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1. 发明授权

US06709571B1 Low pressure naphtha hydrocracking process 有权
标题翻译：低压石脑油加氢裂化工艺
公开(公告)号：US06709571B1
公开(公告)日：2004-03-23
申请号：US09357504
申请日：1999-07-20
申请人： Kenneth J. Del Rossi , David A. Pappal , Brenda H. Rose
发明人： Kenneth J. Del Rossi , David A. Pappal , Brenda H. Rose
IPC分类号： C10G4700
CPC分类号： C10G47/16 , C10G65/12
摘要： This invention is directed to an extinction recycle naphtha hydrocracking processes. Large pore zeolite catalysts with Constraint Indices less than 2, such as USY or beta, which are loaded with noble metals such as Pt or Pd or with transition metals such as Ni in combination with Mo or W are employed. Preferably, low hydrogen partial pressures, and a feedstock relatively rich in hydrogen and low in aromatics content, are used, in order to extend catalyst cycle length.
摘要翻译：本发明涉及消光再循环石脑油加氢裂化方法。使用小于2的约束指数的大孔沸石催化剂，例如USY或β，其负载贵金属如Pt或Pd或与过渡金属如Ni结合使用Mo或W。优选地，为了延长催化剂循环长度，使用低氢分压和相对富氢和低芳烃含量的原料。

2. 发明授权

US5475178A Supported heteropoly acid catalysts 失效
标题翻译：负载型杂多酸催化剂
公开(公告)号：US5475178A
公开(公告)日：1995-12-12
申请号：US292653
申请日：1994-08-18
申请人： Kenneth J. Del Rossi , Gregory A. Jablonski , Charles T. Kresge , Guenter H. Kuehl , David O. Marler , Gayatri S. Rav , Brenda H. Rose
发明人： Kenneth J. Del Rossi , Gregory A. Jablonski , Charles T. Kresge , Guenter H. Kuehl , David O. Marler , Gayatri S. Rav , Brenda H. Rose
IPC分类号： B01J27/188 , B01J29/03 , B01J29/04 , C07C2/62 , C07C2/64 , C07C2/68 , C07C5/22 , C07C15/107
CPC分类号： B01J29/0341 , B01J27/188 , B01J29/041 , B01J29/043 , C07C2/62 , B01J29/0308 , C07C2527/188 , Y02P20/588
摘要： There is provided a catalyst comprising a heteropoly acid, such as phosphotungstic acid, supported on a mesoporous crystalline material, such as M41S. A particular form of this M41S support is designated as MCM-41. There is also provided a method for preparing this catalyst by impregnating the heteropoly acid on the support. There is also provided a process for using this catalyst to catalyze acid catalyzed reactions, such as the isomerization of paraffins and the alkylation of aromatics.
摘要翻译：提供了一种催化剂，其包含负载在介孔结晶材料如M41S上的杂多酸如磷钨酸。该M41S支持的特定形式被指定为MCM-41。还提供了通过将杂多酸浸渍在载体上来制备该催化剂的方法。还提供了一种使用该催化剂催化酸催化反应的方法，例如链烷烃的异构化和芳族化合物的烷基化。

3. 发明授权

US5461183A Removal of ASO from HF/sulfolane alkylation catalyst 失效
标题翻译：从HF /环丁砜烷基化催化剂中除去ASO
公开(公告)号：US5461183A
公开(公告)日：1995-10-24
申请号：US272989
申请日：1994-07-15
申请人： Kenneth J. Del Rossi , Tomas R. Melli
发明人： Kenneth J. Del Rossi , Tomas R. Melli
IPC分类号： C01B7/19 , C07C2/62 , C07C9/16 , C07D333/48 , C07C7/10
CPC分类号： C07D333/48 , C01B7/195 , C07C2/62 , C07C9/16 , C07C2527/1206
摘要： A method for separating conjunct polymers which are formed as byproducts of acid catalyzed isoparaffin-olefin alkylation and sulfolane from a mixture containing conjunct polymers, sulfolane, and hydrofluoric acid comprising stripping HF from the spent catalyst, treating the stripped, spent catalyst with hydrogen to provide a stripped hydrotreated catalyst stream, and gravitationally separating the stripped hydrotreated catalyst stream to remove conjunct polymeric byproducts.
摘要翻译：一种从含有结合聚合物，环丁砜和氢氟酸的混合物形成的作为酸催化的异链烷烃烯烃烷基化和环丁砜的副产物的结合聚合物的方法，包括从废催化剂中汽提HF，用氢气处理汽提的废催化剂以提供汽提的加氢处理的催化剂流，并重力分离汽提的加氢处理的催化剂流以除去结合的聚合副产物。

