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1. 发明授权

US5859276A Organotransition metal compounds 失效
标题翻译：有机过渡金属化合物
公开(公告)号：US5859276A
公开(公告)日：1999-01-12
申请号：US935422
申请日：1997-09-23
申请人： Kunihiko Murata , Junichi Hori , Masahiro Yoshida
发明人： Kunihiko Murata , Junichi Hori , Masahiro Yoshida
IPC分类号： C07C211/48 , C07C211/49 , C07F7/00 , C07F17/00 , C08F10/00
CPC分类号： C07F17/00 , C07F7/006 , C08F10/00 , Y10S526/943
摘要： New metallocene compounds (II) and their synthetic intermediates (I) used for olefin polymerization catalysts represented by the general formulas (I) and (II) ##STR1## (wherein X can be identical or different and is each independently of one another a halogen atom, M.sup.1 is a group IV transition metal atom, A is a nitrogen or phosphorus atoms, R.sup.1 is an aryl group, R.sup.2 is a saturated hydrocarbon group having 1-10 carbon atoms, whereby each of R.sup.2 can bind one another to constitute a ring containing A and M.sup.1, L.sup.1 and L.sup.2 can be each other identical or different and are a substituted cyclopentadienyl, indenyl, substituted indenyl or substituted fluorenyl groups, B is a hydrocarbon having 1-20 carbon atoms, silylene having 1-20 carbon atoms, oligosilylene or germylene groups, binding to L.sup.1 and L.sup.2, and M.sup.1 can be also coordinated with an ether or an amine at any coordination number.).
摘要翻译：用于由通式（I）和（II）表示的烯烃聚合催化剂的新的茂金属化合物（II）及其合成中间体（I）（I）其中X可以相同或不同并且各自独立地为卤素原子，M1为IV族过渡金属原子，A为氮原子或磷原子，R1为芳基，R2为碳原子数1〜10的饱和烃基， R2可以彼此结合以构成含有A和M1的环，L1和L2可以彼此相同或不同，并且是取代的环戊二烯基，茚基，取代的茚基或取代的芴基，B是具有1-20个碳原子的烃，具有1-20个碳原子的亚甲硅基，低级亚烯基或亚甲硅烷基，与L1和L2结合，以及M1也可以任何配位数与醚或胺配位。

2. 发明授权

US5892075A Process for synthesizing metallocene compounds 失效
标题翻译：合成茂金属化合物的方法
公开(公告)号：US5892075A
公开(公告)日：1999-04-06
申请号：US936169
申请日：1997-09-23
申请人： Kunihiko Murata , Junichi Hori , Masahiro Yoshida
发明人： Kunihiko Murata , Junichi Hori , Masahiro Yoshida
IPC分类号： C07F17/00 , C07F7/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： The object of the invention resides in the development of an improved process for synthesizing metallocene compounds useful as olefin polymerization catalysts.A new process for synthesizing metallocene compounds of formulae (IV) and (IV') comprises a reaction of formula (I) with formula (II) or (II') to afford formula (III) or (III'), and then a reaction of a halogenating agent.In formulae (IV) and (IV') described below, M.sup.1 is a group IV transition-metal atom, L.sup.1 and L.sup.2 can be each other identical or different and are substituted or unsubstituted cyclopentadienyl, substituted or unsubstituted indenyl or substituted or unsubstituted fluorenyl groups, B is a hydrocarbon having 1-20 carbon atoms, silylene having 1-20 carbon atoms, oligosilylene or germylene groups, binding to L.sup.1 and L.sup.2, Y can be identical or different and is each independently of one another a halogen atom. Further, M.sup.1 can be coordinated with an ether or an amine at any coordination number. ##STR1##
摘要翻译：本发明的目的在于开发可用作烯烃聚合催化剂的金属茂化合物的改进方法。用于合成式（IV）和（IV'）的茂金属化合物的新方法包括式（I）与式（II）或（II'）的反应，得到式（III）或（III'），然后卤化剂的反应。在下述式（IV）和（IV'）中，M1是IV族过渡金属原子，L1和L2可以彼此相同或不同，并且是取代或未取代的环戊二烯基，取代或未取代的茚基或取代或未取代的芴基 B是具有1-20个碳原子的烃，具有1-20个碳原子的亚甲硅基，低级亚烯基或亚甲硅烷基，与L1和L2结合，Y可以相同或不同，并且各自独立地为卤素原子。此外，M1可以任何配位数与醚或胺配位。反应方案2

