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1. 发明授权

US4091055A Light transmitting polyvinylidene fluoride or vinylidene fluoride copolymer compositions 失效
标题翻译：透光聚偏氟乙烯或偏二氟乙烯共聚物组合物
公开(公告)号：US4091055A
公开(公告)日：1978-05-23
申请号：US687763
申请日：1976-05-19
申请人： Kunizoh Kidoh , Yoshio Kudo , Fujio Suzuki
发明人： Kunizoh Kidoh , Yoshio Kudo , Fujio Suzuki
IPC分类号： C08L1/00 , C08L27/00 , C08L27/14 , C08L27/16 , C08L33/00 , C08L33/02 , C08L33/06 , C08L51/00 , C08L51/02
CPC分类号： C08L27/14 , C08L27/16 , C08L33/06 , Y10S260/32
摘要： Light-transmitting compositions containing (1) 50-99% by weight of polyvinylidene fluoride or a vinylidene fluoride copolymer and (2) 1-50% by weight of a copolymer of a vinyl fluoride monomer and at least one acrylate monomer selected from the group consisting of alkyl acrylates and alkyl methacrylates wherein the alkyl group contains from one to four carbon atoms.
摘要翻译：透光性组合物，其含有（1）50-99重量％的聚偏二氟乙烯或1,1-二氟乙烯共聚物，和（2）1-50重量％的氟乙烯单体和至少一种选自下组的丙烯酸酯单体的共聚物由丙烯酸烷基酯和甲基丙烯酸烷基酯组成，其中烷基含有1至4个碳原子。

2. 发明授权

US4501870A Fine particles of polyvinyl chloride and process for producing the same 失效
标题翻译：聚氯乙烯微粒及其制备方法
公开(公告)号：US4501870A
公开(公告)日：1985-02-26
申请号：US614223
申请日：1984-05-24
申请人： Kunizoh Kidoh , Hideki Wakamori , Fujio Suzuki , Takao Iwasaki
发明人： Kunizoh Kidoh , Hideki Wakamori , Fujio Suzuki , Takao Iwasaki
IPC分类号： C08L27/00 , C08F2/00 , C08F2/02 , C08F14/06 , C08F114/06 , C08K5/12 , C08L1/00 , C08L27/06 , C08L33/00 , C08L33/02
CPC分类号： C08F114/06 , C08F14/06 , Y10T428/2982
摘要： Fine particles of polyvinyl chloride produced by bulk polymerization which comprise substantially discrete spherical particles with particle sizes of 0.2 to 2 microns, a plastisol prepared by adding 80 parts by weight of dioctylphthalate to 100 parts by weight of said particles having a viscosity of 50,000 centipoise or less (measured by a B-type viscometer, No. 4 rotor, 12 rpm, 25.degree. C.) and a process for producing the same which comprises subjecting vinyl chloride to bulk polymerization in the presence of a dispersing stabilizer under gentle stirring without causing sedimentation or agglomeration of the polymer particles formed, wherein polymerization is terminated at a polymerization yield of 5 to 30%.
摘要翻译：通过本体聚合制造的聚氯乙烯细颗粒，其包含基本上离散的粒径为0.2至2微米的球形颗粒，通过向100重量份所述粘度为50,000厘泊的颗粒中加入80重量份邻苯二甲酸二辛酯制备的增塑溶胶或较少（通过B型粘度计，4号转子，12rpm，25℃测定）及其制造方法，其包括在温和搅拌下在分散稳定剂存在下使氯乙烯进行本体聚合而不引起所形成的聚合物颗粒的沉降或凝聚，其中以聚合产率5至30％终止聚合。

