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1. 发明授权

US5389705A Polymers suitable as binders 失效
标题翻译：聚合物适合作为粘合剂
公开(公告)号：US5389705A
公开(公告)日：1995-02-14
申请号：US102756
申请日：1993-08-06
申请人： Klaus Huemke , Helmut Fobbe , Konrad Knoll
发明人： Klaus Huemke , Helmut Fobbe , Konrad Knoll
IPC分类号： C08G18/28 , C08G18/32 , C08G18/38 , C08G18/62 , C08G59/50 , C08G59/54 , C08L63/00 , C09D5/44 , C09D163/00 , C08J3/00 , C08K3/20
CPC分类号： C09D163/00
摘要： Novel polymers which are suitable as binders are obtainable by reacting(A) a base resin which has an average molecular weight M.sub.w of from 200 to 5,000 and contains on average from 1 to 3 epoxy or isocyanato groups as the reactive groups per moleculewith(B) a mixture of(B1) 5 to 50% by weight of polyisobutylene which is terminated with primary amino groups and has an average molecular weight M.sub.w of from 500 to 5,000 and(B2) 5-95% by weight of an amidoamine which carries primary amino groups and is obtainable by condensation of diprimary diamines of 2 to 20 carbon atoms with aliphatic C.sub.2 -C.sub.44 -dicarboxylic acids,the amounts being such that from 1 to 5 equivalents of primary amino groups of (B) are present per equivalent of reactive groups of (A).
摘要翻译：适合作为粘合剂的新型聚合物可以通过使（A）平均分子量＆Upbar＆Mw为200〜5,000的基础树脂与平均1〜3个环氧基或异氰酸酯基作为每分子的反应性基团反应，得到（ B）5〜50重量％的以伯氨基封端的聚异丁烯的混合物，其平均分子量＆gt; Mw为500〜5,000，（B2）为5-95重量％的酰氨基胺，携带伯氨基，可通过将2至20个碳原子的二原子二胺与脂肪族C 2 -C 44二羧酸缩合获得，其量相当于每当量的（B）存在1至5当量的（B）伯氨基（A）的反应性基团。

2. 发明授权

US5356959A Epoxy resins for ternary sulfonium electrocoating compositions 失效
标题翻译：三元锍电涂组合物用环氧树脂
公开(公告)号：US5356959A
公开(公告)日：1994-10-18
申请号：US96991
申请日：1993-07-27
申请人： Klaus Huemke , Christian Sinn
发明人： Klaus Huemke , Christian Sinn
IPC分类号： C08G59/14 , C08G59/04 , C08G59/16 , C09D5/44 , C09D17/00 , C09D163/00 , C08G59/50 , C08L63/02
CPC分类号： C09D5/4492 , C08G59/04 , C08G59/1455 , C09D17/001 , Y10T428/31529
摘要： Epoxy resins obtainable by reactingA) a polyfunctional epoxide, which carries on average 1.5 to 2.5 epoxy groups per molecule and has an epoxide equivalent weight of from 100 to 2000, with based on 1 mol of epoxy groupsB) from 0.1 to 0.5 mol of an alkylphenol, the alkyl groups of which carry from 6 to 20 carbon atoms, andC) from 1 to 100 mmol of a polyoxyalkylenediol obtained from 1,2-propylene oxide, or of a copolymer obtained from 1,2-propylene oxide and other alkylene oxides, which has an average molecular weight of from 200 to 5000 and, on average, from 1 to 4 sulfonic acid groups bonded to methyl groups per molecule, and alsoD) from 0.2 to 0.3 mol of a diol, which isd1) a phenolic diol and/ord2) a polyoxyalkylenediol which has an average molecular weight of from 200 to 5000,with the proviso that the reaction product has an epoxide equivalent weight of from 1000 to 5000, can be converted to pigment resins suitable for electrodeposition coating and pigment pastes can then be prepared from said resins.
摘要翻译：环氧树脂可以通过使A）多官能环氧化物，其每分子平均具有1.5至2.5个环氧基并且具有100至2000的环氧当量，基于1摩尔环氧基B）0.1至0.5摩尔的烷基苯酚，其烷基含有6至20个碳原子，以及C）1至100mmol由1,2-环氧丙烷获得的聚氧化烯二醇或由1,2-环氧丙烷和其它物质获得的共聚物平均分子量为200〜5000，平均每1分子与甲基键合1〜4个磺酸基的氧化烯，以及D）0.2〜0.3摩尔的二醇，其为d1）酚二醇和/或d2）平均分子量为200至5000的聚氧化烯二醇，条件是反应产物的环氧当量为1000至5000，可以转化成适用于电沉积涂料的颜料树脂然后可以使用颜料糊由所述树脂制备。

