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1. 发明申请

US20110232530A1 FLUORINATED ETHER URETHANES AND METHODS OF USING THE SAME 审中-公开
标题翻译：氟化物的使用方法及其使用方法
公开(公告)号：US20110232530A1
公开(公告)日：2011-09-29
申请号：US13130856
申请日：2009-11-23
申请人： Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jurgens , Harald Kaspar , Kai Helmut Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Werner Schwertfeger , Tilman C. Zipplies
发明人： Rudolf J. Dams , Miguel A. Guerra , Klaus Hintzer , Michael Jurgens , Harald Kaspar , Kai Helmut Lochhaas , Andreas R. Maurer , Zai-Ming Qiu , Werner Schwertfeger , Tilman C. Zipplies
IPC分类号： C09D7/12 , C07C237/06 , C07F7/10
CPC分类号： C09D175/04 , C08G18/2885 , C08G18/289 , C08G18/3812 , C08G18/673 , C08G18/7831 , C08G18/8064 , C08G18/8077
摘要： Compounds comprising end groups represented by formula (Rf-Q)a-X-(A-)b and compounds comprising the reaction product of components comprising a multifunctional isocyanate compound and a fluorinated compound represented by formula (Rf-Q)a-X—(Z)b. Each Rf is independently a partially fluorinated or fully fluorinated group selected from RfA(O)2CHL′-(CF2)n—; [RfB—(O)1—C(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)Z—; and CF3—O—(CF2)3—O—CF—. Methods of making an article having a surface using the fluorinated compounds and treated articles are also disclosed.
摘要翻译：包含由式（Rf-Q）aX-（A-）b表示的端基的化合物和包含由式（Rf-Q）aX-（Z）b表示的多官能异氰酸酯化合物和氟化化合物的组分的反应产物的化合物。每个Rf独立地是选自RfA（O）2 CHL' - （CF 2）n - 的部分氟化或完全氟化基团; [RfB-（O）1 -C（L）H-CF 2 -O] m -W-; CF 3 CFH-O-（CF 2）p-; CF3-（O-CF2）Z-; 和CF 3 -O-（CF 2）3 -O-CF-。还公开了使用氟化化合物和处理制品制造具有表面的制品的方法。

2. 发明授权

US07560517B2 Fluoropolymer for making a fluoroelastomer 失效
标题翻译：用于制造含氟弹性体的含氟聚合物
公开(公告)号：US07560517B2
公开(公告)日：2009-07-14
申请号：US11280880
申请日：2005-11-16
申请人： Klaus Hintzer , Michael Jurgens , Harald Kaspar , Kai Helmut Lochhaas , Werner Schwertfeger
发明人： Klaus Hintzer , Michael Jurgens , Harald Kaspar , Kai Helmut Lochhaas , Werner Schwertfeger
IPC分类号： C08F8/32
CPC分类号： C08F214/186 , C08F214/18
摘要： The present invention relates to a fluoropolymer comprising repeating units derived from one or more gaseous fluorinated olefins and having one or more cure sites comprising (a) a halogen capable of participating in a peroxide cure reaction or (b) a nitrile group, said fluoropolymer further comprising repeating units derived from one or more fluorinated allyl ethers of the formula: CF2═CF—CF(Z)—O—Rf (I) wherein Z represents F or CF3 and Rf represents a fluorinated alkyl group that may contain one or more catenary oxygen atoms. The fluoropolymer can be cured to a fluoroelastomer. The invention also relates to a curable fluoroelastomer composition comprising the fluoropolymer and a curing agent.
摘要翻译：本发明涉及包含衍生自一种或多种气态氟化烯烃并具有一个或多个固化位点的重复单元的含氟聚合物，其包含（a）能够参与过氧化物固化反应的卤素或（b）腈基，所述含氟聚合物进一步包含衍生自下式的一种或多种氟化烯丙基醚的重复单元：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF2-CF-CF（Z）-O-Rf（ I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Z表示F或CF 3，Rf表示可含有一个或多个链状氧原子的氟化烷基。氟聚合物可以固化成含氟弹性体。本发明还涉及含氟聚合物和固化剂的可固化含氟弹性体组合物。

3. 发明申请

US20070276068A1 COATING COMPOSITION 有权
标题翻译：涂料组合物
公开(公告)号：US20070276068A1
公开(公告)日：2007-11-29
申请号：US11420431
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jurgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G.I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jurgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G.I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08K5/00
CPC分类号： C09D127/18 , C08K5/06 , C08K5/09 , C08L27/12 , C08L71/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/14
摘要： A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.
摘要翻译：一种涂料组合物，其具有（i）含氟聚合物颗粒的水分散体，其包含四氟乙烯的不可熔融加工聚合物，（ii）氟化表面活性剂，（iii）非离子非氟化表面活性剂和（iv）非氟化聚合物其中氟化表面活性剂选自通式（I）的氟化羧酸或其盐：<？in-line-formula description =“In-line Formulas”end =“lead”→> [R f （I）<？in-line-formula description =“In-line-formula” 式“end =”tail“？>其中L表示直链部分或完全氟化的亚烷基或脂族烃基，R f表示直链部分或完全氟化的脂族基团或部分或完全线性的直链被一个或多个氧原子间断的氟化脂肪族基团，X i表示具有i价和i为1,2或3的阳离子。

