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1. 发明专利

JPS6172238A Silver halide color photosensitive material 失效
标题翻译：银黑色彩色感光材料
公开(公告)号：JPS6172238A
公开(公告)日：1986-04-14
申请号：JP19360984
申请日：1984-09-14
申请人： Konishiroku Photo Ind Co Ltd
发明人： IIJIMA TOSHIBUMI , KUMASHIRO KENJI , KASHIWAGI KANJI , HATTA KOICHI
IPC分类号： G03C7/26 , G03C7/20 , G03C7/38
CPC分类号： G03C7/3835
摘要： PURPOSE:To obtain a color photosensitive material having high sensitivity and resistance to harmful gases by incorporating a specific compd. into a green sensitive silver halide emulsion layer having high sensitivity. CONSTITUTION:The blue sensitive silver halide emulsion layer, green sensitive silver halide emulsion layer and red sensitive silver halide emulsion layer are provided on a substrate. Each of the sensitive silver halide emulsion layers consists of plural layers having different sensitivities. At least the red sensitive silver halide layer and green sensitive silver halide emulsion layer having the high sensitivity are provided between the blue sensitive silver halide emulsion layer having the high sensitivity and the blue sensitive silver halide emulsion layer having the sensitivity lower than the high blue sensitive silver halide emulsion layer. At least one of the compd. expressed by the formula is incorporated into the green sensitive silver halide emulsion layer having the high sensitivity.
摘要翻译：目的：通过结合特定的化合物获得具有高灵敏度和耐有害气体的彩色感光材料。成为具有高灵敏度的绿色感光卤化银乳剂层。构成：将蓝色感光卤化银乳剂层，绿色感光卤化银乳剂层和红色感光卤化银乳剂层提供在基材上。每个感光卤化银乳剂层由具有不同灵敏度的多层组成。在具有高灵敏度的蓝色感光卤化银乳剂层和敏感性低于蓝色敏感度的蓝色感光卤化银乳剂层之间，至少提供具有高灵敏度的红色感光卤化银层和绿色感光卤化银乳剂层卤化银乳剂层。至少有一个compd。由公式表示的是具有高灵敏度的绿色感光卤化银乳剂层。

2. 发明专利

JPS59180536A Silver halide photographic emulsion 失效
标题翻译：银色摄影乳液
公开(公告)号：JPS59180536A
公开(公告)日：1984-10-13
申请号：JP5672283
申请日：1983-03-30
申请人： Konishiroku Photo Ind Co Ltd
发明人： MIYAMOTO AKIHIKO , TAKIGUCHI HIDEKI , MATSUZAKA MASASHI , KASHIWAGI KANJI , NONAKA YOSHIYUKI
IPC分类号： G03C1/035 , G03C1/08 , G03C1/09
CPC分类号： G03C1/08
摘要： PURPOSE:To improve sensitivity without any photographic fog by having monodisperse silver halide particles consisting of silver iodobromide sensitized with selenium in the presence of a silver halide solvent. CONSTITUTION:A titled emulsion has monodisperse silver halide particles consisting substantially of silver iodobromide sensitized with selenium in the presence of a silver halide solvent. The monodisperse silver halide particles refer to the silver halide particles which are
摘要翻译：目的：通过在卤化银溶剂的存在下，通过使用由硒敏感的碘溴化银组成的单分散卤化银颗粒来提高灵敏度而不造成任何摄影。构成：在卤化银溶剂的存在下，标题乳液具有基本上由硒敏化的碘溴化银组成的单分散卤化银颗粒。单分散的卤化银颗粒是指在该系中<= 0.20的卤化银颗粒。当用电子显微镜照片观察时，其粒度分布的波动。卤化银颗粒是基本上由碘溴化银组成的卤化银颗粒，其中碘溴化银中碘溴化银的平均含量优选为0.5-15mol％，更优选为5-12mol％，余量为溴化银。

