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    • 2. 发明授权
    • High contrast negative image-forming process
    • 高对比度负成像过程
    • US4929535A
    • 1990-05-29
    • US214892
    • 1988-06-30
    • Toshiro TakahashiKimitaka KameokaYoshio Inagaki
    • Toshiro TakahashiKimitaka KameokaYoshio Inagaki
    • G03C1/06G03C5/26G03C5/29
    • G03C1/061Y10S430/15
    • This invention is a process of quickly forming high contrast negative images, which are useful for photomechanical process, by development-processing a silver halide photographic material containing a hydrazine derivative in at least one of silver halide emulsion layer(s) and other hydrophilic colloid layer(s) after imagewise exposure in the existence of a compound represented by general formula (A); ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represents an alkyl group, a cycloalkyl group, an aryl group, an alkenyl group, a cycloalkenyl group, or a heterocyclic ring residue, these groups may have a substituent; m represents an integer; L represents an m-valent organic group bonded to the P atom through a carbon atom; n represents an integer of 1 to 3; and X represents an n-valent anion; said X may be bonded to L; using a stable processing solution. Furthermore, the invention is a high contrast negative type silver halide photographic material containing the compound of the above-described general formula (A) in at least one of the silver halide emulsion layer(s) and other hydrophilic colloid layer(s) thereof.
    • 本发明是通过在卤化银乳剂层和其它亲水胶体层中的至少一种中含有肼衍生物的卤化银照相材料进行显影处理来快速形成用于光机械处理的高对比度负像的方法 在通式(A)表示的化合物的存在下成像曝光后, (A)其中R1,R2和R3各自表示烷基,环烷基,芳基,烯基,环烯基或杂环残基,这些基团可以具有取代基; m表示整数; L表示通过碳原子与P原子结合的m价有机基团; n表示1〜3的整数, X表示n价阴离子; 所述X可以与L键合; 使用稳定的处理方案。 此外,本发明是在至少一个卤化银乳剂层和其它亲水胶体层中含有上述通式(A)的化合物的高对比度负型卤化银照相材料。
    • 3. 发明授权
    • Silver halide photographic material and method for forming high contrast
negative image using the same
    • 卤化银照相材料和使用其形成高对比度负像的方法
    • US4681836A
    • 1987-07-21
    • US933258
    • 1986-11-20
    • Nobuaki InoueYoshio InagakiKimitaka Kameoka
    • Nobuaki InoueYoshio InagakiKimitaka Kameoka
    • G03C1/06G03C1/09G03C5/29G03C1/10G03C1/34
    • G03C1/06G03C1/061G03C1/09Y10S430/15
    • A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.3 to result in formation of high contrast negative image.
    • 一种卤化银照相材料,其具有至少一个卤化银乳剂层,其含有每摩尔银含有1×10 -8至8×10 -6摩尔铑盐的卤化银颗粒,并且在所述乳剂层或另一亲水性胶体层中含有化合物 由式(I)表示的R1-NHNH-G-R2(I)其中R1表示脂族基团或芳族基团; R2表示氢原子,取代或未取代的烷基,取代或未取代的芳基,取代或未取代的烷氧基或取代或未取代的芳氧基; G表示羰基,磺酰基,亚砜氧基,磷酰基或N-取代或未取代的亚氨基; 暴露于成像图案,然后用含有0.15摩尔/升或更多亚硫酸根离子的显影剂显影处理,并将pH调节至9.5至12.3,导致形成高对比度负像。
    • 6. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US4824764A
    • 1989-04-25
    • US051800
    • 1987-05-20
    • Yoshio InagakiNobuaki Inoue
    • Yoshio InagakiNobuaki Inoue
    • G03C1/06G03C1/30G03C1/10G03C1/34
    • G03C1/30G03C1/061Y10S430/15
    • A silver halide photographic material comprising a support having at least one light-sensitive silver halide emulsion layer on the support, wherein at least one of the emulsion layer and other constituent layers contains at least one compound represented by formula (I) and at least one compound represented by formula (II): ##STR1## wherein R.sub.0 is an organic group having 7 to 30 carbon atoms, A is a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group, and X is NH or 0, ##STR2## wherein R.sub.1 is an aliphatic, aromatic or heterocyclic group; R.sub.2 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted amino group; G is a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted iminomethylene group (NH.dbd.C
    • 一种卤化银照相材料,其包括在载体上具有至少一个感光卤化银乳剂层的载体,其中乳剂层和其它构成层中的至少一个含有至少一种由式(I)表示的化合物和至少一种 由式(II)表示的化合物:其中R 0是具有7至30个碳原子的有机基团,A是取代或未取代的亚苯基或取代或未取代的亚萘基,X是NH或O (II)其中R1是脂族,芳族或杂环基团; R2是氢原子,取代或未取代的烷基,取代或未取代的芳烷基,取代或未取代的烷氧基,取代或未取代的芳基,取代或未取代的芳氧基或取代或未取代的氨基; G为羰基,磺酰基,亚砜氧基,磷酰基或N-取代或未取代的亚氨基亚甲基(NH = C <); R10和R100均为氢原子,或一个或R10和R100为氢原子,另一个为取代或未取代的烷基磺酰基,取代或未取代的芳基磺酰基或酰基; 和G,R2,R100和G,R2和R100连接的氮原子可以形成腙的部分结构(-N = C <),条件是由式(II)表示的化合物与 由式(I)表示的化合物,R1和R2的总碳原子数为14〜60。
    • 7. 发明授权
