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    • 1. 发明授权
    • Method of texturing a superconductive oxide precursor
    • 纹理化超导氧化物前体的方法
    • US6001777A
    • 1999-12-14
    • US902588
    • 1997-07-29
    • Kenneth L. DeMoranvilleQi LiPeter D. AntayaCraig J. ChristophersonGilbert N. Riley, Jr.Jeffrey M. Seuntjens
    • Kenneth L. DeMoranvilleQi LiPeter D. AntayaCraig J. ChristophersonGilbert N. Riley, Jr.Jeffrey M. Seuntjens
    • H01L39/24H01L39/00
    • H01L39/248
    • A method of forming a textured superconductor wire includes constraining an elongated superconductor precursor between two constraining elongated members placed in contact therewith on opposite sides of the superconductor precursor, and passing the superconductor precursor with the two constraining members through flat rolls to form the textured superconductor wire. The method includes selecting desired cross-sectional shape and size constraining members to control the width of the formed superconductor wire. A textured superconductor wire formed by the method of the invention has regular-shaped, curved sides and is free of flashing. A rolling assembly for single-pass rolling of the elongated precursor superconductor includes two rolls, two constraining members, and a fixture for feeding the precursor superconductor and the constraining members between the rolls. In alternate embodiments of the invention, the rolls can have machined regions which will contact only the elongated constraining members and affect the lateral deformation and movement of those members during the rolling process.
    • 形成纹理超导体线的方法包括在超导体前体的相对侧上将与超导体前体相对设置的两个约束细长构件之间的细长超导体前体约束,并且使超导体前体与两个约束构件通过平辊以形成织构化的超导体线 。 该方法包括选择期望的横截面形状和尺寸约束构件以控制形成的超导体线的宽度。 通过本发明的方法形成的纹理超导体线具有规则形状的弯曲侧面并且不闪烁。 用于细长前驱体超导体的单次轧制的滚动组件包括两个辊,两个约束构件和用于在辊之间供给前体超导体和约束构件的固定装置。 在本发明的替代实施例中,辊可以具有仅与细长的约束构件接触并且在轧制过程中影响这些构件的横向变形和移动的加工区域。
    • 3. 发明授权
    • Low resistance cabled conductors comprising superconducting ceramics
    • 低电阻电缆导体包括超导陶瓷
    • US06284979B1
    • 2001-09-04
    • US08851719
    • 1997-05-05
    • Alexis P. MalozemoffGregory L. SnitchlerWilliam L. BarnesAlexander OttoGilbert N. Riley, Jr.Jeffrey M. Seuntjens
    • Alexis P. MalozemoffGregory L. SnitchlerWilliam L. BarnesAlexander OttoGilbert N. Riley, Jr.Jeffrey M. Seuntjens
    • H01B1210
    • H01L39/143
    • A cabled conductor is provided for use in a cryogenically cooled circuit including refrigeration having a predetermined operating temperature and efficiency. The conductor includes multiple conductor strands cabled about the longitudinal axis of the conductor at a preselected cabling period, each strand including a composite of superconducting ceramic in intimate contact with conductive matrix material. Each filament has high performance regions in which the filament material is well-textured with its preferred direction aligned perpendicular to the widest longitudinal cross-section of the conductor alternating with poorly superconducting regions which are at least about half the diameter of a filament in length and in which the superconducting ceramic filament is strained by transposition in excess of its critical strain limit. In the poorly superconducting regions, the conductive matrix material provides an alternate current path. The ratio of the average length of the poorly superconducting regions to the preselected cabling period is less than about (&rgr;300e/&rgr;oe)&egr;E, where &rgr;oe is the resistivity of the composite at the operating temperature; &rgr;300e is the resistivity of the composite at 300 Kelvins; and &egr; is the predetermined efficiency of the refrigeration means at its operating temperature. In the preferred embodiment, this ratio is less than 1:4, and preferably less than 1:20.
    • 提供一种用于低温冷却回路中的电缆导体,包括具有预定工作温度和效率的制冷。 导体包括在预选布线周期围绕导体的纵向轴线布置的多个导线,每个线包括与导电基体材料紧密接触的超导陶瓷的复合材料。 每个灯丝具有高性能区域,其中长丝材料具有良好的织构,其优选的方向垂直于导体的最宽纵向横截面排列,与导体长度的至少约一半长度的不良超导区交替, 其中超导陶瓷细丝通过转移超过其临界应变极限而变形。 在较差的超导区域中,导电基体材料提供了交替的电流路径。 不良超导区域的平均长度与预选布线周期的比值小于约(rho300e / rhooe)epsiE,其中r为复合材料在工作温度下的电阻率; rho300e是300 Kelvins的复合材料的电阻率; 而epsi是制冷装置在其工作温度下的预定效率。 在优选实施方案中,该比率小于1:4,优选小于1:20。
    • 4. 发明授权
    • Method for making cabled conductors containing anisotropic superconducting compounds
    • 制造含各向异性超导化合物的电缆导体的方法
    • US06247225B1
    • 2001-06-19
    • US08554814
    • 1995-11-07
    • Gregory L. SnitchlerJeffrey M. SeuntjensWilliam L. BarnesGilbert N. Riley, Jr.
