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1. 发明授权

US08124791B2 Active energy ray curable liquid composition and liquid cartridge 有权
标题翻译：活性能量射线固化液体组合物和液体盒
公开(公告)号：US08124791B2
公开(公告)日：2012-02-28
申请号：US12530720
申请日：2008-03-25
申请人： Kenji Shinjo , Norio Ohkuma , Shoji Shiba , Hikaru Ueda , Hiroe Ishikura , Shinsuke Tsuji , Yoshikazu Saito , Kouji Harada , Yuichiro Kanasugi
发明人： Kenji Shinjo , Norio Ohkuma , Shoji Shiba , Hikaru Ueda , Hiroe Ishikura , Shinsuke Tsuji , Yoshikazu Saito , Kouji Harada , Yuichiro Kanasugi
IPC分类号： C07D403/14
CPC分类号： C09D11/30 , C08F222/40 , C09D11/101
摘要： The invention provides an active energy ray curable liquid composition containing a compound represented by a general formula (I): wherein A is a hydrogen atom or a monovalent organic residue which may be substituted, R1 and R2 are, independently of each other, a divalent organic group which may be substituted, E is an amide bond, Rn is a cyclic linking group having a carbonyl group and an unsaturated carbon-carbon bond adjacent to the carbon atom of the carbonyl group, m is a number of 0 or greater, n is a number of 2 or greater, m+n is 3, and Z is a secondary or tertiary amino bond structure, with the proviso that the amino bond may be a salt of a secondary or tertiary amine, and a liquid cartridge.
摘要翻译：本发明提供含有通式（I）表示的化合物的活性能量射线固化性液体组合物：其中A为氢原子或可被取代的一价有机残基，R 1和R 2彼此独立地为二价可以被取代的有机基团，E是酰胺键，Rn是与羰基的碳原子相邻的具有羰基和不饱和碳 - 碳键的环状连接基，m为0以上数，n 是2或更大的数，m + n是3，Z是仲或叔氨基键结构，条件是氨基键可以是仲胺或叔胺的盐和液体盒。

2. 发明申请

US20100094024A1 ACTIVE ENERGY RAY CURABLE LIQUID COMPOSITION AND LIQUID CARTRIDGE 有权
标题翻译：活性能量可固化液体组合物和液体盒
公开(公告)号：US20100094024A1
公开(公告)日：2010-04-15
申请号：US12530720
申请日：2008-03-25
申请人： Kenji Shinjo , Norio Ohkuma , Shoji Shiba , Hikaru Ueda , Hiroe Ishikura , Shinsuke Tsuji , Yoshikazu Saito , Kouji Harada , Yuichiro Kanasugi
发明人： Kenji Shinjo , Norio Ohkuma , Shoji Shiba , Hikaru Ueda , Hiroe Ishikura , Shinsuke Tsuji , Yoshikazu Saito , Kouji Harada , Yuichiro Kanasugi
IPC分类号： C07D403/12 , C07D403/14
CPC分类号： C09D11/30 , C08F222/40 , C09D11/101
摘要： The invention provides an active energy ray curable liquid composition containing a compound represented by a general formula (I): wherein A is a hydrogen atom or a monovalent organic residue which may be substituted, R1 and R2 are, independently of each other, a divalent organic group which may be substituted, E is an amide bond, Rn is a cyclic linking group having a carbonyl group and an unsaturated carbon-carbon bond adjacent to the carbon atom of the carbonyl group, m is a number of 0 or greater, n is a number of 2 or greater, m+n is 3, and Z is a secondary or tertiary amino bond structure, with the proviso that the amino bond may be a salt of a secondary or tertiary amine, and a liquid cartridge.
摘要翻译：本发明提供含有通式（I）表示的化合物的活性能量射线固化性液体组合物：其中A为氢原子或可被取代的一价有机残基，R 1和R 2彼此独立地为二价可以被取代的有机基团，E是酰胺键，Rn是与羰基的碳原子相邻的具有羰基和不饱和碳 - 碳键的环状连接基，m为0以上数，n 是2或更大的数，m + n是3，Z是仲或叔氨基键结构，条件是氨基键可以是仲胺或叔胺的盐和液体盒。

