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    • 8. 发明授权
    • Water-thickening copolymers of acrylic and N-alkylmaleamic monomers
    • 丙烯酸和N-烷基马来酰亚胺单体的增稠共聚物
    • US5880236A
    • 1999-03-09
    • US47159
    • 1993-04-13
    • Gerd KonradHeinrich Hartmann
    • Gerd KonradHeinrich Hartmann
    • C08F220/56C08F222/38C08F246/00C09D11/03C09K3/00C09K8/12C09K8/588C09K8/62C09K8/72C09K8/88C08F220/58
    • C09K8/882C08F220/56C08F222/38C08F246/00C09D11/03C09K3/00C09K8/12C09K8/588C09K8/68C09K8/74
    • Water-thickening copolymers are obtainable by copolymerization of(A) one or more monomers of the formula IR.sup.1 HC.dbd.CR.sup.2 R.sup.3 IwhereR.sup.1 and R.sup.2 can be identical or different and each is H or C.sub.1 -C.sub.5 -alkyl, andR.sup.3 is ##STR1## where R.sup.1 and R.sup.2 can be identical or different and each is H or C.sub.1 -C.sub.5 -alkyl,R.sup.4 is H or C.sub.1 -C.sub.5 -alkyl,R.sup.5 is C.sub.1 -C.sub.4 -alkylene,R.sup.6 and R.sup.7 can be identical or different and each is H or C.sub.1 -C.sub.3 -alkyl, andM is hydrogen or an alkali metal, 1/2 alkaline earth metal or ammonium ion, and(B) one or more monomers of the formula IIa or IIb ##STR2## where R.sup.1 and R.sup.2 can be identical or different and each is H or C.sub.1 -C.sub.5 -alkyl,R.sup.4 is H or C.sub.1 -C.sub.5 -alkyl,X is --COOM where M is hydrogen or alkali metal, 1/2 alkaline earth metal or ammonium ion,Y is ##STR3## where R.sup.8 is C.sub.6 -C.sub.30 -alkyl, alkylaryl or aryl and R.sup.9 is H, C.sub.1 -C.sub.30 -alkyl, alkylaryl or aryl, andA and B are different and each has the meaning of X or Y.
    • 水增稠共聚物可以通过(A)一种或多种式I的化合物R1HC = CR2R3I的共聚获得,其中R1和R2可以相同或不同,并且各自为H或C1-C5-烷基,R3为< 其中R 1和R 2可以相同或不同,且各自为H或C 1 -C 5 - 烷基,R 4为H或C 1 -C 5 - 烷基,R 5为C 1 -C 4亚烷基,R 6和 R7可以相同或不同,分别为H或C1-C3-烷基,M为氢或碱金属+ E,fra 1/2 + EE碱土金属或铵离子,(B)一种或多种单体 式IIa或IIb其中R 1和R 2可以相同或不同并且各自为H或C 1 -C 5 - 烷基,R 4为H或C 1 -C 5 - 烷基,X为-COOM,其中M为氢 或碱金属,+ E,fra 1/2 + EE碱土金属或铵离子,Y是其中R 8是C 6 -C 30 - 烷基,烷基芳基或芳基,R 9是H,C 1 -C 30 - 烷基,烷基芳基或 芳基,A和B不同,各自具有X或Y的含义。