3. 发明专利

JPS61110136A Silver halide photographic sensitive material 失效
标题翻译：银色摄影感光材料
公开(公告)号：JPS61110136A
公开(公告)日：1986-05-28
申请号：JP23279084
申请日：1984-11-05
申请人： Konishiroku Photo Ind Co Ltd
发明人： KASHIWAGI KANJI , IIJIMA TOSHIBUMI , KUMASHIRO KENJI
IPC分类号： G03C7/26 , G03C7/388 , G03C7/392
CPC分类号： G03C7/39216 , G03C7/3885
摘要： PURPOSE:To improve dispersibility and colorability by providing a silver halide emulsion layer contg. the coupler dispersed by the high boiling org. solvent expressed by the specific chemical formula and the compd. expressed by the specific chemical formula on a base. CONSTITUTION:The silver halide emulsion layer contg. the coupler dispersed by using the high boiling org. solvent contg. the compd. expressed by the formu la II is provided on the base to form the silver halide photographic sensitive material. The compd. expressed by the formula I is requird to be incorporated into at least one layer of the above-mentioned silver halide emulsion layer. In the formula I and the formula II, R denotes an alkyl group, aryl group, etc., R denotes a univalent group, S denotes 0-3 integer, R denotes an alkyl group of 1-20C, R denotes an alkyl group and cycloalkyl group of 1-20C. The total sum of members of carbon atoms of the groups R and R is 4-24 and n is 0-3 integer.
摘要翻译：目的：通过提供卤化银乳剂层来提高分散性和着色性。该成色剂由高沸点组分分散。溶剂由特定化学式表示，由基础上的具体化学式表示。构成：卤化银乳剂层该成色剂通过使用高沸点组分分散。溶剂对比 compd。在底物上提供由形成物IIII表示以形成卤化银感光材料。 compd。由式I表示，必须掺入至少一层上述卤化银乳剂层中。在式I和式II中，R 1表示烷基，芳基等，R 2表示一价基团，S表示0-3整数，R 4表示1的烷基 -20℃，R 2表示1-20℃的烷基和环烷基。 R 3和R 4基团的碳原子的总和为4-24，n为0-3个整数。

4. 发明专利

JPS59185330A Silver halide emulsion 失效
标题翻译：银粉乳液
公开(公告)号：JPS59185330A
公开(公告)日：1984-10-20
申请号：JP6058383
申请日：1983-04-05
申请人： Konishiroku Photo Ind Co Ltd
发明人： MIYAMOTO AKIHIKO , TAKIGUCHI HIDEKI , MATSUZAKA MASASHI , KASHIWAGI KANJI , NONAKA YOSHIYUKI
IPC分类号： G03C1/035 , G03C1/09 , G03C1/18 , G03C1/28
CPC分类号： G03C1/28
摘要： PURPOSE:To enhance sensitivity, to control fogging, and to improve storage stability by using a monodispersed silver halide emulsion sensitized with Se and spectrally sensitized with a specified cyanine dye. CONSTITUTION:An emulsion contg. a monodispersed silver halide sensitized with Se is used and it is also spectrally sensitized with a cyanine dye represented by the fomula shown here in which Z1, Z2 are each an atomic group necessary to complete a thiazole, benzothiazole, naphthothiazole, oxazole, benzoxazole, or naphthoxazole ring; R1, R2 are each alkyl optionally substd. by OH, COOH, or SO2; X1 is an anion; (n) is 1 or 2, and when said dye forms an intramolecular salt, (n) is 1. The silver halide grains contained in this monodispersed emulsion are composed essentially of tetradecahedron and/or octahedron grains, and this emulsion is sensitized with gold and Se. The variation coefft. of grain diameter distribution of these monodispersed silver halide grains is controlled to about 0.15. The silver halide emulsion thus obtained is especially suitable for color photography, and since it is high in sensitivity and low in fog, it is preferably usable for many photosensitive materials. It is also good in storage stability.
摘要翻译：目的：通过使用用Se敏化的单分散的卤化银乳剂和用特定的花青染料进行光谱增感来提高灵敏度，控制起雾和提高储存稳定性。构成：乳液使用用Se敏化的单分散卤化银，并且还用由此处所示的花青染料进行光谱增感，其中Z1，Z2各自是完成噻唑，苯并噻唑，萘并噻唑，恶唑，苯并恶唑或必需的原子团萘恶唑环; R1，R2各自为烷基任选取代。通过OH，COOH或SO 2; X1 < - >是阴离子; （n）为1或2，当所述染料形成分子内盐时，（n）为1.这种单分散乳液中所含的卤化银颗粒基本上由十四面体和/或八面体颗粒组成，并且该乳液用金和Se。变异系。这些单分散卤化银颗粒的粒径分布控制在约0.15。这样获得的卤化银乳剂特别适用于彩色摄影，由于其灵敏度高，雾度低，因此优选可用于许多感光材料。它也具有良好的储存稳定性。

