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    • 6. 发明授权
    • Modified carbon products and inks and coatings containing modified
carbon products
    • 改性碳产品和含有改性碳产品的油墨和涂料
    • US5707432A
    • 1998-01-13
    • US663707
    • 1996-06-14
    • Curtis E. AdamsJames A. Belmont
    • Curtis E. AdamsJames A. Belmont
    • C09C1/56C09C3/08C09D7/12C09D11/02
    • C09D11/324C09C1/56C09C3/08C09D11/037C09D7/1225C01P2006/12C01P2006/22C01P2006/62C01P2006/63C01P2006/64C08K3/04C08K9/04
    • A modified carbon product is described which comprises carbon having attached at least one organic group. The organic group comprises a) at least one aromatic group or a C.sub.1 -C.sub.12 alkyl group and b) at least one ionic group, at least one ionizable group, or a mixture of an ionic group and an ionizable group. The aromatic group or the C.sub.1 -C.sub.12 alkyl group of the organic group is directly attached to the carbon and the organic group is present at a level of from about 0.10 to about 2.5 micromoles/m.sup.2 of the carbon used based on CTAB or t-area of the carbon or in an amount such that the modified carbon product has a residue value of more than about 5 wt %. Also described are aqueous and non-aqueous inks and coatings containing the modified carbon product. A method to increase the flow of an ink, as measured by glass plate flow, by incorporating the modified carbon product as part of the ink is also disclosed. Lastly, non-aqueous ink and coating formulations are described which contain an appropriate solvent and a modified carbon product comprising carbon having attached at least one organic group, wherein the organic group comprises a) at least one aromatic group or C.sub.1 -C.sub.12 alkyl group, and b) at least one ionic group, at least one ionizable group, or a mixture of an ionic group and an ionizable group, wherein the organic group is present in any amount.
    • 描述了包含连接至少一个有机基团的碳的改性碳产物。 有机基团包括a)至少一个芳族基团或C 1 -C 12烷基和b)至少一个离子基团,至少一个可离子化基团,或离子基团和可离子化基团的混合物。 有机基团的芳族基团或C 1 -C 12烷基直接连接到碳上,并且有机基团以基于CTAB或t面积的所用碳的约0.10至约2.5微摩尔/ m 2的水平存在 的碳或其量使得改性碳产物具有大于约5重量%的残留值。 还描述了含有改性碳产物的水性和非水性油墨和涂料。 还公开了通过将改性碳产物作为油墨的一部分并入而增加墨水流动的方法,如通过玻璃板流量测量的。 最后,描述了含有合适溶剂和包含连接至少一个有机基团的碳的改性碳产物的非水性油墨和涂料配方,其中有机基团包括a)至少一个芳族基团或C 1 -C 12烷基, 和b)至少一个离子基团,至少一个可离子化基团,或离子基团和可离子化基团的混合物,其中所述有机基团以任何量存在。
    • 9. 发明授权
    • Polymeric products containing modified carbon products and methods of making and using the same
    • 含有改性碳产品的聚合产品及其制造和使用方法
    • US06472471B2
    • 2002-10-29
    • US09210370
    • 1998-12-14
    • Joel M. CookeCollin P. GallowayMark A. BissellCurtis E. AdamsMichael C. YuJames A. BelmontRobert M. Amici
    • Joel M. CookeCollin P. GallowayMark A. BissellCurtis E. AdamsMichael C. YuJames A. BelmontRobert M. Amici
    • C08L6702
    • C08K9/04
    • Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: —Ar—CO2—R or —CnH2nCO2—R where R is an organic group, monomeric group, or a polymeric group. The third type of modified carbon product contains a) a carbon product having attached at least one organic group directly attached to the carbon product, b) at least one ionic group, ionizable group, or a mixture thereof attached to the organic group, and c) at least one counter-ionic group or counter-ionizable group with at least one organic group, monomeric group, or polymeric group, or mixture thereof, where the counter-ionic or counter-ionizable group is attached to the ionic and/or ionizable group. A method of improving the dispersion of carbon products in polymers is also disclosed which involves dispersing the modified carbon products described above in a polymer to form a polymeric product.
