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1. 发明授权

US07981500B2 Carbon fiber reinforced prepreg of gas barrier properties, carbon fiber reinforced plastic and methods of producing the same 有权
标题翻译：阻燃性碳纤维增强预浸料，碳纤维增强塑料及其制造方法
公开(公告)号：US07981500B2
公开(公告)日：2011-07-19
申请号：US12741553
申请日：2008-10-27
申请人： Koichi Yonemoto , Takeo Ebina , Fujio Mizukami , Keiichi Okuyama , Shoji Kamiya
发明人： Koichi Yonemoto , Takeo Ebina , Fujio Mizukami , Keiichi Okuyama , Shoji Kamiya
IPC分类号： B32B27/04
CPC分类号： C08J5/24 , B32B5/16 , B32B5/26 , B32B5/30 , B32B27/12 , B32B27/18 , B32B27/281 , B32B27/283 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/38 , B32B27/40 , B32B27/42 , B32B2255/02 , B32B2255/26 , B32B2260/021 , B32B2260/025 , B32B2260/046 , B32B2262/106 , B32B2264/10 , B32B2307/50 , B32B2307/7242 , B32B2439/40 , B32B2605/00 , C08J5/042 , C08J5/10 , C08J2363/02 , Y10T156/10 , Y10T428/24994 , Y10T428/30
摘要： There are provided a carbon fiber reinforced prepreg of gas barrier properties comprising a sheet-like carbon fiber reinforcement and a matrix resin including therein a gas barrier layer having a clay mineral with a plate-like crystal structure unidirectionally aligned and densely laminated, and a carbon fiber reinforced plastic produced from the carbon fiber reinforced prepreg. Such prepreg is obtained by disposing a film material of gas barrier properties having a clay mineral with a plate-like crystal structure unidirectionally aligned and densely laminated, in at least one interlayer of a laminate of a carbon fiber reinforced prepreg comprising a sheet form carbon fiber reinforcement and a matrix resin; and then heating and/or pressurizing the laminate. The carbon fiber-reinforced composite material of the invention exhibits high gas barrier properties, and particularly hydrogen gas barrier properties.
摘要翻译：提供一种阻气性碳纤维增强预浸料，其包括片状碳纤维增强材料和基体树脂，其中包含具有单向排列和密集层压的板状晶体结构的粘土矿物的阻气层，碳由碳纤维增强预浸料生产的纤维增强塑料。这样的预浸料是通过将具有粘土矿物的薄膜材料在板状碳纤维的碳纤维增强预浸料的层叠体的至少一个中间层中配置而成的单向排列密集层叠而得到的。增强和基体树脂; 然后加热和/或加压层压体。本发明的碳纤维增强复合材料具有高阻气性，特别是氢气阻隔性。

2. 发明申请

US20100304145A1 CARBON FIBER REINFORCED PREPREG OF GAS BARRIER PROPERTIES, CARBON FIBER REINFORCED PLASTIC AND METHODS OF PRODUCING THE SAME 有权
标题翻译：碳纤维增强碳纤维增强型碳纤维增强塑料及其生产方法
公开(公告)号：US20100304145A1
公开(公告)日：2010-12-02
申请号：US12741553
申请日：2008-10-27
申请人： Koichi Yonemoto , Takeo Ebina , Fujio Mizukami , Keiichi Okuyama , Shoji Kamiya
发明人： Koichi Yonemoto , Takeo Ebina , Fujio Mizukami , Keiichi Okuyama , Shoji Kamiya
IPC分类号： C08J5/24 , B32B9/00 , B32B37/02 , B32B37/24 , B65H81/00 , B32B5/30
CPC分类号： C08J5/24 , B32B5/16 , B32B5/26 , B32B5/30 , B32B27/12 , B32B27/18 , B32B27/281 , B32B27/283 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/38 , B32B27/40 , B32B27/42 , B32B2255/02 , B32B2255/26 , B32B2260/021 , B32B2260/025 , B32B2260/046 , B32B2262/106 , B32B2264/10 , B32B2307/50 , B32B2307/7242 , B32B2439/40 , B32B2605/00 , C08J5/042 , C08J5/10 , C08J2363/02 , Y10T156/10 , Y10T428/24994 , Y10T428/30
摘要： There are provided a carbon fiber reinforced prepreg of gas barrier properties comprising a sheet-like carbon fiber reinforcement and a matrix resin including therein a gas barrier layer having a clay mineral with a plate-like crystal structure unidirectionally aligned and densely laminated, and a carbon fiber reinforced plastic produced from the carbon fiber reinforced prepreg. Such prepreg is obtained by disposing a film material of gas barrier properties having a clay mineral with a plate-like crystal structure unidirectionally aligned and densely laminated, in at least one interlayer of a laminate of a carbon fiber reinforced prepreg comprising a sheet form carbon fiber reinforcement and a matrix resin; and then heating and/or pressurizing the laminate. The carbon fiber-reinforced composite material of the invention exhibits high gas barrier properties, and particularly hydrogen gas barrier properties.
摘要翻译：提供一种阻气性碳纤维增强预浸料，其包括片状碳纤维增强材料和基体树脂，其中包含具有单向排列和密集层压的板状晶体结构的粘土矿物的阻气层，碳由碳纤维增强预浸料生产的纤维增强塑料。这样的预浸料是通过将具有粘土矿物的薄膜材料在板状碳纤维的碳纤维增强预浸料的层叠体的至少一个中间层中配置而成的单向排列密集层叠而得到的。增强和基体树脂; 然后加热和/或加压层压体。本发明的碳纤维增强复合材料具有高阻气性，特别是氢气阻隔性。

