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1. 发明授权

US6017603A Ultraviolet-curing adhesive composition and article 失效
标题翻译：紫外线固化胶粘剂组合物和制品
公开(公告)号：US6017603A
公开(公告)日：2000-01-25
申请号：US981576
申请日：1997-12-22
申请人： Kiyohisa Tokuda , Kenji Yoshida , Kazuhiko Ishii , Minoru Yokoshima
发明人： Kiyohisa Tokuda , Kenji Yoshida , Kazuhiko Ishii , Minoru Yokoshima
IPC分类号： C08F2/46 , C08F290/06 , G11B7/26 , B32B3/00 , B32B3/02
CPC分类号： C08F290/064 , C08F290/067 , G11B7/26 , Y10S428/904 , Y10S428/91 , Y10S428/913 , Y10S428/916 , Y10S428/927 , Y10T428/187 , Y10T428/195 , Y10T428/21
摘要： An ultraviolet-curable adhesive composition which comprises (A) a bisphenol type epoxy (meth)acrylate having a molecular weight of 450 to 3,000, (B) a urethane (meth)acrylate having a molecular weight of 400 to 10,000, (E) a (meth)acrylate monomer other than (A) and (B), and (F) a photopolymerization initiator, and an article having a cured layer of the above adhesive composition.
摘要翻译： PCT No.PCT / JP97 / 01445 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT 1997年4月24日PCT PCT。公开号WO97 / 40115 PCT 日期：1997年10月30日含有（A）分子量为450〜3000的双酚型环氧（甲基）丙烯酸酯，（B）分子量为400〜10000的氨基甲酸酯（甲基）丙烯酸酯的紫外线固化型粘合剂组合物，（E）除（A）和（B）以外的（甲基）丙烯酸酯单体，和（F）光聚合引发剂，以及具有上述粘合剂组合物的固化层的制品。

2. 发明授权

US06254958B1 Photosensitive resin composition and articles 失效
标题翻译：感光树脂组合物和制品
公开(公告)号：US06254958B1
公开(公告)日：2001-07-03
申请号：US09117128
申请日：1998-07-22
申请人： Kenji Yoshida , Kiyohisa Tokuda , Kazuhiko Ishii
发明人： Kenji Yoshida , Kiyohisa Tokuda , Kazuhiko Ishii
IPC分类号： B32B902
CPC分类号： C09D4/00 , B41M5/5209 , B41M5/5236 , B41M5/5245 , B41M5/5254 , Y10T428/24934 , Y10T428/31975 , Y10T428/31982 , Y10T428/31993
摘要： The present invention aims to develop a photosensitive resin composition which exhibits a rapid ink absorption rate, which has an excellent water resistance, and which is appropriate for providing an ink receiving layer forming a sharp ink dot shape and having an excellent color formability of ink. A photosensitive resin composition forming an excellent ink receiving layer is obtained by incorporating at least one selected from an ethylenically unsaturated group-containing compound having quaternary nitrogen and a grain flour (filler) such as a wheat flour or the like in a photosensitive resin composition containing a quaternary nitrogen-free ethylenically unsaturated group-containing compound, a photopolymerization initiator etc.
摘要翻译：本发明旨在开发一种具有快速吸墨速率的感光性树脂组合物，它具有优异的耐水性，适用于提供形成清晰墨点形状并具有优异的油墨着色性的油墨接收层。形成油墨接收层优异的感光性树脂组合物通过将含有季氮的含烯键式不饱和基团的化合物和小麦粉等粒状粉末（填料）中的至少一种掺入含有含无氮烯键式不饱和基团的化合物，光聚合引发剂等