3. 发明申请

US20080252689A1 LIQUID DISCHARGE HEAD AND METHOD FOR MANUFACTURING THE SAME 有权
标题翻译：液体放电头及其制造方法
公开(公告)号：US20080252689A1
公开(公告)日：2008-10-16
申请号：US11941431
申请日：2007-11-16
申请人： Shoji Shiba , Akihiko Okano , Yoshikazu Saito , Kazuhiro Asai , Tamaki Sato , Takumi Suzuki , Masahiko Kubota , Maki Kato , Hiroe Ishikura , Shinsuke Tsuji
发明人： Shoji Shiba , Akihiko Okano , Yoshikazu Saito , Kazuhiro Asai , Tamaki Sato , Takumi Suzuki , Masahiko Kubota , Maki Kato , Hiroe Ishikura , Shinsuke Tsuji
IPC分类号： B41J2/135 , G03F7/20
CPC分类号： B41J2/162 , B41J2/1629 , B41J2/1631 , B41J2/1645 , B41J2002/14475 , B41J2202/11 , G03F1/00 , G03F1/50 , G03F1/70
摘要： A method for manufacturing a liquid discharge head including an energy generating element, which generates energy utilized for discharging a liquid, and a discharge portion provided at a position facing the energy generating element and having a discharge port for discharging the liquid is provided. This method includes the steps of forming a negative photosensitive resin layer used for a member that forms the discharge port on the substrate, and exposing the layer to an i-line to form the discharge portion that is tapered in a direction from the substrate to the discharge port, wherein the layer has an absorbance per 1 μm thickness of about 0.02 to about 0.07 for light used for the exposure.
摘要翻译：本发明提供一种液体排出头的制造方法，该液体排出头包括产生用于排出液体的能量的能量产生元件，以及设置在面向能量产生元件的位置并具有用于排出液体的排出口的排出部分。该方法包括以下步骤：形成用于在基板上形成排出口的部件的负型感光性树脂层，并且将该层暴露于i线以形成沿着从基板到排出口，其中该层对于曝光用的光，每1μm厚度的吸光度为约0.02至约0.07。

4. 发明授权

US07971964B2 Liquid discharge head and method for manufacturing the same 有权
标题翻译：液体排出头及其制造方法
公开(公告)号：US07971964B2
公开(公告)日：2011-07-05
申请号：US11941431
申请日：2007-11-16
申请人： Shoji Shiba , Akihiko Okano , Yoshikazu Saito , Kazuhiro Asai , Tamaki Sato , Takumi Suzuki , Masahiko Kubota , Maki Kato , Hiroe Ishikura , Shinsuke Tsuji
发明人： Shoji Shiba , Akihiko Okano , Yoshikazu Saito , Kazuhiro Asai , Tamaki Sato , Takumi Suzuki , Masahiko Kubota , Maki Kato , Hiroe Ishikura , Shinsuke Tsuji
IPC分类号： B41J2/14
CPC分类号： B41J2/162 , B41J2/1629 , B41J2/1631 , B41J2/1645 , B41J2002/14475 , B41J2202/11 , G03F1/00 , G03F1/50 , G03F1/70
摘要： A method for manufacturing a liquid discharge head including an energy generating element, which generates energy utilized for discharging a liquid, and a discharge portion provided at a position facing the energy generating element and having a discharge port for discharging the liquid is provided. This method includes the steps of forming a negative photosensitive resin layer used for a member that forms the discharge port on the substrate, and exposing the layer to an i-line to form the discharge portion that is tapered in a direction from the substrate to the discharge port, wherein the layer has an absorbance per 1 μm thickness of about 0.02 to about 0.07 for light used for the exposure.
摘要翻译：本发明提供一种液体排出头的制造方法，该液体排出头包括产生用于排出液体的能量的能量产生元件，以及设置在面向能量产生元件的位置并具有用于排出液体的排出口的排出部分。该方法包括以下步骤：形成用于在基板上形成排出口的部件的负型感光性树脂层，并且将该层暴露于i线以形成沿着从基板到排出口，其中该层对于曝光用的光具有每1μm厚度的约0.02至约0.07的吸光度。

