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    • 1. 发明授权
    • Light control element, optical device, and electrical device, and method of producing thereof
    • 光控元件,光学元件及电气元件及其制造方法
    • US06486932B1
    • 2002-11-26
    • US09693912
    • 2000-10-23
    • Kenji NakaoSeiji NishiyamaHirofumi KubotaTsuyoshi UemuraMasao Yamamoto
    • Kenji NakaoSeiji NishiyamaHirofumi KubotaTsuyoshi UemuraMasao Yamamoto
    • G02F11333
    • G02F1/1341G02F1/133377G02F1/1334G02F2001/133368
    • A liquid crystal display device of the invention comprises a transparent substrate 2, a transparent electrode 6 formed on the inner surface of the transparent substrate 2, an alignment layer 7 formed over the transparent electrode 6, a composite 5 formed over the alignment layer 7, and a transparent electrode 8 on the upper surface of the composite 5. The composite 5 comprises a transparent polymer 4 and a liquid crystal droplet 3. The liquid crystal droplet 3 is configured in a substantially hemispherical shape such that a bottom surface of the droplet is in contact with the alignment layer and the remaining surface excluding the bottom surface bulges towards an upper surface of the composite 5. The polymer 4 constitutes the other surface of the composite 5 such that the polymer 4 covers the hemispherical liquid crystal droplets 3. Thus, the invention achieves a liquid crystal display device in which one of the pair of substrates is eliminated and thereby the weight of the device is significantly reduced.
    • 本发明的液晶显示装置包括透明基板2,形成在透明基板2的内表面上的透明电极6,在透明电极6上形成的取向层7,在取向层7上形成的复合体5, 以及在复合材料5的上表面上的透明电极8.复合材料5包括透明聚合物4和液晶微滴3.液晶微滴3构成为大致半球状,使得液滴的底面为 与对准层接触并且除了底表面之外的剩余表面朝向复合材料5的上表面凸出。聚合物4构成复合材料5的另一表面,使得聚合物4覆盖半球形液晶微滴3.因此, 本发明实现了一种液晶显示装置,其中一对基板中的一个被去除,从而装置的重量为s 明显减少
    • 3. 发明授权
    • Polymer dispersion type liquid crystal display element, producing method therefor and apparatus for use in the producing method
    • 聚合物分散型液晶显示元件,其制造方法和制造方法中使用的装置
    • US06452650B1
    • 2002-09-17
    • US08934901
    • 1997-09-22
    • Kenji NakaoShinya KosakoTsuyoshi UemuraHirofumi KubotaMasao YamamotoKazuo InoueSeiji Nishiyama
    • Kenji NakaoShinya KosakoTsuyoshi UemuraHirofumi KubotaMasao YamamotoKazuo InoueSeiji Nishiyama
    • G02F11334
    • G02F1/1334G02F1/1341
    • A polymer dispersion type liquid crystal display element according to the invention is structured such that a complex of polymer and liquid crystal droplets is held between a pair of substrates. The liquid crystal droplets are deformed into a compressed structure of their being contracted in a cell gap direction and an amount of deformation of the liquid crystal droplets is set to be in range in which a phenomenon of liquid crystal molecules rising up in the cell gap direction is not caused by excluded volume effects of the liquid crystals. This construction that the amount of deformation of the liquid crystal droplets is set to be in range in which the phenomenon of liquid crystal molecules rising up in the cell gap direction is not caused by excluded volume effects of the liquid crystals can provide an increased tendency of the liquid crystal molecules to align in parallel to a phase boundary of the substrates. As a result of this, the polymer dispersion type liquid crystal display element having excellent threshold characteristics and scattering characteristics and high display characteristics can be achieved.