3. 发明授权

US5258460A Polymeric reaction products 失效
标题翻译：聚合反应产物
公开(公告)号：US5258460A
公开(公告)日：1993-11-02
申请号：US856828
申请日：1992-03-25
申请人： Dieter Faul , Gerhard Hoffmann , Klaus Huemke , Ulrich Heimann , John A. Gilbert
发明人： Dieter Faul , Gerhard Hoffmann , Klaus Huemke , Ulrich Heimann , John A. Gilbert
IPC分类号： C08L63/00 , C09D5/02 , C09D5/44 , C08L63/02
CPC分类号： C09D5/4492 , C08L63/00 , C09D5/024 , Y10T428/31696
摘要： Polymeric reaction products useful as additions to electrocoating baths are obtainable fromA. a polyoxyalkylene which has an average molecular weight M.sub.n of from 140 to 10,000 and contains on average from 1.5 to 3.0 primary and/or secondary amino groups andB. a polymer which is based on a conjugated diene, has an average molecular weight M.sub.n of from 250 to 50,000, contains on average from 1.5 to 3.0 epoxy groups per molecule and is obtainable by reacting a hydroxyl- or carboxyl-containing polymer with a glycidyl compound.
摘要翻译：可用作电涂浴的添加剂的聚合反应产物可从A.具有平均分子量＆Upbar＆Mn为140至10,000并含有平均1.5至3.0个伯和/或仲氨基和B的聚氧化烯获得。基于共轭二烯，平均分子量＆Upbar＆Mn为250〜50,000，每分子平均含有1.5〜3.0个环氧基团，可通过含羟基或含羧基的聚合物与缩水甘油基化合物反应而获得。

4. 发明授权

US5446084A Synthetic resins 失效
标题翻译：合成树脂
公开(公告)号：US5446084A
公开(公告)日：1995-08-29
申请号：US27942
申请日：1993-03-08
申请人： Klaus Huemke , Gerhard Hoffmann , Dieter Faul
发明人： Klaus Huemke , Gerhard Hoffmann , Dieter Faul
IPC分类号： C08F291/00 , C08L9/06 , C08L51/00 , C08L63/00 , C08L101/00 , C08L101/02 , C09D5/44 , C09D201/02
CPC分类号： C09D5/4473 , C08F291/00 , C08L101/02 , C08L51/003 , C08L63/00 , C08L9/06 , Y10S525/902
摘要： Synthetic resins contain, as essential components,A) from 20 to 95% by weight of a crosslinkable binder selected from the group consisting of the polymers, polyadducts or polycondensates having reactive centers in the form of hydroxyl, thio, primary and/or secondary amino groups and/or hydrophilic centers in the form of ammonium, sulfonium and/or phosphonium groups andB) from 5 to 80% by weight of polymers consisting of a core and one or more shells and furthermoreC) from 0 to 10% by weight of one or more crosslinking agents andD) from 0 to 10% by weight of a pigment formulation consisting of one or more pigments and a resin having surfactant properties andE) from 0 to 10% by weight of additives and/or assistants.
摘要翻译：合成树脂含有作为必需组分的A）20至95重量％的可交联粘合剂，其选自具有羟基，硫原子，伯和/或仲氨基的反应中心的聚合物，聚加成物或缩聚物基团和/或亲水中心，以及B）5至80重量％的由核心和一个或多个壳体组成的聚合物，此外C）0至10重量％的一种或多种交联剂和D）0至10重量％的由一种或多种颜料和具有表面活性剂性质的树脂组成的颜料制剂，以及E）0至10重量％的添加剂和/或助剂。

5. 发明授权

US5274011A Cationic resins based on copolymers of butadiene and acrylonitrile 失效
标题翻译：基于丁二烯和丙烯腈共聚物的阳离子树脂
公开(公告)号：US5274011A
公开(公告)日：1993-12-28
申请号：US964822
申请日：1992-10-22
申请人： Dieter Faul , Gerhard Hoffmann , Klaus Huemke , Ulrich Heimann
发明人： Dieter Faul , Gerhard Hoffmann , Klaus Huemke , Ulrich Heimann
IPC分类号： C08L33/20 , C08C19/36 , C08L33/18 , C09D5/44 , C09D133/02 , C09D133/20 , C08L63/02
CPC分类号： C09D5/4403 , C08C19/36 , Y10T428/31681
摘要： Cationic resins are obtainable by reaction ofA) a carboxyl-containing copolymer containing as comonomersa) 35-100 mol % of butadiene,b) 0-45 mol % of acrylonitrile, andc) 0-20 mol % of further comonomers, which has an average molecular weight of 500-50,000 and carries on average from 1.5 to 4 carboxyl groups per molecule, andB) a condensation product ofd) a polybasic aliphatic C.sub.10 -C.sub.100 -carboxylic acid, ande) an amine which is polyfunctional in respect of primary and secondary amino groups, the amount of e) having been determined in such a way that, arithmetically, there are from 1.05 to 4 amino groups for every carboxyl group of d),with the proviso that the amount of B) is chosen in such a way that there are from 1.05 to 4 mol of amino groups per mole of the carboxyl groups present in A).
摘要翻译：阳离子树脂可以通过A）含有共聚单体a）35-100摩尔％的丁二烯，b）0-45摩尔％的丙烯腈和c）0-20摩尔％的其它共聚单体反应获得，其中平均分子量为500-50,000，每分子平均载有1.5至4个羧基，B）d）多元脂族C 10 -C 100 - 羧酸的缩合产物，和e）多官能的胺对于伯氨基和仲氨基的考虑，e）的量已经以这样的方式确定：对于d）的每个羧基，在算术上为1.05至4个氨基，条件是B）的量为以这样的方式进行选择：每摩尔A）中存在的羧基存在1.05至4摩尔的氨基。

