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1. 发明申请

US20090234088A1 Hyperbranched Polymer and Method for Producing the Same 审中-公开
标题翻译：超支化聚合物及其制备方法
公开(公告)号：US20090234088A1
公开(公告)日：2009-09-17
申请号：US12227407
申请日：2007-05-18
申请人： Hiroki Takemoto , Masaaki Ozawa , Akihiro Tanaka , Kei Yasui , Koji Ishizu
发明人： Hiroki Takemoto , Masaaki Ozawa , Akihiro Tanaka , Kei Yasui , Koji Ishizu
IPC分类号： C08F222/08
CPC分类号： C08F212/14 , C08F8/04 , C08F8/12 , C08F8/44 , C08F222/08 , C08G83/005 , C08J3/28 , C08F222/06 , C08F212/12
摘要： Disclosed are a novel hyperbranched polymer which is optically and thermally stable and another novel hyperbranched polymer which is water-soluble, and optically and thermally stable. Also disclosed are methods for producing them. Specifically disclosed is a hyperbranched polymer obtained by reducing a molecular terminal (dithiocarbamate group) of a hyperbranched polymer, which is obtained through living-radical polymerization of a dithiocarbamate compound having a vinyl group structure and a maleic anhydride, to a hydrogen atom. Also disclosed is a hyperbranched polymer obtained by hydrolyzing the maleic anhydride unit of the above-obtained polymer, or a hyperbranched polymer obtained by hydrolyzing the maleic anhydride unit of the hyperbranched polymer obtained through living-radical polymerization of a dithiocarbamate compound having a vinyl group structure and a maleic anhydride.
摘要翻译：公开了一种光学和热稳定性的新型超支化聚合物，以及另一种新型的超支化聚合物，其是水溶性的，光学和热稳定的。还公开了制造它们的方法。具体公开了通过将通过具有乙烯基结构的二硫代氨基甲酸酯化合物和马来酸酐的自由基聚合得到的超支化聚合物的分子末端（二硫代氨基甲酸酯基）还原成氢原子得到的超支化聚合物。还公开了通过水解上述获得的聚合物的马来酸酐单元获得的超支化聚合物，或通过水解由具有乙烯基结构的二硫代氨基甲酸酯化合物的活性自由基聚合获得的超支化聚合物的马来酸酐单元获得的超支化聚合物和马来酸酐。

2. 发明申请

US20080139692A1 Hyperbranched Polymer and Production Method Thereof 审中-公开
标题翻译：超支化聚合物及其制备方法
公开(公告)号：US20080139692A1
公开(公告)日：2008-06-12
申请号：US11885320
申请日：2006-02-24
申请人： Koji Ishizu , Masaaki Ozawa , Akihiro Tanaka , Hiroki Takemoto , Kei Yasui
发明人： Koji Ishizu , Masaaki Ozawa , Akihiro Tanaka , Hiroki Takemoto , Kei Yasui
IPC分类号： C08F2/46 , C08F12/08 , C08F12/30
CPC分类号： C08F220/18 , C08F8/04 , C08F12/12 , C08F12/14 , C08F12/32 , C08G83/005
摘要： [Problems] To provide a novel hyperbranched polymer that is optically and thermally stable, and production method thereof. [Means for solving Problems] A hyperbranched polymer represented by Formula (1): and having a hydrogen atom or a thiol group at a molecular terminal thereof. The hyperbranched polymer can be produced by reducing a hyperbranched polymer having a dithiocarbamate group at a molecular terminal which is produced by living radical polymerization of a dithiocarbamate compound having a vinyl group structure, or by reacting the hyperbranched polymer having a dithiocarbamate group at a molecular terminal with a thiolation converting agent.
摘要翻译： [问题]提供光学和热稳定性的新型超支化聚合物及其制造方法。解决问题的手段由式（1）表示的超支化聚合物：在其分子末端具有氢原子或硫醇基。通过在分子末端还原具有二硫代氨基甲酸酯基的超支化聚合物，可以通过在具有乙烯基结构的二硫代氨基甲酸酯化合物的活性自由基聚合制备的反应中，或在分子末端使具有二硫代氨基甲酸酯基的超支化聚合物反应来制备超支化聚合物与硫醇转化剂。

