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1. 发明授权

US08242190B2 Crayon and process for producing the same 有权
标题翻译：蜡笔和制作相同的过程
公开(公告)号：US08242190B2
公开(公告)日：2012-08-14
申请号：US12439438
申请日：2007-08-29
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： B29C33/60 , B32B7/12 , B60C1/00 , C04B24/22 , C08G73/10 , C08J3/00 , C08K3/04 , C08K5/00 , C08K5/06 , C08K5/16 , C08K5/51 , C08K5/52 , C09D5/00 , C09D11/02 , C09D11/10 , C09D13/00 , C09K3/00 , D06P1/52
CPC分类号： C09D13/00
摘要： The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment.The process comprises: dissolving and dispersing a resin component, carbon black having a pH of less than 5.0 and an organic amine in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution, pouring the raw material solution into a molding container, and cooling and gelling the raw material solution.
摘要翻译：本发明提供一种使用亚苄基山梨糖醇胶凝剂与使用炭黑作为黑色颜料一起稳定地制备具有所需硬度的蜡笔的方法，而没有差的凝胶化。该方法包括：将树脂组分，pH小于5.0的炭黑和有机胺在有机溶剂中溶解和分散，将至少一种选自二亚苄基山梨糖醇，三亚苄基山梨醇及其衍生物的胶凝剂溶解在加热制成原料溶液，将原料溶液倒入成型容器中，冷却凝胶化原料溶液。

2. 发明申请

US20100016471A1 CRAYON AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：其生产方法及其制造方法
公开(公告)号：US20100016471A1
公开(公告)日：2010-01-21
申请号：US12439438
申请日：2007-08-29
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00
CPC分类号： C09D13/00
摘要： The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises:dissolving and dispersing a resin component, carbon black having a pH of less than 5.0 and an organic amine in an organic solvent,dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution,pouring the raw material solution into a molding container, andcooling and gelling the raw material solution.
摘要翻译：本发明提供一种使用亚苄基山梨糖醇胶凝剂与使用炭黑作为黑色颜料一起稳定地制备具有所需硬度的蜡笔的方法，而没有差的凝胶化。该方法包括：将树脂组分，pH小于5.0的炭黑和有机胺在有机溶剂中溶解和分散，将至少一种选自二亚苄基山梨糖醇，三亚苄基山梨醇及其衍生物的胶凝剂溶解在加热制成原料溶液，将原料溶液倒入成型容器中，冷却凝胶化原料溶液。

3. 发明申请

US20090326096A1 CRAYON AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：其生产方法及其制造方法
公开(公告)号：US20090326096A1
公开(公告)日：2009-12-31
申请号：US12439455
申请日：2007-08-29
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00 , B29C39/02
CPC分类号： C09D13/00
摘要： The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises:dissolving and dispersing a resin component and carbon black having a pH of not less than 5.0 in an organic solvent,dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution,pouring the raw material solution into a molding container, andcooling and gelling the raw material solution.
摘要翻译：本发明提供一种使用亚苄基山梨糖醇胶凝剂与使用炭黑作为黑色颜料一起稳定地制备具有所需硬度的蜡笔的方法，而没有差的凝胶化。该方法包括：在有机溶剂中溶解和分散pH为不低于5.0的树脂组分和炭黑，将至少一种选自二亚苄基山梨醇，三亚苄基山梨糖醇及其衍生物的胶凝剂溶解在所得的下面加热以制备原料溶液，将原料溶液倒入模塑容器中，并冷却和胶凝原料溶液。

4. 发明授权

US08431632B2 Crayon 有权
标题翻译：蜡笔
公开(公告)号：US08431632B2
公开(公告)日：2013-04-30
申请号：US12668294
申请日：2008-07-09
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00
CPC分类号： C09D13/00
摘要： The invention provides a crayon which comprises an alternative plasticizer in place of the conventional phthalate ester plasticizers and yet provides writings excellent in water resistance, the crayon comprising a colorant, a gelling agent, an organic solvent, a resin component, and a plasticizer, wherein the plasticizer is at least one selected from diisononyl adipate, acetyltributyl citrate, 1,2-cyclohexanedicarboxylic acid diisononyl, and alkylsulfonic acid phenyl ester and is contained in an amount of 1 to 20% by weight based on the crayon.
摘要翻译：本发明提供一种蜡笔，其包含代替常规邻苯二甲酸酯增塑剂的替代增塑剂，并提供耐水性优异的着色剂，包含着色剂的蜡笔，胶凝剂，有机溶剂，树脂组分和增塑剂，其中增塑剂为选自己二酸二异壬酯，柠檬酸乙酰基三丁酯，1,2-环己烷二羧酸二异壬基和烷基磺酸苯酯中的至少一种，其含量为蜡笔重量的1〜20％。

