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    • 1. 发明授权
    • Salt and photoresist composition containing the same
    • 含有其的盐和光致抗蚀剂组合物
    • US08765351B2
    • 2014-07-01
    • US12946243
    • 2010-11-15
    • Koji IchikawaMasako SugiharaIsao Yoshida
    • Koji IchikawaMasako SugiharaIsao Yoshida
    • G03F7/00C07C309/19
    • C07D307/93G03F7/0045G03F7/0046G03F7/0397G03F7/2041
    • A salt represented by the formula (X): wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, L1 represents a C1-C17 divalent saturated hydrocarbon group in which one or more —CH2— can be replaced by —O— or —CO—, ring W1 represents a C4-C36 lactone ring, R3 is a C1-C6 alkyl group etc., t represents an integer of 0 to 2, Z+ represents an organic counter ion, and W10 represents a group represented by the formula (X-1): wherein L2 represents a single bond etc., ring W2 represents a C3-C36 saturated hydrocarbon ring in which one —CH2— is replaced by —CO— and in which one or more —CH2— can be replaced by —O— or —CO—, R1 represents a C1-C12 hydrocarbon group, R2 is a C1-C6 alkyl group etc., and s represents an integer of 0 to 2, or a group represented by the formula (X-2): wherein L3 represents a C1-C17 divalent saturated hydrocarbon group in which one or more —CH2— can be replaced by —O— or —CO—, ring W3 represents a C3-C36 saturated hydrocarbon ring, R4 is a hydroxyl group etc., R5 is a C1-C6 alkyl group etc., v represents an integer of 1 to 3, and w represents an integer of 0 to 2.
    • 由式(X)表示的盐:其中Q1和Q2各自独立地表示氟原子或C1-C6全氟烷基,L1表示C1-C17二价饱和烃基,其中一个或多个-CH 2 - 可以被 -O-或-CO-,环W1表示C4-C36内酯环,R3表示C1-C6烷基等,t表示0〜2的整数,Z +表示有机抗衡离子,W10表示 由式(X-1)表示:其中L2表示单键等,环W2表示其中一个-CH 2 - 被-CO-替代的C 3 -C 36饱和烃环,其中一个或多个-CH 2 - 可以被-O-或-CO-代替,R1表示C1-C12烃基,R2表示C1-C6烷基等,s表示0〜2的整数,或式( X-2):其中L3表示C1-C17二价饱和烃基,其中一个或多个-CH 2 - 可以被-O-或-CO-代替,环W3重复 呈现C3-C36饱和烃环,R4为羟基等,R5为C1-C6烷基等,v为1〜3的整数,w为0〜2的整数。
    • 4. 发明授权
    • Salt and photoresist composition containing the same
    • 含有其的盐和光致抗蚀剂组合物
    • US08354217B2
    • 2013-01-15
    • US12786799
    • 2010-05-25
    • Koji IchikawaMasako SugiharaTatsuro Masuyama
    • Koji IchikawaMasako SugiharaTatsuro Masuyama
    • G03F7/00G03F7/004G03F7/028G03F7/04
    • C07D307/80G03F7/0045G03F7/0046G03F7/0397
    • A salt represented by the formula (I-AA): wherein Q1 and Q2 each independently represent a fluorine atom or a C1-C4 perfluoroalkyl group, X1 represents a single bond etc., Y1 represents a C1-C36 aliphatic hydrocarbon group etc., A1 and A2 independently each represents a C1-C20 aliphatic hydrocarbon group etc., Ar1 represents a (m4+1)-valent C6-C20 aromatic hydrocarbon group which can have one or more substituents, B1 represents a single bond etc., m1 and m2 independently each represents an integer of 0 to 2, m3 represents an integer of 1 to 3, with the proviso that m1 plus m2 plus m3 equals 3, and m4 represents an integer of 1 to 3, and a photoresist composition comprising the salt represented by the formula (I-AA) and a resin comprising a structural unit having an acid-labile group and being insoluble or poorly soluble in an aqueous alkali solution but becoming soluble in an aqueous alkali solution by the action of an acid.
    • 由式(I-AA)表示的盐:其中Q1和Q2各自独立地表示氟原子或C1-C4全氟烷基,X1表示单键等,Y1表示C1-C36脂族烃基等, A1和A2各自独立地表示C1-C20脂族烃基等,Ar1表示可具有一个或多个取代基的(m4 + 1)价C6-C20芳族烃基,B1表示单键等,m1和 m2独立地表示0至2的整数,m3表示1至3的整数,条件是m1加上m2加m3等于3,m4表示1至3的整数,并且包含表示的盐的光致抗蚀剂组合物 通过式(I-AA)和包含具有酸不稳定基团的结构单元的树脂,并且在碱性水溶液中不溶或难溶,但通过酸作用而溶于碱水溶液中。