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    • 4. 发明授权
    • 6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides
    • 具有至少两个不对称取代的碳原子的6-取代的2,4-二氨基-1,3,5-三嗪衍生物,其制备及其作为除草剂的用途
    • US06358886B1
    • 2002-03-19
    • US09623612
    • 2000-11-03
    • Hans-Jochem RiebelStefan LehrKatharina VoigtMarkus DollingerMark Wilhelm DrewesIngo WetcholowskyRandy Allen MyersYukiyoshi WatanabeToshio Goto
    • Hans-Jochem RiebelStefan LehrKatharina VoigtMarkus DollingerMark Wilhelm DrewesIngo WetcholowskyRandy Allen MyersYukiyoshi WatanabeToshio Goto
    • C07D25118
    • C07D405/12A01N43/68C07D251/48C07D409/12
    • The invention relates to novel substituted optically active aminotriazines having at least two asymmetrically substituted carbon atoms of the formula (I), in which A represents a single bond or represents in each case straight-chain or branched alkanediyl or oxaalkanediyl having in each case up to 6 carbon atoms, Z represents certain carbocyclic or heterocyclic radicals and the substituents R1, R2, R3, R4 and Y are as defined in the description,  with the proviso that in each individual case R2, R3 and Y are different from one another and that the substituents at the two carbon atoms to which R2 and R3 or R4 are attached are configured as follows: (a) R configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“R,R-diastereomers”), (b) R configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“R,S-diastereomers”), (c) S configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“S,R-diastereomers”), (d) S configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“S,S-diastereomers”), (e) R configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“R,racdiastereomers”), (f) S configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“S,rac-diastereomers”), and to a process for preparing the compounds of the formula (I) and to their use as herbicides.
    • 本发明涉及具有式(I)的至少两个不对称取代的碳原子的新的取代的光学活性氨基三嗪,其中A表示单键或表示在每种情况下为直链或支链烷二基或氧杂烷二基,在每种情况下最多为6 碳原子,Z表示某些碳环或杂环基团,并且取代基R 1,R 2,R 3,R 4和Y如说明书中所定义,条件是在各个别情况下,R 2,R 3和Y彼此不同, R2和R3或R4连接的两个碳原子上的取代基配置如下:(a)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的R构型(“ R,R非对映异构体“),(b)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的S构型(”R,S-非对映异构体“),(c)S 配置在碳ato m与R 2相连的碳原子上的R构型(“S,R-非对映异构体”),(d)在R2和R3所连接的碳原子上的S构型, R 4连接的碳原子(“S,S-非对映异构体”),(e)R 2和R 3所连接的碳原子上的R构型,R 4连接的碳原子上的外消旋构型(“R” 外消旋异构体“),(f)R 2和R 3所连接的碳原子上的S构型以及与R4连接的碳原子上的外消旋构型(”S,外消旋 - 非对映体“),以及制备该化合物的方法 的式(I)和它们作为除草剂的用途。
    • 7. 发明授权
    • Substituted benzoylpyrazoles as herbicides
    • 取代的苯甲酰基吡唑作为除草剂
    • US06746989B1
    • 2004-06-08
    • US09937631
    • 2001-09-26
    • Klaus-Helmut MüllerStefan LehrOtto SchallnerHans-Georg SchwarzHeinz-Jürgen WroblowskyMark Wilhelm DrewesDieter FeuchtRolf PontzenIngo Wetcholowsky
    • Klaus-Helmut MüllerStefan LehrOtto SchallnerHans-Georg SchwarzHeinz-Jürgen WroblowskyMark Wilhelm DrewesDieter FeuchtRolf PontzenIngo Wetcholowsky
    • A01N43647
    • C07D401/10C07D403/10C07D413/10C07D417/10C07D471/04C07D487/04
    • The invention relates to novel substituted benzoylpyrazoles of the general formula (I), in which n represents the numbers 0, 1, 2 or 3, A represents a single bond or represents alkanediyl(alkylene), R1 represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, R2 represents hydrogen, cyano, carbamoyl, thiocarbamoyl, halogen, or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkoxycarbonyl or cycloalkyl, R3 represents hydrogen, nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, halogen, or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino or dialkylaminosulfonyl, R4 represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, halogen, or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino or dialkylaminosulfonyl, Y represents hydrogen or represents in each case optionally substituted alkyl, alkylcarbonyl, alkoxycarbonyl, alkylsulfonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkenyl, alkenylcarbonyl, alkenylsulfonyl, alkinyl, alkinylcarbonyl, cycloalkyl, cycloalkylcarbonyl, cycloalkylalkyl, phenylcarbonyl, phenylsulfonyl, phenylalkyl or phenylcarbonylalkyl, and Z represents an optionally substituted 4- to 12-membered saturated or unsaturated monocyclic or bicyclic heterocyclic grouping which contains 1 to 4 heteroatoms (up to 4 nitrogen atoms and optionally—alternatively or additionally—one oxygen atom or one sulfur atom, or an SO grouping or an SO2 grouping) and which additionally contains one to three oxo groups (C═O) and/or thioxo groups (C═S) as component of the heterocycle, and also to processes for their preparation and to their use as herbicides.
    • 本发明涉及通式(I)的新的取代的苯甲酰基吡唑,其中n代表数字0,1,2或3,A表示单键或表示烷二基(亚烷基),R 1表示在每种情况下任选取代 烷基,烯基,炔基或环烷基,R 2表示氢,氰基,氨基甲酰基,硫代氨基甲酰基,卤素,或在每种情况下表示任选取代的烷基,烷氧基,烷硫基,烷氧基羰基或环烷基,R 3表示氢,硝基,氰基 ,羧基,氨基甲酰基,硫代氨基甲酰基,卤素,或在每种情况下表示任选取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基氨基,二烷基氨基或二烷基氨基磺酰基,R 4表示硝基,氰基,羧基,氨基甲酰基,硫代氨基甲酰基,卤素或 在每种情况下表示任选取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基氨基,二烷基氨基或二烷基氨基磺酰基,Y表示氢或表示在任何情况下任选取代 烷基,烷基羰基,烷氧基羰基,烷基磺酰基,烷基氨基羰基,二烷基氨基羰基,烯基,烯基羰基,烯基磺酰基,炔基,烯基羰基,环烷基,环烷基羰基,环烷基烷基,苯基羰基,苯基磺酰基,苯基烷基或苯基羰基烷基,Z表示任选取代的4至12元饱和或不饱和 含有1至4个杂原子(最多4个氮原子,以及任选地或另外一个氧原子或一个硫原子,或一个SO基团或一个SO 2基团)的单环或双环杂环基团,并且另外含有一至三个氧代基 (C = O)和/或硫代基(C = S)作为杂环的组分,以及其制备方法及其作为除草剂的用途。