡萝卜素(混合物)的溶液或分散体和任选的一种或多种脂溶性 甘油三酯或有机溶剂中的赋形剂和/或佐剂,或甘油三酯和有机溶剂的混合物,如果需要,将所得分散体转化成固体组合物。 着色剂组合物,其制备方法以及包含作为着色剂的zeahrotrot(混合物)的食品或药物组合物是本发明的另外的方面。