3. 发明授权

US4317861A Synthetic resin for use as adhesive in preparing composite material comprising polyvinylidene fluoride and polyvinyl chloride, said composite and methods for preparing said resin and said composite material 失效
标题翻译：用于制备包含聚偏氟乙烯和聚氯乙烯的复合材料中的粘合剂的合成树脂，所述复合材料和制备所述树脂和所述复合材料的方法
公开(公告)号：US4317861A
公开(公告)日：1982-03-02
申请号：US181474
申请日：1980-08-26
申请人： Kunizoh Kidoh , Fujio Suzuki , Kazuo Kushida
发明人： Kunizoh Kidoh , Fujio Suzuki , Kazuo Kushida
IPC分类号： C08F14/00 , B32B27/30 , C08F265/00 , C08F265/04 , C09J151/00 , B32B27/08
CPC分类号： C09J151/003 , C08F265/04 , Y10T428/3154 , Y10T428/3192 , Y10T428/31928
摘要： A synthetic resin for use in adhering polyvinylidene fluoride and polyvinyl chloride, the thus prepared composite material comprising polyvinylidene fluoride, the synthetic resin as an adhesive and polyvinyl chloride, and the methods for preparing the synthetic resin and the composite material are described as well as the composite material.
摘要翻译：用于粘合聚偏二氟乙烯和聚氯乙烯的合成树脂，由此制备的包含聚偏二氟乙烯的复合材料，作为粘合剂的合成树脂和聚氯乙烯，以及制备合成树脂和复合材料的方法，以及复合材料。

4. 发明授权

US3966696A Process for producing vinylchloride resin having a highly porous uniform granular structure 失效
标题翻译：具有高度多孔均匀粒状结构的氯乙烯树脂的制造方法
公开(公告)号：US3966696A
公开(公告)日：1976-06-29
申请号：US555994
申请日：1975-03-06
申请人： Kunizoh Kidoh , Hidetora Kashio , Toshio Hosokawa , Kazuo Kusida
发明人： Kunizoh Kidoh , Hidetora Kashio , Toshio Hosokawa , Kazuo Kusida
IPC分类号： C08F14/00 , C08F2/00 , C08F2/18 , C08F14/06 , C08F114/02 , C08L1/28 , C08L5/00
CPC分类号： C08F14/06
摘要： A process for suspension polymerization of vinyl chloride or a mixture of vinyl chloride and a monomer copolymerizable therewith in an aqueous medium in the presence of an oil-soluble polymerization catalyst is improved by the use of a suspending agent comprising a well known protective colloid and a saccharose alkyl ester.
摘要翻译：通过使用包含公知的保护胶体和悬浮聚合物的悬浮剂，改进了在油溶性聚合催化剂存在下，在含水介质中氯乙烯或可与其共聚的单体的混合物的悬浮聚合方法蔗糖烷基酯。

5. 发明授权

US4069291A Densification of particulate porous fluorinated resins 失效
标题翻译：颗粒状多孔氟化树脂的致密化
公开(公告)号：US4069291A
公开(公告)日：1978-01-17
申请号：US697735
申请日：1976-06-18
申请人： Kunizoh Kidoh , Hideki Wakamori , Genzo Asai , Kazuo Kusida
发明人： Kunizoh Kidoh , Hideki Wakamori , Genzo Asai , Kazuo Kusida
IPC分类号： C08L27/12 , C08J3/12 , C08L1/00 , C08L27/00 , B29C23/00
CPC分类号： C08J3/12 , C08J3/16 , C08J2327/12 , Y10S521/918
摘要： A suspension of a particulate porous fluorinated resin in an aqueous medium containing a powder of an inorganic suspension stabilizer is heated approximately at a melting temperature of the resin whereby the resin is densified, the degree of densification of the resin depending on the heating temperature.
摘要翻译：颗粒状多孔氟化树脂在含有无机悬浮稳定剂粉末的水性介质中的悬浮液大约在树脂的熔融温度下加热，由此树脂致密化，树脂的致密化程度取决于加热温度。

6. 发明授权

US4032497A Method and apparatus for removal of unreacted monomer from synthesized high polymer latex 失效
标题翻译：从合成高分子聚合物中除去不需要的单体的方法和装置
公开(公告)号：US4032497A
公开(公告)日：1977-06-28
申请号：US596062
申请日：1975-07-15
申请人： Kunizoh Kidoh , Hideki Wakamori , Kamizo Iimura
发明人： Kunizoh Kidoh , Hideki Wakamori , Kamizo Iimura
IPC分类号： C08F6/00 , C08C1/04 , C08F6/16 , C08L27/06
CPC分类号： C08C1/04 , C08F6/16
摘要： From a synthesized high polymer latex, the unreacted monomer remaining therein can be removed efficiently by causing a hollow cylinder inclined by a gradient of 1/100 to 1/10 with reference to the horizontal plane to be rotated around its axis, then introducing the synthesized high polymer latex and a gas containing moisture into the interior of the hollow cylinder which is maintained in continuous rotation and allowing the latex and the gas to come into mutual contact within the hollow cylinder.