    • Silver halide photographic material capable of being handled in a bright
room during steps of photomechanical process
    • 卤化银照相材料能够在光机械过程的步骤中在明亮的房间中处理
    • US4847180A
    • 1989-07-11
    • US44856
    • 1987-05-01
    • Junji MiyataKen-ichi KuwabaraToshiro TakahashiYoshio InagakiShigeo Hirano
    • Junji MiyataKen-ichi KuwabaraToshiro TakahashiYoshio InagakiShigeo Hirano
    • G03C1/005G03C1/06
    • G03C1/061Y10S430/15
    • A silver halide photographic material which may be handled in a bright room, which comprises a support having provided thereon at least one silver halide emulsion layer containing silver chlorobromide grains (bromide content: not more than 20 mol %) or silver chloride grains, said emulsion layer containing 1.times.10.sup.-7 mol to 5.times.10.sup.-4 mol of a rhodium salt per mol of silver, and said emulsion layer or at least one other hydrophilic colloid layer containing at least one hydrazine derivative represented by the following general formula (I): ##STR1## wherein R represents an organic group having 1 to 30 carbon atoms; A represents a substituted or unsubstituted phenylene group or a substituted or unsubstituted naphthylene group; X represents --NH--or --O--; L.sub.1 represents a straight, branched or cyclic alkylene group having 1 to 20 carbon atoms, an aralkylene group having 7 to 20 carbon atoms, a phenylene group, or a divalent group having 1 to 20 carbon atoms, wherein these groups are linked to each other through --O--, --S--, --CO--, --CONH--or --COO--; L.sub.2 represents --CONH--, --SO.sub.2 NH--, --O--or --S--; i and j each independently represents 0 or 1; and B represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted phenyl group having 6 to 20 carbon atoms, a substituted or unsubstituted aralkyl group having a total of 7 to 20 carbon atoms and 1 to 3 carbon atoms in the alkyl moiety thereof, a substituted or unsubstituted alkoxy group haivng 1 to 20 carbon atoms, or a substituted or unsubstituted phenoxy group having 6 to 20 carbon atoms.
    • 一种卤化银照相材料,其可以在明亮的房间中处理,其包括其上提供有至少一个含有氯化银溴化银颗粒(溴含量:不大于20mol%)的卤化银乳剂层或氯化银颗粒的载体,所述乳液 含有每摩尔银1×10-7摩尔至5×10-4摩尔铑盐的层,所述乳剂层或至少一种含有至少一种由以下通式(I)表示的肼衍生物的其它亲水胶体层:(I)其中R表示碳原子数1〜30的有机基团。 A表示取代或未取代的亚苯基或取代或未取代的亚萘基; X表示-NH-或-O-; L1表示碳原子数1〜20的直链,支链或环状亚烷基,碳原子数7〜20的亚芳基,亚苯基或碳原子数1〜20的二价基,其中,这些基彼此相连 -O - , - S - , - CO - , - CONH-或-COO-; L 2表示-CONH-,-SO 2 NH-, - O-或-S-; i和j各自独立地表示0或1; B表示氢原子,取代或未取代的碳原子数1〜20的烷基,取代或未取代的碳原子数6〜20的苯基,取代或未取代的碳原子数为7〜20的芳烷基和1 至少3个碳原子,取代或未取代的碳原子数1〜20的烷氧基,或取代或未取代的碳原子数6〜20的苯氧基。
    • 8. 发明授权
    • Silver halide photographic material and method for forming superhigh
contrast negative images using the same
    • 卤化银照相材料和使用其形成超高对比度负像的方法
    • US4987052A
    • 1991-01-22
    • US139230
    • 1987-12-29
    • Shigeo HiranoKazunobu KatohYoshio InagakiNobuaki Inoue
    • Shigeo HiranoKazunobu KatohYoshio InagakiNobuaki Inoue
    • G03C1/06G03C1/12
    • G03C1/12G03C1/061
    • A silver halide photographic material is disclosed, which comprises at least one silver halide emulsion layer on a support, at least one of the emulson layer and other layers contains at least one hydrazine derivative and at least one of these layers contains at least one compound having both a silver halide adsorbing group and an acid group represented by the general formula (I):C-L-D (I)wherein C represents a group that enhances adsorption to silver halide, D represents an acid group, and L represents a divalent linking group,and possessing substantially no absorption maximum in the visible region. A method for forming superhigh contrast negative images is also disclosed, comprising imagewise exposing this silver halide photographic material, followed by developing with a developing solution containing sulfite ions in an amount of about 0.15 mol or more per liter and having a pH of about 10.5 to about 12.3.
    • 公开了一种卤化银照相材料,其包含至少一个卤化银乳剂层,其中至少一个乳化剂层和其它层含有至少一个肼衍生物,并且这些层中的至少一个含有至少一种具有 卤化银吸附基团和由通式(I)表示的酸基团:CLD(I)其中C表示增强对卤化银的吸附的基团,D表示酸基,L表示二价连接基团, 在可见区域基本上没有吸收最大值。 还公开了一种用于形成超高对比度负像的方法,包括成像曝光该卤化银照相材料,然后用含有约0.15摩尔或更高/升每升的量的亚硫酸根离子的显影溶液显影,并具有约10.5的pH至 约12.3。