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1. 发明授权

US4356160A Process for producing titanium trihalides by reducing titanium tetrahalides 失效
标题翻译：通过还原四卤化钛生产三卤化钛的方法
公开(公告)号：US4356160A
公开(公告)日：1982-10-26
申请号：US254667
申请日：1981-04-16
申请人： Kenya Makino , Hieo Sakurai , Masaru Watanabe , Toshiyuki Nishimura
发明人： Kenya Makino , Hieo Sakurai , Masaru Watanabe , Toshiyuki Nishimura
IPC分类号： C08F4/00 , C01G23/02 , C08F4/60 , C08F4/642 , C08F10/00
CPC分类号： C08F10/00 , C01G23/026 , C08F2410/04
摘要： In a process for producing a titanium trihalide by reducing a titanium tetrahalide with hydrogen, the improvement wherein the reduction is carried out in an organic solvent in the presence of an ether and at least one member of the group consisting of metals of Groups IB, IIB, IVB and VIII of the periodic table and compounds of these materials.
摘要翻译：在通过用氢还原四卤化钛制备三卤化钛的方法中，其改进在于在有机溶剂中，在醚存在下和至少一种由IB，IIB族金属组成的组中进行还原，IVB和VIII以及这些材料的化合物。

2. 发明授权

US4377671A Process for producing olefinic copolymer rubbers 失效
标题翻译：制备烯烃共聚物橡胶的方法
公开(公告)号：US4377671A
公开(公告)日：1983-03-22
申请号：US281048
申请日：1981-07-07
申请人： Kenya Makino , Hideo Sakurai , Masaru Watanabe , Toshiyuki Nishimura
发明人： Kenya Makino , Hideo Sakurai , Masaru Watanabe , Toshiyuki Nishimura
IPC分类号： C08F4/44 , C08F4/64 , C08F4/642 , C08F210/16 , C08F210/18 , C08F4/66 , C08F4/68
CPC分类号： C08F210/16 , C08F210/18
摘要： In a process for producing a rubbery olefinic copolymer which comprises random-copolymerizing at least two olefins in the presence of a catalyst composed of (A) a titanium compound and (B) an organometallic compound of a metal of Groups I to III of the periodic table, the improvement wherein the titanium compound (A) of the catalyst is a solution of a solid titanium halide in a hydrocarbon solvent, a halogenated hydrocarbon solvent or a mixture of both, said solid titanium halide being rendered soluble in said solvent.
摘要翻译：在制备橡胶状烯烃共聚物的方法中，该方法包括在由（A）钛化合物和（B）有机金属化合物存在下，使至少两种烯烃共聚，所述催化剂由（A）钛化合物和表中，其中催化剂的钛化合物（A）是固体卤化钛在烃溶剂，卤代烃溶剂或二者的混合物中的溶液的改进，所述固体卤化钛可溶于所述溶剂。