    • Gregory L. SnitchlerJeffrey M. SeuntjensWilliam L. BarnesGilbert N. Riley, Jr.
    • H01L3924
    • H01L39/143H01L39/248Y10S505/884Y10S505/926Y10T29/49014
    • A cabled conductor comprises a plurality of transposed strands each comprising one or more preferably twisted filaments preferably surrounded or supported by a matrix material and comprising textured anisotropic superconducting compounds which have crystallographic grain alignment that is substantially unidirectional and independent of the rotational orientation of the strands and filaments in the cabled conductor. The cabled conductor is made by forming a plurality of suitable composite strands, forming a cabled intermediate from the strands by transposing them about the longitudinal axis of the conductor at a preselected strand lay pitch, and, texturing the strands in one or more steps including at least one step involving application of a texturing process with a primary component directed orthogonal to the widest longitudinal cross-section of the cabled intermediate, at least one such orthogonal texturing step occurring subsequent to said strand transposition step. In a preferred embodiment, the filament cross-section, filament twist pitch, and strand lay pitch are cooperatively selected to provide a filament transposition area which is always at least ten times the preferred direction area of a typical grain of the desired anisotropic superconducting compound. For materials requiring biaxial texture, the texturing step preferably includes application of a texturing process with a second primary component in a predetermined direction in the plane of the widest longitudinal cross-section of the conductor.
    • 电缆导体包括多个转置的绞合线,每个绞合线包括一个或多个优选的绞合长丝,优选地被基质材料包围或支撑,并且包括纹理各向异性超导化合物,其具有基本上单向且不依赖于线的旋转取向的晶体取向, 电缆导体中的细丝。 电缆导体通过形成多个合适的复合线材制成,通过以预选的绞线间距将导体的纵向轴线绕它们绕导体的纵向轴线形成缆线中间体,并且以一个或多个步骤将绞合线组织包括在 至少一个步骤涉及使用与所述有线中间件的最宽纵向横截面垂直的主要部件进行纹理化处理,在所述链转置步骤之后发生的至少一个这样的正交纹理化步骤。 在优选的实施方案中,协调地选择细丝横截面,长丝扭曲节距和绞线间距,以提供总是至少是所需各向异性超导化合物的典型颗粒的优选方向面积的十倍的细丝转置区域。 对于需要双轴纹理的材料,纹理化步骤优选地包括在导体的最宽纵向截面的平面中沿预定方向施加具有第二主要部件的纹理处理。
    • 5. 发明授权
    • Cabled conductors containing anisotropic superconducting compounds
    • 含各向异性超导化合物的电缆导体
    • US06906265B2
    • 2005-06-14
    • US09769705
    • 2001-01-25
    • Gregory L. SnitchlerJeffrey M. SeuntjensWilliam L. BarnesGilbert N. Riley, Jr.
    • Gregory L. SnitchlerJeffrey M. SeuntjensWilliam L. BarnesGilbert N. Riley, Jr.
    • H01B12/08H01B13/00H01L39/14H01L39/24H01B12/00
    • H01L39/143H01L39/248Y10S505/884Y10S505/926Y10T29/49014
    • A cabled conductor comprises a plurality of transposed strands each comprising one or more preferably twisted filaments preferably surrounded or supported by a matrix material and comprising textured anisotropic superconducting compounds which have crystallographic grain alignment that is substantially unidirectional and independent of the rotational orientation of the strands and filaments in the cabled conductors. The cabled conductor is made by forming a plurality of suitable composite strands, forming a cabled intermediate from the strands by transposing them about the longitudinal axis of the conductor at a preselected strand lay pitch, and, texturing the strands in one or more steps including at least one step involving application of a texturing process with a primary component directed orthogonal to the widest longitudinal cross-section of the cabled intermediate, at least one such orthogonal texturing step occurring subsequent to said strand transposition step. In a preferred embodiment, the filament cross-section, filament twist pitch, and strand lay pitch are cooperatively selected to provide a filament transposition area which is always at least ten times the preferred direction area of a typical grain of the desired anisotropic superconducting compound. For materials requiring biaxial texture, the texturing step preferably includes application of a texturing process with a second primary component in a predetermined direction in the plane of the widest longitudinal cross-section of the conductor.