5. 发明申请

US20080292993A1 PHOTO-CATIONIC POLYMERIZABLE EPOXY RESIN COMPOSITION, LIQUID DISCHARGE HEAD, AND MANUFACTURING METHOD THEREOF 审中-公开
标题翻译：光聚合环氧树脂组合物，液体排出头及其制造方法
公开(公告)号：US20080292993A1
公开(公告)日：2008-11-27
申请号：US11954689
申请日：2007-12-12
申请人： Hiroe Ishikura , Shoji Shiba , Shinsuke Tsuji , Akihiko Okano
发明人： Hiroe Ishikura , Shoji Shiba , Shinsuke Tsuji , Akihiko Okano
IPC分类号： G03F7/20 , C08K5/34 , C08K5/45 , C08K5/28 , B41J2/105
CPC分类号： B41J2/1603 , B41J2/1623 , B41J2/1629 , B41J2/1631 , B41J2/1639 , B41J2/1645 , C08L63/00 , C08L77/06 , G03F7/008 , G03F7/038
摘要： A liquid discharge head having a substrate provided with energy generating elements for generating energy to discharge a liquid, discharge portions including discharge ports for discharging the liquid, and flow paths supplying the liquid to the discharge portions and a method for its manufacture are provided. The method includes the steps of forming a layer of a negative type photosensitive resin on the substrate, and exposing the layer to light having a wavelength of 365 nm to form the discharge portions.
摘要翻译：一种液体排出头，其具有设置有用于产生排出液体的能量产生元件的基板，包括用于排出液体的排出口的排出部以及将液体供给到排出部的流路以及其制造方法。该方法包括以下步骤：在衬底上形成负型感光树脂层，并将该层暴露于波长为365nm的光以形成放电部分。

6. 发明授权

US07670757B2 Photosensitive resin composition, method of forming level difference pattern using the photosensitive resin composition, and method of producing ink jet head 失效
标题翻译：光敏树脂组合物，使用感光性树脂组合物形成水平差异图案的方法，以及制造喷墨头的方法
公开(公告)号：US07670757B2
公开(公告)日：2010-03-02
申请号：US10577218
申请日：2005-06-24
申请人： Shoji Shiba , Hiroe Ishikura , Akihiko Okano
发明人： Shoji Shiba , Hiroe Ishikura , Akihiko Okano
IPC分类号： G03F7/40 , B41J1/135
CPC分类号： B41J2/1631 , B41J2/1603 , B41J2/1639 , G03F7/0392 , G03F7/2024
摘要： To provide a positive type photosensitive resin composition, containing at least an acrylic resin having a carboxylic anhydride structure in a molecule, and a compound that generates an acid when irradiated with light.
摘要翻译：提供一种含有分子中至少含有羧酸酐结构的丙烯酸树脂的正型感光性树脂组合物和在照射时产生酸的化合物。

7. 发明授权

US07611827B2 Photosensitive resin composition, ink jet head using photosensitive resin composition, and process for manufacturing ink jet head 失效
标题翻译：感光性树脂组合物，使用感光性树脂组合物的喷墨头，以及喷墨头的制造方法
公开(公告)号：US07611827B2
公开(公告)日：2009-11-03
申请号：US10577255
申请日：2005-06-24
申请人： Hiroe Ishikura , Shoji Shiba , Akihiko Okano
发明人： Hiroe Ishikura , Shoji Shiba , Akihiko Okano
IPC分类号： G03F7/26
CPC分类号： G03F7/0392 , B41J2/1603 , B41J2/1631 , B41J2/1639
摘要： A positive type photosensitive resin composition comprises a polyacrylate resin having, in the structure, at least a structural unit represented by the following general formula (1): wherein X represents a hydroxyl group, an alkylol group having 2 to 4 carbon atoms, or a methylolamino group; R1 and R2 independently represents a hydrogen atom, or an alkyl group having 1 to 3 carbon atoms; R3 represents an alkyl group having 1 to 3 carbon atoms, an alkoxyl group having 1 to 3 carbon atoms, or an aralkyl group having an aryl group or alkyl group with 1 to 2 carbon atoms; n represents a positive integer; and m represents 0 or a positive integer, and a condensable crosslinker.
摘要翻译：正型感光性树脂组合物包含在结构中至少具有以下通式（1）表示的结构单元的聚丙烯酸酯树脂：其中X表示羟基，具有2〜4个碳原子的羟烷基，或羟甲基氨基; R1和R2独立地表示氢原子或碳原子数1〜3的烷基。 R3表示碳原子数1〜3的烷基，碳原子数1〜3的烷氧基或具有1〜2个碳原子的芳基或烷基的芳烷基。 n表示正整数; m表示0或正整数，可缩合交联剂。