3. 发明申请

US20120145038A1 CLAY DISPERSION LIQUID, AND METHOD FOR PRODUCING THE SAME, CLAY FILM, AND METHOD FOR PRODUCING THE SAME, AND TRANSPARENT MATERIAL 审中-公开
标题翻译：粘土液体及其制造方法，粘土膜及其制造方法和透明材料
公开(公告)号：US20120145038A1
公开(公告)日：2012-06-14
申请号：US13391881
申请日：2010-08-24
申请人： Hajime Tsuda , Katsumi Motegi , Yusuke Takechi , Kazunori Kawasaki , Takeo Ebina , Fujio Mizukami
发明人： Hajime Tsuda , Katsumi Motegi , Yusuke Takechi , Kazunori Kawasaki , Takeo Ebina , Fujio Mizukami
IPC分类号： C09D1/00 , B28B13/02
CPC分类号： H01L51/0097 , C01B33/40 , H01L51/0096 , H01L51/5253 , Y02E10/549 , Y02P70/521
摘要： An object of the present invention is to provide a clay dispersion liquid which is capable of obtaining a clay film which realizes compatibility between heat resistance and water resistance, and a method for producing the same; a clay film and a transparent material, produced from the lay dispersion. The clay dispersion liquid of the present invention contains a liquid containing water as a main component, and a tetraphenylphosphonium-modified clay. The clay film and the transparent material of the present invention are obtained by applying the clay dispersion liquid on a surface of a supporting body to form a film.
摘要翻译：本发明的目的是提供一种能获得实现耐热性和耐水性之间的相容性的粘土膜的粘土分散液及其制造方法。一种粘土膜和一种透明材料，由敷料分散体制成。本发明的粘土分散液含有以水为主要成分的液体和四苯基鏻改性粘土。本发明的粘土膜和透明材料通过将粘土分散液涂布在支撑体的表面上以形成膜而获得。

4. 发明申请

US20070027248A1 Clay film 有权
标题翻译：粘土电影
公开(公告)号：US20070027248A1
公开(公告)日：2007-02-01
申请号：US10571107
申请日：2004-09-08
申请人： Takeo Ebina , Fujio Mizukami
发明人： Takeo Ebina , Fujio Mizukami
IPC分类号： C08K9/04
CPC分类号： B29D7/01 , B29K2105/16 , C01B33/40 , Y10T428/1331 , Y10T428/1379 , Y10T428/1383
摘要： The present invention provides a clay film with excellent flexibility, whose main component is natural clay or synthetic clay, and in which there is uniform orientation in the clay particle layer, and relates to a novel clay film that has enough mechanical strength to be used as a self-supporting film, and has a structure in which layers of clay particles are highly oriented, and in which the main constituent component of the clay film is mica, vermiculite, montmorillonite, iron montmorillonite, beidellite, saponite, hectorite, stevensite, or nontronite, and which has excellent flexibility, undergoes no structural change at high temperatures of 250° C. and up to 600° C., contains no pinholes, and has a gas permeation coefficient of less than 3.2×10−11 cm2s−1cmHg−1 at room temperature for helium, hydrogen, oxygen, nitrogen, or air.
摘要翻译：本发明提供了一种具有优良柔性的粘土膜，其主要成分是天然粘土或合成粘土，其中在粘土颗粒层中具有均匀的取向，并且涉及一种具有足够机械强度的新型粘土膜作为自支撑膜，并且具有粘土颗粒层高度取向的结构，并且其中粘土膜的主要构成成分是云母，蛭石，蒙脱石，铁蒙脱石，贝得石，皂石，锂蒙脱石，硬脂酸盐或并且具有优异的柔性，在250℃和高达600℃的高温下不会发生结构变化，不含针孔，并且气体透过系数小于3.2×10 -6〜在氦气，氢气，氧气，氮气或空气中，在室温下，对于氦气，氢气，氧气，氮气或空气，在室温下进行冷却至0℃至0℃。