3. 发明申请

US20100069683A1 Organic metal compound and process for preparing optically-active alcohols using the same 审中-公开
标题翻译：有机金属化合物及使用其制备光学活性醇的方法
公开(公告)号：US20100069683A1
公开(公告)日：2010-03-18
申请号：US12583943
申请日：2009-08-28
申请人： Takashi Miki , Junichi Hori , Toshihide Takemoto , Noriyuki Utsumi , Takeaki Katayama , Masahito Watanabe , Kunihiko Murata
发明人： Takashi Miki , Junichi Hori , Toshihide Takemoto , Noriyuki Utsumi , Takeaki Katayama , Masahito Watanabe , Kunihiko Murata
IPC分类号： C07C37/00
CPC分类号： C07B53/00 , B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2531/0238 , B01J2531/822 , B01J2531/827 , C07F17/02
摘要： The present invention provides an asymmetric reduction catalyst effective in preparing optically-active alcohol compounds having various functional groups, and a process for preparing optically-active alcohol compounds using said asymmetric reduction catalyst.The organic metal compound of the present invention is represented by the following general formula (1): wherein R1 and R2 may be mutually identical or different, and are an alkyl group, a phenyl group, a naphthyl group, a cycloalkyl group, or an alicyclic ring formed by binding R1 and R2, which may have a substituent; R3 is a hydrogen atom or an alkyl group; Cp is a cyclopentadienyl group, which may have a substituent, bound to M1 via a π bond; X1 is a halogen atom or a hydrido group; M1 is rhodium or iridium; and * denotes asymmetric carbon.
摘要翻译：本发明提供了一种有效地制备具有各种官能团的光学活性醇化合物的不对称还原催化剂，以及使用该不对称还原催化剂制备光学活性醇化合物的方法。本发明的有机金属化合物由以下通式（1）表示：其中R1和R2可以相同或不同，为烷基，苯基，萘基，环烷基或通过结合可以具有取代基的R 1和R 2形成的脂环; R3是氢原子或烷基; Cp是可以具有取代基的环戊二烯基，其通过a和p结合到M1; 键; X1是卤原子或氢环; M1是铑或铱; 和*表示不对称碳。

4. 发明授权

US08481735B2 Organic metal complex and process for preparing amine compound 有权
公开(公告)号：US08481735B2
公开(公告)日：2013-07-09
申请号：US12722819
申请日：2010-03-12
申请人： Masahito Watanabe , Junichi Hori , Kunihiko Murata
发明人： Masahito Watanabe , Junichi Hori , Kunihiko Murata
IPC分类号： C07F15/00 , B01J31/12
CPC分类号： B01J31/2295 , C07C209/78 , C07F15/004 , C07F15/0053 , C07F15/008
摘要： [Problem]The present invention aims to provide a novel organometallic compound that can be used as a general-use highly active catalyst with superior selectivity for functional groups.[Means for Solving Problem]The present invention relates to an organometallic compound having a novel specific structure of general formula (1): and to a general-use highly active catalyst used in reductive amination reaction with superior selectivity for functional groups that comprises said organometallic compound, and to a process for preparing amine compounds by reductive amination reaction using said catalyst.

5. 发明申请

US20080033221A1 Hydrogenation Promoter, Hydrogenation Catalyst, and Process for Producing Alkene Compound 失效
标题翻译：氢化促进剂，氢化催化剂和生产烯烃化合物的方法
公开(公告)号：US20080033221A1
公开(公告)日：2008-02-07
申请号：US11547002
申请日：2005-03-30
申请人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
发明人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
IPC分类号： B01J31/00 , C07C5/09 , C07F15/00
CPC分类号： B01J31/2291 , B01J23/44 , B01J31/2286 , B01J35/0013 , B01J35/006 , B01J2231/645 , B01J2531/824 , B82Y30/00 , C07C5/09 , C07C17/354 , C07C29/17 , C07C2531/22 , C07F15/006 , C07F15/0066 , C07C11/02 , C07C21/04 , C07C33/046 , C07C33/044 , C07C33/042 , C07C33/025
摘要： A hydrogenation promoter of the present invention is produced by reacting an alkyne compound or an alkene compound, a palladium compound represented by a general formula Pd(II)XjLk (where L represents a monodentate ligand or a polydendate ligand other than a phosphorus-containing ligand (when two or more Ls are present in the compound, the Ls may be the same or different), X represents an anionic group, j represents a value determined according to the valence of X so that Xj has a valence of −2 as a whole, and k represents an integer in the range of 0 to 4), and a base in an organic solvent. Specifically, The hydrogenation promoter of the invention includes palladium nanoparticles containing the alkyne compound or the alkene compound as an agglomeration-preventing agent.
摘要翻译：本发明的氢化助催化剂是通过使炔化合物或烯烃化合物，通式Pd（II）所示的钯化合物（N）其中L表示除含磷配体以外的单齿配体或多齿配体（当化合物中存在两个或更多个L时，L可以相同或不同），X表示阴离子基团，j表示确定的值根据X的化合价，使X X整体上的化合价为-2，k表示0〜4的整数）和有机溶剂中的碱。具体地说，本发明的氢化促进剂包括含有炔化合物或烯化合物作为防结块剂的钯纳米颗粒。