5. 发明申请

US20100273914A1 CRAYON 有权
标题翻译：蜡笔
公开(公告)号：US20100273914A1
公开(公告)日：2010-10-28
申请号：US12668294
申请日：2008-07-09
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00
CPC分类号： C09D13/00
摘要： The invention provides a crayon which comprises an alternative plasticizer in place of the conventional phthalate ester plasticizers and yet provides writings excellent in water resistance, the crayon comprising a colorant, a gelling agent, an organic solvent, a resin component, and a plasticizer, wherein the plasticizer is at least one selected from diisononyl adipate, acetyltributyl citrate, 1,2-cyclohexanedicarboxylic acid diisononyl, and alkylsulfonic acid phenyl ester and is contained in an amount of 1 to 20% by weight based on the crayon.
摘要翻译：本发明提供一种蜡笔，其包含代替常规邻苯二甲酸酯增塑剂的替代增塑剂，并提供耐水性优异的着色剂，包含着色剂的蜡笔，胶凝剂，有机溶剂，树脂组分和增塑剂，其中增塑剂为选自己二酸二异壬酯，柠檬酸乙酰基三丁酯，1,2-环己烷二羧酸二异壬基和烷基磺酸苯酯中的至少一种，其含量为蜡笔重量的1〜20％。

6. 发明申请

US20060210924A1 Photostorage solid drawing medium 失效
公开(公告)号：US20060210924A1
公开(公告)日：2006-09-21
申请号：US11399543
申请日：2006-04-07
申请人： Hidetoshi Fukuo , Masamitsu Takahashi , Kotaro Sumitomo
发明人： Hidetoshi Fukuo , Masamitsu Takahashi , Kotaro Sumitomo
IPC分类号： G03C1/00
CPC分类号： C09D11/17 , C09D7/41 , C09D11/50 , Y10S430/106
摘要： The invention provides a photostorage solid drawing medium comprising a solvent, a resin soluble in the solvent, a photostorage pigment and a gelling agent, wherein the photostorage pigment comprises a long afterglow fluorescent substance comprising an alkaline earth aluminosilicate as a matrix activated with a rare earth element wherein the alkaline earth element is at least one selected from the group consisting of strontium, calcium, magnesium and barium. The solvent used is a polar solvent, particularly a mixture of water and a water-soluble organic solvent, or at least one alcoholic solvent selected from the group consisting of glycols, glycol ethers, glycol ether esters and monovalent alcohols.

7. 发明授权

US08299143B2 Crayon and process for producing the same 有权
标题翻译：蜡笔和制作相同的过程
公开(公告)号：US08299143B2
公开(公告)日：2012-10-30
申请号：US12439455
申请日：2007-08-29
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00
CPC分类号： C09D13/00
摘要： The invention provides a process for producing a crayon having a desired hardness stably without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises: dissolving and dispersing a resin component and carbon black having a pH of not less than 5.0 in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating to prepare a raw material solution, pouring the raw material solution into a molding container, and cooling and gelling the raw material solution.
摘要翻译：本发明提供一种使用亚苄基山梨糖醇胶凝剂与使用炭黑作为黑色颜料一起稳定地制备具有所需硬度的蜡笔的方法，而没有差的凝胶化。该方法包括：在有机溶剂中溶解和分散pH为不低于5.0的树脂组分和炭黑，将至少一种选自二亚苄基山梨醇，三亚苄基山梨糖醇及其衍生物的胶凝剂溶解在所得的下面加热以制备原料溶液，将原料溶液倒入模塑容器中，并冷却和胶凝原料溶液。