5. 发明申请

US20090141230A1 Clay Thin Film Substrate, Clay Thin Film Substrate with Electrode, and Display Device Using the Same 有权
标题翻译：粘土薄膜基板，带电极的粘土薄膜基板及使用其的显示装置
公开(公告)号：US20090141230A1
公开(公告)日：2009-06-04
申请号：US12067666
申请日：2006-09-19
申请人： Tomohito Inoue , Hajime Tsuda , Katsumi Motegi , Takeo Ebina , Fujio Mizukami
发明人： Tomohito Inoue , Hajime Tsuda , Katsumi Motegi , Takeo Ebina , Fujio Mizukami
IPC分类号： G02F1/1333 , C09K19/00 , H01J1/62 , H05K1/03
CPC分类号： H01L51/52 , C04B35/597 , C04B41/009 , C04B41/5035 , C04B41/52 , C04B2111/00275 , C04B2111/28 , C04B2235/963 , C23C16/401 , G02F1/133305 , G02F2001/133302 , H01L51/0097 , H01L51/5256 , H01L51/5262 , Y02E10/549 , Y10T428/1055 , Y10T428/1086 , Y10T428/1095 , C04B14/106 , C04B41/4531 , C04B41/0045 , C04B41/483 , C04B41/522 , C04B41/4533
摘要： A clay thin film substrate including a clay thin film having a structure, in which oriented clay particles are laminated; and at least a gas barrier inorganic layer which is laminated on at least one surface of the clay thin film.
摘要翻译：一种粘土薄膜基材，包括具有结构的粘土薄膜，其中层压有取向的粘土颗粒; 以及至少层压在粘土薄膜的至少一个表面上的阻气性无机层。

6. 发明授权

US08647744B2 Graphite clay composite material, process for producing the same, gasket or packing comprising the composite material, and clay dispersion used for the composite material 有权
标题翻译：石墨粘土复合材料，其制造方法，包含复合材料的垫圈或填料，以及用于复合材料的粘土分散体
公开(公告)号：US08647744B2
公开(公告)日：2014-02-11
申请号：US12296107
申请日：2007-04-03
申请人： Takeo Ebina , Yasuhisa Hasegawa , Fujio Mizukami , Nobuhiko Teshima , Katsuro Tsukamoto
发明人： Takeo Ebina , Yasuhisa Hasegawa , Fujio Mizukami , Nobuhiko Teshima , Katsuro Tsukamoto
IPC分类号： F16J15/06 , B32B9/04 , B32B5/00 , B32B3/02
CPC分类号： C09K3/10 , B32B18/00 , C04B35/536 , C04B41/009 , C04B41/5037 , C04B41/87 , C04B2235/3218 , C04B2235/349 , C04B2235/9661 , C04B2237/341 , C04B2237/363 , C04B2237/704 , C09K2200/0252 , F16J15/064 , F16J15/104 , F16J15/122 , F16J15/126 , Y10T156/10 , Y10T428/215 , Y10T428/249922 , Y10T428/26 , Y10T428/261 , Y10T428/30 , C04B41/4539
摘要： To provide a composite that can find application to various uses in a wide spectrum of fields, for example, sealing members, such as a joint sheet, a gasket and a packing, for use in junction portions, etc. of pipings of power plant and chemical plant, radiation sheets, electromagnetic wave shielding members, soundproof sheets, etc., and provide a process for producing the composite; a gasket or packing based on the composite and a clay dispersion liquid used for the composite. There is provided a composite composed mainly of graphite and clay and having the structure of graphite laminated with and/or impregnated with clay. The composite is produced by subjecting an exfoliated graphite sheet or film or a molding therefrom to coating with and/or immersion in a clay dispersion liquid with clay particles dispersed therein, or by laminating together of an exfoliated graphite sheet and/or film and a sheet and/or film composed mainly of clay. Further, a gasket or packing is produced by molding the composite.
摘要翻译：为了提供一种能够广泛应用于各种领域的各种用途的复合材料，例如密封构件，例如接头片，垫圈和填料，用于发电厂管道的接合部分等，以及化学工厂，辐射片，电磁波屏蔽构件，隔音片等，并提供复合材料的制造方法; 基于复合材料的垫圈或填料和用于复合材料的粘土分散液。提供了一种主要由石墨和粘土组成的复合材料，并具有与粘土层压和/或浸渍的石墨结构。复合材料通过将剥离的石墨片或膜或其成型体经由在其中分散有粘土颗粒的粘土分散液中涂覆和/或浸入其中，或通过层压在一起的剥离的石墨片和/或膜和片材和/或主要由粘土组成的薄膜。此外，通过模制复合材料来生产垫圈或填料。