6. 发明授权

US5096555A Heat-curable coating composition for cathodic electrocoating 失效
标题翻译：用于阴极电解的热固化涂料组合物
公开(公告)号：US5096555A
公开(公告)日：1992-03-17
申请号：US470380
申请日：1990-01-25
申请人： Hans Schupp , Thomas Schwerzel , Klaus Huemke , Dieter Faul
发明人： Hans Schupp , Thomas Schwerzel , Klaus Huemke , Dieter Faul
IPC分类号： C09D5/44
CPC分类号： C09D5/4488
摘要： A heat-curable, cathodically depositable aqueous electrocoating composition contains(A) from 50 to 95% by weight of a polymerization or polycondensation or polyaddition product which has an average molecular weight of from 200 to 20,000 and primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups and is water-thinnable on protonation with an acid, and(B) from 5 to 50% by weight of a water-thinnable crosslinking agent having cationic groups or groups which are convertible into cationic groups by protonation with an acid.
摘要翻译：可热固化的阴极可沉积的水性电涂组合物包含（A）50至95重量％的平均分子量为200至20,000的聚合或缩聚或加聚产物，以及伯和/或仲羟基和伯，仲和/或叔氨基，并且在用酸质子化时可水稀释，和（B）5至50重量％的具有阳离子基团的水可稀释交联剂，其可通过质子化转化成阳离子基团与酸。

7. 发明授权

US5336722A Polymeric reaction products 失效
标题翻译：聚合反应产物
公开(公告)号：US5336722A
公开(公告)日：1994-08-09
申请号：US979313
申请日：1992-11-20
申请人： Dieter Faul , Gerhard Hoffmann , Klaus Huemke , Ulrich Heimann , John A. Gilbert
发明人： Dieter Faul , Gerhard Hoffmann , Klaus Huemke , Ulrich Heimann , John A. Gilbert
IPC分类号： C08F8/00 , C08F36/00 , C08F36/04 , C08G59/14 , C08G81/02 , C08J3/24 , C08K5/14 , C08L63/00 , C08L71/02 , C09D5/02 , C09D5/44 , C09D163/00 , C08L63/10
CPC分类号： C09D5/4492 , C08G81/025 , C08J3/246 , C08L63/00 , C08L71/02 , Y10T428/31529
摘要： Polymeric reaction products are obtained by reactingI) prepolymers obtained fromA) polyoxyalkylenes which have an average molecular weight M.sub.n of from 140 to 10,000 and contain on average from 1.5 to 3.0a.sub.1) primary or secondary amino groups ora.sub.2) epoxy groups per molecule andB) polymers which are based on conjugated dienes, have an average molecular weight M.sub.n of from 250 to 50,000 and contain on average from 1.5 to 3.0b.sub.1) primary or secondary amino groups orb.sub.2) epoxy groups per molecule, the components (a.sub.1) and ( b.sub.2) or (a.sub.2) and (b.sub.1) being reacted with one another so that from at least an amino equivalent excess to 3 amino equivalents of component (a.sub.1) or (b.sub.1) are present per epoxide equivalent of component (a.sub.2) or (b.sub.2), withII) at least one compound which forms free radicals.
摘要翻译：聚合反应产物是通过使I）得自A）聚氧亚烷的平均分子量＆Upbar＆Mn为140〜10,000，平均含有1.5〜3.0个a1）伯或仲氨基或a2）环氧基的分子得到的预聚物和B）基于共轭二烯的聚合物，其平均分子量＆gt;＆gt; Mn为250至50,000，并且平均含有1.5至3.0个b1）伯或仲氨基或每个分子的b2）环氧基，组分（a1 ）和（b2）或（a2）和（b1）彼此反应，使得由组分（a2）的每个环氧当量存在至少一个氨基当量过量至3个氨基当量的组分（a1）或（b1）或（b2），II）至少一种形成自由基的化合物。