7. 发明授权

US4606144A Monofilament of improved vinylidene fluoride-based resin 失效
标题翻译：改进偏二氟乙烯基树脂的单丝
公开(公告)号：US4606144A
公开(公告)日：1986-08-19
申请号：US697869
申请日：1985-02-04
申请人： Tohru Sasaki , Kunizoh Kidoh , Hiroyuki Endoh
发明人： Tohru Sasaki , Kunizoh Kidoh , Hiroyuki Endoh
IPC分类号： A01K91/00 , D01F6/48 , D02G3/00
CPC分类号： D01F6/48 , A01K91/00 , Y10T428/2913
摘要： A flexible monofilament of at least 0.08 mm in diameter excellent in transparency, high in impact strength and durability and showing a tensile strength of not less than 30 kg/mm.sup.2 and a modulus of elasticity of 60 to 120 kg/mm.sup.2, which is essentially composed of a vinylidene fluoride-based resin, a polymeric substance and a polyester plasticizer and is prepared by the process comprising the steps of:melt-spinning of a resin composition comprising essentially of 100 parts by weight of said vinylidene fluoride based resin selected from homopolymers of vinylidene fluoride and copolymers thereof; 5 to 15 parts by weight of said polymeric substance selected from homopolymers of methyl acrylate, copolymers comprising at least 85% by weight of methyl acrylate units and at most 15% by weight of isobutylene units and mixture thereof; and 2 to 7 parts by weight of said polyester plasticizer selected from the group consisting of polyesters of 1,100 to 5,000 in molecular weight obtained from an alcohol of 4 to 7 carbon atoms and a carboxylic acid of 4 to 8 carbon atoms and polyesters of 1,500 to 4,000 in molecular weight obtained from a dihydric alcohol of 2 to 4 carbon atoms and a dicarboxylic acid of 4 to 6 carbon atoms, thereby obtaining an unstretched monofilament,stretching the thus obtained unstretched monofilament in a heating medium, andsubjecting the thus stretched monofilament to relaxation thereby obtaining said flexible monofilament.
摘要翻译：直径至少为0.08mm的柔性单丝透明度优异，冲击强度和耐久性高，拉伸强度不低于30kg / mm2，弹性模量为60〜120kg / mm2，其基本上组成偏二氟乙烯基树脂，聚合物和聚酯增塑剂，并且通过包括以下步骤的方法制备：将基本上由100重量份所述偏二氟乙烯基树脂组成的树脂组合物熔融纺丝，所述偏二氟乙烯基树脂选自偏二氟乙烯及其共聚物; 5至15重量份的选自丙烯酸甲酯的均聚物的共聚物，包含至少85重量％的丙烯酸甲酯单元和至多15重量％的异丁烯单元及其混合物的共聚物; 和2至7重量份的所述聚酯增塑剂，其选自由4至7个碳原子的醇和4至8个碳原子的羧酸获得的分子量为1,100至5,000的聚酯，并且聚酯为1500至从2至4个碳原子的二元醇和4至6个碳原子的二羧酸获得的分子量为4000，从而获得未拉伸的单丝，将由此得到的未拉伸单丝在加热介质中拉伸，并将由此拉伸的单丝松弛，从而获得所述柔性单丝。

