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1. 发明申请

US20130261229A1 RESIN COMPOSITION, COMPOSITE CURED PRODUCT USING SAME, AND METHOD FOR PRODUCING THE COMPOSITE CURED PRODUCT 有权
标题翻译：树脂组合物，使用其的复合固化产品以及生产复合固化产品的方法
公开(公告)号：US20130261229A1
公开(公告)日：2013-10-03
申请号：US13993185
申请日：2011-12-07
申请人： Kentaro Sano , Yuki Mitsutsuji , Masato Honma
发明人： Kentaro Sano , Yuki Mitsutsuji , Masato Honma
IPC分类号： C08L79/08 , C08L71/00 , C08L63/00 , C08L81/04
CPC分类号： C08L79/08 , C08G65/4081 , C08G2650/40 , C08K3/04 , C08K7/06 , C08K7/14 , C08L63/00 , C08L71/00 , C08L81/04 , C08L87/00
摘要： A resin composition including 10 to 90% by mass of (A) a component to be polymerized containing a compound represented by Formula (1), and 90 to 10% by mass of (B) a thermosetting resin, the (A) and (B) each being capable of undergoing a reaction to increase molecular weight by itself when heated: wherein, Ar represents an aryl; and X represents at least one selected from the group consisting of ethers, ketones, sulfides, sulfones, amides, carbonates and esters.
摘要翻译：一种树脂组合物，其含有（A）含有式（1）表示的化合物的聚合性成分和90〜10质量％的（B）热固性树脂，（A）和（ B）各自能够经受反应以在加热时自身增加分子量：其中，Ar表示芳基; X表示选自醚，酮，硫化物，砜，酰胺，碳酸酯和酯中的至少一种。

2. 发明授权

US09340672B2 Resin composition, composite cured product using same, and method for producing the composite cured product 有权
标题翻译：树脂组合物，使用其的复合固化物，以及复合固化物的制造方法
公开(公告)号：US09340672B2
公开(公告)日：2016-05-17
申请号：US13993185
申请日：2011-12-07
申请人： Kentaro Sano , Yuki Mitsutsuji , Masato Honma
发明人： Kentaro Sano , Yuki Mitsutsuji , Masato Honma
IPC分类号： C08L81/04 , C08L63/00 , C08L87/00 , C08G75/14 , C08K3/04 , C08K7/06 , C08K7/14 , C08L79/08 , C08L71/00
CPC分类号： C08L79/08 , C08G65/4081 , C08G2650/40 , C08K3/04 , C08K7/06 , C08K7/14 , C08L63/00 , C08L71/00 , C08L81/04 , C08L87/00
摘要： A resin composition including 10 to 90% by mass of (A) a component to be polymerized containing a compound represented by Formula (1), and 90 to 10% by mass of (B) a thermosetting resin, the (A) and (B) each being capable of undergoing a reaction to increase molecular weight by itself when heated: wherein, Ar represents an aryl; and X represents at least one selected from the group consisting of ethers, ketones, sulfides, sulfones, amides, carbonates and esters.
摘要翻译：一种树脂组合物，其含有（A）含有式（1）表示的化合物的聚合性成分和90〜10质量％的（B）热固性树脂，（A）和（ B）各自能够经受反应以在加热时自身增加分子量：其中，Ar表示芳基; X表示选自醚，酮，硫化物，砜，酰胺，碳酸酯和酯中的至少一种。

