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1. 发明申请

US20120129058A1 Electrical Energy Storage Device 审中-公开
标题翻译：电力储能装置
公开(公告)号：US20120129058A1
公开(公告)日：2012-05-24
申请号：US12953553
申请日：2010-11-24
申请人： Kevin P. Litzinger , Wolfgang Drenckhahn , Nicolas Vortmeyer , Shailesh D. Vora , Wolfgang Menapace
发明人： Kevin P. Litzinger , Wolfgang Drenckhahn , Nicolas Vortmeyer , Shailesh D. Vora , Wolfgang Menapace
IPC分类号： H01M12/04
CPC分类号： H01M12/08 , Y02E60/128
摘要： An electrical energy storage device is provided which comprises at least one module with an anode, a cathode made from an anion generating material or material combination and conducting anions, and an anion conducting solid electrolyte located between the anode and the cathode. The anode of each module comprises a porous structure that conducts anions and is infiltrated by a liquid infiltration mass which comprises a metal in a non-oxidised and/or in an oxidised state.
摘要翻译：提供了一种电能存储装置，其包括至少一个具有阳极的模块，由阴离子产生材料或材料组合制成的阴极和导电阴离子，以及位于阳极和阴极之间的阴离子导电固体电解质。每个模块的阳极包括导电阴离子并被包含非氧化和/或氧化状态的金属的液体渗透物质渗透的多孔结构。

2. 发明授权

US09054366B2 Electrical energy storage device 有权
标题翻译：电能储存装置
公开(公告)号：US09054366B2
公开(公告)日：2015-06-09
申请号：US12953507
申请日：2010-11-24
申请人： Wolfgang Drenckhahn , Harald Landes , Wolfgang Menapace , Shailesh D. Vora , Nicolas Vortmeyer
发明人： Wolfgang Drenckhahn , Harald Landes , Wolfgang Menapace , Shailesh D. Vora , Nicolas Vortmeyer
IPC分类号： H01M4/13 , H01M4/36 , H01M4/38 , H01M4/48 , H01M4/02 , H01M8/18 , H01M8/20 , H01M12/08 , H01M14/00 , H01M8/12
CPC分类号： H01M8/18 , H01M8/20 , H01M12/08 , H01M14/00 , H01M2008/1293 , H01M2300/0071 , Y02E60/128 , Y02E60/525 , Y02E60/528
摘要： An electrical energy storage device is provided which comprises at least one module with a negative electrode, a positive electrode made from an anion generating material or material combination and conducting anions, and an anion conducting solid electrolyte located between the negative electrode and the positive electrode. The negative electrode of each module comprises a porous structure that conducts anions and the pore space of which is at least partially filled by a first redox mass which comprises a metal/metal oxide pair. The positive electrode of each module comprises a porous structure that conducts anions and the pore space of which is at least partially filled by a second redox mass which comprises a metal/metal oxide pair with an increased oxidation potential compared to the first redox mass.
摘要翻译：提供了一种电能存储装置，其包括至少一个具有负极的模块，由阴离子产生材料或材料组合制成的正极和导电阴离子，以及位于负极和正极之间的阴离子导电固体电解质。每个模块的负电极包括多孔结构，其导电阴离子，其孔隙空间至少部分地被包含金属/金属氧化物对的第一氧化还原物质填充。每个模块的正电极包括多孔结构，其导电阴离子，其孔隙空间至少部分地被第二氧化还原物质填充，其包含与第一氧化还原物质相比具有增加的氧化电位的金属/金属氧化物对。

