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    • 1. 发明授权
    • Method for preparing azide photo-initiators
    • 叠氮化物光引发剂的制备方法
    • US06313314B1
    • 2001-11-06
    • US09634466
    • 2000-08-07
    • Kung-Lung ChengShu-Chen LinWoan-Shiow TzengSe-Tsun Hong
    • Kung-Lung ChengShu-Chen LinWoan-Shiow TzengSe-Tsun Hong
    • C07D207452
    • C07D207/452
    • The present invention provides a novel method for the preparation of N-azidosulfonyl-arylimides, which are known as photo-initiators. At the outset, substitution reaction of 4-acetamidobenzenesulfonyl halide with MN3 (M denotes hydrogen or alkaline metal) provides the corresponding azide. After de-protection to remove the actyl group, aminoarylsulfonyl azide is extracted with organic solvent, and the extract is directly used for addition reaction with maleic anhydride without concentration. Finally, end products are obtained by dehydration of the addition products using acetic anhydride/metal acetate, followed by re-crystallization in alcohol solvent. The end products are obtained in purer form and greater yield than that in conventional methods.
    • 本发明提供了一种制备N-叠氮基磺酰基 - 芳基酰亚胺的新方法,其被称为光引发剂。 首先,4-乙酰氨基苯磺酰卤与MN3的取代反应(M表示氢或碱金属)提供相应的叠氮化物。 脱保护后除去actyl基团,氨基芳基磺酰基叠氮化物用有机溶剂萃取,提取物直接用于马来酸酐的加成反应而不浓缩。 最后,通过使用乙酸酐/金属乙酸酯脱水加成产物,然后在醇溶剂中重结晶获得最终产物。 与常规方法相比,最终产品以更纯的形式获得并且产率更高。
    • 3. 发明授权
    • Process for preparing phenolepoxy resins in the absence of an aqueous
phase
    • 在没有水相的情况下制备苯酚酚醛树脂的方法
    • US5844062A
    • 1998-12-01
    • US841728
    • 1997-04-29
    • Kung-Lung ChengWoan-Shiow TzengShu-Chen Lin
    • Kung-Lung ChengWoan-Shiow TzengShu-Chen Lin
    • C07D303/22C07D303/24C08G59/24C08G59/32H05K1/03C08G59/06C08G59/08
    • C07D303/22C07D303/24C08G59/245C08G59/3218H05K1/0326
    • A process for preparing phenolepoxy resin represented by the following formula: ##STR1## wherein: (a) R.sup.1, R.sup.2, R.sup.3, and R.sup.4, which can be the same or different, are hydrogen, C.sub.1 to C.sub.6 alkyl groups, C.sub.6 to C.sub.10 aromatic groups, or C.sub.1 to C.sub.6 alkyl group-substituted C.sub.6 to C.sub.10 aromatic groups; (b) R.sup.5 and R.sup.6, which can be the same or different, are hydrogen, C.sub.1 to C.sub.6 alkyl groups, C.sub.6 to C.sub.10 aromatic groups, or C.sub.1 to C.sub.6 alkyl group-substituted C.sub.6 to C.sub.10 aromatic groups; ##STR2## (c) R.sup.7 is hydrogen, C.sub.1 to C.sub.6 alkyl groups, C.sub.6 to C.sub.10 aromatic groups, or C.sub.1 to C.sub.6 alkyl group-substituted C.sub.6 to C.sub.10 aromatic groups; (d) R.sup.8 and R.sup.9, which can be the same of different, are hydrogen, C.sub.1 to C.sub.6 alkyl groups, C.sub.6 to C.sub.10 aromatic groups, or C.sub.1 to C.sub.6 alkyl group-substituted C.sub.6 to C.sub.10 aromatic groups; and (e) n is an integer of 0 or 1. The phenolepoxy resin can be advantageously used in making packaging materials for ICs, as a substrate additive for printed circuit boards, and as adhesive for the electronic industry. The process includes the steps of preparing a reaction medium which contains only polyphenol, epihalohydrinl and an imidazole catalyst, and then causing the reaction medium to react in the absence of an aqueous phase.
    • 一种制备由下式表示的苯氧基树脂的方法:其中:(a)可以相同或不同的R 1,R 2,R 3和R 4为氢,C 1至C 6烷基,C 6至C 10芳族 或C 1〜C 6烷基取代的C 6〜C 10芳香族基团; (b)R5和R6可以相同或不同,为氢,C1至C6烷基,C6至C10芳族基团或C1至C6烷基取代的C6至C10芳族基团; (c)R7是氢,C1至C6烷基,C6至C10芳族基团或C1至C6烷基取代的C6至C10芳族基团; (d)可以相同不同的R 8和R 9为氢,C 1至C 6烷基,C 6至C 10芳族基团或C 1至C 6烷基取代的C 6至C 10芳族基团; 和(e)n为0或1的整数。苯酚环氧树脂可以有利地用于制造用于IC的包装材料,作为印刷电路板的基材添加剂和作为电子工业的粘合剂。 该方法包括制备仅含有多酚,表卤代醇和咪唑催化剂的反应介质,然后使反应介质在不存在水相的情况下反应的步骤。