4. 发明授权

US5334792A Combined paraffin isomerization/ring opening process for c5+naphtha 失效
标题翻译： c5 +石脑油组合石蜡异构化/开环方法
公开(公告)号：US5334792A
公开(公告)日：1994-08-02
申请号：US958826
申请日：1992-10-09
申请人： Kenneth J. Del Rossi , David J. Dovedytis , David J. Esteves , Mohsen N. Harandi , Albin Huss, Jr.
发明人： Kenneth J. Del Rossi , David J. Dovedytis , David J. Esteves , Mohsen N. Harandi , Albin Huss, Jr.
IPC分类号： C10G59/02 , C07C5/02 , C07C5/13 , C07C5/23
CPC分类号： C10G59/02 , Y10S585/94
摘要： There is provided a process for ring opening of aromatics and cycloaliphatics, as well as isomerization of aliphatics. The feedstream to this process comprises hydrocarbons having 6 carbon atoms. The process involves the use of at least two reactors connected in series. The first reactor contains a zeolite catalyst and is operated under conditions which particularly promote ring opening. The catalyst in this first reactor may comprise zeolite Beta and platinum. A downstream reactor is operated under conditions to promote isomerization of aliphatics. The catalyst in the second reactor may comprise alumina, platinum and a chloride component.
摘要翻译：提供了芳烃和环烯烃开环方法以及脂肪族异构化方法。该方法的进料流包含具有6个碳原子的烃。该方法涉及使用串联连接的至少两个反应器。第一反应器含有沸石催化剂，并在特别促进开环的条件下操作。该第一反应器中的催化剂可以包括沸石β和铂。下游反应器在促进脂肪族异构化的条件下运行。第二反应器中的催化剂可以包括氧化铝，铂和氯化物组分。

5. 发明授权

US5173467A Isoparaffin:olefin alkylation process and catalyst complex 失效
标题翻译：异链烷烃：烯烃烷基化方法和催化剂配合物
公开(公告)号：US5173467A
公开(公告)日：1992-12-22
申请号：US806030
申请日：1991-12-12
申请人： Kenneth J. Del Rossi
发明人： Kenneth J. Del Rossi
IPC分类号： B01J27/12 , B01J27/16 , C07C2/62
CPC分类号： C07C2/62 , B01J27/12 , B01J27/16 , C07C2527/1213 , C07C2527/16
摘要： The invention provides a catalyst complex for promoting alkylation of an isoparaffin with an olefin, said catalyst complex comprising the reaction product of Lewis acid and at least one fluorophosphoric acid; and, additionally, excess Lewis acid in concentration of from about 10 ppm (weight) to about 10000 ppm by weight of the total isoparaffin and olefin feed. The invention further provides a process for the alkylation of an isoparaffin with an olefin by contacting a mixture of isoparaffin and olefin with the catalyst complex of the invention.
摘要翻译：本发明提供一种用于促进异链烷烃与烯烃的烷基化的催化剂配合物，所述催化剂配合物包含路易斯酸与至少一种氟代磷酸的反应产物; 另外，过量的路易斯酸的浓度为总异链烷烃和烯烃进料的约10ppm（重量）至约10000ppm。本发明还提供了通过使异链烷烃和烯烃的混合物与本发明的催化剂络合物接触来使烯烃与烯烃烷基化的方法。

