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    • 1. 发明授权
    • Method for solidifying radioactive waste
    • 固化放射性废物的方法
    • US5481061A
    • 1996-01-02
    • US141541
    • 1993-10-27
    • Kiyomi FunabashiKoichi ChinoOsamu KuriyamaTsutomu BabaShunsuke UchidaMakoto Kikuchi
    • Kiyomi FunabashiKoichi ChinoOsamu KuriyamaTsutomu BabaShunsuke UchidaMakoto Kikuchi
    • C04B28/02G21F9/16G21F9/30G21F9/00
    • C04B28/02G21F9/16G21F9/165G21F9/304
    • The present invention relates to a method of solidifying radioactive waste with cement, comprising forming a mixture comprising water, a hydrophilic material and cement substantially non-shrinkable or expansible with respect to volume change upon hardening, mixing said mixture with the radioactive waste, followed by hardening to form a solid body.The present invention enables the formation of a compact solid body having voids, such as capillary voids, of reduced volume, which makes it possible to reduce the leaching rate of hazardous materials. Further, since no shrinkage accompanies hardening, no tensile stress occurs in the cement surrounding minute waste particles within the hardened material, thereby enabling a decrease in the strength of the solid body to be minimized. This in turn enables an increase in the amount of packing of waste. Prior addition of a hydrophilic material enables the cement fluidity before hardening to be maintained even after complete absorption of water by a water absorptive waste. This is extremely advantageous in carrying out hardening.
    • 本发明涉及一种用水泥固化放射性废物的方法,包括形成水,亲水材料和水泥在混合物硬化后基本上不可收缩或可膨胀的混合物,将所述混合物与放射性废物混合,然后 硬化形成固体。 本发明能够形成具有减小体积的诸如毛细管空隙的空隙的紧凑的固体,这使得可以降低有害材料的浸出率。 此外,由于没有收缩伴随硬化,所以在硬化材料内的微小废弃颗粒周围的水泥中不产生拉伸应力,从而能够使固体的强度降低到最小。 这又可以增加废物的包装量。 亲水性材料的先前添加使得即使在通过吸水性废物完全吸收水之后,硬化前的水泥流动性仍能保持。 这在进行硬化方面是非常有利的。
    • 2. 发明授权
    • Waste water concentrator and waste water disposal plant
    • 废水集中器和废水处理厂
    • US5028298A
    • 1991-07-02
    • US273513
    • 1988-11-04
    • Tsutomu BabaKoichi ChinoShunsuke UchidaToshio SawaMakoto Kikuchi
    • Tsutomu BabaKoichi ChinoShunsuke UchidaToshio SawaMakoto Kikuchi
    • G21F9/08B01D1/30B01D19/00B01D46/00C02F1/04G21F9/00
    • B01D1/305B01D19/0031C02F1/048Y10S159/12Y10S159/27Y10S159/28Y10S203/16
    • The present invention relates to a technique of concentrating waste water whereby the water content of the waste water is removed with a high decontamination factor, employs a porous membrane having a property allowing gas such as steam to permeate but not allowing a liquid such as water to do, as a membrane for concentrating the waste water, and adopts a method wherein the waste water is turned into a vapor flow and this vapor flow is made to contact the porous membrane so as for the waste water to be concentrated on the occasion when the waste water is to be concentrated by means of this porous membrane. By turning the waste water into the vapor flow, most of various metal ions, a surfactant, etc. existing in the waste water are separated from the vapor flow. Mist, metal ions in the mist and others contained in the vapor flow are removed by the aforesaid porous membrane from the steam while permeating the same. This enables the disposal of the waste water with a high decontamination factor, for a long duration and in a stable manner. When this technique of concentrating waste water is adapted to a plant for disposal of waste water of high electroconductivity produced from a nuclear power station, for instance, various tanks, a demineralizer, ion-exchange resin, etc. provided on the downstream of a concentrator are dispensed with, and thus the plant for disposal can be simplified to a large extent.
