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1. 发明授权

US06733925B2 Non-aqueous electrolytic solution secondary battery with electrodes having a specific thickness and porosity 有权
标题翻译：具有特定厚度和孔隙率的电极的非水电解液二次电池
公开(公告)号：US06733925B2
公开(公告)日：2004-05-11
申请号：US09773484
申请日：2001-02-02
申请人： Kensuke Hironaka , Kenji Nakai , Yoshimasa Koishikawa , Yuichi Takatsuka , Kenji Hara , Tomohiro Iguchi , Katsunori Suzuki , Koji Higashimoto , Takeshi Nakano
发明人： Kensuke Hironaka , Kenji Nakai , Yoshimasa Koishikawa , Yuichi Takatsuka , Kenji Hara , Tomohiro Iguchi , Katsunori Suzuki , Koji Higashimoto , Takeshi Nakano
IPC分类号： H01M404
CPC分类号： H01M10/0525 , H01M2/06 , H01M2/1653 , H01M2/1686 , H01M2/30 , H01M4/505 , H01M6/10 , H01M2010/4292 , Y02T10/7011
摘要： A non-aqueous electrolytic secondary battery that can prevent a drop in the power even in a large current discharge is provided. Porosity of a separator is larger than or the same as porosity of a positive electrode mixture and a porosity of a negative electrode mixture. Particularly, the porosity of the positive electrode mixture is 20% to 50%, the porosity of the negative electrode mixture is 20% to 50%, and the porosity of the separator is 20% to 60%. The separator becomes rich in the volume of the electrolytic solution that infiltrates into interfacial aperture between the separator and the negative electrode. When the large current discharge is carried out in a short time, lithium-ions are released/occluded from the electrodes and the electrolytic solution can gain the released/occluded lithium-ions with a small interfacial resistance.
摘要翻译：提供即使在大电流放电时也能够防止功率下降的非水电解二次电池。隔膜的孔隙率大于或等于正极混合物的孔隙率和负极混合物的孔隙率。特别是，正极合剂的孔隙率为20〜50％，负极混合物的孔隙率为20〜50％，隔膜的孔隙率为20〜60％。分离器变得富含电解液的体积，其渗透到分离器和负极之间的界面孔中。当在短时间内进行大电流放电时，从电极释放/吸收锂离子，并且电解液可以以较小的界面电阻获得释放/封闭的锂离子。

2. 发明授权

US06447946B1 Lithium-ion battery 有权
标题翻译：锂离子电池
公开(公告)号：US06447946B1
公开(公告)日：2002-09-10
申请号：US09519464
申请日：2000-03-06
申请人： Kenji Nakai , Takeshi Nakano , Kensuke Hironaka , Koji Higashimoto , Kenji Hara , Katsunori Suzuki , Tomohiro Iguchi
发明人： Kenji Nakai , Takeshi Nakano , Kensuke Hironaka , Koji Higashimoto , Kenji Hara , Katsunori Suzuki , Tomohiro Iguchi
IPC分类号： H01M212
CPC分类号： H01M4/505 , H01M2/12 , H01M4/131 , H01M4/625 , H01M10/0525 , H01M10/0587 , Y10T29/49115
摘要： A cylindrical lithium-ion battery with high safety, high capacity and high power has a winding group having a positive electrode, a negative electrode and at least one separator, and a connecting portion for connecting to respective terminals from the winding group accommodated in a battery container, and which is provided with an inner pressure-reducing mechanism for discharging gas according to an increase in inner pressure inside the battery container. The positive electrode includes a collector whose both surfaces are applied with composing material including lithium-manganese complex oxide, the thickness of the composing material on the both surfaces of the collector is at least 210 &mgr;m and the amount of the active material per one surface of the collector is at least 240 g/m2. The compounding ratio of the lithium-manganese complex oxide in the composing material is preferably at least 80 wt %.
摘要翻译：具有高安全性，高容量和高功率的圆柱形锂离子电池具有正极，负极和至少一个隔板的绕组，以及用于连接到容纳在电池中的绕组组的各个端子的连接部分容器，并且其具有根据电池容器内部的内部压力的增加来排出气体的内部减压机构。正极包括两个表面被施加有包括锂锰复合氧化物的组成材料的集电体，集电体两面上的组成材料的厚度为至少210μm，并且每个表面的活性材料的量收集器至少240克/平方米。构成材料中的锂锰复合氧化物的配合比优选为80重量％以上。

