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    • 1. 发明授权
    • Color photographic light-sensitive material
    • US4351897A
    • 1982-09-28
    • US291886
    • 1981-08-11
    • Kozo AokiNobuo SetoYoshiharu YabukiMasakazu MorigakiNobuo FurutachiKotaro Nakamura
    • Kozo AokiNobuo SetoYoshiharu YabukiMasakazu MorigakiNobuo FurutachiKotaro Nakamura
    • G03C7/38C07D231/52C09B26/02G03C7/384G03C1/40
    • C07D231/52G03C7/384
    • A silver halide color photographic light-sensitive material is described comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) ##STR1## wherein Ar represents a phenyl group substituted with at least one substituent selected from a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; X represents a halogen atom or an alkoxy group; R.sub.1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R.sub.2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; R.sub.3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R.sub.2 and R.sub.3 represents an alkoxy group; m.sub.1 and m.sub.2 each represents an integer from 1 to 4; R.sub.4 represents an alkyl group or an aryl group; R.sub.5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m.sub.1, m.sub.2 and n each is 2 or more, each R.sub.1, R.sub.3 and R.sub.5 may be the same or different.The color photographic light-sensitive material containing a 2-equivalent magenta color image-forming coupler as described above has various advantages, for example, in that the dye formation efficiency in the color development step is high, the photographic properties are not influenced by variations in the pH of the color development bath, and the color images formed are fast to heat or light.
    • 2. 发明授权
    • Silver halide color photographic light-sensitive material containing
stabilizer
    • 卤化银彩色摄影感光材料含稳定剂
    • US4559297A
    • 1985-12-17
    • US699091
    • 1985-02-07
    • Nobuo SetoNobuo FurutachiMasakazu MorigakiKiyoshi Nakazyo
    • Nobuo SetoNobuo FurutachiMasakazu MorigakiKiyoshi Nakazyo
    • C07F7/08G03C7/392G03C7/26
    • G03C7/39288C07F7/0812C07F7/0818
    • A silver halide photographic light-sensitive material is described, the material comprising a support having thereon at least one photographic layer containing at least one compound represented by formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, ##STR2## a substituted or unsubstituted silyl group, a substituted or unsubstituted phosphoric acid group, or a divalent group derived from the above-described groups which forms a ring together with the oxygen atom linking to --R and the carbon atom which is in the ortho-position to --O--R and to which ##STR3## is not bonded; R.sub.1, R.sub.2 and R.sub.3 which may be the same or different each represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group or a substituent thereof; Q represents an atomic group necessary to form a substituted or unsubstituted aromatic ring; R.sub.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a cycloamino group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group or a substituent thereof; and R.sub.5 represents an H atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group or a substituent thereof.
    • 描述了一种卤化银照相感光材料,该材料包括其上具有至少一个含有至少一种由式(I)表示的化合物的照相层的载体:其中R表示氢原子,取代的 或未取代的烷基,取代或未取代的烯基,取代或未取代的环烷基,取代或未取代的芳基,取代或未取代的杂环基,取代或未取代的甲硅烷基,取代或未取代的磷酸基 或衍生自上述基团的二价基团,其与连接到-R的氧原子和与-OR邻位并且未键合的碳原子一起形成环; 可以相同或不同的R 1,R 2和R 3表示氢原子,烷基,烯基,环烷基,芳烷基,芳基或其取代基; Q表示形成取代或未取代的芳环所必需的原子团; R4表示氢原子,烷基,环烷基,烯基,芳基,烷氧基,芳氧基,氨基,环氨基,烷硫基,芳硫基,酰基, 烷氧基羰基或其取代基; R5代表H原子,烷基,环烷基,烯基,芳基或取代基。
    • 3. 发明授权
    • Silver halide color photographic materials containing image stabilizer
and anti-staining agent and color photographs containing the same
    • 含有图像稳定剂和防污染剂的卤化银彩色照相材料和含有相同的彩色照片
    • US5212055A
    • 1993-05-18
    • US553839
    • 1990-07-18
    • Masakazu MorigakiNobuo SetoKozo Aoki
    • Masakazu MorigakiNobuo SetoKozo Aoki
    • G03C7/26G03C7/30G03C7/38G03C7/392
    • G03C7/301G03C7/38
    • A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising a dispersion of silver halide grains in a binder, wherein the silver halide emulsion layer contains (a) at least one coupler represented by formula (I), (b) at least one compound represented by the formula (II), and (c) at least one compound represented by formula (III), and the photographic material contains (d) at least one compound represented by formulae (IV), (V) or (VI): ##STR1## wherein R, Y, Za, Zb and Zc each is as defined in the specification; ##STR2## wherein R.sub.1, R.sub.2, R.sub.5 and R.sub.6, and R.sub.7 each is as defined in the specification ##STR3## wherein R.sub.11, R.sub.12 and R.sub.13, R.sub.14, R.sub.15, R.sub.16 and R.sub.17 each is as defined in the specification; ##STR4## wherein R.sub.21, R.sub.22 A, B, X, Y.sub.1 and n each is as defined in the specification; andR.sub.30 --Z (VI)R.sub.30 and Z is as defined in the specification; and a photograph containing (i) a magenta dye derived from the magenta coupler represented by formula (I), (ii) a compound represented by formula (II), a compound represented by formula (III), and at least one compound represented by formula (IV), (V) or (VI).