3. 发明授权

US08980427B2 Carbon fiber bundle 有权
标题翻译：碳纤维束
公开(公告)号：US08980427B2
公开(公告)日：2015-03-17
申请号：US13515983
申请日：2011-01-06
申请人： Noriyuki Hirano , Atsuki Tsuchiya , Masato Honma
发明人： Noriyuki Hirano , Atsuki Tsuchiya , Masato Honma
IPC分类号： B32B3/00 , B60C3/04 , C08G18/48 , C08G18/32 , C08G18/66 , C08G18/76 , C08J5/06 , D06M15/568 , D06M101/40
CPC分类号： C08G18/4833 , C08G18/3221 , C08G18/6674 , C08G18/7621 , C08J5/06 , D06M15/568 , D06M2101/40 , Y10T428/2918 , Y10T428/292
摘要： A carbon fiber bundle has carbon fibers and a sizing agent, wherein the sizing agent comprises a water soluble polyurethane resin having an SP value of 11.2 to 13.3, and the sizing agent is deposited on the carbon fibers at a rate of 0.5 to 7% by mass. In another carbon fiber bundle, the sizing agent is composed of the component shown in (A) and the component shown in (B1) or (B2) below, and the sizing agent is deposited on the carbon fibers at a rate of 0.5 to 7% by mass: (A) 73 to 98% by mass of a polyoxyalkylene unit; (B1) 0.5 to 15% by mass of an aromatic ester unit, 1.5 to 10% by mass of an aromatic urethane unit; and (B2) 0.5 to 10% by mass of an aromatic ester unit, 1.5 to 11% by mass of an aliphatic urethane unit.
摘要翻译：碳纤维束具有碳纤维和上浆剂，其中上浆剂含有SP值为11.2〜13.3的水溶性聚氨酯树脂，上浆剂以0.5〜7％的比率沉积在碳纤维上，通过质量在另一种碳纤维束中，施胶剂由（A）所示的成分和下述（B1）或（B2）所示的成分构成，上浆剂以0.5〜7的比例沉积在碳纤维上质量％：（A）73〜98质量％的聚氧化烯单元; （B1）0.5〜15质量％的芳香族酯单元，1.5〜10质量％的芳香族聚氨酯单元; 和（B2）0.5〜10质量％的芳香族酯单元，1.5〜11质量％的脂肪族聚氨酯单元。

4. 发明授权

US08530565B2 Fiber reinforced propylene resin composition 有权
标题翻译：纤维增强丙烯树脂组合物
公开(公告)号：US08530565B2
公开(公告)日：2013-09-10
申请号：US13141671
申请日：2009-12-24
申请人： Masato Honma , Atsuki Tsuchiya , Keiichi Asami
发明人： Masato Honma , Atsuki Tsuchiya , Keiichi Asami
IPC分类号： C08K3/04 , C08L51/04 , C08L31/04
CPC分类号： C08L23/10 , B29K2023/12 , B29K2105/06 , C08L23/142 , C08L2205/02 , C08L2205/16 , C08L2666/02
摘要： [Object] The invention provides a fiber reinforced propylene resin composition having interfacial adhesion between a propylene resin and a reinforcing fiber and capable of preparing molded articles having high mechanical properties.[Means for Achieving the Object] The fiber reinforced propylene resin composition comprises: (A) 1 to 75% by weight of a reinforcing fiber, (B) 0.01 to 10% by weight of a first propylene resin containing 50 to 99% by mol of a constituting unit derived from propylene of an olefin component, (C) 0.01 to 10% by weight of a second propylene resin at least containing a carboxylic acid salt bonded to a polymer chain and (D) 5 to 98.98% by weight of a third propylene resin, wherein the order of the weight average molecular weights Mw of the components (B), (C) and (D) satisfy the following relation; component (D)>component (B)>component (C).
摘要翻译：本发明提供了一种在丙烯树脂和增强纤维之间具有界面粘合性且能够制备具有高机械性能的模塑制品的纤维增强丙烯树脂组合物。实现目标的手段纤维增强丙烯树脂组合物包含：（A）1〜75重量％的增强纤维，（B）0.01〜10重量％的含有50〜99摩尔％的衍生自烯烃组分的丙烯的构成单元，（C）0.01至10重量％的至少含有与聚合物链键合的羧酸盐的第二丙烯树脂和（D）5至98.98重量％的（B），（C）和（D）的重均分子量Mw的顺序满足以下关系：组分（D）>组分（B）>组分（C）。