3. 发明申请

US20120129039A1 ELECTRICAL ENERGY STORAGE DEVICE 有权
标题翻译：电力储存装置
公开(公告)号：US20120129039A1
公开(公告)日：2012-05-24
申请号：US12953507
申请日：2010-11-24
申请人： Wolfgang Drenckhahn , Harald Landes , Wolfgang Menapace , Nicolas Vortmeyer , Shailesh D. Vora
发明人： Wolfgang Drenckhahn , Harald Landes , Wolfgang Menapace , Nicolas Vortmeyer , Shailesh D. Vora
IPC分类号： H01M2/24 , H01M4/50 , H01M4/52 , H01M4/48 , H01M4/56
CPC分类号： H01M8/18 , H01M8/20 , H01M12/08 , H01M14/00 , H01M2008/1293 , H01M2300/0071 , Y02E60/128 , Y02E60/525 , Y02E60/528
摘要： An electrical energy storage device is provided which comprises at least one module with a negative electrode, a positive electrode made from an anion generating material or material combination and conducting anions, and an anion conducting solid electrolyte located between the negative electrode and the positive electrode. The negative electrode of each module comprises a porous structure that conducts anions and the pore space of which is at least partially filled by a first redox mass which comprises a metal/metal oxide pair. The positive electrode of each module comprises a porous structure that conducts anions and the pore space of which is at least partially filled by a second redox mass which comprises a metal/metal oxide pair with an increased oxidation potential compared to the first redox mass.
摘要翻译：提供了一种电能存储装置，其包括至少一个具有负极的模块，由阴离子产生材料或材料组合制成的正极和导电阴离子，以及位于负极和正极之间的阴离子导电固体电解质。每个模块的负电极包括多孔结构，其导电阴离子，其孔隙空间至少部分地被包含金属/金属氧化物对的第一氧化还原物质填充。每个模块的正电极包括多孔结构，其导电阴离子，其孔隙空间至少部分地被第二氧化还原物质填充，其包含与第一氧化还原物质相比具有增加的氧化电位的金属/金属氧化物对。

4. 发明申请

US20110033769A1 Electrical Storage Device Including Oxide-ion Battery Cell Bank and Module Configurations 审中-公开
标题翻译：包括氧化物电池单元组和模块配置的电气存储设备
公开(公告)号：US20110033769A1
公开(公告)日：2011-02-10
申请号：US12695386
申请日：2010-01-28
申请人： Kevin Huang , Shailesh D. Vora , Mehrdad Tartibi , Nicolas Vortmeyer , Kevin P. Litzinger , Chun Lu , Michael Josef Suess
发明人： Kevin Huang , Shailesh D. Vora , Mehrdad Tartibi , Nicolas Vortmeyer , Kevin P. Litzinger , Chun Lu , Michael Josef Suess
IPC分类号： H01M8/10 , H01M4/02
CPC分类号： H01M12/005 , H01M12/085 , H01M14/00 , H01M2008/1293 , H01M2300/0065 , Y02E60/128
摘要： A rechargeable electrical storage device is disclosed, where one embodiment utilizes an anion (“A”) conducting electrolyte (18) and ion transfer between two electrodes (17, 19) where one electrode is preferably a metal electrode 19 that contains a mixture of metal and metal oxide, so that during operation, oxide-ions shuttle between the two electrodes (17, 19) in charging and discharging modes and the metal electrode (19) serves as a reservoir of species relevant to anion “A”.
摘要翻译：公开了一种可再充电的电存储装置，其中一个实施例使用导电电解质（18）的阴离子（“A”）和在两个电极（17,19）之间的离子转移，其中一个电极优选地是金属电极19，其含有金属和金属氧化物，使得在操作期间，在充电和放电模式下在两个电极（17,19）之间穿过氧化物离子，并且金属电极（19）用作与阴离子“A”相关的物质的储存器。