3. 发明申请

US20060074209A1 Uv-cure adhesive composition for optical disk, cured material and goods 审中-公开
标题翻译： Uv固化胶粘剂组合物用于光盘，固化材料和商品
公开(公告)号：US20060074209A1
公开(公告)日：2006-04-06
申请号：US10535142
申请日：2003-11-18
申请人： Go Mizutani , Kiyohisa Tokuda , Kazuhiko Ishii
发明人： Go Mizutani , Kiyohisa Tokuda , Kazuhiko Ishii
IPC分类号： C08F118/02
CPC分类号： C09J4/00 , C08F290/064 , C09J133/06 , C09J163/10 , G03F7/027 , G03F7/038 , G11B7/256 , C08F220/32 , C08F222/1006
摘要： A UV-cure adhesive for bonding an optical disk substrates one or both of which having a semitransparent reflective film of silver, a silver alloy, or the like. The thus produced bonded optical disk has a high durability equivalent to those of optical disks using a conventional gold semitransparent reflective film and is free of voids (air bubbles) that might be produced while the optical disk is manufactured by an optical disk manufacturing apparatus. The degradation in reflectance of the semitransparent reflective film can be suppressed even when the produced optical disk is exposed to direct sunlight for a long time. A UV-cure adhesive resin composition for bonding optical disk substrates contains (A) an epoxy (meth)acrylate, 2,2-dimethoxy-1,2-diphenylethan-1-one and (E) a monofunctional, bifunctional, trifunctional (meth)acrylate monomer, and has an electrical resistivity of 1000 MΩ·cm or less at 25° C.
摘要翻译：一种UV固化粘合剂，用于粘结其中一个或两个具有银半透明反射膜，银合金等的光盘基片。如此制造的粘合光盘具有与使用传统的金半透明反射膜的光盘相当的耐久性，并且在由光盘制造装置制造光盘时可以产生空隙（气泡）。即使所制造的光盘长时间暴露在阳光直射下，也可以抑制半透射反射膜的反射率的劣化。用于粘合光盘基片的UV固化粘合树脂组合物包含（A）环氧（甲基）丙烯酸酯，2,2-二甲氧基-1,2-二苯基乙烷-1-酮和（E）单官能，双官能，三官能（甲基））丙烯酸酯单体，在25℃下的电阻率为1000Moga.cm以下

4. 发明申请

US20060223904A1 Adhesive composition and optical disc prepared therewith 审中-公开
标题翻译：粘合剂组合物和用其制备的光盘
公开(公告)号：US20060223904A1
公开(公告)日：2006-10-05
申请号：US10567294
申请日：2004-08-11
申请人： Go Mizutani , Kiyohisa Tokuda , Kazuhiko Ishii , Masahiro Naitoh , Takeo Miyake
发明人： Go Mizutani , Kiyohisa Tokuda , Kazuhiko Ishii , Masahiro Naitoh , Takeo Miyake
IPC分类号： C08F290/00 , C08F2/46
CPC分类号： C09J163/10 , G11B7/256
摘要： The present invention provides an adhesive composition (a UV-curable resin composition) comprising a bisphenol type epoxy(meth)acrylate (A), a di(meth)acrylate compound (B) having a cyclic ether structure, and a photo-polymerization initiator (C), and a bonded optical disk which is adhered with a cured product of said adhesive composition. By adhering with said composition optical disk substrates having a translucent reflection film or a total reflection film comprising silver, a silver alloy, or the like, and obtaining a bonded optical disk, high durability equivalent to those of conventional bonded optical disks in which a translucent reflection film of gold is used, and high adhesion strength between a reflection film and an adhesive cured product, and a polycarbonate substrate and an adhesive cured product, can be obtained.
摘要翻译：本发明提供包含双酚型环氧（甲基）丙烯酸酯（A），具有环状醚结构的二（甲基）丙烯酸酯化合物（B））和光聚合引发剂的粘合剂组合物（UV可固化树脂组合物）（C）和粘合光盘，其粘合有所述粘合剂组合物的固化产物。通过粘合具有半透明反射膜的所述组成光盘基片或包含银，银合金等的全反射膜，并获得粘结光盘，与传统的粘合光盘相比，具有高透光性使用金的反射膜，并且可以获得反射膜和粘合剂固化产物之间的高粘合强度，以及聚碳酸酯基材和粘合剂固化产物。

5. 发明授权

US07052756B2 Adhesive for optical disk and optical disk 有权
标题翻译：光盘和光盘粘合剂
公开(公告)号：US07052756B2
公开(公告)日：2006-05-30
申请号：US10477818
申请日：2002-05-15
申请人： Kiyohisa Tokuda , Kazuhiko Ishii , Go Mizutani
发明人： Kiyohisa Tokuda , Kazuhiko Ishii , Go Mizutani
IPC分类号： B32B3/02
CPC分类号： G11B7/256 , C08G2190/00 , C09J4/00 , C09J175/16 , G11B7/24 , G11B7/259 , G11B7/2595 , Y10T428/21 , Y10T428/31942
摘要： The present invention provides an adhesive that can provide an excellent durability (reliability) to a bonded optical disk having a translucent reflection film comprising silicone, silver or a silver alloy. The adhesive of the present invention contains a (meth)acrylate monomer (A) having a solution resistance of 1.0×1010 Ω·cm or more.
摘要翻译：本发明提供一种能够对具有硅酮，银或银合金的半透明反射膜的粘合光盘提供优异的耐久性（可靠性）的粘合剂。本发明的粘合剂含有溶解电阻为1.0×10 10Ω·cm以上的（甲基）丙烯酸酯单体（A）。

