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    • 1. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5512373A
    • 1996-04-30
    • US208756
    • 1994-03-09
    • Kunihiro UedaKoji KobayashiMitsuru TakaiMasashi Higo
    • Kunihiro UedaKoji KobayashiMitsuru TakaiMasashi Higo
    • G11B5/725B32B27/00G11B5/66
    • G11B5/725Y10S428/90Y10T428/3154Y10T428/31544
    • The problem of rusting relating to a magnetic recording medium composed of a non-magnetic base and a magnetic recording layer of a ferromagnetic metal layer formed thereon is overcome by a magnetic recording medium comprising a non-magnetic support, a ferromagnetic metal thin film as a magnetic recording layer and a lubricating layer, wherein the lubricating layer contains a mixture of a first lubricant having a polar perfluoro radial and a second lubricant expressed by the following formula: ##STR1## where R is a divalent radical having 2 or fewer carbons atoms;D is a polar radical selected from phosphorus-containing radical, hydroxyl, carboxyl and esterified carboxyl;R.sup.1 is selected from F, CF.sub.3 and C.sub.2 F.sub.5 ; andR.sup.2 and R.sub.3 are selected from F, CF.sub.3 and C.sub.2 F.sub.5, CF(CF.sub.3).sub.2 and C(CF.sub.3).sub.3.
    • 由形成在其上的强磁性金属层的非磁性基底和磁记录层构成的磁记录介质的生锈问题由包括非磁性载体,强磁性金属薄膜 磁记录层和润滑层,其中润滑层包含具有极性全氟径向的第一润滑剂和由下式表示的第二润滑剂的混合物:其中R是具有2个或更少碳原子的二价基团; D是选自含磷自由基,羟基,羧基和酯化羧基的极性基团; R1选自F,CF3和C2F5; 并且R 2和R 3选自F,CF 3和C 2 F 5,CF(CF 3)2和C(CF 3)3。
    • 4. 发明授权
    • Magnetic recording medium
    • 磁记录介质
    • US5549979A
    • 1996-08-27
    • US159422
    • 1993-11-29
    • Shinji MiyazakiMitsuru TakaiKoji Kobayashi
    • Shinji MiyazakiMitsuru TakaiKoji Kobayashi
    • C23C14/06G11B5/64G11B5/66G11B5/73G11B5/738G11B5/84G11B5/85H01F10/16H01F41/20
    • G11B5/7325G11B5/66G11B5/8404Y10S428/90Y10T428/12931Y10T428/30
    • A magnetic recording medium comprising a nonmagnetic base, an SiO.sub.x (x=1.2-1.95) undercoat, an under-layer ferromagnetic metal film consisting of a Co--Ni alloy, an SiO.sub.x (x=1.2-1.95) intermediate layer, an upper-layer ferromagnetic metal protective film consisting of a Co--Ni alloy, a diamond-like carbon protective film, and a lubricant layer, formed in the order of mention, the angles of vapor deposition as measured from lines normal to the upper- and under-layer ferromagnetic metal films being all decreasing toward the upper surfaces. The magnetic recording medium is made by forming an SiO.sub.x (x=1.2-1.95) undercoat by vapor deposition on a flexible nonmagnetic base being fed, forming an under-layer ferromagnetic metal film by vapor deposition of a Co--Ni alloy at a large deposition angle on the supply side and at a small deposition angle on the take up side, rewinding the semi-finished product thus obtained, repeating the foregoing process steps, forming a diamond-like carbon protective film, and further forming a lubricant layer over the diamond-like carbon protective film, all within a vacuum chamber.