8. 发明授权

US5212309A 3-aminobenzene-1,2,4,5-tetracarboxylic dihydrazides and composition capable of chemiluminescence, and 3-aminobenzene-1,2,4,5-tetracarboxylic dianhydrides 失效
标题翻译： 3-氨基苯基-1,2,4,5-四唑氧基二氢化物和可溶于三乙胺的组合物和3-氨基苯基-1,2,4,5-四氯乙酰二胺
公开(公告)号：US5212309A
公开(公告)日：1993-05-18
申请号：US829631
申请日：1992-02-03
申请人： Ernst Schefczik , Klaus Huemke
发明人： Ernst Schefczik , Klaus Huemke
IPC分类号： C07D487/04 , C07D493/04
CPC分类号： C07D487/04 , C07D493/04 , Y10T436/147777
摘要： Chemiluminescenct 3-aminobenzene-1,2,4,5-tetracarboxylic dihydrazides.
摘要翻译：化学结构3-氨基苯-1,2,4,5-四羧酸二酰肼。

9. 发明授权

US5401823A Binders for electrocoating 失效
标题翻译：电泳用粘合剂
公开(公告)号：US5401823A
公开(公告)日：1995-03-28
申请号：US27841
申请日：1993-03-08
申请人： Klaus Huemke , Gerhard Hoffmann , Dieter Faul , Rainer Blum
发明人： Klaus Huemke , Gerhard Hoffmann , Dieter Faul , Rainer Blum
IPC分类号： C08G18/08 , C08G18/22 , C08G18/64 , C08G18/80 , C09D5/44 , C09D175/00 , C09D175/04 , C08G
CPC分类号： C08G18/643 , C08G18/0809 , C08G18/222 , C08G18/80 , C09D5/4457 , C09D5/4492
摘要： Binder systems suitable for electrocoating and consisting of a base resin A which carries groups which can be protonated with acids or cationic quaternary groups and, if desired, hydroxyl or thiol groups, a crosslinking component B which carries at least two blocked isocyanate groups per molecule and an organic iron compound C which is partially or completely soluble in water, as a catalyst for the thermal crosslinking of components A and B, and if desired, an additive D which increases the catalytic activity of C, are used to prepare dispersions which are used for electrocoating.
摘要翻译：粘合剂系统适用于电泳并由基础树脂A组成，基础树脂A携带可用酸或阳离子季铵基团质子化的基团，以及如果需要的话，羟基或硫醇基团，每个分子携带至少两个封闭的异氰酸酯基团的交联组分B，以及作为部分或完全可溶于水的有机铁化合物C，作为用于组分A和B的热交联的催化剂，如果需要，使用增加C的催化活性的添加剂D用于制备使用的分散体用于电涂。

10. 发明授权

US5350636A Synthetic resin 失效
标题翻译：合成树脂
公开(公告)号：US5350636A
公开(公告)日：1994-09-27
申请号：US979314
申请日：1992-11-20
申请人： Klaus Huemke , Dieter Faul , Gerhard Hoffmann
发明人： Klaus Huemke , Dieter Faul , Gerhard Hoffmann
IPC分类号： C08G18/00 , C08G18/40 , C08G18/58 , C08G18/77 , C08G18/83 , C08L75/00 , C09D5/44 , C09D175/00 , C09D175/04 , B32B15/08
CPC分类号： C08G18/771 , C08G18/584 , C09D5/4496 , Y10T428/31529
摘要： A synthetic resin contains, as essential components,A) a crosslinkable binder selected from the group consisting of the polymers, polyadducts or polycondensates having reactive centers in the form of hydroxyl, thio or primary or secondary amino groups andB) a crosslinking agent based on at least one polyoxyalkylene polyisocyanate andC) a crosslinking agent which differs from (B) and is based on.gamma..sub.1) a polyfunctional isocyanate which differs from (B) or.gamma..sub.2) an organic compound which reacts at elevated temperatures with free amino groups of component (A) with amide formation or.gamma..sub.3) an organic compound which reacts at elevated temperatures with hydroxyl groups of component (A) with transesterification or.gamma..sub.4) a phenolic Mannich base ora mixture of two or more crosslinking agents (.gamma..sub.1) to (.gamma..sub.4).
摘要翻译：合成树脂作为必要组分含有A）选自具有羟基，硫原子或伯或仲氨基形式的反应中心的聚合物，聚加成物或缩聚物的可交联粘合剂，以及B）基于至少一种聚氧亚烷基多异氰酸酯和C）不同于（B）并且基于γ的交联剂1）与（B）或γ2不同的多官能异氰酸酯）在升高的温度下与游离氨基反应的有机化合物酰胺形成的组分（A）或γ3）在升高的温度下与组分（A）的羟基与酯交换反应或γ反应的有机化合物4）酚类曼尼希碱或两种或更多种交联剂（γ1）的混合物，到（γ4）。

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