4. 发明授权

US08623957B2 Method of preparing fluoropolymers by aqueous emulsion polymerization 有权
标题翻译：通过水乳液聚合制备含氟聚合物的方法
公开(公告)号：US08623957B2
公开(公告)日：2014-01-07
申请号：US12673241
申请日：2008-08-15
申请人： Klaus Hintzer , Michael Juergens , Harald Kaspar , Kai Helmut Lochhaas , André Streiter , Tilman C. Zipplies , Werner Schwertfeger
发明人： Klaus Hintzer , Michael Juergens , Harald Kaspar , Kai Helmut Lochhaas , André Streiter , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号： C08F2/24
CPC分类号： C08F14/26 , C08F2/24
摘要： Method of making fluoropolymers by emulsion polymerization of one or more fluorinated monomers in an aqueous phase in the presence of a fluorinated emulsifier, said method comprises adding a doping agent in a weight ratio with respect to the emulsifier of from about 1:2 to about 1:20, said doping agent has a melting point of equal or less than 30° C. and a boiling point of at least about 100° C. and is selected from the group consisting of fluorinated cyclic hydrocarbons, fluorinated polyoxyalkenes, fluorinated alkenes and fluorinated polyoxyalkenes.
摘要翻译：在氟化乳化剂存在下，通过在水相中乳液聚合一种或多种氟化单体制备含氟聚合物的方法，所述方法包括将相对于乳化剂的重量比为约1:2至约1的掺杂剂 20，所述掺杂剂的熔点等于或小于30℃，沸点为至少约100℃，并且选自氟化环状烃，氟化聚氧乙烯，氟化烯和氟化的聚氧乙烯

5. 发明授权

US07671112B2 Method of making fluoropolymer dispersion 有权
标题翻译：制备含氟聚合物分散体的方法
公开(公告)号：US07671112B2
公开(公告)日：2010-03-02
申请号：US11420386
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译：首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示线性部分或完全氟化的亚烷基或脂族烃基，Rf表示直链部分或完全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或全部氟化脂族基，X i +表示具有i价和我是1,2或3; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于分散体的总重量，同时保持或增加分散体中固体的量。

6. 发明授权

US08614265B2 Method of making fluoropolymer dispersion 有权
标题翻译：制备含氟聚合物分散体的方法
公开(公告)号：US08614265B2
公开(公告)日：2013-12-24
申请号：US13494260
申请日：2012-06-12
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译：首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于分散体的总重量，同时保持或增加分散体中固体的量。

7. 发明申请

US20120252949A1 METHOD OF MAKING FLUOROPOLYMER DISPERSION 有权
标题翻译：制备氟聚合物分散体的方法
公开(公告)号：US20120252949A1
公开(公告)日：2012-10-04
申请号：US13494260
申请日：2012-06-12
申请人： Klaus Hintzer , Michael JÜRGENS , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G.I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael JÜRGENS , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G.I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L27/18 , C08K5/095
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译：首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于分散体的总重量，同时保持或增加分散体中固体的量。

8. 发明授权

US08222322B2 Method of making fluoropolymer dispersion 有权
标题翻译：制备含氟聚合物分散体的方法
公开(公告)号：US08222322B2
公开(公告)日：2012-07-17
申请号：US12684239
申请日：2010-01-08
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译：首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示线性全氟化亚烷基，Rf表示直链部分或完全氟化的脂族基团或被一个氧原子间隔的直链部分或全氟化的脂族基团，X i +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于分散体的总重量，同时保持或增加分散体中固体的量。

9. 发明申请

US20110294951A1 METHOD OF PREPARING FLUOROPOLYMERS BY AQUEOUS EMULSION POLYMERIZATION 有权
标题翻译：通过水性乳液聚合制备荧光体的方法
公开(公告)号：US20110294951A1
公开(公告)日：2011-12-01
申请号：US12673241
申请日：2008-08-15
申请人： Klaus Hintzer , Michael Juergens , Harald Kaspar , Kai Helmut Lochhaas , André Streiter , Tilman C. Zipplies , Werner Schwertfeger
发明人： Klaus Hintzer , Michael Juergens , Harald Kaspar , Kai Helmut Lochhaas , André Streiter , Tilman C. Zipplies , Werner Schwertfeger
IPC分类号： C08F2/24 , C08L27/18 , C08K5/095 , C08K5/06 , C08K5/02
CPC分类号： C08F14/26 , C08F2/24
摘要： Method of making fluoropolymers by emulsion polymerization of one or more fluorinated monomers in an aqueous phase in the presence of a fluorinated emulsifier, said method comprises adding a doping agent in a weight ratio with respect to the emulsifier of from about 1:2 to about 1:20, said doping agent has a melting point of equal or less than 30° C. and a boiling point of at least about 100° C. and is selected from the group consisting of fluorinated cyclic hydrocarbons, fluorinated polyoxyalkenes, fluorinated alkenes and fluorinated polyoxyalkenes.
摘要翻译：在氟化乳化剂存在下，通过在水相中乳液聚合一种或多种氟化单体制备含氟聚合物的方法，所述方法包括将相对于乳化剂的重量比为约1:2至约1的掺杂剂 20，所述掺杂剂的熔点等于或小于30℃，沸点为至少约100℃，并且选自氟化环状烃，氟化聚氧乙烯，氟化烯和氟化的聚氧乙烯

10. 发明授权

US07754795B2 Coating composition 有权
标题翻译：涂料组成
公开(公告)号：US07754795B2
公开(公告)日：2010-07-13
申请号：US11420431
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08K5/00
CPC分类号： C09D127/18 , C08K5/06 , C08K5/09 , C08L27/12 , C08L71/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/14
摘要： A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.
摘要翻译：一种涂料组合物，其具有（i）含氟聚合物颗粒的水分散体，其包含四氟乙烯的不可熔融加工聚合物，（ii）氟化表面活性剂，（iii）非离子非氟化表面活性剂和（iv）非氟化聚合物其中氟化表面活性剂选自通式（I）的氟化羧酸或其盐：[Rf-OL-COO-] iXi +（I）其中L表示直链部分或完全氟化的亚烷基或脂族烃基 Rf表示直链部分或完全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或全部氟化的脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子。

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