5. 发明专利

JPS59181337A Silver halide photosensitive material 失效
标题翻译：银红色光敏材料
公开(公告)号：JPS59181337A
公开(公告)日：1984-10-15
申请号：JP5764983
申请日：1983-03-31
申请人： Konishiroku Photo Ind Co Ltd
发明人： MIYAMOTO AKIHIKO , TAKIGUCHI HIDEKI , MATSUZAKA MASASHI , KASHIWAGI KANJI , NONAKA YOSHIYUKI
IPC分类号： G03C1/09 , G03C1/005 , G03C1/035 , G03C1/08 , G03C1/10
CPC分类号： G03C1/035 , G03C2001/03535 , G03C2001/03558 , G03C2001/0357 , G03C2200/06
摘要： PURPOSE:To form an image high in contrast with high sensitivity by aging a silver halide emulsion contg. AgI less concd. in shells than in cores in the presence of an instable type Se compd. CONSTITUTION:An emulsion high in sensitivity contains silver halide grains having 0-4mol% AgI content in shells and 1-15mol% AgI as the total content, and 10-300nm shell thickness. An instable type Se compd., such as tetramethylselenourea is added to this emulsion to age it and to prevent said core-shell type emulsion contg. AgI from lowering in contrast. Further, a solvent of silver halide, such as ammonium thiocyanate, is used in combination to age it chemically and to further enhance a sensitization effect, and moreover, one of phenols represented by the formula shown here in which R1-R5 are each H, halogen, CN, carbamoyl, or the like is incorporated to enhance its contrast to a higher degree. As a result, the obtained photosensitive material is high in sensitivity and gamma value, and low in fog.
摘要翻译：目的：通过老化卤化银乳剂来形成与高灵敏度相反的高图像。 AgI较少在壳中比在核心中存在不稳定型Se compd。构成：敏感性高的乳液含有卤化银颗粒，壳中含有0-4mol％AgI含量，总含量为1-15mol％AgI，外壳厚度为10-300nm。将不稳定型Se化合物如四甲基硒脲加入到该乳液中以使其老化并防止所述核 - 壳型乳液对比。 AgI降低对比度。此外，将卤化银如硫氰酸铵的溶剂组合使用以使其化学老化并进一步增强敏化作用，此外，由本文所示的式表示的酚之一，其中R 1 -R 5各自为H，卤素，CN，氨基甲酰基等，以提高其与较高程度的对比度。结果，所得到的感光材料的灵敏度和伽马值高，雾度低。