3. 发明授权

US08153744B2 Hyperbranched polymer and process for production thereof 有权
标题翻译：超支化聚合物及其生产方法
公开(公告)号：US08153744B2
公开(公告)日：2012-04-10
申请号：US12310804
申请日：2007-09-04
申请人： Hiroki Takemoto , Masaaki Ozawa , Koji Ishizu
发明人： Hiroki Takemoto , Masaaki Ozawa , Koji Ishizu
IPC分类号： C08F212/08 , C08F28/02 , C08F2/46 , C08F212/06 , C08F28/00
CPC分类号： C08F20/38 , C08F2/38 , C08F2/48 , C08F212/14 , C08F220/38 , C08F2438/03 , C08L101/005
摘要： There is provided a novel hyperbranched polymer in which the refractive index is precisely controlled while retaining its hyperbranched structure, and a method for producing the hyperbranched polymer. Further, there is also provided an optically and thermally stable novel hyperbranched polymer in which the desired refractive index is precisely controlled, and a method for producing the hyperbranched polymer. The hyperbranched polymer has, as a branched structure, a repeating unit structure produced from two dithiocarbamate compounds each having a vinyl structure, at the polymerization initiation site having a vinyl structure. A specific example of the hyperbranched polymer can be produced by subjecting to a living radical polymerization N,N-diethyldithiocarbamylmethylstyrene in the presence of N,N-diethyldithiocarbamylethyl methacrylate.
摘要翻译：提供了一种新颖的超支化聚合物，其中折射率被精确地控制，同时保持其超支化结构，以及制备超支化聚合物的方法。此外，还提供了光学和热稳定的新型超支化聚合物，其中精确控制所需的折射率，以及制备超支化聚合物的方法。超支化聚合物作为支链结构具有由具有乙烯基结构的两个二硫代氨基甲酸酯化合物产生的重复单元结构，在聚合引发部位具有乙烯基结构。超支化聚合物的具体实例可以通过在N，N-二乙基二硫代氨基甲酰基乙基甲基丙烯酸酯的存在下进行活性自由基聚合N，N-二乙基二硫代氨基甲酰基苯乙烯来制备。

4. 发明申请

US20100240792A1 Hyperbranched Polymer and Method for Producing the Same 审中-公开
标题翻译：超支化聚合物及其制备方法
公开(公告)号：US20100240792A1
公开(公告)日：2010-09-23
申请号：US12308567
申请日：2007-06-13
申请人： Koji Ishizu , Masaaki Ozawa , Hiroki Takemoto
发明人： Koji Ishizu , Masaaki Ozawa , Hiroki Takemoto
IPC分类号： C08F2/48 , C08F228/02
CPC分类号： C08F220/26 , C08F12/30 , C08F212/14 , C08F220/06 , C08F220/32 , C08F2220/281 , C08F2220/325 , C08F2438/03 , C08G83/005 , C09D125/14
摘要： Disclosed is a novel hyperbranched polymer having a functional group in a molecular chain of a repeating unit. Also disclosed is a method for producing such a hyperbranched polymer. Specifically disclosed is a hyperbranched polymer having a repeating unit derived from a (meth)acrylate compound as a linear structure, while having a repeating unit derived from a dithiocarbamate compound having a vinyl group structure as a branched structure. This hyperbranched polymer can be obtained by holding a dithiocarbamate compound having a vinyl group structure and a (meth)acrylate compound together and subjecting them to a living radical polymerization.
摘要翻译：公开了一种在重复单元的分子链中具有官能团的新型超支化聚合物。还公开了制备这种超支化聚合物的方法。具体公开了具有衍生自（甲基）丙烯酸酯化合物的重复单元作为直链结构的超支化聚合物，同时具有衍生自具有乙烯基结构的二硫代氨基甲酸酯化合物作为支化结构的重复单元。这种超支化聚合物可以通过将具有乙烯基结构的二硫代氨基甲酸酯化合物和（甲基）丙烯酸酯化合物一起保持并进行活性自由基聚合而获得。

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