3. 发明授权

US4366297A Process for producing olefinic copolymer rubber with improved titanium compound containing catalyst system 失效
标题翻译：制备含改性钛化合物催化剂体系的烯烃共聚物橡胶的方法
公开(公告)号：US4366297A
公开(公告)日：1982-12-28
申请号：US200066
申请日：1980-10-23
申请人： Kenya Makino , Hideo Sakurai , Masaru Watanabe , Toshiyuki Nishimura
发明人： Kenya Makino , Hideo Sakurai , Masaru Watanabe , Toshiyuki Nishimura
IPC分类号： C08F4/64 , C08F210/00 , C08F210/16 , C08F210/18
CPC分类号： C08F210/16 , C08F10/00 , C08F210/00 , C08F210/18 , C08F2410/04
摘要： In a process for producing a rubber olefin copolymer which comprises random copolymerization of at least two olefins in the presence of a catalyst composed of (A) a titanium compound and (B) an organometallic compound of a metal of Groups I to III of the periodic table, the improvement wherein the titanium compound (A) is a liquid product obtained by treating a titanium tetrahalide of the general formula TiX.sub.4 in which X represents Cl, Br or I in a hydrocarbon, a halogenated hydrocarbon or a mixture of both in the presence of an ether with at least one member selected from the group consisting of (1) an organoaluminum compound, (2) an organomagnesium compound and (3) a combination of hydrogen and at least one metal or metal compound selected from the group consisting of metals of Group IB, IIB, IVB and VIII of the periodic table, compounds of metals of Group VIII of the periodic table, cuprous chloride, titanium hydride and zirconium hydride.
摘要翻译：在一种橡胶烯烃共聚物的制备方法中，该方法包括在（A）钛化合物和（B）有机金属化合物存在下，由至少两种烯烃的无规共聚反应，表中，其中钛化合物（A）是通过在存在下在烃，卤代烃或二者的混合物中处理其中X表示Cl，Br或I的通式TiX 4的四卤化物得到的液体产物的醚与至少一种选自（1）有机铝化合物，（2）有机镁化合物和（3）氢和至少一种选自金属的金属或金属化合物的组合的成员元素周期表第IB族，第IIB族，第IVB族和第VIII族，周期表第Ⅷ族金属化合物，氯化亚铜，氢化钛和氢化锆。

4. 发明授权

US5109069A Hydrogenated diene copolymer-containing resin composition and process for producing the same 失效
标题翻译：加氢二烯共聚物树脂组合物及其制造方法
公开(公告)号：US5109069A
公开(公告)日：1992-04-28
申请号：US446692
申请日：1989-12-06
申请人： Tooru Shibata , Toshio Teramoto , Yasuo Takeuchi , Kenya Makino , Masaaki Mawatari , Minoru Maeda , Shinichi Kimura , Minoru Hasegawa , Kunio Goshima , Mikio Takeuchi
发明人： Tooru Shibata , Toshio Teramoto , Yasuo Takeuchi , Kenya Makino , Masaaki Mawatari , Minoru Maeda , Shinichi Kimura , Minoru Hasegawa , Kunio Goshima , Mikio Takeuchi
IPC分类号： C08J3/00 , C08L15/00 , C08L21/00 , C08L23/00 , C08L23/10 , C08L25/00 , C08L25/10 , C08L37/00 , C08L47/00 , C08L67/00 , C08L71/12 , C08L77/00
CPC分类号： C08L15/00 , C08L71/123 , C08L23/10 , C08L25/02 , C08L67/00 , C08L77/00 , Y10S525/905
摘要： A hydrogenated diene copolymer resin composition comprising (A) 5-70% by weight of a hydrogenated diene copolymer which is a hydrogenation product of a random copolymer of at least one conjugated diene and 3-50% by weight of an alkenyl aromatic compound having a number average molecular weight of 5,000-1,000,000 and a molecular weight distribution (Mw/Mn) of 10 or less, the vinyl content in the diene portion of the random copolymer being 10-90%, at least 70% of the olefinic unsaturation of the random copolymer being hydrogenated, and (B) 95-30% by weight of at least one resin selected from the group consisting of a polypropylene resin, a polyphenylene ether resin and an alkenyl aromatic compound polymer resin. The hydrogenated diene copolymer (A) can be used in combination with (B) a polyphenylene ether resin and (C) at least one member selected from the group consisting of a polyamide and a thermoplastic polyester in such a proportion that the amount of (A) is 1-50 parts by weight, the amount of (B) is 10-89 parts by weight and the amount of (C) is 10-89 parts by weight. The above composition has improved impact resistance and improved gloss and appearance of molded article.