6. 发明申请

US20100234596A1 NOVEL ORGANIC METAL COMPLEX AND PROCESS FOR PREPARING AMINE COMPOUND 有权
标题翻译：新的有机金属复合物和制备胺化合物的方法
公开(公告)号：US20100234596A1
公开(公告)日：2010-09-16
申请号：US12722819
申请日：2010-03-12
申请人： Masahito Watanabe , Junichi Hori , Kunihiko Murata
发明人： Masahito Watanabe , Junichi Hori , Kunihiko Murata
IPC分类号： C07C209/28 , C07F15/00 , C07C253/30 , C07C227/18
CPC分类号： B01J31/2295 , C07C209/78 , C07F15/004 , C07F15/0053 , C07F15/008
摘要： [Problem] The present invention aims to provide a novel organometallic compound that can be used as a general-use highly active catalyst with superior selectivity for functional groups.[Means for Solving Problem] The present invention relates to an organometallic compound having a novel specific structure of general formula (1): and to a general-use highly active catalyst used in reductive amination reaction with superior selectivity for functional groups that comprises said organometallic compound, and to a process for preparing amine compounds by reductive amination reaction using said catalyst.
摘要翻译：本发明的目的在于提供一种新的有机金属化合物，其可以用作对官能团具有优异选择性的通用高活性催化剂。解决问题的手段本发明涉及具有通式（1）的新特异性结构的有机金属化合物：和用于还原胺化反应中的一般用途的高活性催化剂，对包含所述有机金属的官能团具有优异的选择性化合物，以及通过使用所述催化剂的还原胺化反应制备胺化合物的方法。

7. 发明申请

US20090062573A1 Organic metal compound and process for preparing optically-active alcohols using the same 审中-公开
标题翻译：有机金属化合物及使用其制备光学活性醇的方法
公开(公告)号：US20090062573A1
公开(公告)日：2009-03-05
申请号：US12218874
申请日：2008-07-18
申请人： Takashi Miki , Junichi Hori , Toshihide Takemoto , Noriyuki Utsumi , Takeaki Katayama , Masahito Watanabe , Kunihiko Murata
发明人： Takashi Miki , Junichi Hori , Toshihide Takemoto , Noriyuki Utsumi , Takeaki Katayama , Masahito Watanabe , Kunihiko Murata
IPC分类号： C07F15/00 , C07C29/143 , C07C37/00
CPC分类号： C07B53/00 , B01J31/1805 , B01J31/2295 , B01J2231/643 , B01J2531/0238 , B01J2531/822 , B01J2531/827 , C07F17/02
摘要： The present invention provides an asymmetric reduction catalyst effective in preparing optically-active alcohol compounds having various functional groups, and a process for preparing optically-active alcohol compounds using said asymmetric reduction catalyst.The organic metal compound of the present invention is represented by the following general formula (1): wherein R1 and R2 may be mutually identical or different, and are an alkyl group, a phenyl group, a naphthyl group, a cycloalkyl group, or an alicyclic ring formed by binding R1 and R2, which may have a substituent; R3 is a hydrogen atom or an alkyl group; Cp is a cyclopentadienyl group, which may have a substituent, bound to M1 via a π bond; X1 is a halogen atom or a hydrido group; M1 is rhodium or iridium; and * denotes asymmetric carbon.
摘要翻译：本发明提供了一种有效地制备具有各种官能团的光学活性醇化合物的不对称还原催化剂，以及使用该不对称还原催化剂制备光学活性醇化合物的方法。本发明的有机金属化合物由以下通式（1）表示：其中R1和R2可以相同或不同，为烷基，苯基，萘基，环烷基或通过结合可以具有取代基的R 1和R 2形成的脂环; R3是氢原子或烷基; Cp是可以具有取代基的环戊二烯基，其通过π键与M1结合; X1是卤原子或氢环; M1是铑或铱; 和*表示不对称碳。