6. 发明专利

JPS59116648A Silver halide photosensitive material 失效
标题翻译：银红色光敏材料
公开(公告)号：JPS59116648A
公开(公告)日：1984-07-05
申请号：JP21906682
申请日：1982-12-13
申请人： Konishiroku Photo Ind Co Ltd
发明人： TAKIGUCHI HIDEKI , YAMADA YOSHITAKA , OOTANI HIROSHI , KASHIWAGI KANJI
IPC分类号： G03C1/28 , G03C1/29
CPC分类号： G03C1/29 , G03C1/28
摘要： PURPOSE: To reduce fog of a photosensitive material and to improve storage stability with time by incorporating a combination of at least one selected from each of two groups of specified sensitizing dyes in a monodisperse emulsion layer contg. AgI more in the cores than in the shells in order to sensitivity to the red region.
CONSTITUTION: Red sensitivity is enhanced and especially occurrence of fog even in storage at high temps. is reduced by incorporating in an emulsion layer a combination of at least one selected from each of two groups of sensitizing dyes represented by formula I andIIin which Z
1 WZ
8 are each H, halogen, OH, alkoxy, amino, acylamino, acyloxy, alkoxycarbonyl, alkoxycarbonylamino, aryl, alkyl, or CN, and Z
5 , Z
8 are also aryloxycarbonyl or sulfonyl, and (Z
1 and Z
2 ) or (Z
3 and Z
4 ), (Z
5 and Z
6 ) or (Z
7 and Z
8 ) may combine and form a ring; R
1 , R
4 are each H, alkyl, or aryl; R
2 , R
3 , R
5 WR
8 are each alkyl; Y
1 WY
3 are each S or Se, Y
3 is also N; when Y
3 is S or Se, it does not have R
5 ; X
1 , X
2 are each an anion; and (m), (n) are each 1 or 2, and when (m), (n) are each 1, an intramolecular salt is formed.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了减少感光材料的雾化，并通过将两组特定的增感染料中的每一组中选出的至少一种组合并入单分散乳剂层中，随时间改善储存稳定性。 AgI在核心上比在贝壳中更为敏感到红色区域。构成：增强红色灵敏度，特别是即使在高温下储存也会发生雾。通过在乳剂层中并入至少一种选自由式I表示的两组敏化染料和其中Z1-Z8各自为H，卤素，OH，烷氧基，氨基，酰氨基，酰氧基，烷氧基羰基，烷氧基羰基氨基，芳基，烷基或CN，Z5，Z8也是芳氧基羰基或磺酰基，（Z1和Z2）或（Z3和Z4），（Z5和Z6）或（Z7和Z8）可以结合形成环; R1，R4各自为H，烷基或芳基; R2，R3，R5-R8各自为烷基; Y1-Y3分别为S或Se，Y3也为N; 当Y3为S或Se时，不具有R5; X1，X2各自为阴离子; 和（m），（n）各自为1或2，当（m），（n）各为1时，形成分子内的盐。

7. 发明专利

JPS59116647A Silver halide photosensitive material 失效
标题翻译：银红色光敏材料
公开(公告)号：JPS59116647A
公开(公告)日：1984-07-05
申请号：JP21906582
申请日：1982-12-13
申请人： Konishiroku Photo Ind Co Ltd
发明人： TAKIGUCHI HIDEKI , YAMADA YOSHITAKA , OOTANI HIROSHI , KASHIWAGI KANJI
IPC分类号： G03C1/28 , G03C1/29
CPC分类号： G03C1/28 , G03C1/29
摘要： PURPOSE: To enhance storage stability and green sensitivity and to reduce fog by incorporating a combination of at least one selected from each of two groups of specified sensitizing dyes in an emulsion layer contg. monodisperse silver halide grains having a content of AgI higher in the cores than in the shells.
CONSTITUTION: A photosensitive material good in long term storage stability, etc. by adding to an emulsion layer a combination of at least one selected from each of two groups of compds. represented by formulae I and II in which Y
1 W Y
8 are each H, halogen, OH, alkoxy, amino, acylamino, acyloxy, alkoxycarbonyl, alkoxycarbonylamino, aryl, CN, or alkyl, and one of (Y
1 and Y
2 ) and (Y
3 and Y
4 ) may combine and form a naphthoxazole ring; (Y
5 and Y
6 ) or (Y
7 and Y
8 ) may combine and form a naphthoimidazole ring; R
1 , R
4 are each H or alkyl; R
2 , R
3 , R
5 WR
8 are each alkyl; X
1 , X
2 are each an anion; (m), (n) are each 1 or 2; and when (m) is 1, R
1 or R
2 can form an intramolecular salt, and when (n) is 1, one of R
5 WR
8 can form it.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了提高储存稳定性和绿色敏感性，并通过将两组指定的增感染料中的每一组中选出的至少一种结合到乳剂层中来减少雾化。单核分散的卤化银颗粒的核心中的AgI含量高于壳中的AgI含量。构成：通过向乳剂层添加选自两组化合物中的至少一种的组合的长期储存稳定性等的感光材料。其中Y 1 -Y 8各自为H，卤素，OH，烷氧基，氨基，酰氨基，酰氧基，烷氧基羰基，烷氧基羰基氨基，芳基，CN或烷基的式I和II表示，（Y1和Y2）和（Y3和 Y4）可以组合形成萘恶唑环; （Y5和Y6）或（Y7和Y8）可以组合并形成萘并咪唑环; R1，R4各自为H或烷基; R2，R3，R5-R8各自为烷基; X1，X2各自为阴离子; （m），（n）分别为1或2; 当（m）为1时，R1或R2可以形成分子内的盐，当（n）为1时，可以形成R5-R8中的一个。