5. 发明授权

US06248468B1 Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell 有权
标题翻译：含有用于固体氧化物燃料电池的预烧结镍/氧化锆的燃料电极
公开(公告)号：US06248468B1
公开(公告)日：2001-06-19
申请号：US09224157
申请日：1998-12-31
申请人： Roswell J. Ruka , Shailesh D. Vora
发明人： Roswell J. Ruka , Shailesh D. Vora
IPC分类号： H01M810
CPC分类号： H01M4/9066 , H01M2004/8684 , H01M2300/0074
摘要： A fuel cell structure (2) is provided, having a pre-sintered nickel-zirconia fuel electrode (6) and an air electrode (4), with a ceramic electrolyte (5) disposed between the electrodes, where the pre-sintered fuel electrode (6) contains particles selected from the group consisting of nickel oxide, cobalt and cerium dioxide particles and mixtures thereof, and titanium dioxide particles, within a matrix of yttria-stabilized zirconia and spaced-apart filamentary nickel strings having a chain structure, and where the fuel electrode can be sintered to provide an active solid oxide fuel cell.
摘要翻译：提供了具有预烧结的镍 - 氧化锆燃料电极（6）和空气电极（4）的燃料电池结构（2），在电极之间具有陶瓷电解质（5），其中预烧结燃料电极（6）包含选自氧化镍，钴和二氧化铈颗粒及其混合物的颗粒，以及二氧化钛颗粒，其在氧化钇稳定的氧化锆的基质内和具有链结构的间隔开的丝状镍串中，并且其中可以将燃料电极烧结以提供活性固体氧化物燃料电池。

6. 发明授权

US5391440A Method of forming a leak proof plasma sprayed interconnection layer on an electrode of an electrochemical cell 失效
标题翻译：在电化学电池的电极上形成防漏等离子体喷涂互连层的方法
公开(公告)号：US5391440A
公开(公告)日：1995-02-21
申请号：US195335
申请日：1994-02-14
申请人： Lewis J. H. Kuo , Shailesh D. Vora
发明人： Lewis J. H. Kuo , Shailesh D. Vora
IPC分类号： C23C4/10 , C23C4/18 , H01M8/02 , H01M8/12 , B05D5/12
CPC分类号： H01M8/0215 , C23C4/11 , C23C4/18 , H01M2008/1293 , H01M2300/0074 , Y10T29/49115
摘要： A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an electrode structure of an electrochemical cell by: (A) providing an electrode structure; (B) forming on a selected portion of the electrode surface, an interconnection layer having the general formula La.sub.1-x M.sub.x Cr.sub.1-y N.sub.y O.sub.3, where M is a dopant selected from the group of Ca, Sr, Ba, and mixtures thereof, and where N is a dopant selected from the group of Mg, Co, Ni, Al, and mixtures thereof, and where x and y are each independently about 0.075-0.25, by thermally spraying, preferably plasma arc spraying, a flux added interconnection spray powder, preferably agglomerated, the flux added powder comprising flux particles, preferably including dopant, preferably (CaO).sub.12. (Al.sub.2 O.sub.3).sub.7 flux particles including Ca and Al dopant, and LaCrO.sub.3 interconnection particles, preferably undoped LaCrO.sub.3, to form a dense and substantially gas-tight interconnection material bonded to the electrode structure by a single plasma spraying step; and, (C) heat treating the interconnection layer at from about 1200.degree. to 1350.degree. C. to further densify and heal the micro-cracks and macro-cracks of the thermally sprayed interconnection layer. The result is a substantially gas-tight, highly doped, electrically conductive interconnection material bonded to the electrode structure. The electrode structure can be an air electrode, and a solid electrolyte layer can be applied to the unselected portion of the air electrode, and further a fuel electrode can be applied to the solid electrolyte, to form an electrochemical cell for generation of electrical power.
摘要翻译：通过以下方式在电化学电池的电极结构上形成致密的，基本上气密的导电互连层：（A）提供电极结构; （B）在电极表面的选定部分上形成具有通式La1-xMxCr1-yNyO3的互连层，其中M是选自Ca，Sr，Ba及其混合物的掺杂剂，其中N是选自Mg，Co，Ni，Al及其混合物的掺杂剂，其中x和y各自独立地为约0.075-0.25，通过热喷涂，优选等离子体电弧喷涂，添加助焊剂的互连喷雾粉末，优选聚集助焊剂添加粉末包含助焊剂颗粒，优选包括掺杂剂，优选（CaO）12（Al 2 O 3）7助焊剂颗粒，包括Ca和Al掺杂剂，以及LaCrO 3互连颗粒，优选未掺杂的LaCrO 3，以形成致密且基本上气密的互连通过单个等离子体喷涂步骤与电极结构结合的材料; 和（C）在约1200℃至1350℃下对互连层进行热处理，以进一步致密化和热处理热喷涂互连层的微裂纹和大裂纹。结果是结合到电极结构的基本上气密的，高掺杂的导电互连材料。电极结构可以是空气电极，并且可以将固体电解质层施加到空气电极的未选择部分，并且还可以将燃料电极施加到固体电解质上，以形成用于产生电力的电化学电池。