    • 电缆导体包括多个转置的绞合线,每个绞合线包括一个或多个优选的绞合长丝,优选地被基体材料包围或支撑,并且包括纹理各向异性超导化合物,其具有基本上单向且不依赖于线的旋转取向的晶体取向, 电缆导体中的细丝。 电缆导体通过形成多个合适的复合线材制成,通过以预选的绞线间距将导体的纵向轴线绕它们绕导体的纵向轴线形成缆线中间体,并且以一个或多个步骤将绞合线组织包括在 至少一个步骤涉及使用与所述有线中间件的最宽纵向横截面垂直的主要部件进行纹理化处理,在所述链转置步骤之后发生的至少一个这样的正交纹理化步骤。 在优选的实施方案中,协调地选择细丝横截面,长丝扭曲节距和绞线间距,以提供总是至少是所需各向异性超导化合物的典型颗粒的优选方向面积的十倍的细丝转置区域。 对于需要双轴纹理的材料,纹理化步骤优选地包括在导体的最宽纵向截面的平面中沿预定方向施加具有第二主要部件的纹理处理。
    • 6. 发明授权
    • Multifilament composite BSCCO oxide superconductor
    • 多丝复合BSCCO氧化物超导体
    • US06194352B1
    • 2001-02-27
    • US08553184
    • 1995-11-07
    • Gilbert N. Riley, Jr.Jeffrey M. SeuntjensWilliam L. BarnesGregory L. SnitchlerAlexander Otto
    • Gilbert N. Riley, Jr.Jeffrey M. SeuntjensWilliam L. BarnesGregory L. SnitchlerAlexander Otto
    • H01B1202
    • H01L39/248H01F6/06H01F41/063H01F41/069Y10S505/74
    • A method for preparing an oxide superconductor cable includes transposing a plurality of oxide superconductor strands along a longitudinal axis so as to form a cable and exposing the cable to a two step heat treatment after cabling of the oxide strands, the heat treatment comprising, (a) heating the cable to and maintaining the cable at a first temperature sufficient to partially melt the article, such that a liquid phase co-exists with the desired oxide superconductor phase; and (b) cooling the cable to and maintaining the cable at a second temperature sufficient to substantially transform the liquid phase into the desired oxide superconductor. The oxide superconductor multistrand cable includes a plurality of oxide superconductor strands, each of the strands including an oxide superconductor having an irreversible melt characteristic, wherein the plurality of oxide strands are transposed about a longitudinal axis, such that each of the strands are substantially electrically and substantially mechanically isolated; and wherein the cable exhibits critical transport properties (Jc) of at least about 10,000 A/cm2 at 77K, self field.
    • 制备氧化物超导体电缆的方法包括沿着纵向轴线转置多个氧化物超导体股线,以形成电缆,并且在电缆穿过氧化物线束之后将电缆暴露于两步热处理,该热处理包括:(a 将电缆加热并将电缆保持在足以部分熔化制品的第一温度,使得液相与期望的氧化物超导体相共存; 和(b)将电缆冷却到并将电缆保持在足以基本上将液相转变成所需氧化物超导体的第二温度。 氧化物超导体多股线缆包括多个氧化物超导体股线,每个股线包括具有不可逆熔融特性的氧化物超导体,其中多个氧化物股线围绕纵向轴线转置,使得每根股线基本上电气和 基本上机械隔离; 并且其中所述电缆在77K处表现出至少约10,000A / cm 2的临界传输特性(Jc)。
    • 8. 发明授权
    • Composite wires and process of forming same
    • 复合线及其成型工艺
    • US5897963A
    • 1999-04-27
    • US2613
    • 1998-01-05
    • Jeffrey M. Seuntjens
    • Jeffrey M. Seuntjens
    • B21C37/04F25B21/00B32B15/02B21C23/24
    • B21C37/042F25B21/00Y02B30/66Y10T428/12438Y10T428/12486Y10T428/12771Y10T428/12812
    • Disclosed Is a process for the fabrication of rare earth or rare earth alloy materials in the form of fine wires for refrigeration regenerator applications. The wire is a composite consisting of a metal core and a metal sheath. The core material is comprises of at least a 20 atomic percent portion of rare earth metal as a pure metal, an alloy with other rare earth metals, or an intermetallic compound alloy with one or more non rare earth metals. The sheath material is essentially immiscible with the rare earth in the core, has no magnetic phase transitions in the temperature range for the intended operation, and has good corrosion and oxidation resistance. The sheath material is typically a small portion of the total composite wire cross section. The composite wire is fabricated from the co-reduction of an assembled billet by conventional wire processing techniques.
    • 公开了用于制造用于制冷再生器应用的细丝形式的稀土或稀土合金材料的方法。 电线是由金属芯和金属护套组成的复合材料。 核心材料包括至少20原子百分比的稀土金属作为纯金属,与其它稀土金属的合金,或与一种或多种非稀土金属的金属间化合物合金。 护套材料与芯体中的稀土基本上是不混溶的,在预期操作的温度范围内没有磁相转变,并且具有良好的耐腐蚀和抗氧化性。 护套材料通常是总复合导线横截面的一小部分。 复合线材通过常规的丝线加工技术由组装的坯料的共同还原制成。