5. 发明授权

US4255543A Process for the preparation of 1,2-polybutadiene 失效
标题翻译： 1,2-聚丁二烯的制备方法
公开(公告)号：US4255543A
公开(公告)日：1981-03-10
申请号：US066698
申请日：1979-08-15
申请人： Kenya Makino , Toshio Miyabayashi , Noboru Ohshima , Yasumasa Takeuchi
发明人： Kenya Makino , Toshio Miyabayashi , Noboru Ohshima , Yasumasa Takeuchi
IPC分类号： C08F4/00 , C08F2/38 , C08F4/60 , C08F4/70 , C08F36/00 , C08F136/06
CPC分类号： C08F136/06
摘要： In the preparation of 1,2-polybutadiene with a vinyl content of at least 70% by contacting 1,3-butadiene with a catalyst consisting of:(A) a cobalt compound,(B) an organic phosphine compound,(C) a trialkylaluminum compound, and(D) water in an amount of 0.1 to 1.2 moles per mole of said trialkylaluminum,in the presence of a molecular weight regulator,(E) an alkylaluminum halide compound is used as the molecular weight regulator in an amount of at least 0.01 mole per mole of the trialkylaluminum compound (C), whereby 1,2-polybutadiene with a regulated molecular weight can be produced without causing decreased polymerization activity and change of vinyl content and crystallinity of the produced polymer. The alkylaluminum halide compound (E) is preferably used in an amount of 0.05 to 1.0 mole per mole of the trialkylaluminum compound (C).
摘要翻译：在乙烯基含量为至少70％的1,2-聚丁二烯的制备中，通过使1,3-丁二烯与由（A）钴化合物，（B）有机膦化合物组成的催化剂，（C）三烷基铝化合物和（D）在每分子量调节剂存在下，每摩尔三烷基铝为0.1至1.2摩尔量的水，（E）烷基卤化铝化合物用作分子量调节剂，其用量为每摩尔三烷基铝化合物（C）至少0.01摩尔，从而可以制备具有调节分子量的1,2-聚丁二烯，而不会降低聚合活性和所生产的聚合物的乙烯基含量和结晶度的变化。烷基卤化铝化合物（E）的用量相对于每摩尔三烷基铝化合物（C）为0.05〜1.0摩尔。

6. 发明授权

US4506061A Process for producing olefin copolymer rubber 失效
标题翻译：生产烯烃共聚橡胶的方法
公开(公告)号：US4506061A
公开(公告)日：1985-03-19
申请号：US423214
申请日：1982-09-24
申请人： Kenya Makino , Hideo Sakurai , Toshiyuki Toyoda , Yoshitaka Matsuo
发明人： Kenya Makino , Hideo Sakurai , Toshiyuki Toyoda , Yoshitaka Matsuo
IPC分类号： C08F4/00 , C08F4/60 , C08F210/00 , C08F210/16 , C08F4/64
CPC分类号： C08F210/16
摘要： A process for producing an olefin copolymer rubber containing 25 to 75% by weight of propylene, which comprises polymerizing ethylene and propylene, or ethylene, propylene and at least one nonconjugated diene, in solution in the presence of a catalyst, said catalyst being composed of (A) a Ti-containing solid component precipitated from a liquid product obtained by reacting a titanium tetrahalide with an organomagnesium compound in a halogenated hydrocarbon solvent in the presence of an ether represented by the general formula R.sup.1 OR.sup.2 wherein R.sup.1 and R.sup.2 are identical or different and each represents a hydrocarbon group having 2 to 12 carbon atoms, and (B) an organoaluminum compound.
摘要翻译：一种制备含有25〜75重量％丙烯的烯烃共聚物橡胶的方法，该方法包括在催化剂存在下，在溶液中聚合乙烯和丙烯，或乙烯，丙烯和至少一种非共轭二烯，所述催化剂由（A）通过在卤代烃溶剂中，在由通式R1OR2表示的醚的存在下使四卤化钛与有机镁化合物反应而获得的含Ti固体成分，其中R1和R2相同或不同，各自表示碳原子数2〜12的烃基，（B）有机铝化合物。

