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    • 3. 发明授权
    • Optical waveguide array and method of manufacturing the same
    • 光波导阵列及其制造方法
    • US06640039B1
    • 2003-10-28
    • US09601811
    • 2001-01-12
    • Kiyotaka MiuraYuki KondoKazuyuki Hirao
    • Kiyotaka MiuraYuki KondoKazuyuki Hirao
    • G02B610
    • G02B6/08G02B6/13
    • A glass containing one or more of metal microparticles, semiconductor microparticles, transition metal ion, rare earth ion and anion with characteristic absorption in a wavelength region longer than 360 nm is irradiated with a pulsed laser beam condensed at a focal point preset in an inner part of the glass. The condensed irradiation induces change of a refractive index as well as decrease of characteristic absorption in the wavelength region longer than 360 nm at the focal point. Such the domain is continuously formed by relatively shifting the focal point with respect to the glass. The continuous domains serve as optical waveguides, since optical properties are greatly different between the irradiated part and the non-irradiated part.
    • 在长于360nm的波长区域中含有一种或多种金属微粒,半导体微粒,过渡金属离子,稀土离子和具有特征吸收的阴离子的玻璃被照射在预设在内部的焦点处的脉冲激光束 的玻璃。 冷凝照射引起在焦点处长于360nm的波长区域的折射率变化以及特征吸收的降低。 这样的结构域通过相对于玻璃相对移动焦点而连续地形成。 连续域用作光波导,因为照射部分和未照射部分之间的光学特性大大不同。
    • 6. 发明申请
    • Method of forming split phase area inside glass
    • 在玻璃内部形成裂缝相区域的方法
    • US20050193771A1
    • 2005-09-08
    • US10512159
    • 2003-04-18
    • Kiyotaka MiuraSeiji FujiwaraKazuyuki Hirao
    • Kiyotaka MiuraSeiji FujiwaraKazuyuki Hirao
    • C03C10/00C03C14/00C03C23/00C03B32/00
    • C03C23/0025C03C10/00C03C10/0009C03C14/006C03C2214/16
    • When separated phases are formed in a glass by a nucleation and growth mechanism, a phase separation region only in a small desired area is difficult to form by a conventional method, in which the entire glass is heated. Thus, an optical waveguide structure, or a photonic crystal, which requires an orderly arrangement of high-refractive-index regions, cannot be manufactured. The present invention provides a method for forming a phase separation region by converging a laser pulse in a glass containing a metastable immiscible phase to separate only an area at a focal point of the laser or in the vicinity of the focal point into phases. The focal point of the laser is moved continuously or intermittently relative to the glass to form a linear phase separation region or a dotted phase separation region in two or three dimensions in the glass. The pulse width of the laser is preferably between 10 femtoseconds and 10 picoseconds.
    • 当通过成核和生长机理在玻璃中形成分离相时,仅通过加热整个玻璃的常规方法难以形成仅在小的期望区域中的相分离区域。 因此,不能制造需要高折射率区域有序排列的光波导结构或光子晶体。 本发明提供一种用于通过在包含亚稳态不混溶相的玻璃中会聚激光脉冲来形成相分离区域的方法,以仅将激光焦点或焦点附近的区域分离成相。 激光的焦点相对于玻璃连续地或间歇地移动,以在玻璃中形成两维或三维的线性相分离区域或点状相分离区域。 激光的脉冲宽度优选在10飞秒和10皮秒之间。
    • 7. 发明授权
    • Method of selectively reforming an inner part of an inorganic body
    • 选择性地重整无机体内部的方法
    • US06729161B1
    • 2004-05-04
    • US09600195
    • 2000-07-12
    • Kiyotaka MiuraJianrong QiuYuki KondoKazuyuki Hirao
    • Kiyotaka MiuraJianrong QiuYuki KondoKazuyuki Hirao
    • B01J1912
    • C03C23/0025B01J19/121
    • An inorganic body containing rare earth and/or transition metal ions that has been irradiated with a pulsed laser beam in the manner such that a focal point of the pulsed laser beam is adjusted to an inner part of the inorganic body is disclosed. The inorganic body may be a glass or crystal containing one or more of oxide, halide and chalcogenide. The rare earth ion may be one or more of Ce, Nd, Pr, Sm, Eu, Tb, Dy, Tm, Tb. The transition metal ion may be one or more of Ti, Mn, Cr, V, Fe, Cu, Mo and Ru. When the focal point is relatively shifted with respect to the inorganic body, an ionic valence-changed domain is formed with a predetermined pattern at the inner part of the inorganic body. The pulsed laser beam preferably has a pulse width under a picosecond. The ionic valence change occurs at the focal point and its vicinity, but the rare earth or transition metal ion keeps its original valence at all other parts, so as to form a reformed domain with a predetermined pattern in the inorganic body. Since optical properties are selectively changed at the reformed domain, the processed inorganic body is useful as a functional device such as a memory device or a light-emitting device using the differentiated optical properties.
    • 公开了一种含有以脉冲激光束的焦点调节为无机体的内部的脉冲激光束照射的稀土元素和/或过渡金属离子的无机体。 无机体可以是含有氧化物,卤化物和硫族化物中的一种或多种的玻璃或晶体。 稀土离子可以是Ce,Nd,Pr,Sm,Eu,Tb,Dy,Tm,Tb中的一种或多种。 过渡金属离子可以是Ti,Mn,Cr,V,Fe,Cu,Mo和Ru中的一种或多种。 当焦点相对于无机体相对移动时,在无机体的内部形成具有预定图案的离子价改变域。 脉冲激光束优选具有皮秒之下的脉冲宽度。 离子价态变化发生在焦点及其附近,但是稀土或过渡金属离子在其他部分保持其初始价态,从而在无机体中形成具有预定图案的重整畴。 由于光学特性在改性区域选择性地变化,所以经处理的无机体可用作诸如使用差分光学性质的存储器件或发光器件的功能器件。