3. 发明授权

US06706446B2 Non-aqueous electrolytic solution secondary battery 有权
标题翻译：非水电解液二次电池
公开(公告)号：US06706446B2
公开(公告)日：2004-03-16
申请号：US09977305
申请日：2001-10-16
申请人： Kenji Nakai , Yoshimasa Koishikawa , Yuichi Takatsuka , Kensuke Hironaka , Takeshi Nakano , Youshin Yagi
发明人： Kenji Nakai , Yoshimasa Koishikawa , Yuichi Takatsuka , Kensuke Hironaka , Takeshi Nakano , Youshin Yagi
IPC分类号： H01M458
CPC分类号： H01M4/505 , H01M2/022 , H01M4/131 , H01M10/0525 , H01M10/0587
摘要： A cylindrical lithium-ion battery 20 accommodates a winding group 6, is structured by winding a positive electrode using lithium manganate (Li1+xMn2−xO4 or Li1+xMn2−x−yAlyO4) having an average particle diameter of primary particles in a range of from 0.1 &mgr;m to 2 &mgr;m as a positive electrode active material and a negative electrode using amorphous carbon as a negative electrode active material via a separator, and a non-aqueous electrolytic solution within a battery container 7.
摘要翻译：圆筒形锂离子电池20容纳绕组6，通过使用一次粒子的平均粒径的锰酸锂（Li1 + xMn2-xO4或Li1 + xMn2-x-yAlyO4）的卷绕正极来构成，从作为正极活性物质的0.1〜2μm，经由隔膜使用无定形碳作为负极活性物质的负极以及电池容器7内的非水电解液。

4. 发明授权

US06803149B2 Non-aqueous electrolytic solution secondary battery 失效
标题翻译：非水电解液二次电池
公开(公告)号：US06803149B2
公开(公告)日：2004-10-12
申请号：US09977214
申请日：2001-10-16
申请人： Kenji Nakai , Yoshimasa Koishikawa , Youshin Yagi , Kensuke Hironaka
发明人： Kenji Nakai , Yoshimasa Koishikawa , Youshin Yagi , Kensuke Hironaka
IPC分类号： H01M450
CPC分类号： H01M4/505 , H01M2/12 , H01M2/1241 , H01M2/20 , H01M4/131 , H01M4/133 , H01M4/485 , H01M4/587 , H01M6/10 , H01M10/0525 , H01M2004/021 , H01M2010/4292
摘要： The present invention is to provide a non-aqueous electrolytic solution secondary battery which has high safety while maintaining high capacity and high power. A cylindrical lithium-ion battery 20 is provided in a battery lid which is a portion of a battery container with a cleavage valve 11 which cleaves at a predetermined pressure, and includes an electrode winding group 6 prepared by winding a positive electrode, a negative electrode and a separator, connection portions for connecting the electrode winding group 6 to respective electrode terminals, and non-aqueous electrolytic solution therein. As a positive electrode active material, lithium manganate where the amount of elution of manganese into the non-aqueous electrolytic solution is 5% or less based on the lithium manganate in a region where an electrode potential to metal lithium is 4.8V or more is used. As a negative electrode active material, graphite in/from which lithium ions can be occluded/released according to charging and discharging is used.
摘要翻译：本发明提供一种保持高容量，高功率的高安全性的非水电解液二次电池。圆筒形锂离子电池20设置在电池盖中，该电池盖是具有在预定压力下切割的切割阀11的电池容器的一部分，并且包括通过卷绕正电极，负极以及分离器，用于将电极绕组6连接到各个电极端子的连接部分和其中的非水电解液。作为正极活性物质，使用其中非电解电解液中锰析出量相对于金属锂的电极电位为4.8V以上的区域中的锰酸锂为5％以下的锰酸锂。作为负极活性物质，使用可以根据充放电使锂离子被吸留/释放的石墨。

5. 发明授权

US06509114B1 Cylindrical lithium-ion battery 有权
标题翻译：圆柱形锂离子电池
公开(公告)号：US06509114B1
公开(公告)日：2003-01-21
申请号：US09525263
申请日：2000-03-14
申请人： Kenji Nakai , Takeshi Nakano , Kensuke Hironaka
发明人： Kenji Nakai , Takeshi Nakano , Kensuke Hironaka
IPC分类号： H01M400
CPC分类号： H01M10/0431 , H01M4/505 , H01M4/587 , H01M10/0525 , H01M10/0587 , Y02T10/7011
摘要： A cylindrical lithium-ion battery with excellent safety where abnormal heat generation and remarkable deformation of a battery container do not occur even at an abnormal time is provided. When an average diameter of a winding group 6 is A mm, an inner diameter of the battery container 5 is B mm, a longitudinal length of the winding group 6 except for lead pieces extending from the winding group 6 is H mm, and the number of windings where a layer of one unit comprising a negative electrode member/separator/negative electrode member/separator is wound around a shaft core 11 is W, a calculation value K obtained by a formula; K=(B−A)×(10000/(W×H) is set to 0.89 or more. When the calculation value K is 0.89 or more, a gap (B−A) between an outer periphery of the winding group 6 and an inner periphery of the battery container 5 that enables the winding group 6 to expand in its diameter direction at an abnormal time is properly secured.
摘要翻译：提供了即使在异常时也不会发生具有优异安全性的圆柱形锂离子电池，其中异常发热和电池容器的显着变形。当卷绕组6的平均直径为Amm时，电池容器5的内径为Bmm，除了从卷绕组6延伸的引线片以外的卷绕组6的纵向长度为Hmm，其中包括负极构件/隔板/负极构件/隔板的一个单元的层缠绕在轴芯11上的绕组是W，通过公式获得的计算值K; K =（BA）×（10000 /（W×H））为0.89以上，当计算值K为0.89以上时，卷绕组6的外周与电池内周之间的间隙（BA）适当地确保使绕组6在异常时沿其直径方向膨胀的容器5。