    • 公开了可形成含有改性碳产物和聚合物的聚合产物的一部分的各种改性碳产品。 公开的一种类型的改性碳产物是连接有至少一个有机基团,单体基团或聚合物基团的碳产物。 公开的另一种类型的改性碳产物是具有下式基团的碳产物:-Ar-CO 2 -R或-CnH 2 NCO 2 -R,其中R是有机基团,单体基团或聚合物基团。 第三种类型的改性碳产物包含a)具有连接至少一个与碳产物连接的有机基团的碳产物,b)连接到有机基团上的至少一个离子基团,可离子化基团或其混合物,c )至少一种具有至少一个有机基团,单体基团或聚合物基团或其混合物的反离子基团或可逆离子基团,其中所述反离子或可逆离子基团连接到离子和/或可离子化的基团 组。 还公开了一种改进聚合物中碳产物分散的方法,其中包括将上述改性碳产物分散在聚合物中以形成聚合物。
    • 10. 发明授权
    • Modified carbon products and inks and coatings containing modified
carbon products
    • 改性碳产品和含有改性碳产品的油墨和涂料
    • US5885335A
    • 1999-03-23
    • US873021
    • 1997-06-11
    • Curtis E. AdamsJames A. Belmont
    • Curtis E. AdamsJames A. Belmont
    • C09C1/56C09C3/08C09D7/12C09D11/02
    • C09D11/324C09C1/56C09C3/08C09D11/037C09D7/1225C01P2006/12C01P2006/22C01P2006/62C01P2006/63C01P2006/64C08K3/04C08K9/04
    • A modified carbon product is described which comprises carbon having attached at least one organic group. The organic group comprises a) at least one aromatic group or a C.sub.1 -C.sub.12 alkyl group and b) at least one ionic group, at least one ionizable group, or a mixture of an ionic group and an ionizable group. The aromatic group or the C.sub.1 -C.sub.12 alkyl group of the organic group is directly attached to the carbon and the organic group is present at a level of from about 0.10 to about 2.7 micromoles/m.sup.2 of the carbon used based on CTAB or t-area of the carbon or in an amount such that the modified carbon product has a residue value of more than about 5 wt %. Also described are aqueous and non-aqueous inks and coatings containing the modified carbon product. A method to increase the flow of an ink, as measured by glass plate flow, by incorporating the modified carbon product as part of the ink is also disclosed. Lastly, non-aqueous ink and coating formulations are described which contain an appropriate solvent and a modified carbon product comprising carbon having attached at least one organic group, wherein the organic group comprises a) at least one aromatic group or C.sub.1 -C.sub.12 alkyl group, and b) at least one ionic group, at least one ionizable group, or a mixture of an ionic group and an ionizable group, wherein the organic group is present in any amount.
    • 描述了包含连接至少一个有机基团的碳的改性碳产物。 有机基团包括a)至少一个芳族基团或C 1 -C 12烷基和b)至少一个离子基团,至少一个可离子化基团,或离子基团和可离子化基团的混合物。 有机基团的芳族基团或C 1 -C 12烷基直接连接到碳上,并且有机基团以基于CTAB或t-面积的所用碳的约0.10至约2.7微摩尔/ m 2的量存在 的碳或其量使得改性碳产物具有大于约5重量%的残留值。 还描述了含有改性碳产物的水性和非水性油墨和涂料。 还公开了通过将改性碳产物作为油墨的一部分并入而增加墨水流动的方法,如通过玻璃板流量测量的。 最后,描述了含有合适溶剂和包含连接至少一个有机基团的碳的改性碳产物的非水性油墨和涂料配方,其中有机基团包括a)至少一个芳族基团或C 1 -C 12烷基, 和b)至少一个离子基团,至少一个可离子化基团,或离子基团和可离子化基团的混合物,其中所述有机基团以任何量存在。