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1. 发明授权

US07238303B2 Phosphor and plasma display device 有权
标题翻译：荧光粉和等离子体显示装置
公开(公告)号：US07238303B2
公开(公告)日：2007-07-03
申请号：US10928516
申请日：2004-08-27
申请人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
发明人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
IPC分类号： C09K11/64 , C09K11/55 , H01J11/00 , H01J11/02
CPC分类号： C09K11/595 , C09K11/7734 , C09K11/778 , H01J1/63 , H01J2211/42
摘要： Phosphor and a plasma display device are provided whose deterioration in brightness of phosphors and a degree of change in chromaticity are alleviated and whose discharge characteristics are improved and that has excellent initial characteristics. Phosphor of the present invention is an alkaline-earth metal aluminate phosphor containing an element M (where M denotes at least one type of element selected from the group consisting of Nb, Ta, W and B). In this phosphor, a concentration of M in the vicinity of a surface of the phosphor particles is higher than the average concentration of M in the phosphor particles as a whole. A plasma display device according to the present invention includes a plasma display panel in which a plurality of discharge cells in one color or in a plurality of colors are arranged and phosphor layers are arranged so as to correspond to the discharge cells in colors and in which light is emitted by exciting the phosphor layers with ultraviolet rays. The phosphor layers include blue phosphor, where the afore-mentioned phosphor is used as the blue phosphor.
摘要翻译：提供了荧光体和等离子体显示装置，其荧光体的亮度劣化和色度变化程度得到缓解，其放电特性得到改善并具有优异的初始特性。本发明的荧光体是含有元素M的碱土金属铝酸盐荧光体（其中M表示选自Nb，Ta，W和B中的至少一种元素）。在该荧光体中，荧光体粒子表面附近的M浓度高于荧光体粒子的M的平均浓度。根据本发明的等离子体显示装置包括等离子体显示面板，其中排列有一种颜色或多种颜色的多个放电单元，并且荧光体层被布置为与颜色的放电单元相对应，并且其中通过用紫外线激发荧光体层来发射光。荧光体层包括蓝色荧光体，其中上述荧光体用作蓝色荧光体。

2. 发明申请

US20050062417A1 Phosphor and plasma display device 有权
标题翻译：荧光粉和等离子体显示装置
公开(公告)号：US20050062417A1
公开(公告)日：2005-03-24
申请号：US10928516
申请日：2004-08-27
申请人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
发明人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
IPC分类号： C09K11/08 , C09K11/55 , C09K11/59 , C09K11/64 , C09K11/67 , C09K11/68 , C09K11/77 , C09K11/80 , H01J1/62 , H01J1/63 , H01J11/00 , H01J11/22 , H01J11/24 , H01J11/34 , H01J11/42 , H01J63/04 , H01J17/49
CPC分类号： C09K11/595 , C09K11/7734 , C09K11/778 , H01J1/63 , H01J2211/42
摘要： Phosphor and a plasma display device are provided whose deterioration in brightness of phosphors and a degree of change in chromaticity are alleviated and whose discharge characteristics are improved and that has excellent initial characteristics. Phosphor of the present invention is an alkaline-earth metal aluminate phosphor containing an element M (where M denotes at least one type of element selected from the group consisting of Nb, Ta, W and B). In this phosphor, a concentration of M in the vicinity of a surface of the phosphor particles is higher than the average concentration of M in the phosphor particles as a whole. A plasma display device according to the present invention includes a plasma display panel in which a plurality of discharge cells in one color or in a plurality of colors are arranged and phosphor layers are arranged so as to correspond to the discharge cells in colors and in which light is emitted by exciting the phosphor layers with ultraviolet rays. The phosphor layers include blue phosphor, where the afore-mentioned phosphor is used as the blue phosphor.
摘要翻译：提供了荧光体和等离子体显示装置，其荧光体的亮度劣化和色度变化程度得到缓解，其放电特性得到改善并具有优异的初始特性。本发明的荧光体是含有元素M的碱土金属铝酸盐荧光体（其中M表示选自Nb，Ta，W和B中的至少一种元素）。在该荧光体中，荧光体粒子表面附近的M浓度高于荧光体粒子的M的平均浓度。根据本发明的等离子体显示装置包括等离子体显示面板，其中排列有一种颜色或多种颜色的多个放电单元，并且荧光体层被布置为与颜色的放电单元相对应，并且其中通过用紫外线激发荧光体层来发射光。荧光体层包括蓝色荧光体，其中上述荧光体用作蓝色荧光体。