7. 发明授权

US4068063A Catalyst composition for ring-opening polymerization of norbornene derivatives and process for polymerizing same 失效
标题翻译：用于降冰片烯衍生物的开环聚合的催化剂组合物及其聚合方法
公开(公告)号：US4068063A
公开(公告)日：1978-01-10
申请号：US512790
申请日：1974-10-07
申请人： Hiroharu Ikeda , Shuichi Matsumoto , Kenya Makino
发明人： Hiroharu Ikeda , Shuichi Matsumoto , Kenya Makino
IPC分类号： B01J31/02 , B01J31/04 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/22 , B01J31/26 , C08F4/42 , C08G61/08 , C08F4/78
CPC分类号： C08G61/08 , B01J31/0212 , B01J31/0214 , B01J31/04 , B01J31/122 , B01J31/143 , B01J31/2234 , B01J31/26 , B01J2531/48 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/845
摘要： A catalyst composition consisting essentially of a reaction mixture of (A) at least one member selected from the group consisting of compounds of W, Mo, Re and Ta, (B) at least one member selected from the group consisting of organometallic compounds of elements of Groups IA, IIA, IIB and IIIA of the Deming Periodic Table, and (C) at least one member selected from the group consisting of compounds of V, Cr, Mn, and elements of Groups IVB and VIII of the Deming Periodic Table, has a very high activity in the ring-opening polymerization of norbornene derivatives having at least one polar substituent selected from the group consisting of ester groups, nitrile groups, amide groups, imide groups, carboxylic acid anhydride groups and halogens. The metal atom ratio of (C)/(A) is usually 0.001 - 50, and the molar ratio of (B)/(A) is usually 1 - 10. At least one said norbornene derivative and at least one cycloolefin other than cyclohexene can also successfully be subjected to ring-opening copolymerization with said catalyst.
摘要翻译：一种催化剂组合物，主要由（A）至少一种选自W，Mo，Re和Ta的化合物的组分的反应混合物组成，（B）选自元素的有机金属化合物的Deming周期表的IA，IIA，IIB和IIIA族组分，和（C）选自Ving，Cr，Mn的化合物和Deming周期表第IVB和VIII族元素中的至少一种，在具有至少一个选自酯基，腈基，酰胺基，酰亚胺基，羧酸酐基和卤素的极性取代基的降冰片烯衍生物的开环聚合中具有非常高的活性。（C）/（A）的金属原子比通常为0.001〜50，（B）/（A）的摩尔比通常为1〜10.所述降冰片烯衍生物和除环己烯以外的至少一种环烯烃也可以成功地与所述催化剂进行开环共聚。

8. 发明授权

US5854384A Process for preparing poly-.alpha.-amino acid particles 失效
标题翻译：制备聚-α-氨基酸颗粒的方法
公开(公告)号：US5854384A
公开(公告)日：1998-12-29
申请号：US719544
申请日：1996-09-25
申请人： Kyoko Kuroda , Masayuki Hattori , Yoshitaka Yamakawa , Kenya Makino , Toshio Hayashi
发明人： Kyoko Kuroda , Masayuki Hattori , Yoshitaka Yamakawa , Kenya Makino , Toshio Hayashi
IPC分类号： A61K9/16 , C08G69/10 , C08G69/00
CPC分类号： A61K9/1641 , C08G69/10
摘要： A process for preparing poly-.alpha.-amino acid particles comprising polymerizing an .alpha.-amino acid-N-carboxy anhydride using a polymerization initiator in an organic solvent in which both the solubility of the .alpha.-amino acid-N-carboxy anhydride and the solubility of the produced poly-.alpha.-amino acid are 0.1 g/100 ml or less at 25.degree. C. Polyamino acid particles having a high molecular weight and a small bulk specific gravity can be manufactured very easily without requiring specific procedures. The polyamino acid particles can be used as a coating material for papers, resins, rubbers, and fibers; particles for cosmetics; particles for diagnostic drugs; fillers for chromatography; and an encapsulating material for drugs, fertilizers, and perfumes.
摘要翻译：一种制备聚-α-氨基酸颗粒的方法，包括在有机溶剂中使用聚合引发剂聚合α-氨基酸-N-羧酸酐，其中α-氨基酸-N-羧酸酐的溶解度和溶解度的制备的聚-α-氨基酸在25℃下为0.1g / 100ml或更少。具有高分子量和小堆积比重的聚氨基酸颗粒可以非常容易地制造，而不需要特定的程序。聚氨基酸颗粒可用作纸，树脂，橡胶和纤维的涂料; 化妆品颗粒用于诊断药物的颗粒; 色谱填料; 以及用于药物，肥料和香水的包封材料。