    • 一种卤化银彩色照相材料,其包含其上具有至少一个感光卤化银乳剂层的载体,所述感光卤化银乳剂层包括在粘合剂中的卤化银颗粒分散体,其中所述卤化银乳剂层含有(a)至少一种由式 I),(b)至少一种由式(II)表示的化合物和(c)至少一种由式(III)表示的化合物,并且照相材料含有(d)至少一种由式(IV)表示的化合物 ),(V)或(VI):其中R,Y,Za,Zb和Zc各自如说明书中所定义; (II)其中R 1,R 2,R 5和R 6以及R 7各自如说明书中所定义,其中R 11,R 12和R 13,R 14,R 15,R 16和R 17各自如 规范; (IV)其中R21,R22A,B,X,Y1和n各自如说明书中所定义; 和R30-Z(VI)R30和Z如说明书中所定义; 和(i)由式(I)表示的品红色成色剂衍生的品红色染料的染色照片,(ii)由式(II)表示的化合物,式(III)表示的化合物和至少一种由 式(IV),(V)或(VI)。
    • 5. 发明授权
    • Method for preparing magenta couplers having thioether groups
    • 制备具有硫醚基团的品红成色剂的方法
    • US4293691A
    • 1981-10-06
    • US65407
    • 1979-08-10
    • Nobuo FurutachiNobuo Seto
    • Nobuo FurutachiNobuo Seto
    • G03C7/32C07C67/00C07C313/00C07C319/14C07C323/22C07C323/25C07C323/52C07D207/412C07D231/52C07D233/64C07D239/38C07D249/08C07D403/12C07D487/04C09B26/02C09B55/00G03C7/305C07D413/12C07D231/48C07D401/12
    • C07D231/52G03C7/30552
    • A method for preparing image-forming color couplers containing a thioether group at the coupling active position is disclosed which comprises reacting a compound of the formula A-H where A is a cyan, magenta or yellow coupler residue in which a hydrogen atom at the coupling off position is removed with a disulfide of the formula (IIa) or (IIb): ##STR1## where R is a straight chain, branched chain or cyclic alkyl group, a cyclic alkenyl group, or an aralkyl group or a ##STR2## group, B is Y, -D-Y or ##STR3## where D is an oxygen atom or >N--R.sub.4, R.sub.4 is a hydrogen atom, an alkyl group or an aryl group, Y is a straight chain, branched chain or cyclic alkyl group, a straight chain, branched chain or cyclic alkenyl group, an aralkyl group, an aryl group, or a heterocyclic group, Q is a non-metallic atomic group necessary for completing a 5- or 6-membered nitrogen-containing heterocyclic group and R.sub.1, R.sub.2 and R.sub.3 each is a hydrogen atom, an alkyl group, a cycloalkyl group, or an aryl group, an R.sub.2 and R.sub.3 or R.sub.1 and R.sub.3 can combine to form a 5-, 6- or 7-membered nitrogen-containing heterocyclic ring, and X is a halogen atom.
    • 公开了一种用于制备在偶联活性位置含有硫醚基团的成像色成色剂的方法,其包括使式AH化合物与其中A是青色,品红色或黄色成色剂残余物反应,其中偶合离去位置处的氢原子 (IIa)或(IIb)的二硫化物除去:其中R是直链,支链或环状烷基,环状烯基或芳烷基(IIa) 基团或基团,B为Y,-DY或其中D为氧原子或> N-R4,R4为氢原子,烷基或芳基,Y为直链, 支链或环状烷基,直链,支链或环状烯基,芳烷基,芳基或杂环基,Q为完成5-或6-元氮所必需的非金属原子团 的R 1,R 2和R 3各自为氢原子,烷基,环烷基或 芳基,R2和R3或R1和R3可以结合形成5-,6-或7-元含氮杂环,X是卤素原子。