8. 发明授权

US4546149A Vinylidene fluoride resin composition containing glycidyl (meth)acrylate polymer 失效
标题翻译：含有（甲基）丙烯酸缩水甘油酯聚合物的偏二氟乙烯树脂组合物
公开(公告)号：US4546149A
公开(公告)日：1985-10-08
申请号：US605707
申请日：1984-04-30
申请人： Kunizoh Kidoh , Mitsuru Ohta
发明人： Kunizoh Kidoh , Mitsuru Ohta
IPC分类号： C08L27/12 , C08L1/00 , C08L27/00 , C08L27/16 , C08L33/00 , C08L33/02 , C08L33/14
CPC分类号： C08L27/16 , C08L33/14 , Y10S525/913
摘要： A vinylidene fluoride resin composition which comprises 100 parts by weight of vinylidene fluoride resin and 0.1 to 10 parts by weight of glycidyl (meth)acrylate resin, said glycidyl (meth)acrylate resin being a polymer composed of at least one of glycidyl acrylate and glycidyl methacrylate, or a copolymer composed of a monomer selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate and ethyl methacrylate and at least one of glycidyl acrylate and glycidyl methacrylate.The resin composition has improved thermal stability and electrical properties, and is immune to deleterious discoloration.
摘要翻译：一种偏氟乙烯树脂组合物，其包含100重量份的偏二氟乙烯树脂和0.1至10重量份的（甲基）丙烯酸缩水甘油酯树脂，所述缩水甘油基（甲基）丙烯酸酯树脂是由至少一种丙烯酸缩水甘油酯和缩水甘油基甲基丙烯酸甲酯，或由选自丙烯酸甲酯，甲基丙烯酸甲酯，丙烯酸乙酯和甲基丙烯酸乙酯的单体组成的共聚物和丙烯酸缩水甘油酯和甲基丙烯酸缩水甘油酯中的至少一种。树脂组合物具有改善的热稳定性和电性能，并且对有害变色是免疫的。

9. 发明授权

US4251405A Process for producing plasticized vinylidene chloride-vinyl chloride copolymer 失效
标题翻译：生产塑化偏二氯乙烯 - 氯乙烯共聚物的方法
公开(公告)号：US4251405A
公开(公告)日：1981-02-17
申请号：US33984
申请日：1979-04-27
申请人： Kunizoh Kidoh , Hideki Wakamori , Hidetora Kashio
发明人： Kunizoh Kidoh , Hideki Wakamori , Hidetora Kashio
IPC分类号： C08F214/00 , C08F2/00 , C08F2/20 , C08F2/44 , C08F14/00 , C08F214/08 , C08L91/00 , C08F14/08 , C08F114/08
CPC分类号： C08F214/08
摘要： A plasticized vinylidene chloride-vinyl chloride copolymer is produced by copolymerizing 65 to 95 wt. % of vinylidene chloride and 35 to 5 wt. % of vinyl chloride or a mixture of vinyl chloride as a main component and a comonomer wherein 0.5 to 10.0 wt. parts of a plasticizer being soluble in said monomer mixture is added to 100 wt. parts of said monomer mixture and said monomer mixture is copolymerized by a suspension polymerization in the presence of an oil soluble radical initiator and a macromolecular suspending agent in water whereby a blending step can be eliminated.
摘要翻译：通过将65〜95重量份的共聚物制造塑化的偏二氯乙烯 - 氯乙烯共聚物。％偏二氯乙烯和35〜5wt。％的氯乙烯或氯乙烯作为主要成分的混合物和共聚单体，其中0.5至10.0wt。将可溶于所述单体混合物的增塑剂的部分加入到100重量％所述单体混合物和所述单体混合物的部分通过在油溶性自由基引发剂和大分子悬浮剂存在下在水中的悬浮聚合共聚合，由此可以除去共混步骤。

10. 发明授权

US4484894A Sheet for lining denture base 失效
标题翻译：内衬义齿底片
公开(公告)号：US4484894A
公开(公告)日：1984-11-27
申请号：US351467
申请日：1982-02-23
申请人： Eiichi Masuhara , Kunizoh Kidoh , Nobuo Bannai
发明人： Eiichi Masuhara , Kunizoh Kidoh , Nobuo Bannai
IPC分类号： A61C13/07 , A61K6/083 , A61C13/02
CPC分类号： A61K6/083 , A61C13/0025
摘要： Disclosed herein are sheet for lining denture base prepared by molding a copolymer consisting of vinylidene fluoride units, tetrafluoroethylene units, hexafluoropropylene units and/or chlorotrifluoroethylene units in their mutual ratio within a predetermined range into shapes of sheets.
摘要翻译：本文公开了通过将由偏二氟乙烯单元，四氟乙烯单元，六氟丙烯单元和/或三氟氯乙烯单元组成的共聚物以预定范围内的相互比例模制成片的形状而制备的衬里义齿底片。

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