3. 发明授权

US07285913B2 Plasma display device having blue phosphor layers with alkaline earth metal aluminate containing molybdenum or tungsten 有权
标题翻译：具有含有钼或钨的碱土金属铝酸盐的蓝色荧光体层的等离子体显示装置
公开(公告)号：US07285913B2
公开(公告)日：2007-10-23
申请号：US10927265
申请日：2004-08-26
申请人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
发明人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
IPC分类号： H01J17/49
CPC分类号： C09K11/595 , C09K11/7734 , C09K11/778 , H01J1/63 , H01J2211/42
摘要： A plasma display device is provided in which deterioration in brightness of phosphor layers can be avoided. The plasma display device includes a plasma display panel in which a plurality of discharge cells in one color or in a plurality of colors are arranged and phosphor layers are arranged so as to correspond to the discharge cells in colors and in which light is emitted by exciting the phosphor layers with ultraviolet rays. The phosphor layers include blue phosphor, the blue phosphor being composed of an alkaline-earth metal aluminate phosphor containing at least one element selected from the group consisting of Mo and W. The addition of hexavalent ions (Mo, W) in the blue phosphor allows the elimination of oxygen defects in the vicinity of a layer containing Ba atoms (Ba—O layer), the suppression of adsorption of water to the surface of the blue phosphor and the improvement of deterioration in brightness and a change in chromaticity for the respective phosphors and discharge characteristics.
摘要翻译：提供了一种能够避免荧光体层的亮度劣化的等离子体显示装置。等离子体显示装置包括等离子体显示面板，其中排列有一种颜色或多种颜色的多个放电单元，并且荧光体层被布置成与颜色对应于放电单元并且通过激发发光具有紫外线的荧光体层。荧光体层包括蓝色荧光体，蓝色荧光体由含有选自Mo和W中的至少一种元素的碱土金属铝酸盐荧光体构成。在蓝色荧光体中添加六价离子（Mo，W）允许消除含有Ba原子（Ba-O层）的层附近的氧缺陷，抑制水对蓝色荧光体表面的吸附以及改善亮度劣化和各种荧光体的色度变化和放电特性。