7. 发明申请

US20090239037A1 METHOD FOR PRODUCING CLAY THIN FILM AND CLAY THIN FILM 有权
标题翻译：生产粘膜薄膜和粘膜薄膜的方法
公开(公告)号：US20090239037A1
公开(公告)日：2009-09-24
申请号：US12067338
申请日：2006-09-19
申请人： Hajime Tsuda , Tomohito Inoue , Katsumi Motegi , Takeo Ebina , Fujio Mizukami
发明人： Hajime Tsuda , Tomohito Inoue , Katsumi Motegi , Takeo Ebina , Fujio Mizukami
IPC分类号： B32B3/00 , B29C39/38
CPC分类号： B28B1/30 , G02F2001/133302 , H01L51/5237 , Y10T428/24413
摘要： A method for producing a clay thin film, which is formed of clay alone or in combination with an additive and has a structure where oriented clay particles are laminated, the method including paste-making in which clay alone or in combination with an additive are dispersed in a dispersion medium formed of water, an organic solvent, or a mixed solvent of water and an organic solvent to prepare clay paste; coating in which a thin film is formed by coating the clay paste on a substrate; planarization in which the thin film is planarized; drying in which water, an organic solvent, or water and an organic solvent are removed from the thin film; and separation in which the thin film is separated from the substrate.
摘要翻译：一种粘土薄膜的制造方法，其由单独的粘土或与添加剂组合形成并具有层压有取向粘土颗粒的结构的粘土薄膜，该方法包括仅分散粘土或与添加剂组合的粘土制造在由水，有机溶剂或水和有机溶剂的混合溶剂形成的分散介质中制备粘土糊; 通过将粘土糊涂布在基材上而形成薄膜的涂层; 平面化，其中薄膜被平坦化; 从薄膜中除去水，有机溶剂或水和有机溶剂的干燥; 以及其中薄膜与基底分离的分离。

8. 发明授权

US08197741B2 Method for producing clay thin film 有权
标题翻译：生产粘土薄膜的方法
公开(公告)号：US08197741B2
公开(公告)日：2012-06-12
申请号：US12067338
申请日：2006-09-19
申请人： Hajime Tsuda , Tomohito Inoue , Katsumi Motegi , Takeo Ebina , Fujio Mizukami
发明人： Hajime Tsuda , Tomohito Inoue , Katsumi Motegi , Takeo Ebina , Fujio Mizukami
IPC分类号： B27N3/18
CPC分类号： B28B1/30 , G02F2001/133302 , H01L51/5237 , Y10T428/24413
摘要： A method for producing a clay thin film, which is formed of clay alone or in combination with an additive and has a structure where oriented clay particles are laminated, the method including paste-making in which clay alone or in combination with an additive are dispersed in a dispersion medium formed of water, an organic solvent, or a mixed solvent of water and an organic solvent to prepare clay paste; coating in which a thin film is formed by coating the clay paste on a substrate; planarization in which the thin film is planarized; drying in which water, an organic solvent, or water and an organic solvent are removed from the thin film; and separation in which the thin film is separated from the substrate.
摘要翻译：一种粘土薄膜的制造方法，其由单独的粘土或与添加剂组合形成并具有层压有取向粘土颗粒的结构的粘土薄膜，该方法包括仅分散粘土或与添加剂组合的粘土制造在由水，有机溶剂或水和有机溶剂的混合溶剂形成的分散介质中制备粘土糊料; 通过将粘土糊涂布在基材上而形成薄膜的涂层; 平面化，其中薄膜被平坦化; 从薄膜中除去水，有机溶剂或水和有机溶剂的干燥; 以及其中薄膜与基底分离的分离。