    • 包含非磁性基底,SiOx(x = 1.2-1.95)底涂层的磁记录介质,由Co-Ni合金,SiOx(x = 1.2-1.95)中间层构成的底层强磁性金属膜, 由Co-Ni合金,类金刚石碳保护膜和润滑剂层构成的层状铁磁性金属保护膜,按顺序形成,从垂直于上,下的线的线测得的蒸镀角度, 层铁磁性金属膜全部向上表面减小。 磁记录介质是通过气相沉积形成SiOx(x = 1.2-1.95)底涂层而制成的,该柔性非磁性基体被馈送,通过Co-Ni合金在大量沉积下气相沉积形成底层强磁性金属膜 在供给侧的角度和在卷绕侧的小沉积角度,重新卷绕由此获得的半成品,重复上述工艺步骤,形成类金刚石碳保护膜,并进一步在金刚石上形成润滑剂层 样的碳保护膜,都在真空室内。
    • 6. 发明授权
    • Perpendicular magnetic recording medium and method for making
    • 垂直磁记录介质及其制造方法
    • US5525398A
    • 1996-06-11
    • US854892
    • 1992-03-20
    • Mitsuru TakaiKoji KobayashiJiro Yoshinari
    • Mitsuru TakaiKoji KobayashiJiro Yoshinari
    • G11B5/64G11B5/65G11B5/66G11B5/73G11B5/733G11B5/85B32B3/10B32B7/02
    • G11B5/85G11B5/66Y10S428/90Y10T428/24355Y10T428/24942Y10T428/265
    • A perpendicular magnetic recording medium has a magnetic layer comprised of two stacked sublayers each in the form of ferromagnetic metal thin film consisting of columnar crystal grains wherein the angle .theta. between the average growth direction of the columnar crystal grains and a normal to the substrate is .theta..gtoreq.45.degree. for the lower sublayer and .theta..ltoreq.30.degree. for the upper sublayer, and the mean maximum diameter of columnar crystal grains of the lower sublayer is not smaller than the mean maximum diameter of columnar crystal grains of the upper sublayer. An apparatus suitable for the evaporation of the magnetic layer is arranged as shown in the Figure. Magnetic flux associated with the upper sublayer finds an escape to the lower sublayer, preventing formation of a closed loop of magnetic flux within the columnar crystal grains of the upper sublayer. The lower sublayer is magnetized, thus contributing to an improvement in reproduction output.
    • 垂直磁记录介质具有由两个堆叠的子层组成的磁性层,每个层叠子层由柱状晶粒构成的强磁性金属薄膜形式,其中柱状晶粒的平均生长方向与基板的法线之间的角度θ为θ > / = 45°,下层的θ= 30°,下层的柱状晶粒的平均最大直径不小于上层的柱状晶粒的平均最大直径 。 如图所示,配置适合于磁性层蒸发的装置。 与上部子层相关联的磁通量向下部子层发现逃逸,从而防止在上部子层的柱状晶粒内形成磁通的闭环。 下部子层被磁化,因此有助于再现输出的改善。
    • 8. 发明授权
    • Magnetic recording medium having a specified plasma polymerized hydrogen
containing carbon film and lubricant
    • 具有特定等离子体聚合氢的碳膜和润滑剂的磁记录介质
    • US5677051A
    • 1997-10-14
    • US651902
    • 1996-05-21
    • Kunihiro UedaMasatoshi NakayamaKiyoshi YazuKoji KobayashiHiromichi Kanazawa
    • Kunihiro UedaMasatoshi NakayamaKiyoshi YazuKoji KobayashiHiromichi Kanazawa
    • G11B5/72G11B5/84G11B5/66
    • G11B5/8408G11B5/72Y10S427/106Y10S428/90Y10T428/265Y10T428/30Y10T428/31544Y10T428/31678
    • A magnetic recording medium possessing excellent electromagnetic characteristics, corrosion resistance, durability, abrasion resistance and lubricity, has an undercoat layer, a ferromagnetic metal layer, a protective layer and a lubricating layer formed in this order on a non-magnetic substrate, or has an undercoat layer, a ferromagnetic metal layer, an intercepting layer, a protective layer and a lubricating layer formed in this order on a non-magnetic substrate, wherein the protective layer is a plasma-polymerized hydrogen-containing carbon film having a refractive index of 1.90 or more and a contact angle of less than 80 degrees, the film thickness of the protective layer or the total film thickness of the protective layer and the intercepting layer is 30 to 150 .ANG., the undercoat layer, as well as the intercepting layer, is a film formed of silicon oxide represented by SiOx (x=1.8-1.95), and the lubricating layer is formed of a compound selected from the group consisting of polar perfluoropolyethers, non-polar perfluoropolyethers, perfluorocarboxylic acids, phosphazens, perfluoroalkylates and perfluoroacrylate compounds; and a method for producing the recording medium.
    • 具有优异的电磁特性,耐腐蚀性,耐久性,耐磨性和润滑性的磁记录介质具有在非磁性基板上依次形成的底涂层,强磁性金属层,保护层和润滑层,或具有 底涂层,强磁性金属层,截留层,保护层和润滑层,其依次形成在非磁性基板上,其中保护层是折射率为1.90的等离子体聚合的含氢碳膜 以上,接触角小于80度,保护层的膜厚或保护层和截留层的总膜厚为30〜150安培,底涂层以及截留层为 由SiOx(x = 1.8-1.95)表示的由氧化硅形成的膜,并且润滑层由选自p 全氟聚醚,非极性全氟聚醚,全氟羧酸,磷腈,全氟烷基化物和全氟丙烯酸酯化合物; 以及记录介质的制造方法。