4. 发明申请

US20050046330A1 Plasma display device 有权
标题翻译：等离子显示装置
公开(公告)号：US20050046330A1
公开(公告)日：2005-03-03
申请号：US10927265
申请日：2004-08-26
申请人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
发明人： Kojiro Okuyama , Takehiro Zukawa , Masahiro Sakai , Seigo Shiraishi , Kazuhiko Sugimoto , Masaki Aoki , Junichi Hibino
IPC分类号： C09K11/08 , C09K11/55 , C09K11/59 , C09K11/64 , C09K11/67 , C09K11/68 , C09K11/77 , C09K11/80 , H01J1/62 , H01J1/63 , H01J11/00 , H01J11/22 , H01J11/24 , H01J11/34 , H01J11/42 , H01J63/04
CPC分类号： C09K11/595 , C09K11/7734 , C09K11/778 , H01J1/63 , H01J2211/42
摘要： A plasma display device is provided in which deterioration in brightness of phosphor layers can be avoided. The plasma display device includes a plasma display panel in which a plurality of discharge cells in one color or in a plurality of colors are arranged and phosphor layers are arranged so as to correspond to the discharge cells in colors and in which light is emitted by exciting the phosphor layers with ultraviolet rays. The phosphor layers include blue phosphor, the blue phosphor being composed of an alkaline-earth metal aluminate phosphor containing at least one element selected from the group consisting of Mo and W. The addition of hexavalent ions (Mo, W) in the blue phosphor allows the elimination of oxygen defects in the vicinity of a layer containing Ba atoms (Ba—O layer), the suppression of adsorption of water to the surface of the blue phosphor and the improvement of deterioration in brightness and a change in chromaticity for the respective phosphors and discharge characteristics.
摘要翻译：提供了一种能够避免荧光体层的亮度劣化的等离子体显示装置。等离子体显示装置包括等离子体显示面板，其中排列有一种颜色或多种颜色的多个放电单元，并且荧光体层被布置成与颜色相对应的放电单元并且通过激发发光具有紫外线的荧光体层。荧光体层包括蓝色荧光体，蓝色荧光体由含有选自Mo和W中的至少一种元素的碱土金属铝酸盐荧光体构成。在蓝色荧光体中添加六价离子（Mo，W）允许消除含有Ba原子（Ba-O层）的层附近的氧缺陷，抑制水对蓝色荧光体表面的吸附以及改善亮度劣化和各种荧光体的色度变化和放电特性。

5. 发明授权

US07486010B2 Plasma display device and method of preparing phosphor 失效
标题翻译：等离子体显示装置及其制备方法
公开(公告)号：US07486010B2
公开(公告)日：2009-02-03
申请号：US10517262
申请日：2004-02-18
申请人： Kazuhiko Sugimoto , Junichi Hibino , Masaki Aoki , Yoshinori Tanaka , Hiroshi Setoguchi
发明人： Kazuhiko Sugimoto , Junichi Hibino , Masaki Aoki , Yoshinori Tanaka , Hiroshi Setoguchi
IPC分类号： C09K11/08 , C09K11/64 , H01J17/49
CPC分类号： C09K11/7734 , H01J2211/42
摘要： In a phosphor whose host crystal is constituted of an oxide, a method of preparing the phosphor where the oxygen deficiencies in the phosphor are not many, and a plasma display device using the same are provided. After processes of weighing, mixing and filling powders of the phosphor, a process for firing in a reducing atmosphere and a process for firing in an oxidizing atmosphere after the last reducing atmosphere process are provided. In addition, a firing temperature in the oxidizing atmosphere process is not less than 600° C. and not more than 1000° C.
摘要翻译：在主晶体由氧化物构成的荧光体中，提供了荧光体中的氧缺乏量不多的荧光体的制造方法和使用该荧光体的等离子体显示装置。在进行称重，混合和填充荧光体粉末的工艺之后，提供在还原气氛中焙烧的方法和在最后的还原气氛处理之后在氧化气氛中烧制的方法。此外，氧化气氛中的烧成温度为600℃以上1000℃以下

6. 发明授权

US07439675B2 Plasma display panel having a magnesium oxide protective film and method for producing same 失效
标题翻译：具有氧化镁保护膜的等离子显示面板及其制造方法
公开(公告)号：US07439675B2
公开(公告)日：2008-10-21
申请号：US10518697
申请日：2004-04-21
申请人： Masaki Aoki , Yumi Kondo , Kazuhiko Sugimoto , Hiroshi Setoguchi , Junichi Hibino , Yoshinori Tanaka , Teppei Hosokawa
发明人： Masaki Aoki , Yumi Kondo , Kazuhiko Sugimoto , Hiroshi Setoguchi , Junichi Hibino , Yoshinori Tanaka , Teppei Hosokawa
IPC分类号： H01J17/49
CPC分类号： H01J11/40 , H01J9/02 , H01J11/12
摘要： The present invention provides a plasma display panel that suppresses discharge sustain voltage, and reduces brightness degradation of a phosphor. In the plasma display panel, as protective film (14) made of magnesium oxide (MgO) formed on dielectric glass layer (13), protective film (14) made of magnesium oxide (MgO) with oxide added with an electronegativity of 1.4 or higher, is formed to suppress impure gas adsorption by protective film (14), stabilizes discharge sustain voltage, and reduces brightness degradation.
摘要翻译：本发明提供一种等离子体显示面板，其抑制放电维持电压，降低荧光体的亮度劣化。在等离子体显示面板中，作为在电介质玻璃层（13）上形成的由氧化镁（MgO）构成的保护膜（14），由氧化镁（MgO）构成的保护膜（14）的电负性为1.4以上形成为通过保护膜（14）抑制不纯气体吸附，稳定放电维持电压，降低亮度劣化。