5. 发明授权

US07824770B2 Molding material, prepreg and fiber-reinforced composite material, and method for producing fiber-reinforced molding substrate 有权
标题翻译：成型材料，预浸料和纤维增强复合材料，以及纤维增强成型基材的制造方法
公开(公告)号：US07824770B2
公开(公告)日：2010-11-02
申请号：US12531621
申请日：2008-02-22
申请人： Masato Honma , Shiro Honda , Shunsuke Horiuchi , Koji Yamauchi
发明人： Masato Honma , Shiro Honda , Shunsuke Horiuchi , Koji Yamauchi
IPC分类号： D02G3/00
CPC分类号： B29B15/12 , B29B15/125 , B29C70/086 , B29C70/20 , B29C70/504 , B29K2081/04 , B29K2995/0089 , C08J5/24 , C08J2381/04 , Y10T428/24994 , Y10T428/2924 , Y10T428/2929 , Y10T428/2931 , Y10T428/2938 , Y10T428/298
摘要： This invention relates to: a molding material comprising a bundle of continuous reinforcing fibers (A), a polyarylene sulfide prepolymer (B) comprising at least 50% by weight of cyclic polyarylene sulfide and having the weight average molecular weight of less than 10,000 or polyarylene sulfide (B′) having the weight average molecular weight of 10,000 or greater and the degree of dispersion of 2.5 or lower, and thermoplastic resin (C); a prepreg comprising a resin composition comprising the polyarylene sulfide prepolymer (B) impregnated into a reinforcing fiber; and a method for producing a fiber-reinforced molding substrate comprising step (I) of continuously feeding a bundle of continuous reinforcing fibers, step (II) of combining cyclic polyarylene sulfide with the reinforcing fiber bundle, step (III) of heating the composite obtained in step (II) to subject the cyclic polyarylene sulfide to ring-opening polymerization to convert into polyarylene sulfide, and step (IV) of cooling the composite obtained in step (III) and withdrawing the same.
摘要翻译：本发明涉及：包含一束连续增强纤维（A）的成型材料，包含至少50重量％的环状聚芳硫醚并且重均分子量小于10,000的聚芳硫醚预聚物（B）或聚亚芳基重均分子量为10,000以上，分散度为2.5以下的硫化物（B'）和热塑性树脂（C）; 预浸料，其包含含有浸渍在增强纤维中的聚芳硫醚预聚物（B）的树脂组合物; 以及包含连续供给一束连续增强纤维的工序（I）的制造方法，将聚芳撑硫醚与增强纤维束组合的工序（II），将所得复合体在步骤（II）中使环状聚芳硫醚进行开环聚合以转化为聚芳硫醚，以及步骤（IV）冷却步骤（III）中得到的复合物并将其取出。

6. 发明申请

US20100068518A1 MOLDING MATERIAL, PREPREG AND FIBER-REINFORCED COMPOSITE MATERIAL, AND METHOD FOR PRODUCING FIBER-REINFORCED MOLDING SUBSTRATE 有权
标题翻译：成型材料，预制和纤维增强复合材料，以及用于生产纤维增强模塑基材的方法
公开(公告)号：US20100068518A1
公开(公告)日：2010-03-18
申请号：US12531621
申请日：2008-02-22
申请人： Masato Honma , Shiro Honda , Shunsuke Horiuchi , Koji Yamauchi
发明人： Masato Honma , Shiro Honda , Shunsuke Horiuchi , Koji Yamauchi
IPC分类号： D02G3/00 , C08L81/04
CPC分类号： B29B15/12 , B29B15/125 , B29C70/086 , B29C70/20 , B29C70/504 , B29K2081/04 , B29K2995/0089 , C08J5/24 , C08J2381/04 , Y10T428/24994 , Y10T428/2924 , Y10T428/2929 , Y10T428/2931 , Y10T428/2938 , Y10T428/298
摘要： This invention relates to: a molding material comprising a bundle of continuous reinforcing fibers (A), a polyarylene sulfide prepolymer (B) comprising at least 50% by weight of cyclic polyarylene sulfide and having the weight average molecular weight of less than 10,000 or polyarylene sulfide (B′) having the weight average molecular weight of 10,000 or greater and the degree of dispersion of 2.5 or lower, and thermoplastic resin (C); a prepreg comprising a resin composition comprising the polyarylene sulfide prepolymer (B) impregnated into a reinforcing fiber; and a method for producing a fiber-reinforced molding substrate comprising step (I) of continuously feeding a bundle of continuous reinforcing fibers, step (II) of combining cyclic polyarylene sulfide with the reinforcing fiber bundle, step (III) of heating the composite obtained in step (II) to subject the cyclic polyarylene sulfide to ring-opening polymerization to convert into polyarylene sulfide, and step (IV) of cooling the composite obtained in step (III) and withdrawing the same.
摘要翻译：本发明涉及：包含一束连续增强纤维（A）的成型材料，包含至少50重量％的环状聚芳硫醚并且重均分子量小于10,000的聚芳硫醚预聚物（B）或聚亚芳基重均分子量为10,000以上，分散度为2.5以下的硫化物（B'）和热塑性树脂（C）; 预浸料，其包含含有浸渍在增强纤维中的聚芳硫醚预聚物（B）的树脂组合物; 以及包含连续供给一束连续增强纤维的工序（I）的制造方法，将聚芳撑硫醚与增强纤维束组合的工序（II），将所得复合体在步骤（II）中使环状聚芳硫醚进行开环聚合以转化为聚芳硫醚，以及步骤（IV）冷却步骤（III）中得到的复合物并将其取出。