8. 发明申请

US20060117564A1 Photosensitive resin composition, ink jet recording head using such composition and method for manufacturing such recording head 失效
标题翻译：感光树脂组合物，使用这种组合物的喷墨记录头和用于制造这种记录头的方法
公开(公告)号：US20060117564A1
公开(公告)日：2006-06-08
申请号：US11291956
申请日：2005-12-02
申请人： Hiroe Ishikura , Shoji Shiba , Akihiko Okano
发明人： Hiroe Ishikura , Shoji Shiba , Akihiko Okano
IPC分类号： B21D53/76 , B41J2/01
CPC分类号： B41J2/1603 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1634 , B41J2/1639 , B41J2/1645 , Y10T29/49401
摘要： The present invention provides a method for manufacturing a high quality ink jet head, and an ink jet head manufactured by such a method, in which, in a case where a coating resin layer constituting ink flow path walls is formed, even when a solvent having a strong dissolving force is used, it is not feared that a configuration of an ink flow path pattern is distorted. In the method, a photosensitive resin composition layer in which an inter-molecule bridging reaction proceeds by irradiation of an ionization radiant ray having a first wavelength band and a molecule decaying reaction of main chain decomposing type of the resin proceeds by irradiation of an ionization radiant ray having a second wavelength band different from the first wavelength band is formed on a substrate on which energy generating elements were provided. Thereafter, an ink flow path pattern is formed by the irradiation of the ionization radiant ray having the first wavelength band and a developing process. Then, a coating resin layer constituting ink flow path walls is formed on the ink flow path pattern. After ink discharge ports are formed, the photosensitive resin composition layer forming the ink flow path pattern is dissolved and removed by irradiating the ionization radiant ray having the second wavelength band.
摘要翻译：本发明提供一种制造高品质喷墨头的方法和通过这样一种方法制造的喷墨头，其中在形成油墨流路壁的涂布树脂层的情况下，即使当具有使用强的溶解力，不怕油墨流路图案的构造变形。在该方法中，通过照射具有第一波长带的电离辐射线和主链分解型树脂的分子衰减反应进行分子间桥接反应的感光性树脂组合物层通过照射电离辐射在具有能量产生元件的基板上形成具有与第一波长带不同的第二波长带的光线。此后，通过照射具有第一波长带和显影处理的电离辐射线形成墨流路图案。然后，在油墨流路图案上形成构成油墨流路壁的涂布树脂层。在形成喷墨口之后，通过照射具有第二波长带的电离辐射线来溶解形成油墨流路图形的感光性树脂组合物层。