6. 发明授权

US06294239B1 Ultraviolet-curable adhesive composition 失效
标题翻译：紫外线固化型粘合剂组合物
公开(公告)号：US06294239B1
公开(公告)日：2001-09-25
申请号：US09569668
申请日：2000-05-12
申请人： Kiyohisa Tokuda , Kazuhiko Ishii
发明人： Kiyohisa Tokuda , Kazuhiko Ishii
IPC分类号： B32B302
CPC分类号： G11B7/256 , C08F290/067 , C08F290/14 , C09J4/00 , C09J4/06 , G11B7/2533 , G11B7/2534 , G11B7/2542 , G11B7/2585 , G11B7/26 , C08F222/1006 , C08F220/18 , C08F220/30
摘要： An ultraviolet-curable adhesive composition comprising a photopolymerization initiator whose molar absorption coefficient at a wavelength of 360-450 nm is at least 400 and an ultraviolet-curable compound. The adhesive composition of this invention can bond substrates which show transmittances of 0.01-20% to all of energy beams of a wavelength of 280-380 nm, to one another.
摘要翻译：包含光聚合引发剂的紫外线固化性粘合剂组合物，其波长360-450nm的摩尔吸光系数为400以上，紫外线固化性化合物。本发明的粘合剂组合物可以将表现出波长为280-380nm的所有能量束的透射率为0.01-20％的基板彼此粘合。

7. 发明申请

US20080152857A1 Adhesive Compositon for Optical Disk, Cured Product and Article 审中-公开
标题翻译：光盘粘合剂，固化产品及其制品
公开(公告)号：US20080152857A1
公开(公告)日：2008-06-26
申请号：US11660013
申请日：2005-08-10
申请人： Go Mizutani , Kiyohisa Tokuda , Kazuhiko Ishii , Masahiro Naitou , Takeo Miyake
发明人： Go Mizutani , Kiyohisa Tokuda , Kazuhiko Ishii , Masahiro Naitou , Takeo Miyake
IPC分类号： C08F2/46 , B32B3/26
CPC分类号： G11B7/256 , C09J175/16
摘要： Disclosed is an adhesive which enables to obtain a bonded optical disk, wherein optical disks having a total reflection film or a translucent reflection film made of silver or a silver alloy are bonded together, which exhibits high adhesion strength between the reflection film and a cured product of the adhesive as well as between a polycarbonate substrate and the cured product of the adhesive, while having high durability equivalent to those of the conventional optical disks using translucent reflective film made of gold. Specifically disclosed is an ultraviolet-curable adhesive resin composition containing a bisphenol-type epoxy (meth)acrylate (A), a di(meth)acrylate (B) and a photopolymerization initiator (C) which is characterized in that the di(meth)acrylate (B) is composed of one or more selected from a di(meth)acrylate (B-1) having an adipate structure, a di(meth)acrylate (B-2) having a caprolactone-modified structure, an alkylene oxide-modified neopentyl glycol di(meth)acrylate compound (B-3) and an alkylene oxide-modified 1,6-hexanediol di(meth)acrylate compound (B-4).
摘要翻译：公开了一种能够获得粘合光盘的粘合剂，其中具有全反射膜或由银或银合金制成的半透明反射膜的光盘结合在一起，其在反射膜和固化产物之间显示出高的粘合强度的粘合剂以及聚碳酸酯基材和粘合剂的固化产物之间，同时具有与使用由金制成的半透明反射膜的常规光盘相当的高耐用性。具体公开了含有双酚型环氧（甲基）丙烯酸酯（A），二（甲基）丙烯酸酯（B）和光聚合引发剂（C））的紫外线固化性粘合性树脂组合物，其特征在于，所述二（甲基）丙烯酸酯（B）由选自具有己二酸酯结构的二（甲基）丙烯酸酯（B-1），具有己内酯改性结构的二（甲基）丙烯酸酯（B-2），烯化氧 - 改性新戊二醇二（甲基）丙烯酸酯化合物（B-3）和烯化氧改性的1,6-己二醇二（甲基）丙烯酸酯化合物（B-4）。