7. 发明授权

US09731440B2 Molding material and resin-adhered reinforcing fiber bundle 有权
公开(公告)号：US09731440B2
公开(公告)日：2017-08-15
申请号：US13138030
申请日：2009-12-24
申请人： Masato Honma , Atsuki Tsuchiya , Keiichi Asami
发明人： Masato Honma , Atsuki Tsuchiya , Keiichi Asami
IPC分类号： D02G3/36 , C08L23/10 , C08K7/06 , B29C45/00 , B29K23/00 , B29K105/06
CPC分类号： B29C45/0001 , B29C45/0005 , B29K2023/12 , B29K2105/06 , C08L23/10 , Y10T428/2933 , C08L2666/02
摘要： A molding material comprising the following components (A) to (D) at the following ratios, in which the component (D) is bonded to a composite comprising the components (A) to (C) and the order in the weight average molecular weight is component (D)>component (B)>component (C); (A) 1 to 75 wt % of a reinforcing fiber bundle; (B) 0.01 to 10 wt % of a first propylene-based resin; (C) 0.01 to 10 wt % of a second propylene-based resin having carboxylate groups bound to the polymer chains thereof; and (D) 5 to 98.98 wt % of a third propylene-based resin. A molding material of this invention provides a long fiber-reinforced thermoplastic resin molding material containing a propylene-based resin as the matrix resin, which allows the reinforcing fibers to be well dispersed into the molded article produced at the time of injection molding and allows the molded article produced to have excellent mechanical properties.

8. 发明授权

US09505177B2 Method for producing a metal composite 有权
标题翻译：金属复合材料的制造方法
公开(公告)号：US09505177B2
公开(公告)日：2016-11-29
申请号：US13990970
申请日：2011-11-24
申请人： Takashi Fujioka , Masato Honma
发明人： Takashi Fujioka , Masato Honma
IPC分类号： B29C70/00 , B29C70/02 , B29C45/14 , B32B1/00 , B32B15/14 , B32B15/20 , H05K9/00 , B29C70/46 , B29C70/88 , B29C70/08 , H05K7/02 , B29K701/10 , B29K705/00
CPC分类号： B29C70/021 , B29C43/18 , B29C43/36 , B29C45/14221 , B29C45/14811 , B29C70/088 , B29C70/46 , B29C70/885 , B29C2045/14245 , B29C2045/14286 , B29K2701/10 , B29K2705/00 , B32B1/00 , B32B15/14 , B32B15/20 , B32B2250/03 , B32B2250/40 , B32B2260/021 , B32B2260/046 , B32B2305/076 , B32B2305/77 , B32B2457/00 , H05K7/02 , H05K9/0084
摘要： A method is provided for producing a metal composite. The composite includes a metal material and a resin curing layer provided along the metal material, and is obtained by using heat and pressure to mold a preform. The preform includes a sheet-shaped base material containing a thermosetting resin, and a metal material arranged or layered so as to contact the sheet-shaped base material. The method for producing a metal composite includes heating the sheet-shaped base material and semi-curing the thermosetting resin while the metal material in the preform arranged inside a mold is heated to a temperature exceeding 180° C., and molding the preform into a composite using pressure, wherein the thermosetting resin is at least one type selected from the group consisting of epoxy resins, phenol resins, benzoxazine resins, and unsaturated polyester resins.
摘要翻译：提供了一种用于制备金属复合材料的方法。复合材料包括金属材料和沿着金属材料设置的树脂固化层，并且通过使用热和压力来模制预成型件而获得。预成型体包括含有热固性树脂的片状基材，以及布置或层叠以与片状基材接触的金属材料。制造金属复合体的方法包括加热片状基材并半固化热固性树脂，同时将配置在模具内的预成型体中的金属材料加热至超过180℃的温度，并将预成型件成型为复合材料使用压力，其中所述热固性树脂是选自环氧树脂，酚醛树脂，苯并恶嗪树脂和不饱和聚酯树脂中的至少一种。