6. 发明授权

US06506518B1 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US06506518B1
公开(公告)日：2003-01-14
申请号：US09525264
申请日：2000-03-14
申请人： Koutaro Kobayashi , Yoshimasa Koishikawa , Kensuke Hironaka
发明人： Koutaro Kobayashi , Yoshimasa Koishikawa , Kensuke Hironaka
IPC分类号： H01M458
CPC分类号： H01M4/505 , H01M4/133 , H01M4/587 , H01M10/0525 , H01M2010/4292 , Y02T10/7011 , Y10T29/49108 , Y10T29/49115
摘要： A lithium secondary battery capable of improving high temperature cycle life characteristic effectively without decreasing discharge capacity. Amorphous carbon powder with a specific surface area of 10.0 m2/g and a mean particle diameter of 7.0 &mgr;m is used as negative electrode active material and lithium manganate with a Li/Mn ratio of 0.58 is used as positive electrode active material. Since a surface area of the negative electrode active material layer is made large by setting the mean particle diameter of the amorphous carbon powder to 10 &mgr;m or less, the surface area of the negative electrode active material layer is sufficiently large that, even when inert coating is formed on the surface of the negative electrode due to manganese deposition caused by manganese elution from the positive electrode, high temperature cycle life characteristic can be improved without high temperature deterioration.
摘要翻译：能够有效地提高高温循环寿命特性而不降低放电容量的锂二次电池。使用比表面积为10.0m 2 / g，平均粒径为7.0μm的无定形碳粉末作为负极活性物质，Li / Mn比为0.58的锰酸锂用作正极活性物质。由于通过将非晶碳粉末的平均粒径设定为10μm以下，使负极活性物质层的表面积变大，所以负极活性物质层的表面积足够大，即使在惰性涂布由于由正极中的锰洗脱引起的锰沉积而形成在负极的表面上，可以提高高温循环寿命特性，而不会导致高温劣化。

7. 发明授权

US4758482A Enclosed type lead batteries and method for producing the same 失效
标题翻译：封闭型铅电池及其制造方法
公开(公告)号：US4758482A
公开(公告)日：1988-07-19
申请号：US101266
申请日：1987-09-25
申请人： Takumi Yamana , Tomoyuki Ohkura , Akira Ishiodori , Yoshimi Yabui , Yutaka Suzuki , Masayoshi Aoki , Mikio Oguma , Masatoshi Takasu , Akio Komaki , Takumi Hayakawa , Kensuke Hironaka , Hironao Wada , Satoshi Matsubayashi
发明人： Takumi Yamana , Tomoyuki Ohkura , Akira Ishiodori , Yoshimi Yabui , Yutaka Suzuki , Masayoshi Aoki , Mikio Oguma , Masatoshi Takasu , Akio Komaki , Takumi Hayakawa , Kensuke Hironaka , Hironao Wada , Satoshi Matsubayashi
IPC分类号： H01M2/02 , H01M2/12 , H01M10/12
CPC分类号： H01M2/0275 , H01M10/126 , H01M2/021 , H01M2/1229
摘要： An enclosed type lead battery comprises in combination:a cap formed of a synthetic resin, which is integrally formed with anodec and cathodec terminals formed of lead or a lead alloy inserted therein and an exhaust portion to which a safety valve is attached,a plate stack having its ears connected to said terminals, andan enclosure formed of a film or sheet made of a synthetic resin, in which said plate stack is placed, and which is thermally fused at the peripheral edge of its opening to said cap.
摘要翻译：一种封闭式铅蓄电池包括：由合成树脂形成的盖，其与由其中插入的铅或铅合金形成的阳极和阴极端子整体形成，以及安装有安全阀的排气部分，板堆叠其耳朵连接到所述端子，以及由合成树脂制成的膜或片形成的外壳，其中放置所述板堆叠，并且在其开口的周边缘处热熔合到所述盖。

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