    • PCT No.PCT / JP88 / 00245 Sec。 371日期:1988年11月4日 102(e)日期1988年11月4日PCT PCT。 出版物WO88 / 06914 日本公开日1988年9月22日。本发明涉及一种浓缩废水的技术,其中废水的含水量以高净化因子除去,采用具有允许诸如蒸汽的气体渗透但不允许的性质的多孔膜 允许诸如水的液体作为用于浓缩废水的膜,并且采用其中废水变成蒸汽流的方法,并使该蒸汽流与多孔膜接触,以使废水达到 集中在废水通过该多孔膜浓缩的场合。 通过将废水转化为蒸汽流,存在于废水中的大多数各种金属离子,表面活性剂等与蒸汽流分离。 雾中的金属离子和包含在蒸气流中的其它物质被透过前述多孔膜从蒸汽中除去。 这样可以长时间和稳定地处理具有高去污因子的废水。 当这种将废水浓缩的技术适用于处理从核电站产生的高导电性废水的设备,例如设置在浓缩器下游的各种罐,脱盐装置,离子交换树脂等 可以在很大程度上简化处理设备。
    • 7. 发明授权
    • Method for analyzing impurities in liquid and apparatus therefor
    • 分析液体杂质的方法及其设备
    • US4738536A
    • 1988-04-19
    • US790464
    • 1985-10-23
    • Takehiko KitamoriShunsuke UchidaSatoru KawasakiMasahiro Kondo
    • Takehiko KitamoriShunsuke UchidaSatoru KawasakiMasahiro Kondo
    • G01N21/00G01N21/17G01N29/00
    • G01N21/1702
    • A method for analyzing impurities in liquid and an apparatus therefor are disclosed, which are adapted to classify impurities contained in various liquids to be measured into soluble substance, insoluble substance and impurities in the form of bubbles and to measure their concentration separately; especially the impurities in liquid are analyzed by the method such that photoacoustic signals obtained by irradiating a liquid to be measured with intensity-modulated light are measured; the correlation between the modulation frequency of the intensity-modulated light (light modulation frequency) and the phase of the intensity-modulated light, with which the liquid to be measured is irradiated, as well as that of their photoacoustic signals are obtained; and impurities in the liquid to be measured are detected, while classifying them into soluble and insoluble ones and those in the form of bubbles on the basis of the information thus obtained; and the apparatus comprises a light source, at least one light modulator for transforming light from the light source into intensity-modulated light having a given constant frequency, at least one cell disposed at a position, where it is irradiated with the intensity-modulated light, and containing liquid to be measured, at least one phase detection device for detecting the phase of the photoacoustic signals coming from the cell, a calculating device for analyzing impurities in the liquid on the basis of this phase detection device, and a control device for controlling the modulation frequency (light modulation frequency) of the intensity-modulated light in the light modulator.
    • 公开了一种用于分析液体中的杂质的方法及其装置,其适于将待测量的各种待测物质中所含的杂质分类为可溶性物质,不溶物质和气泡形式的杂质,并分别测量其浓度; 特别是通过以下方法分析液体中的杂质,从而测量通过用强度调制光照射被测量的液体获得的光声信号; 获得强度调制光的调制频率(光调制频率)与照射被测定液体的强度调制光的相位之间的相关性以及它们的光声信号的相关性; 检测待测液体中的杂质,同时根据得到的信息将它们分类为可溶性和不溶性物质,以及气泡形式的杂质; 并且该装置包括光源,至少一个光调制器,用于将来自光源的光转换成具有给定恒定频率的强度调制光,设置在其中被强度调制光照射的位置的至少一个单元 并且包含待测量液体,用于检测来自该单元的光声信号的相位的至少一个相位检测装置,用于基于该相位检测装置分析液体中的杂质的计算装置,以及用于 控制光调制器中的强度调制光的调制频率(光调制频率)。
    • 8. 发明授权
    • Method and apparatus for measuring dissolved gas concentrations
    • 测量溶解气体浓度的方法和装置
    • US4578154A
    • 1986-03-25
    • US746010
    • 1985-06-19
    • Masao KitamuraNorio NakayamaRyoei KatsuraHidefumi IbeShunsuke Uchida
    • Masao KitamuraNorio NakayamaRyoei KatsuraHidefumi IbeShunsuke Uchida
    • G01N27/404G01N27/416G01N27/49G01N27/54
    • G01N27/404G01N27/4045G01N27/49
    • Two dissolved gas components in sample water, for example, oxygen and hydrogen in core water, are readily quantitatively determined in one and same membrane-type oxygen meter by using a membrane producing an overlapped potential region where a potential region for an oxidation limiting current plateau is overlapped with that for a reduction limiting current plateau between two dissolved gas components, and applying to between a pair of an electrode and a counter-electrode a more positive potential than the equilibrium potential for oxidation-reduction reaction of one of the two dissolved gas components principally, thereby measuring a current generated between the electrodes, and a more negative potential than the equilibrium potential for oxidation-reduction reaction of the other dissolved gas component, when desired, thereby measuring a current generated between the electrodes, and quantitatively determining a concentration of the first dissolved gas component from the latter current quantity and quantitatively determining a concentration of the other dissolved gas component from a difference between the said two current quantities.