9. 发明授权

US09475929B2 Fiber-reinforced thermoplastic resin composition, reinforcing fiber bundle, and process for production of fiber-reinforced thermoplastic resin composition 有权
标题翻译：纤维增强热塑性树脂组合物，增强纤维束，以及纤维增强热塑性树脂组合物的制造方法
公开(公告)号：US09475929B2
公开(公告)日：2016-10-25
申请号：US13575749
申请日：2011-01-26
申请人： Atsuki Tsuchiya , Hideaki Sasaki , Masato Honma , Yumi Ando
发明人： Atsuki Tsuchiya , Hideaki Sasaki , Masato Honma , Ichiji Kageishi , Yumi Ando
IPC分类号： C08K3/04 , C08K7/06 , C08L33/06 , C08L33/10 , C08L23/26 , C08J5/04 , C08L77/00 , C08L81/04 , C08L51/06
CPC分类号： C08L23/26 , C08J5/042 , C08J2333/10 , C08L51/06 , C08L77/00 , C08L81/04 , C08L33/26 , C08L33/066
摘要： The present invention relates to fiber-reinforced thermoplastic resin composition comprising 0.1 to 10 mass % of a (meth)acrylic-based polymer, 1 to 70 mass % of reinforcing fiber, and 20 to 98.9 mass % of thermoplastic resin, wherein the (meth)acrylic-based polymer has, in a side chain, at least one functional group selected from a hydroxyl group, a carboxyl group, an amide group, and an urea group, and has a cohesive energy density (CED) of 385 to 550 MPa. The present invention provides, particularly in the case of using a polyolefin-based resin as matrix resin, a fiber-reinforced thermoplastic resin composition and a reinforcing fiber bundle which have high adhesiveness and good mechanical characteristics.
摘要翻译：本发明涉及含有0.1〜10质量％的（甲基）丙烯酸系聚合物，1〜70质量％的增强纤维和20〜98.9质量％的热塑性树脂的纤维增强热塑性树脂组合物，其中，（甲基））丙烯酸类聚合物在侧链中具有选自羟基，羧基，酰胺基和脲基中的至少一种官能团，并且具有385〜550MPa的内聚能密度（CED）。特别是在使用聚烯烃类树脂作为基体树脂的情况下，具有高粘合性和良好的机械特性的纤维增强热塑性树脂组合物和增强纤维束。

10. 发明授权

US08685537B2 Fiber reinforced resin composition, molding material, and method for producing fiber reinforced resin composition 有权
标题翻译：纤维增强树脂组合物，成型材料以及纤维增强树脂组合物的制造方法
公开(公告)号：US08685537B2
公开(公告)日：2014-04-01
申请号：US13138658
申请日：2010-03-16
申请人： Naokichi Imai , Masato Honma , Takayuki Fujiwara , Takashi Fujioka , Masaru Akita , Makiko Saito
发明人： Naokichi Imai , Masato Honma , Takayuki Fujiwara , Takashi Fujioka , Masaru Akita , Makiko Saito
IPC分类号： B29C45/14 , C08L77/06 , C08K7/06
CPC分类号： C08J5/24 , B29C47/6037 , B29C47/6056 , B29C47/6087 , C08J5/04 , C08J5/042 , C08J2300/22 , C08J2300/24 , C08J2363/00 , C08J2400/22 , C08J2423/28 , C08L23/10 , C08L101/02 , Y10T428/2991
摘要： The invention provides a fiber reinforced resin composition comprising a melt-kneaded product (A) prepared by melt-kneading a first resin (A1) and a second resin (A2) that has a reactive functional group as well as a third resin (B) and a fibrous filler (C), wherein, with respect to the contents of the components, the first resin (A1), the second resin with a reactive functional group (A2), and the third resin (B) account for 0.1 to 75 wt %, 0.1 to 15 wt %, and 10 to 99.8 wt %, respectively, to form a resin composition while said fibrous filler (C) accounts for 0.1 to 300 parts by weight per 100 parts by weight of said resin composition, said first resin (A1) and said third resin (B) forming a matrix resin, said second resin (A2) being dispersed as particles in said matrix resin, and said particles having a number average particle diameter of 10 to 1,000 nm. The invention relates to a fiber reinforced resin composition having rigidity and impact resistance in a good balance, a molding material, and a production method thereof.
摘要翻译：本发明提供一种纤维增强树脂组合物，其包含通过熔融捏合第一树脂（A1）和具有反应性官能团的第二树脂（A2）以及第三树脂（B）制备的熔融捏合产物（A）和纤维状填料（C），其中，相对于成分的含量，第一树脂（A1），具有反应性官能团（A2）的第二树脂和第三树脂（B）占0.1〜75 重量％，0.1〜15重量％，10〜99.8重量％，形成树脂组合物，同时所述纤维填料（C）相对于100重量份所述树脂组合物为0.1〜300重量份，树脂（A1）和形成基质树脂的所述第三树脂（B），所述第二树脂（A2）作为颗粒分散在所述基体树脂中，所述颗粒的数均粒径为10〜1000nm。本发明涉及具有良好平衡的刚性和耐冲击性的纤维增强树脂组合物，成型材料及其制造方法。

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