8. 发明专利

JPS6180248A Silver halide color photographic sensitive material 失效
标题翻译：银色彩色摄影感光材料
公开(公告)号：JPS6180248A
公开(公告)日：1986-04-23
申请号：JP20206684
申请日：1984-09-28
申请人： Konishiroku Photo Ind Co Ltd
发明人： KUMASHIRO KENJI , IIJIMA TOSHIBUMI , AKAMATSU HIDEO , KASHIWAGI KANJI
IPC分类号： G03C7/20 , G03C7/30
CPC分类号： G03C7/3029 , G03C2007/3039 , G03C2200/11 , G03C2200/29 , G03C2200/53
摘要： PURPOSE:To obtain an image high in sensitivity by forming specified yellow filters near a blue sensitive silver halide layer and a green-sensitive silver halide layer and/or a red-sensitive silver halide layer in a photosensitive material composed of blue-, green-, and red-sensitive silver halide multilayers. CONSTITUTION:The high-sensitivity green-sensitive silver halide layer, thehigh- sensitivity red-sensitive silver halide layer, the low-sensitivity green-sensitive silver halide layer, and the blue sensitive silver halide layer are successively laminated on a suport. At that time, a yellow filter layer is formed near the blue-sensitive layer to control blue light absorption density to 0-0.6. Another yellow filter layer is formed near the green- and/or red-sensitive layer to control blue light absorption density to
摘要翻译：目的：通过在蓝色感光卤化银层附近形成规定的黄色滤光片和感光性感光卤化物层和/或红色感光型卤化银层，在感光材料中形成蓝色，绿色，和红敏卤化银多层。构成：高灵敏度的绿敏卤化银层，高灵敏度的感红卤化银层，低灵敏度的绿敏卤化银层和蓝色敏感的卤化银层依次层叠在一起。此时，在蓝色感光层附近形成黄色滤光层，以将蓝光吸收密度控制为0-0.6。在绿色和/或红色敏感层附近形成另一个黄色滤光层，以控制蓝色光吸收密度为<= 0.8，从而通过形成指定的黄色滤光片，以高灵敏度形成图像清晰度和色彩再现性良好的图像中间层吸收蓝光。

