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    • 3. 发明申请
    • CHROMIUM (III) CARBONATE AND PROCESS FOR PRODUCING THE SAME
    • 碳酸铯(III)及其制造方法
    • US20110168051A1
    • 2011-07-14
    • US13062478
    • 2009-08-27
    • Hiroyuki KuwanoTomohiro BandaYasuyuki Tanaka
    • Hiroyuki KuwanoTomohiro BandaYasuyuki Tanaka
    • C23C16/06C01G37/00C23C16/18
    • C25D3/10C01G37/00C01P2006/62C01P2006/63C01P2006/64C23C2222/10C25D3/06
    • The chromium (III) carbonate of the present invention exhibits a light blue color in a solid state. This chromium (III) carbonate has an L* value of 50 to 70, an a* value of −4 to −2, and a b* value of −10 to −7, which are represented by the L*a*b* color system (JIS Z8729). This chromium (III) carbonate is preferably completely dissolved within 30 minutes when the chromium (III) carbonate is added, in an amount corresponding to a Cr content of 1 g, to 1 liter of an aqueous solution of hydrochloric acid having a pH of 0.2 at a temperature of 25° C. This chromium (III) carbonate is preferably obtained by contacting an aqueous solution of carbonate and an aqueous solution containing trivalent chromium at a pH of 6 to 12 under the condition of a reaction liquid temperature of 0° C. or more and less than 50° C. Also, preferably, after production of the chromium (III) carbonate, filtration is performed, and the chromium (III) carbonate is washed with water until the conductivity of the filtrate is 5 mS/cm or less.
    • 本发明的碳酸铬(III)表现出固态的浅蓝色。 该碳酸铬(III)的L *值为50〜70,a *值为-4〜-2,ab *为-10〜-7,由L * a * b *颜色 系统(JIS Z8729)。 当碳酸铬(III)以相当于Cr含量的1g的量添加碳酸铬(III)至1升pH为0.2的盐酸水溶液时,优选在30分钟内完全溶解该碳酸铬(III) 该温度为25℃。这种碳酸铬(III)优选通过在反应液温度为0℃的条件下使碳酸盐水溶液和含有三价铬的水溶液在6至12的pH下接触 以上且小于50℃。此外,优选在碳酸铬(III)的制造之后,进行过滤,并用水洗涤碳酸铬(III),直至滤液的电导率为5mS / cm 或更少。
    • 6. 发明申请
    • CHROMIUM (III)-CONTAINING AQUEOUS SOLUTION AND PROCESS FOR PRODUCING THE SAME
    • 铬(III) - 水溶液及其生产方法
    • US20110162556A1
    • 2011-07-07
    • US13062486
    • 2009-08-27
    • Tomohiro BandaHiroyuki Kuwano
    • Tomohiro BandaHiroyuki Kuwano
    • C09D7/12
    • C25D3/06C01G37/00C01G37/08C23C22/08C23C22/10C23C22/53C23C2222/10C25D3/10
    • It is intended to provide a chromium (III)-containing aqueous solution which has widely adjustable molar ratios of various acid radicals to Cr and is useful as a source of trivalent chromium or a supplementary source of trivalent chromium for the bath in the surface treatment of various metals. Specifically, the chromium (III)-containing aqueous solution is characterized by containing a complex chromium (III) salt which is produced by performing chromic acid reduction reaction in the simultaneous or sequential presence of two or more acids selected from an inorganic acid other than chromic acid and an organic acid. Furthermore, it is intended to provide a process for producing a chromium (III)-containing aqueous solution by performing chromic acid reduction reaction by the contact of chromic acid with an acid other than chromic acid and/or an organic reducing agent in a water solvent, characterized in that the chromic acid reduction reaction is performed in the simultaneous or sequential presence of at least two or more acids selected as the acid other than chromic acid from an inorganic acid and an organic acid.
    • 旨在提供一种含铬(III)的水溶液,其具有广泛可调的各种酸基与Cr的摩尔比,并且可用作三价铬的来源或用于在表面处理中的浴中的三价铬的补充来源 各种金属。 具体地说,含铬(III)的水溶液的特征在于,含有复合铬(III)盐,它是通过在两种或更多种选自铬酸盐以外的无机酸的同时或相继存在下进行铬酸还原反应 酸和有机酸。 此外,本发明旨在提供一种通过在水溶剂中使铬酸与铬酸和/或有机还原剂之间的酸接触进行铬酸还原反应来制备含铬(III)的水溶液的方法 其特征在于,所述铬酸还原反应是在无机酸和有机酸中选择为不同于铬酸的酸的至少两种或多种酸的同时或相继存在下进行的。
    • 8. 发明授权
    • Chromium (III) carbonate and process for producing the same
    • 碳酸铬(III)及其制备方法
    • US08580221B2
    • 2013-11-12
    • US13062478
    • 2009-08-27
    • Hiroyuki KuwanoTomohiro BandaYasuyuki Tanaka
    • Hiroyuki KuwanoTomohiro BandaYasuyuki Tanaka
    • C01B31/24
    • C25D3/10C01G37/00C01P2006/62C01P2006/63C01P2006/64C23C2222/10C25D3/06
    • The chromium (III) carbonate of the present invention exhibits a light blue color in a solid state. This chromium (III) carbonate has an L* value of 50 to 70, an a* value of −4 to −2, and a b* value of −10 to −7, which are represented by the L*a*b* color system (JIS Z8729). This chromium (III) carbonate is preferably completely dissolved within 30 minutes when the chromium (III) carbonate is added, in an amount corresponding to a Cr content of 1 g, to 1 liter of an aqueous solution of hydrochloric acid having a pH of 0.2 at a temperature of 25° C. This chromium (III) carbonate is preferably obtained by contacting an aqueous solution of carbonate and an aqueous solution containing trivalent chromium at a pH of 6 to 12 under the condition of a reaction liquid temperature of 0° C. or more and less than 50° C. Also, preferably, after production of the chromium (III) carbonate, filtration is performed, and the chromium (III) carbonate is washed with water until the conductivity of the filtrate is 5 mS/cm or less.
    • 本发明的碳酸铬(III)表现出固态的浅蓝色。 该碳酸铬(III)的L *值为50〜70,a *值为-4〜-2,ab *为-10〜-7,由L * a * b *颜色 系统(JIS Z8729)。 当碳酸铬(III)以相当于Cr含量的1g的量添加碳酸铬(III)至1升pH为0.2的盐酸水溶液时,优选在30分钟内完全溶解该碳酸铬(III) 该温度为25℃。这种碳酸铬(III)优选通过在反应液温度为0℃的条件下使碳酸盐水溶液和含有三价铬的水溶液在6至12的pH下接触 以上且小于50℃。此外,优选在碳酸铬(III)的制造之后,进行过滤,并用水洗涤碳酸铬(III),直至滤液的电导率为5mS / cm 或更少。