7. 发明授权

US07223987B2 Process for producing phosphor and plasma display panel unit 失效
标题翻译：磷光体和等离子体显示面板单元的制造方法
公开(公告)号：US07223987B2
公开(公告)日：2007-05-29
申请号：US10512416
申请日：2004-02-19
申请人： Kazuhiko Sugimoto , Junichi Hibino , Masaki Aoki , Yoshinori Tanaka , Hiroshi Setoguchi
发明人： Kazuhiko Sugimoto , Junichi Hibino , Masaki Aoki , Yoshinori Tanaka , Hiroshi Setoguchi
IPC分类号： C09K11/08 , G01J1/58 , G01N21/64 , H01J1/62
CPC分类号： H01J11/12 , C09K11/7734 , H01J11/42
摘要： Fine particles of a phosphor are weighed, mixed, and filled. Provided after this step are at least one step of firing the particles in a reducing atmosphere, and a step of pulverizing, dispersing, rinsing, drying and then treating the particles in an ozone atmosphere after the last step of treatment in the reducing atmosphere. This method recovers oxygen vacancy in the host crystal of the phosphor.
摘要翻译：称量，混合和填充磷光体的细颗粒。在该步骤之后，在还原气氛中进行至少一个烧成颗粒的步骤，以及在还原气氛中的最后一步处理之后，在臭氧气氛中粉碎，分散，漂洗，干燥，然后处理颗粒的步骤。该方法回收磷光体的主晶体中的氧空位。

8. 发明授权

US07192325B2 Process for producing phosphor and plasma display panel unit 失效
标题翻译：磷光体和等离子体显示面板单元的制造方法
公开(公告)号：US07192325B2
公开(公告)日：2007-03-20
申请号：US10512443
申请日：2004-02-19
申请人： Kazuhiko Sugimoto , Junichi Hibino , Masaki Aoki , Yoshinori Tanaka , Hiroshi Setoguchi
发明人： Kazuhiko Sugimoto , Junichi Hibino , Masaki Aoki , Yoshinori Tanaka , Hiroshi Setoguchi
IPC分类号： H01J9/00
CPC分类号： C09K11/7734 , H01J2211/42
摘要： Fine particles of a phosphor are weighed, mixed, and filled. Provided after this step are at least one step of firing the particles in a reducing atmosphere, and a step of pulverizing, dispersing, rinsing, drying and then performing oxygen ion implantation treatment for implanting oxygen ions and annealing the particles, after the step of treatment in the reducing atmosphere. This method recovers oxygen vacancy in the host crystal of the phosphor.
摘要翻译：称量，混合和填充磷光体的细颗粒。在该步骤之后提供在还原气氛中烧成颗粒的至少一个步骤，以及在处理步骤之后粉碎，分散，漂洗，干燥然后进行氧离子注入处理以注入氧离子和退火颗粒的步骤在还原气氛中。该方法回收磷光体的主晶体中的氧空位。