9. 发明专利

JPS59192241A Photosensitive silver halide material 失效
标题翻译：感光银卤素材料
公开(公告)号：JPS59192241A
公开(公告)日：1984-10-31
申请号：JP6718183
申请日：1983-04-15
申请人： Konishiroku Photo Ind Co Ltd
发明人： MIYAMOTO AKIHIKO , TAKIGUCHI HIDEKI , MATSUZAKA MASASHI , KASHIWAGI KANJI , NONAKA YOSHIYUKI
IPC分类号： G03C1/005 , G03C1/08
CPC分类号： G03C1/08 , G03C2001/03535 , G03C2001/03558 , G03C2001/0357 , G03C2200/06
摘要： PURPOSE:To provide high sensitivity and to prevent fog and contrast reduction by forming a silver halide emulsion layer contg. specified core/shell type silver halide particles on a support. CONSTITUTION:A silver halide emulsion layer contg. core/shell type silver halide particles sensitized with Se and S is formed on a support. Each of the core/shell type silver halide particles consists of two or more layers having different silver iodide contents, and the outermost layer is practically made of silver bromide. The core/shell type silver halide particles are prepd. by coating singly dispersible silver halide particles as a core part with a shell part. The preferred thickness of each shell is 0.01-0.3mum. The sensitizing effect and fog of said core/ shell type silver iodobromide emulsion sensitized with Se and S are controlled by adjusting the silver iodide content and the thickness of each shell.
摘要翻译：目的：提供高灵敏度，并通过形成卤化银乳剂层来防止雾化和对比度降低。指定的核/壳型卤化银颗粒在载体上。构成：卤化银乳剂层在载体上形成用Se和S敏化的核/壳型卤化银颗粒。每个核/壳型卤化银颗粒由具有不同碘化银含量的两层或更多层构成，最外层实际上由溴化银制成。核/壳型卤化银颗粒是制备的。通过用壳部分涂覆单分散卤化银颗粒作为核心部分。每个壳体的优选厚度为0.01-0.3μm。通过调节碘化银含量和每个壳的厚度来控制用Se和S敏化的所述核/壳型碘溴化银乳剂的敏化作用和雾化。

10. 发明专利

JPS6167852A Silver halide photosensitive material 失效
标题翻译：银红色光敏材料
公开(公告)号：JPS6167852A
公开(公告)日：1986-04-08
申请号：JP19034784
申请日：1984-09-11
申请人： Konishiroku Photo Ind Co Ltd
发明人： KASHIWAGI KANJI , KUMASHIRO KENJI , IIJIMA TOSHIBUMI
IPC分类号： G03C7/26 , G03C1/035 , G03C7/30 , G03C7/38 , G03C7/392
CPC分类号： G03C7/301
摘要： PURPOSE:To suppress efficiently fogging and to obtain satisfactory coloration with high sensitivity by providing a silver halide emulsion layer contg. a specific triazole type coupler onto a base and incorporating a specific compd. therein. CONSTITUTION:One layer of the silver halide emulsion layer contg. the 1H- pyrazolo[3,2-C]-S-triazole type coupler is formed on the base. At least one kind of the compd. expressed by the formula I, II or III (R -R , R -R , R , R are respectively H, alkyl. R is H, aliphat. group, aromatic group or heterocyclic group. R , R are respectively H, aliphat. group or heterocyclic group, including the case in which both R and R form a ring. R is H, alkyl, etc.) is incorporated preferably into the layer contg. the above-mentioned coupler or the layer adjacent thereto. The above-mentioned coupler is incorporated as the coupler for forming magenta color image into the photosensitive emulsion layer. The fogging is suppressed efficiently without causing inconveniences such as toe vanishing phenomenon and the deterioration in the performance as the photosensitive material. The satisfactory coloration of the triazole type coupler with the good performance and high sensitivity is made possible.
摘要翻译：目的：通过提供卤化银乳剂层来有效地抑制雾化并获得令人满意的高灵敏度着色。一种特定的三唑型成色剂在基料上并加入特定的化合物。其中。构成：一层卤化银乳剂层，在基体上形成1H-吡唑并[3,2-C] -S-三唑型偶合剂。至少有一种compd 由式I，II或III表示（R 2 -R 3，R 5 -R 7，R 10，R 11分别是H，烷基，R 4是 H，脂族基团，芳族基团或杂环基，R 8，R 9分别是H，脂族基或杂环基，包括R 8和R 9都形成环的情况 R 12是H，烷基等）优选结合到层中。上述耦合器或与其相邻的层。上述耦合器被并入用作形成品红色图像的感光乳剂层的耦合器。雾化被有效地抑制，而不会引起诸如脚趾消失现象和作为感光材料的性能劣化的不便。具有良好性能和高灵敏度的三唑型耦合器的令人满意的着色成为可能。

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