7. 发明申请

US20110256448A1 MOLTEN SALT-CONTAINING METAL ELECTRODE FOR RECHARGEABLE OXIDE-ION BATTERY CELLS OPERATING BELOW 800?C 有权
标题翻译：用于可充电氧化物电池的MALTEN含盐金属电极，操作下面800？C
公开(公告)号：US20110256448A1
公开(公告)日：2011-10-20
申请号：US12850086
申请日：2010-08-04
申请人： Kevin Huang , Chun Lu , James L. Shull , Shih-Yu W. Liu , Shailesh D. Vora
发明人： Kevin Huang , Chun Lu , James L. Shull , Shih-Yu W. Liu , Shailesh D. Vora
IPC分类号： H01M4/60 , H01M10/02 , H01M4/90 , H01M4/36
CPC分类号： H01M10/399 , H01M4/582
摘要： A rechargeable oxide-ion battery cell 20, operating below 800° C., containing a molten salt-containing electrode 22, made of active metal-active metal oxide-active metal salt, preferably a Fe—FeO—Fe halide; which electrode is associated with an electrolyte 24 and an air electrode 26 to provide the cell 20.
摘要翻译：在800℃以下操作的可充电氧化物离子电池单元20，其含有由活性金属 - 活性金属氧化物 - 活性金属盐，优选Fe-FeO-Fe卤化物制成的含熔融盐电极22。该电极与电解质24和空气电极26相关联以提供电池20。

8. 发明授权

US09325036B2 Molten salt-containing metal electrode for rechargeable oxide-ion battery cells operating below 800°C 有权
标题翻译：用于在800°C以下工作的可再充电氧化物离子电池的熔盐盐金属电极
公开(公告)号：US09325036B2
公开(公告)日：2016-04-26
申请号：US12850086
申请日：2010-08-04
申请人： Kevin Huang , Chun Lu , James L. Shull , Shih-Yu W. Liu , Shailesh D. Vora
发明人： Kevin Huang , Chun Lu , James L. Shull , Shih-Yu W. Liu , Shailesh D. Vora
IPC分类号： H01M10/39 , H01M4/58
CPC分类号： H01M10/399 , H01M4/582
摘要： A rechargeable oxide-ion battery cell 20, operating below 800° C., containing a molten salt-containing electrode 22, made of active metal-active metal oxide-active metal salt; which electrode is associated with an electrolyte 24 and an air electrode 26 to provide the cell 20.
摘要翻译：在含有含活性金属 - 活性金属氧化物 - 活性金属盐的熔融盐电极22的800℃以下的可再充电氧化物离子电池单元20。该电极与电解质24和空气电极26相关联以提供电池20。