6. 发明授权

US5534657A Isoparaffin-olefin alkylation 失效
标题翻译：异链烷烃烯烃烷基化
公开(公告)号：US5534657A
公开(公告)日：1996-07-09
申请号：US376176
申请日：1995-01-20
申请人： Bruce B. Randolph , Ronald G. Abbott , Jonathan E. Child , Kenneth J. Del Rossi
发明人： Bruce B. Randolph , Ronald G. Abbott , Jonathan E. Child , Kenneth J. Del Rossi
IPC分类号： B01D5/00 , B01J27/12 , B01J31/02 , C01B7/19 , C07C2/62
CPC分类号： B01J31/0222 , B01D5/00 , C01B7/191 , C07C2/62 , B01J2231/323 , B01J27/12 , C07C2527/1206
摘要： A novel alkylation catalyst is described which is used in processes for alkylating olefin hydrocarbons with isoparaffin hydrocarbons to produce high octane alkylate products suitable for use as blending components of gasoline motor fuel. The novel catalyst comprises a mixture of a hydrogen halide, a sulfone and water and has suitable corrosion properties which permit its utilization in alkylation process systems. The novel alkylation catalyst is utilized in a novel process for alkylating olefin hydrocarbons with isoparaffin hydrocarbons.
摘要翻译：描述了一种新的烷基化催化剂，其用于使用异链烷烃烷基化烯烃的方法，以产生适合用作汽油发动机燃料混合组分的高辛烷基烷基化物产物。新型催化剂包括卤化氢，砜和水的混合物，并且具有合适的腐蚀性质，其允许其在烷基化方法体系中的应用。新型烷基化催化剂用于使用异链烷烃对烯烃进行烷基化的新方法。

7. 发明授权

US5196628A Liquid acid alkylation catalyst and isoparaffin:olefin alkylation process 失效
标题翻译：液体酸烷基化催化剂和异链烷烃：烯烃烷基化方法
公开(公告)号：US5196628A
公开(公告)日：1993-03-23
申请号：US719277
申请日：1991-06-21
申请人： Kenneth J. Del Rossi , Albin Huss, Jr.
发明人： Kenneth J. Del Rossi , Albin Huss, Jr.
IPC分类号： C07C2/62
CPC分类号： C07C2/62 , C07C2527/1206 , C07C2531/02 , C07C2531/025
摘要： The invention provides an isoparaffin:olefin alkylation catalyst composition and a process employing the same, wherein the catalyst composition comprises from about 10 to about 90 percent of at least one acid selected from the group consisting of hydrofluoric acid and the halogen-substituted sulfonic acids, together with from about 10 to about 90 weight percent of an additive having the formula R--(NO.sub.2).sub.n, wherein R is an alkyl, aromatic, alkyl halide or halide-substituted aromatic group having from about 1 to about 30 carbon atoms.
摘要翻译：本发明提供了一种异链烷烃：烯烃烷基化催化剂组合物及其应用方法，其中催化剂组合物包含约10-约90％的至少一种选自氢氟酸和卤素取代的磺酸的酸，以及约10至约90重量％的具有式R-（NO 2）n的添加剂，其中R是具有约1至约30个碳原子的烷基，芳族，烷基卤或卤素取代的芳族基团。

8. 发明授权

US5191148A Isoparaffin/olefin alkylation 失效
标题翻译：异链烷烃/烯烃烷基化
公开(公告)号：US5191148A
公开(公告)日：1993-03-02
申请号：US696484
申请日：1991-05-06
申请人： Thomas F. Degnan , Kenneth J. Del Rossi , Albin Huss, Jr.
发明人： Thomas F. Degnan , Kenneth J. Del Rossi , Albin Huss, Jr.
IPC分类号： C07C2/60
CPC分类号： C07C2/60 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2527/1213 , C07C2527/126 , C07C2527/133
摘要： The present invention provides a process for alkylating an isoparaffin with an olefin comprising contacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in an alkylation reaction zone at temperature from about -20.degree. C. to about 150.degree. C. with an alkylation catalyst complex comprising a Lewis acid and an inorganic, porous crystalline phase material having, after calcination, a d-spacing greater than about 18 Angstrom Units and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 50 torr and 25.degree. C., wherein the molar ratio of said isoparaffin to said olefin is from about 1 to about 250 to evolve a product stream containing C.sub.5 +alkylate. In a preferred embodiment, the alkylation catalyst complex comprises a Lewis acid and an inorganic, porous crystalline phase material having, after calcination, a hexagonal arrangement of uniformly-sized pores having diameters of at least about 13 Angstrom Units and exhibiting a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units.
摘要翻译：本发明提供了一种用烯烃烷基化异链烷烃的方法，包括在烷基化反应区中将约4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃在约-20℃至约具有包含路易斯酸和无机多孔结晶相材料的烷基化催化剂络合物，其在煅烧之后具有大于约18埃单位的d间距，并且苯的吸附能力大于15克苯/ 100 所述材料在50托和25℃下的克数，其中所述异链烷烃与所述烯烃的摩尔比为约1至约250以释放含有C5 +烷基化物的产物流。在优选的实施方案中，烷基化催化剂络合物包含路易斯酸和无机多孔结晶相材料，其在煅烧之后具有直径为至少约13埃单位的均匀尺寸的孔的六边形排列并且显示六方电子衍射图可以用大于约18埃单位的d100值进行索引。