    • 样品水中的两种溶解气体组分,例如核心水中的氧气和氢气,可以通过使用产生重叠电位区域的膜在一个相同的膜式氧气计中进行定量测定,其中氧化极限电流平台的电位区域 与用于两个溶解气体组分之间的还原极限电流平台的那些重叠,并且在一对电极和对电极之间施加比两个溶解气体之一的氧化还原反应的平衡电位更正的电位 从而测量电极之间产生的电流,从而测量电极之间产生的电流,并且在需要时测量另外的溶解气体成分的氧化 - 还原反应的平衡电位的负电势,从而测量电极之间产生的电流,并定量测定浓度 的第一溶解气体组分 量并且根据所述两个电流量之间的差定量地确定其它溶解气体组分的浓度。
    • 9. 发明授权
    • Control rods and method of producing same
    • 控制棒及其制造方法
    • US4451428A
    • 1984-05-29
    • US222060
    • 1981-01-02
    • Eiichi NishimuraShunsuke UchidaMasao KitamuraKoichi SaitoEishi IbeTatsuo Hayashi
    • Eiichi NishimuraShunsuke UchidaMasao KitamuraKoichi SaitoEishi IbeTatsuo Hayashi
    • G21C7/10G21C7/113G21C7/24
    • G21C7/113G21Y2002/206G21Y2004/10G21Y2004/30Y02E30/31Y02E30/39
    • A control rod for a boiling-water reactor having blades arranged in the form of a cross in transverse cross section includes a plurality of poison tubes disposed therein. Boron carbide powder which is a neutron absorbing material causing an (n, .alpha.) reaction to take place is charged in the poison tubes. The control rod has plates of Hf-Zr alloy arranged in the blades in a position nearer to a forward end of the control rod at which the control rod is inserted in a reactor core than the poison tubes. The plates of Hf-Zr alloy are formed of an alloy of Hf having a large neutron absorption cross section and Zr having a small neutron absorption cross section. The concentration of Hf in the plates of Hf-Zr alloy is successively reduced in going from an end thereof adjacent the poison tubes toward and end thereof at the inserting end of the control rod. The plates of Hf-Zr alloy and the poison tubes have the same neutron absorbing capacity at the boundary therebetween at which they are in contact with each other.
    • 一种沸水反应器的控制棒,其具有以十字横截面形式布置的叶片,其中包括多个设置在其中的毒药管。 将引起(n,α)反应的中子吸收材料的碳化硼粉末装入毒药管中。 控制杆具有在叶片中布置在更靠近控制棒的前端的位置的Hf-Zr合金板,在该位置控制杆插入反应堆芯中而不是毒药管。 Hf-Zr合金的板由具有大的中子吸收截面的Hf的合金和具有小的中子吸收截面的Zr形成。 Hf-Zr合金板中Hf的浓度从控制棒插入端的毒药管附近的端部朝向其末端逐渐减小。 Hf-Zr合金板和毒药管在它们彼此接触的边界处具有相同的中子吸收能力。