8. 发明授权

US07619125B2 Hydrogenation promoter, hydrogenation catalyst, and process for producing alkene compound 失效
标题翻译：氢化促进剂，氢化催化剂和烯烃化合物的制备方法
公开(公告)号：US07619125B2
公开(公告)日：2009-11-17
申请号：US11547002
申请日：2005-03-30
申请人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
发明人： Junichi Hori , Kunihiko Murata , Nobuhito Kurono , Takeshi Ohkuma , Ryoji Noyori
IPC分类号： B01J31/00
CPC分类号： B01J31/2291 , B01J23/44 , B01J31/2286 , B01J35/0013 , B01J35/006 , B01J2231/645 , B01J2531/824 , B82Y30/00 , C07C5/09 , C07C17/354 , C07C29/17 , C07C2531/22 , C07F15/006 , C07F15/0066 , C07C11/02 , C07C21/04 , C07C33/046 , C07C33/044 , C07C33/042 , C07C33/025
摘要： A hydrogenation promoter of the present invention is produced by reacting an alkyne compound or an alkene compound, a palladium compound represented by a general formula Pd(II)XjLk (where L represents a monodentate ligand or a polydendate ligand other than a phosphorus-containing ligand (when two or more Ls are present in the compound, the Ls may be the same or different), X represents an anionic group, j represents a value determined according to the valence of X so that Xj has a valence of −2 as a whole, and k represents an integer in the range of 0 to 4), and a base in an organic solvent. Specifically, The hydrogenation promoter of the invention includes palladium nanoparticles containing the alkyne compound or the alkene compound as an agglomeration-preventing agent.
摘要翻译：本发明的氢化促进剂是通过使炔烃化合物或烯烃化合物，通式Pd（II）XjLk（其中L代表单配体或除了含磷配体之外的多齿配位体）表示的钯化合物（当化合物中存在两个或更多个L时，L可以相同或不同），X表示阴离子基团，j表示根据X的化合价确定的值，使得Xj的化合价为-2，为整数，k表示0〜4的整数）和有机溶剂中的碱。具体地说，本发明的氢化促进剂包括含有炔化合物或烯化合物作为防结块剂的钯纳米颗粒。

9. 发明申请

US20090216019A1 Process for Production of Optically Active Quinuclidinols 有权
标题翻译：光学活性喹硫烷的制备方法
公开(公告)号：US20090216019A1
公开(公告)日：2009-08-27
申请号：US11887340
申请日：2005-03-30
申请人： Ryoji Noyori , Takeshi Okuma , Kunihiko Tsutsumi , Nariyuki Utsumi , Kunihiko Murata , Takeaki Katayama
发明人： Ryoji Noyori , Takeshi Okuma , Kunihiko Tsutsumi , Nariyuki Utsumi , Kunihiko Murata , Takeaki Katayama
IPC分类号： C07F15/00 , C07D453/02
CPC分类号： C07F9/5027 , B01J31/1815 , B01J31/182 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B53/00 , C07D453/02 , C07F15/0046 , C07F15/0053
摘要： A novel ruthenium complex which is a highly efficient catalyst useful for the production of optically active 3-quinuclidinols, and a process for production of optically active 3-quinuclidinols using the ruthenium complex as a catalyst, where the optically active 3-quinuclidinols are useful as an optically active, physiologically active compound utilized in medicines and agrichemicals or as a synthetic intermediate such as a liquid crystal material.
摘要翻译：一种新型的钌络合物，其是用于制备光学活性3-奎宁环的高效催化剂，以及使用钌络合物作为催化剂生产光学活性3-奎宁环的方法，其中光学活性3-奎宁环醇可用作用于药物和农药的光学活性的生理活性化合物或作为液晶材料的合成中间体。

10. 发明授权

US07332622B2 Process for preparing optically active nitro compounds and cyano compounds 失效
标题翻译：光学活性硝基化合物和氰基化合物的制备方法
公开(公告)号：US07332622B2
公开(公告)日：2008-02-19
申请号：US10934338
申请日：2004-09-03
申请人： Masahito Watanabe , Kunihiko Murata , Takao Ikariya
发明人： Masahito Watanabe , Kunihiko Murata , Takao Ikariya
IPC分类号： C07C255/00 , C07C69/76
CPC分类号： B01J31/1805 , B01J31/2295 , B01J2231/348 , B01J2531/821 , B01J2540/34 , C07C253/30 , C07C255/22
摘要： A process for preparing optically active nitro compounds and cyano compounds using a metal complex, which is obtained by reaction of an optically active nitrogen-containing compound and a periodic table group VIII metal complex, in the asymmetric Michael reaction.
摘要翻译：在非对称迈克尔反应中使用通过光学活性含氮化合物和周期表VIII族金属络合物的反应获得的金属络合物制备旋光性硝基化合物和氰基化合物的方法。

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