9. 发明申请

US20110045378A1 FUEL CELL 审中-公开
标题翻译：燃料电池
公开(公告)号：US20110045378A1
公开(公告)日：2011-02-24
申请号：US12863344
申请日：2009-01-16
申请人： Tomio Miyazaki , Takeo Ebina , Fujio Mizukami
发明人： Tomio Miyazaki , Takeo Ebina , Fujio Mizukami
IPC分类号： H01M8/04 , H01M8/24
CPC分类号： H01M8/243 , H01M8/0206 , H01M8/021 , H01M8/0247 , H01M8/0271 , H01M8/0282 , H01M8/0284 , H01M8/24 , H01M8/2425 , H01M8/247 , H01M8/2483
摘要： A separator includes: a sandwiching unit which sandwiches an electrolyte/electrode assembly and has a fuel gas channel and an oxidizing gas channel which are arranged separately; a fuel gas supply unit having a fuel gas supply communication hole formed in the layering direction for supplying the fuel gas into the fuel gas channel; and a seal member arranged at an outer periphery of the fuel gas supply communication hole. The seal member has a clay film formed from a clay mineral and an organic polymer.
摘要翻译：分离器包括：三明治电解质/电极组件并具有单独布置的燃料气体通道和氧化气体通道的夹持单元; 燃料气体供给单元，其具有沿着层叠方向形成的燃料气体供给连通孔，用于将燃料气体供给到燃料气体通道中; 以及设置在燃料气体供给连通孔的外周的密封构件。密封件具有由粘土矿物和有机聚合物形成的粘土膜。

10. 发明授权

US07799395B2 Clay film 有权
标题翻译：粘土电影
公开(公告)号：US07799395B2
公开(公告)日：2010-09-21
申请号：US10571107
申请日：2004-09-08
申请人： Takeo Ebina , Fujio Mizukami
发明人： Takeo Ebina , Fujio Mizukami
IPC分类号： B32B27/08
CPC分类号： B29D7/01 , B29K2105/16 , C01B33/40 , Y10T428/1331 , Y10T428/1379 , Y10T428/1383
摘要： The present invention provides a clay film with excellent flexibility, whose main component is natural clay or synthetic clay, and in which there is uniform orientation in the clay particle layer, and relates to a novel clay film that has enough mechanical strength to be used as a self-supporting film, and has a structure in which layers of clay particles are highly oriented, and in which the main constituent component of the clay film is mica, vermiculite, montmorillonite, iron montmorillonite, beidellite, saponite, hectorite, stevensite, or nontronite, and which has excellent flexibility, undergoes no structural change at high temperatures of 250° C. and up to 600° C., contains no pinholes, and has a gas permeation coefficient of less than 3.2×10−11 cm2s−1cmHg−1 at room temperature for helium, hydrogen, oxygen, nitrogen, or air.
摘要翻译：本发明提供了一种具有优良柔性的粘土膜，其主要成分是天然粘土或合成粘土，其中在粘土颗粒层中具有均匀的取向，并且涉及一种具有足够机械强度的新型粘土膜作为自支撑膜，并且具有粘土颗粒层高度取向的结构，并且其中粘土膜的主要构成成分是云母，蛭石，蒙脱石，铁蒙脱石，贝得石，皂石，锂蒙脱石，硬脂酸盐或具有优异的柔韧性，在250℃和高达600℃的高温下不发生结构变化，不含针孔，气体渗透系数小于3.2×10-11cm 2 -1cmHg- 1在室温下用于氦气，氢气，氧气，氮气或空气。

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