    • 根据本发明的聚合物分散型液晶显示元件被构造成使得聚合物和液晶微滴的复合物保持在一对基板之间。 液晶小滴变形为压缩结构,它们在单元间隙方向上收缩,并且液晶微滴的变形量设定在液晶分子在单元间隙方向上升的现象 不是由液晶的排除体积效应引起的。 将液晶微滴的变形量设定为在液晶间隙方向上升的液晶分子的现象不是由液晶的排除体积效应引起的范围的结构,可以提高 液晶分子与衬底的相边界平行排列。 结果,可以实现具有优异的阈值特性和散射特性以及高显示特性的聚合物分散型液晶显示元件。
    • 4. 发明授权
    • Light control element, optical device, and electrical device having lightweight, and method of producing thereof
    • 轻量化的光控元件,光学元件和电器件及其制造方法
    • US06400430B2
    • 2002-06-04
    • US09439090
    • 1999-11-12
    • Kenji NakaoSeiji NishiyamaHirofumi KubotaTsuyoshi UemuraMasao Yamamoto
    • Kenji NakaoSeiji NishiyamaHirofumi KubotaTsuyoshi UemuraMasao Yamamoto
    • G02F11333
    • G02F1/1341G02F1/133377G02F1/1334G02F2001/133368
    • A liquid crystal display device of the invention comprises a transparent substrate 2 a transparent electrode 6 formed on the inner surface of the transparent substrate 2, an alignment layer 7 formed over the transparent electrode 6, a composite 5 formed over the alignment layer 7, and a transparent electrode 8 on the upper surface of the composite 5. The composite 5 comprises a transparent polymer 4 and a liquid crystal droplet 3. The liquid crystal droplet 3 is configured in a substantially hemispherical shape such that a bottom surface of the droplet is in contact with the alignment layer and the remaining surface excluding the bottom surface bulges towards an upper surface of the composite 5. The polymer 4 constitutes the other surface of the composite 5 such that the polymer 4 covers the hemispherical liquid crystal droplets 3. Thus, the invention achieves a liquid crystal display device in which one of the pair of substrates is eliminated and thereby the weight of the device is significantly reduced.
    • 本发明的液晶显示装置包括透明基板2,形成在透明基板2的内表面上的透明电极6,形成在透明电极6上的取向层7,在取向层7上形成的复合材料5,以及 在复合材料5的上表面上的透明电极8.复合材料5包括透明聚合物4和液晶微滴3.液晶微滴3被构造成大致半球形,使得液滴的底面处于 与配向层接触并且除了底表面之外的剩余表面朝向复合材料5的上表面凸出。聚合物4构成复合材料5的另一表面,使得聚合物4覆盖半球状液晶微滴3.因此, 本发明实现了一种液晶显示装置,其中一对基板中的一个被去除,从而装置的重量为si 大大减少。
    • 5. 发明授权
    • Polymer dispersion type liquid crystal display panel and its manufacturing method
    • 聚合物分散型液晶显示面板及其制造方法
    • US06429914B1
    • 2002-08-06
    • US09355011
    • 1999-07-22
    • Hirofumi KubotaTsuyoshi UemuraKenji NakaoSeiji Nishiyama
    • Hirofumi KubotaTsuyoshi UemuraKenji NakaoSeiji Nishiyama
    • G02F11333
    • G02F1/134363G02F1/1334G02F1/133553G02F2001/13756
    • The polymer dispersion type liquid crystal display panel comprises a pair of substrates 10, 11, a polymer dispersion type liquid crystal layer 12 comprising a liquid crystal 18 and a liquid crystalline polymer 17, a driving electrode 7 and an opposite electrode 8. The driving electrode 7 and the opposite electrode 8 are formed on the lower substrate 11, and an electric field is applied approximately in parallel with the above-mentioned lower substrate 11. Under no application of voltage, the above-mentioned liquid crystal 18 and the polymer 17 adjacent to the liquid crystal, which composes an interface, are aligned in approximately the same direction on a plane parallel with the substrates according to an alignment treatment of the substrates, and thereby a transparent state is obtained. Under an application of voltage, the liquid crystal 18 rotates on a plane parallel with the substrates, and the polymer 17 and the liquid crystal 18 are made a disposition state of forming angles on a plane parallel with the substrates, and thereby a scattering state is obtained.