9. 发明授权

US5852109A Poly-.alpha.-amino acid particles, emulsions containing the same and process for preparing the same 失效
标题翻译：聚-α-氨基酸颗粒，含有其的乳液及其制备方法
公开(公告)号：US5852109A
公开(公告)日：1998-12-22
申请号：US526694
申请日：1995-09-11
申请人： Kenya Makino , Seiji Fukuhara , Kyoko Kuroda , Toshio Hayashi
发明人： Kenya Makino , Seiji Fukuhara , Kyoko Kuroda , Toshio Hayashi
IPC分类号： C08G69/10 , C08L37/00
CPC分类号： A61Q13/00 , A61K8/88 , C08G69/10 , A61K2800/56
摘要： Solid poly-.alpha.-amino acid particles are obtained by preparing an oil-in-water emulsion from water and an organic solvent having a water solubility of 10 g/100 ml or less, and polymerizing an .alpha.-amino acid-N-carboxy anhydride by emulsion polymerization in the oil-in-water emulsion, or by polymerizing an .alpha.-amino acid-N-carboxy anhydride in water in the presence of an emulsifier and an initiator. Hollow particles can be obtained by adding a poor solvent for the poly-.alpha.-amino acid to the poly-.alpha.-amino acid particles and removing the solvents. These poly-.alpha.-amino acid particles are useful as a novel raw materials for coating on papers, rubbers and fibers, for encapsulating cosmetics, drugs, agricultural chemicals and fertilizers, and as particles for diagnostic reagents.
摘要翻译：固体聚-α-氨基酸颗粒通过从水和水溶解度为10g / 100ml或更低的有机溶剂制备水包油乳液得到，并且将α-氨基酸-N-羧酸酐通过水包油乳液中的乳液聚合，或者在乳化剂和引发剂的存在下，通过聚合α-氨基酸-N-羧酸酐在水中。可以通过向聚-α-氨基酸颗粒中加入不良的聚-α-氨基酸溶剂并除去溶剂来获得中空颗粒。这些聚-α-氨基酸颗粒可用作纸张，橡胶和纤维上的新型原料，用于包装化妆品，药物，农药和肥料以及作为诊断试剂的颗粒。

10. 发明授权

US5593639A Blood-sampling vessel 失效
标题翻译：血液取样容器
公开(公告)号：US5593639A
公开(公告)日：1997-01-14
申请号：US450144
申请日：1995-05-26
申请人： Kenya Makino , Yoshitaka Yamakawa , Mitsuhiro Murata , Toshio Hayashi
发明人： Kenya Makino , Yoshitaka Yamakawa , Mitsuhiro Murata , Toshio Hayashi
IPC分类号： B01L3/14 , A61B5/14
CPC分类号： B01L3/5082
摘要： A blood-sampling vessel containing therein a conjugated diene (co)polymer with a weight average molecular weight, reduced to sodium polystyrene sulfonate, of at least 3,000 and containing 2 mmol/g or more of at least one sulfonic acid group or a salt thereof. The vessel can be easily manufactured and constantly exhibits high anticoagulant and fibrinogen-removing capability to the blood contained therein, with no adverse effects on a variety of inspections and tests.
摘要翻译：一种血液取样容器，其中含有重均分子量为至少3,000并且含有2mmol / g或更多的至少一种磺酸基或其盐的共聚二烯（共）聚合物，其重量平均分子量降低至聚苯乙烯磺酸钠。该容器可以容易地制造，并且对其中所含的血液持续显示高抗凝和纤维蛋白原去除能力，对各种检查和试验没有不利影响。

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