9. 发明申请

US20060072301A1 Plasma display and method for producing phosphor used therein 失效
标题翻译：等离子显示器及其中使用的荧光体的制造方法
公开(公告)号：US20060072301A1
公开(公告)日：2006-04-06
申请号：US10537156
申请日：2004-09-24
申请人： Yuichiro Miyamae , Masaki Aoki , Kazuhiko Sugimoto , Keiji Horikawa , Junichi Hibino , Tanaka Yoshinori , Setoguchi Hiroshi
发明人： Yuichiro Miyamae , Masaki Aoki , Kazuhiko Sugimoto , Keiji Horikawa , Junichi Hibino , Tanaka Yoshinori , Setoguchi Hiroshi
IPC分类号： F21V9/16
CPC分类号： C09K11/592 , C09K11/7734 , C09K11/7797 , H01J2211/42
摘要： The present invention relates to a plasma display device and to a method of producing a phosphor to be used for the device, that prevents the phosphor layer from deteriorating, and improves the luminance, life, and reliability, of a PDP. The plasma display device is equipped with a plasma display panel in which a plurality of discharge cells are arranged, phosphor layers (110R, 110G, 110B) in color corresponding to each discharge cell are disposed, and phosphor layers (110R, 110G, 110B) are excited by ultraviolet light to emit light. Green phosphor layer (110G) has a green phosphor including Zn2SiO4:Mn, the element ratio of zinc (Zn) to silicon (Si) at the proximity of its surface is 2/1, which is the stoichiometric ratio, and the layer is positively charged or zero-charged.
摘要翻译：等离子体显示装置及其制造方法技术领域本发明涉及等离子体显示装置及其制造方法，该方法是防止荧光体层劣化，提高PDP的亮度，寿命和可靠性。等离子体显示装置配备有配置有多个放电单元的等离子体显示面板，配置与各放电单元对应的颜色的荧光体层（110R，110G，110B），荧光体层（110R， 110G，110B）被紫外线激发以发光。绿色荧光体层（110G）具有包含Zn 2 SiO 4·Mn的绿色荧光体，锌（Zn）与硅（Si）的接近的元素比例其表面为化学计量比为2/1，层为正电荷或零电荷。

10. 发明申请

US20050212429A1 Plasma display panel and method for producing same 失效
标题翻译：等离子显示面板及其制造方法
公开(公告)号：US20050212429A1
公开(公告)日：2005-09-29
申请号：US10518697
申请日：2004-04-21
申请人： Masaki Aoki , Yumi Kondo , Kazuhiko Sugimoto , Hiroshi Setoguchi , Junichi Hibino , Yoshinori Tanaka , Teppeo Hosokawa
发明人： Masaki Aoki , Yumi Kondo , Kazuhiko Sugimoto , Hiroshi Setoguchi , Junichi Hibino , Yoshinori Tanaka , Teppeo Hosokawa
IPC分类号： H01J9/02 , H01J9/00 , H01J11/12 , H01J11/22 , H01J11/24 , H01J11/26 , H01J11/34 , H01J11/40 , H01J17/49
CPC分类号： H01J11/40 , H01J9/02 , H01J11/12
摘要： The preresent invention provides a plasma display panel that suppresses discharge sustain voltage, and reduces brightness degradation of a phosphor. In the plasma display panel, as protective film (14) made of magnesium oxide (MgO) formed on dielectric glass layer (13), protective film (14) made of magnesium oxide (MgO) with oxide added with an electronegativity of 1.4 or higher, is formed to suppress impure gas adsorption by protective film (14), stabilizes discharge sustain voltage, and reduces brightness degradation.
摘要翻译：本发明提供一种等离子体显示面板，其抑制放电维持电压，并且降低荧光体的亮度劣化。在等离子体显示面板中，作为在电介质玻璃层（13）上形成的由氧化镁（MgO）构成的保护膜（14），由氧化镁（MgO）构成的保护膜（14）的电负性为1.4以上形成为通过保护膜（14）抑制不纯气体吸附，稳定放电维持电压，降低亮度劣化。

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