9. 发明授权

US5108969A Low acidity catalyst for conversion of paraffins to olefins and/or aromatics 失效
标题翻译：用于将烷烃转化为烯烃和/或芳族化合物的低酸度催化剂
公开(公告)号：US5108969A
公开(公告)日：1992-04-28
申请号：US571470
申请日：1990-08-22
申请人： Kenneth J. Del Rossi , Ralph M. Dessau , Albin Huss, Jr. , Garry W. Kirker , David O. Marler , Randall D. Partridge
发明人： Kenneth J. Del Rossi , Ralph M. Dessau , Albin Huss, Jr. , Garry W. Kirker , David O. Marler , Randall D. Partridge
IPC分类号： B01J29/04 , C07C2/12 , C07C5/41
CPC分类号： C07C5/41 , B01J29/04 , C07C2/12 , C07C2529/04 , C07C2529/70
摘要： A low acidity Group VIII metal-containing zeolite MCM-22 catalyst, said zeolite exhibiting an Alpha value of not greater than about 150, is provided for conversion of aliphatic C.sub.2 to C.sub.12 hydrocarbon(s) to olefin(s) and/or aromatic(s).
摘要翻译：提供了低含量的含VIII族金属的沸石MCM-22催化剂，所述沸石表现出不大于约150的α值，用于将脂族C2转化为C12烃到烯烃和/或芳族（ s）。

10. 发明授权

US5382730A Combined paraffin isomerization/ring opening process 失效
标题翻译：联合石蜡异构化/开环过程
公开(公告)号：US5382730A
公开(公告)日：1995-01-17
申请号：US90357
申请日：1993-07-12
申请人： Lloyd L. Breckenridge , Kenneth J. Del Rossi , Albin Huss, Jr. , Clinton R. Kennedy , Garry W. Kirker
发明人： Lloyd L. Breckenridge , Kenneth J. Del Rossi , Albin Huss, Jr. , Clinton R. Kennedy , Garry W. Kirker
IPC分类号： B01J29/70 , C07B61/00 , C07C5/10 , C07C5/27 , C07C5/31 , C07C9/00 , C07C9/16 , C10G35/04 , C10G45/54 , C10G45/64 , C10G65/08 , C10G69/08
CPC分类号： C07C9/00 , C07C5/10 , C07C5/2702 , C07C5/31 , C07C2521/04 , C07C2523/42 , C07C2527/10 , C07C2529/08 , C07C2529/70 , Y10S585/94
摘要： There is provided a process for ring opening of aromatics and cycloaliphatics, as well as isomerization of aliphatics. The feedstream to this process comprises hydrocarbons having 6 carbon atoms. The process involves the use of at least two reactors connected in series. The first reactor comprises a zeolite catalyst and is operated under conditions which particularly promote ring opening. The catalyst in this first reactor may comprise zeolite Beta and platinum. A downstream reactor is operated under conditions to promote isomerization of aliphatics. The catalyst in the second reactor may comprise alumina, platinum and a chloride component. Hydrogen in the effluent of the first reactor may be removed and recycled to the first reactor. Hydrogen required for the second reactor may be satisfied by hydrogen remaining dissolved in the effluent from the first reactor after hydrogen is recycled to the first reactor.
摘要翻译：提供了芳烃和环烯烃开环方法以及脂肪族异构化方法。该方法的进料流包含具有6个碳原子的烃。该方法涉及使用串联连接的至少两个反应器。第一反应器包括沸石催化剂，并在特别促进开环的条件下操作。该第一反应器中的催化剂可以包括沸石β和铂。下游反应器在促进脂肪族异构化的条件下运行。第二反应器中的催化剂可以包括氧化铝，铂和氯化物组分。可以将第一反应器的流出物中的氢气除去并再循环至第一反应器。在再循环到第一反应器之后，第二反应器所需的氢可以通过剩余的溶解在来自第一反应器的流出物中的氢来满足。

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