9. 发明授权

US08017307B2 Method for manufacturing minute structure, method for manufacturing liquid discharge head, and liquid discharge head 有权
标题翻译：微细结构的制造方法，液体排出头的制造方法和排液头
公开(公告)号：US08017307B2
公开(公告)日：2011-09-13
申请号：US10568341
申请日：2005-06-27
申请人： Masahiko Kubota , Takumi Suzuki , Tamaki Sato , Ryoji Kanri , Maki Hatta , Kazuhiro Asai , Shoji Shiba , Hiroe Ishikura , Akihiko Okano
发明人： Masahiko Kubota , Takumi Suzuki , Tamaki Sato , Ryoji Kanri , Maki Hatta , Kazuhiro Asai , Shoji Shiba , Hiroe Ishikura , Akihiko Okano
IPC分类号： G03F7/20
CPC分类号： B41J2/1603 , B41J2/1404 , B41J2/1628 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1634 , B41J2/1639 , B41J2/1645 , B41J2202/11 , G03F7/095 , Y10T29/49401
摘要： A method for manufacturing a minute structure comprises a step of forming an ionizing radiation decomposing type positive type resist layer including a methyl isopropenyl ketone as a first positive type photosensitive material layer, a step of forming an ionizing radiation decomposing type positive type resist layer including a photosensitive material of a copolymer as a second positive type photosensitive material layer to be sensitized by an ionizing radiation of a second wavelength range on the first positive type photosensitive material layer, a step of forming a desired pattern in the above-mentioned second positive type photosensitive material layer, and development using a developing solution, and then, a step of forming a desired pattern in the above-mentioned first positive type photosensitive material layer to form a convex shape pattern.
摘要翻译：微细结构体的制造方法包括形成电离辐射分解型正型抗蚀剂层的步骤，该电离辐射分解型正型抗蚀剂层包括甲基异丙烯基酮作为第一正型感光材料层，形成电离辐射分解型正型抗蚀剂层的步骤包括作为通过第一正型感光材料层上的第二波长范围的电离辐射致敏的作为第二正型感光材料层的共聚物的感光材料，在上述第二正型感光材料层中形成所需图案的步骤材料层和使用显影溶液的显影，然后，在上述第一正型感光材料层中形成所需图案以形成凸形图案的步骤。

10. 发明申请

US20070132811A1 Ink jet head manufacturing method and ink jet head manufactured by the manufacturing method 有权
标题翻译：喷墨头制造方法和通过制造方法制造的喷墨头
公开(公告)号：US20070132811A1
公开(公告)日：2007-06-14
申请号：US10576247
申请日：2005-06-27
申请人： Akihiko Okano , Shoji Shiba , Hiroe Ishikura
发明人： Akihiko Okano , Shoji Shiba , Hiroe Ishikura
IPC分类号： G03C5/00 , B41J2/04
CPC分类号： B41J2/1603 , B41J2/1631 , B41J2/1639 , B41J2/1645
摘要： A method of manufacturing an ink jet head which includes a discharge port for discharging an ink droplet, an ink flow path communicated with the discharge port, and an energy generating element for discharging the ink droplet from the discharge port, the method for manufacturing an ink jet head includes a process of forming a photodegradable positive type resist layer on a substrate having the energy generating element, a process of forming a structure which becomes the ink flow path by exposing and developing the photodegradable positive type resist layer, a process of coating the substrate having the structure which becomes the ink flow path with a negative type resist layer, a process of forming the ink discharge port in the negative type resist layer, and a process of forming the ink flow path communicated with the discharge port by removing the structure which becomes the ink flow path, wherein the photodegradable positive type resist layer includes an acrylic copolymer composition, the acrylic copolymer composition containing at least a unit obtained from (meta)acrylic ester as a main content, the acrylic copolymer composition further containing a unit obtained from (meta)acrylic acid, the acrylic copolymer composition contains the (meta)acrylic acid unit at a proportion of 5 to 30 weight %, and weight average molecular weight of the acrylic copolymer ranges from 50000 to 300000.
摘要翻译：一种制造喷墨头的方法，该喷墨头包括用于排出墨滴的排出口，与排出口连通的油墨流路，以及用于从排出口排出墨滴的能量产生元件，用于制造墨水的方法喷墨头包括在具有能量产生元件的基板上形成可光降解的正型抗蚀剂层的工艺，通过曝光和显影可光降解的正型抗蚀剂层形成成为油墨流动路径的结构的工艺，具有成为具有负型抗蚀剂层的油墨流路的结构的基板，在负型抗蚀剂层中形成油墨排出口的工序，以及通过除去结构形成与排出口连通的油墨流路的工序其变为油墨流动路径，其中可光降解的正型抗蚀剂层包括丙烯酸共聚物组合物 n，至少含有由（甲基）丙烯酸酯作为主要成分的单元的丙烯酸共聚物组合物，所述丙烯酸共聚物组合物还含有由（甲基）丙烯酸得到的单元，所述丙烯酸共聚物组合物含有（甲基）丙烯酸单元的比例为5〜30重量％，丙烯酸系共聚物的重均分子量为50000〜300000。

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