8. 发明申请

US20090247668A1 PROCESS FOR PRODUCTION OF BLACK CRAYON 有权
标题翻译：黑色生产工艺
公开(公告)号：US20090247668A1
公开(公告)日：2009-10-01
申请号：US12373130
申请日：2007-07-09
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00
CPC分类号： B43K19/02 , B43K19/18 , C09D13/00
摘要： The invention provides a process for producing a crayon without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises dissolving and dispersing carbon black and a resin component in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating, pouring the obtained raw material solution into a molding container, and then cooling and solidifying the solution, wherein carbon black having an average particle diameter of primary particles of 20 to 100 nm is used as the carbon black.
摘要翻译：本发明提供一种使用亚苄基山梨醇胶凝剂与炭黑作为黑色颜料一起生产不具有差的凝胶化的蜡笔的方法。该方法包括将炭黑和树脂组分溶解并分散在有机溶剂中，在加热过程中将至少一种选自二亚苄基山梨醇，三亚苄基山梨醇及其衍生物的胶凝剂溶解在所得物中，将得到的原料溶液倒入成型容器，然后冷却固化溶液，其中使用平均粒径为20〜100nm的碳黑作为炭黑。

9. 发明申请

US20050197423A1 Photostorage solid drawing medium 审中-公开
标题翻译： Photostorage固体拉伸介质
公开(公告)号：US20050197423A1
公开(公告)日：2005-09-08
申请号：US10980336
申请日：2004-11-04
申请人： Hidetoshi Fukuo , Masamitsu Takahashi , Kotaro Sumitomo
发明人： Hidetoshi Fukuo , Masamitsu Takahashi , Kotaro Sumitomo
IPC分类号： C03C17/00 , C09D11/00 , C09K11/02 , C09K11/06
CPC分类号： C09D11/17 , B43K19/00 , C09D11/50 , C09K11/02 , C09K11/646
摘要： The invention provides a photostorage solid drawing medium comprising a solvent, a resin soluble in the solvent, a photostorage pigment and a gelling agent, wherein the photostorage pigment comprises a fluorescent substance represented by the general formula MO.Al2SiO8 wherein M is at least one metal element selected from the group consisting of strontium, calcium, magnesium and barium. The solvent used is a polar solvent, particularly a mixture of water and a water-soluble organic solvent, or at least one alcoholic solvent selected from the group consisting of glycols, glycol ethers, glycol ether esters and monovalent alcohols.
摘要翻译：本发明提供一种包含溶剂，可溶于溶剂的树脂，光存储颜料和胶凝剂的光存储固体拉伸介质，其中所述光存储颜料包含由通式MO表示的荧光物质。 > SiO 8其中M是选自锶，钙，镁和钡中的至少一种金属元素。使用的溶剂是极性溶剂，特别是水和水溶性有机溶剂的混合物，或至少一种选自二醇，二醇醚，二醇醚酯和一元醇的醇溶剂。

10. 发明授权

US07943684B2 Process for production of black crayon 有权
标题翻译：生产黑色蜡笔的过程
公开(公告)号：US07943684B2
公开(公告)日：2011-05-17
申请号：US12373130
申请日：2007-07-09
申请人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
发明人： Kotaro Sumitomo , Masamitsu Takahashi , Hidetoshi Fukuo
IPC分类号： C09D13/00
CPC分类号： B43K19/02 , B43K19/18 , C09D13/00
摘要： The invention provides a process for producing a crayon without poor gelation using a benzylidene sorbitol gelling agent together with the use of carbon black as a black pigment. The process comprises dissolving and dispersing carbon black and a resin component in an organic solvent, dissolving at least one gelling agent selected from the group consisting of dibenzylidene sorbitol, tribenzylidene sorbitol and derivatives thereof in the resultant under heating, pouring the obtained raw material solution into a molding container, and then cooling and solidifying the solution, wherein carbon black having an average particle diameter of primary particles of 20 to 100 nm is used as the carbon black.
摘要翻译：本发明提供一种使用亚苄基山梨醇胶凝剂与炭黑作为黑色颜料一起生产不具有差的凝胶化的蜡笔的方法。该方法包括将炭黑和树脂组分溶解并分散在有机溶剂中，在加热过程中将至少一种选自二亚苄基山梨醇，三亚苄基山梨醇及其衍生物的胶凝剂溶解在所得物中，将得到的原料溶液倒入成型容器，然后冷却固化溶液，其中使用平均粒径为20〜100nm的碳黑作为炭黑。

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