8. 发明申请

US20060264588A1 Ultraviolet-curing resin composition and cured product thereof 审中-公开
标题翻译：紫外线固化树脂组合物及其固化物
公开(公告)号：US20060264588A1
公开(公告)日：2006-11-23
申请号：US10568899
申请日：2004-08-24
申请人： Kiyohisa Tokuda , Kazuhiko Ishii , Go Mizutani , Takeo Miyake
发明人： Kiyohisa Tokuda , Kazuhiko Ishii , Go Mizutani , Takeo Miyake
IPC分类号： C08F2/00
CPC分类号： G11B7/256 , C08F290/06 , C08F290/061 , G11B7/2534 , G11B7/2542
摘要： The present invention enables to provide a highly durable protective coating film or adhesive layer for high-density optical disks with less warp, which is superior in transmission for blue lasers, transparency and low water-absorption, by using an ultraviolet-curing resin composition essentially comprising a compound (A) represented by the following general formula (I), [Chemical Formula 7], (wherein, R represents each independently a hydrogen atom or a C1-C3 alkyl group, and n and m each represents the number of repetition from 0 to 5) and a photopolymerization initiator.
摘要翻译：本发明能够通过使用紫外线固化树脂组合物基本上提供用于蓝色激光器的透射率优异，透明性和低吸水性的高密度光盘的高度耐久的保护涂膜或粘合剂层包含由以下通式（I）表示的化合物（A），[化学式7]（其中，R表示各自独立地为氢原子或C1-C3烷基，n和m各自表示重复次数 0至5）和光聚合引发剂。

9. 发明授权

US06284185B1 Ultraviolet-curable adhesive composition for bonding opaque substrates 失效
标题翻译：用于粘合不透明基材的紫外线固化型粘合剂组合物
公开(公告)号：US06284185B1
公开(公告)日：2001-09-04
申请号：US09521547
申请日：2000-03-09
申请人： Kiyohisa Tokuda , Kazuhiko Ishii
发明人： Kiyohisa Tokuda , Kazuhiko Ishii
IPC分类号： B29C3508
CPC分类号： G11B7/256 , C08F290/067 , C08F290/14 , C09J4/00 , C09J4/06 , G11B7/2533 , G11B7/2534 , G11B7/258 , G11B7/26 , C08F220/18 , C08F220/30 , C08F222/1006
摘要： An ultraviolet-curable adhesive composition comprising a photopolymerization initiator whose molar absorption coefficient at a wavelength of 360-450 nm is at least 400 and an ultraviolet-curable compound. The adhesive composition of this invention can bond substrates which show transmittances of 0.01-20% to all of energy beams of a wavelength of 280-380 nm, to one another such as base boards for an optical disk.
摘要翻译：包含光聚合引发剂的紫外线固化性粘合剂组合物，其波长360-450nm的摩尔吸光系数为400以上，紫外线固化性化合物。本发明的粘合剂组合物可以将对于波长280-380nm的能量束的透射率为0.01-20％的基板彼此粘合，例如用于光盘的基板。

10. 发明申请

US20110052855A1 Ultraviolet-Curable Resin Composition For Optical Disk, Cured Product And Optical Disk 审中-公开
标题翻译：用于光盘，固化产品和光盘的紫外线固化树脂组合物
公开(公告)号：US20110052855A1
公开(公告)日：2011-03-03
申请号：US12990689
申请日：2009-05-27
申请人： Daisuke Kobayashi , Masahiro Naitou , Go Mizutani , Hitoshi Takahashi , Kiyohisa Tokuda
发明人： Daisuke Kobayashi , Masahiro Naitou , Go Mizutani , Hitoshi Takahashi , Kiyohisa Tokuda
IPC分类号： B32B3/02 , C08K5/37
CPC分类号： C08F2/50 , C08F2/44 , C08F8/34 , C08F290/067 , C08G18/4854 , C08G18/672 , C08G18/755 , C08G77/46 , C08L63/10 , C09D175/16 , G03F7/031 , G11B7/2467 , G11B7/2542 , G11B7/256 , G11B7/266 , C08G18/48 , C08F2222/1013
摘要： The present invention relates to an ultraviolet-curable resin composition for an optical disk containing a sulfur-containing compound (A) represented by the following formula (1): (wherein, R1 and R2 each dependently represent a hydrogen atom, a hydroxy group, an alkyloxy group, an alkyl group, an aryl group, a carboxy group, an alkylthio ether group or a halogen atom) a photopolymerizable compound (B) and a photopolymerization initiator (C), and an optical disk having a thin film of the cured product of said resin composition, particularly an optical disk having a reflective film comprising silver or a silver alloy; and said optical disk is prevented from changing the properties of its reflective film comprising silver or a silver alloy, and thus has a higher durability.
摘要翻译：本发明涉及含有下式（1）表示的含硫化合物（A）的光盘用紫外线固化性树脂组合物：（其中，R1和R2各自依赖性地表示氢原子，羟基，烷氧基，烷基，芳基，羧基，烷硫基醚基或卤素原子）光聚合性化合物（B）和光聚合引发剂（C），以及具有固化的所述树脂组合物的产物，特别是具有包含银或银合金的反射膜的光盘; 并且防止所述光盘改变其包含银或银合金的反射膜的性质，因此具有较高的耐久性。

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