9. 发明申请

US20120058396A1 OXIDATION-RESISTANT METAL SUPPORTED RECHARGEABLE OXIDE-ION BATTERY CELLS AND METHODS TO PRODUCE THE SAME 审中-公开
标题翻译：耐氧化金属支持的可充电氧化物 - 电池电池及其生产方法
公开(公告)号：US20120058396A1
公开(公告)日：2012-03-08
申请号：US12876391
申请日：2010-09-07
申请人： Chun Lu , Kevin Huang , James L. Shull , Shih-Yu W. Liu , Harold D. Harter , Shailesh D. Vora
发明人： Chun Lu , Kevin Huang , James L. Shull , Shih-Yu W. Liu , Harold D. Harter , Shailesh D. Vora
IPC分类号： H01M4/38 , H01M4/02
CPC分类号： H01M12/08 , H01M4/02 , H01M4/38 , H01M4/628 , Y02E60/128
摘要： The invention describes the application of oxidation-resistant metal (preferably, stainless steel) 140 in a metal electrode 200 combination, as a support and current collector for a rechargeable oxide-ion battery cell where the metal electrode 200 consists of a bottom layer 120, and where the oxidation-resistant metal 140 has surfaces preferably coated with protective coating 160. The metal electrode 200 is integrated with oxide-ion conductive electrolyte 220 and air electrode 240 to yield an oxidation-resistant metal supported cell.
摘要翻译：本发明描述了在金属电极200组合中应用抗氧化金属（优选不锈钢）140作为用于可再充电氧化物离子电池单元的载体和集电器，其中金属电极200由底层120，并且其中抗氧化金属140具有优选涂覆有保护涂层160的表面。金属电极200与氧化物离子导电电解质220和空气电极240一体化以产生耐氧化金属负载的电池。

10. 发明授权

US5426003A Method of forming a plasma sprayed interconnection layer on an electrode of an electrochemical cell 失效
标题翻译：在电化学电池的电极上形成等离子体喷涂互连层的方法
公开(公告)号：US5426003A
公开(公告)日：1995-06-20
申请号：US195774
申请日：1994-02-14
申请人： Charles J. Spengler , George R. Folser , Shailesh D. Vora , Lewis Kuo , Von L. Richards
发明人： Charles J. Spengler , George R. Folser , Shailesh D. Vora , Lewis Kuo , Von L. Richards
IPC分类号： C04B41/87 , C01G37/033 , C23C4/06 , C23C4/10 , C23C4/18 , H01M4/90 , H01M8/02 , H01M8/12 , B05D5/12
CPC分类号： H01M8/0215 , C23C4/06 , C23C4/18 , H01M2008/1293 , H01M2300/0074 , Y10T29/49115
摘要： A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO.sub.3 particles doped with an element selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by plasma spraying doped LaCrO.sub.3 powder, preferably compensated with chromium as Cr.sub.2 O.sub.3 and/or dopant element, preferably by plasma arc spraying; and, (C) heating the doped and compensated LaCrO.sub.3 layer to about 1100.degree. C. to 1300.degree. C. to provide a dense, substantially gas-tight, substantially hydration-free, electrically conductive interconnection material bonded to the electrode surface. A solid electrolyte layer can be applied to the unselected portion of the air electrode, and a fuel electrode can be applied to the solid electrolyte, to provide an electrochemical cell.
摘要翻译：通过（A）提供电极表面，在电化学电池的空气电极结构上形成致密的，基本上气密的导电互连层; （B）在所述电极表面的选定部分上形成掺杂有选自Ca，Sr，Ba，Mg，Co，Ni，Al的元素的掺杂LaCrO 3颗粒层，以及通过等离子体喷涂掺杂的LaCrO 3粉末的混合物，优选地被补偿铬作为Cr 2 O 3和/或掺杂元素，优选通过等离子体电弧喷涂; 和（C）将掺杂和补偿的LaCrO 3层加热至约1100℃至1300℃，以提供键合到电极表面的致密的，基本上气密的，基本上不含水合的导电互连材料。可以将固体电解质层施加到空气电极的未选择部分，并且可以将燃料电极施加到固体电解质上，以提供电化学电池。

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