    • 聚合物分散型液晶显示面板包括一对基板10,11,包括液晶18和液晶聚合物17的聚合物分散型液晶层12,驱动电极7和相对电极8.驱动电极 7和相对电极8形成在下基板11上,并且与上述下基板11大致平行地施加电场。在不施加电压的情况下,上述液晶18和相邻的聚合物17 构成界面的液晶根据基板的取向处理在与基板平行的平面上大致相同的方向排列,从而获得透明状态。 在电压施加下,液晶18在与基板平行的平面上旋转,聚合物17和液晶18成为在与基板平行的平面上形成角度的配置状态,从而散射状态为 获得。
    • 6. 发明授权
    • Polymer dispersion type liquid crystal display panel and manufacturing method thereof
    • 聚合物分散型液晶显示面板及其制造方法
    • US06630969B2
    • 2003-10-07
    • US10072586
    • 2002-02-11
    • Hirofumi KubotaTsuyoshi UemuraKenji NakaoSeiji Nishiyama
    • Hirofumi KubotaTsuyoshi UemuraKenji NakaoSeiji Nishiyama
    • G02F11333
    • G02F1/134363G02F1/1334G02F1/133553G02F2001/13756
    • The purpose is to provide a polymer dispersion type liquid crystal display panel wherein both a high contrast and a low driving voltage are obtained and scattering performance is superior. The polymer dispersion type liquid crystal display panel comprises a pair of substrates 10, 11, a polymer dispersion type liquid crystal layer 12 comprising a liquid crystal 18 and a liquid crystalline polymer 17, a driving electrode 7 and an opposite electrode 8. The driving electrode 7 and the opposite electrode 8 are formed on the lower substrate 11, and an electric field is applied approximately in parallel with the above-mentioned lower substrate 11. Under no application of voltage, the above-mentioned liquid crystal 18 and the polymer 17 adjacent to the liquid crystal, which composes an interface, are aligned in approximately the same direction on a plane parallel with the substrates according to an alignment treatment of the substrates, and thereby a transparent state is obtained. Under an application of voltage, the liquid crystal 18 rotates on a plane parallel with the substrates, and the polymer 17 and the liquid crystal 18 are made a disposition state of forming angles on a plane parallel with the substrates, and thereby a scattering state is obtained.
    • 其目的是提供一种聚合物分散型液晶显示面板,其中获得高对比度和低驱动电压,散射性能优异。聚合物分散型液晶显示面板包括一对基板10,11,聚合物 包括液晶18和液晶聚合物17的分散型液晶层12,驱动电极7和相对电极8.驱动电极7和相对电极8形成在下基板11上,电场为 与上述下基板11大致平行地施加。在不施加电压的情况下,上述液晶18和与构成界面的液晶相邻的聚合物17在大致相同的方向上排列在 根据基板的取向处理与基板平行的平面,从而获得透明状态。 在电压施加下,液晶18在与基板平行的平面上旋转,聚合物17和液晶18成为在与基板平行的平面上形成角度的配置状态,从而散射状态为 获得。
    • 7. 发明授权
    • Macromolecular dispersion type liquid crystal display element and method of manufacturing the same
    • 高分子分散型液晶显示元件及其制造方法
    • US06368680B1
    • 2002-04-09
    • US09712249
    • 2000-11-15
    • Hirofumi KubotaShinya KosakoKenji NakaoNoriko NaitoTsuyoshi UemuraMasao Yamamoto
    • Hirofumi KubotaShinya KosakoKenji NakaoNoriko NaitoTsuyoshi UemuraMasao Yamamoto
    • C09K1938
    • C09K19/544C09K2019/546G02F1/1334Y10T428/10Y10T428/2984
    • A method of making a polymer dispersion type liquid crystal display element including a phase separation step. The method calls for placing a liquid crystal polymer precursor compatible solution having a liquid crystal and a polymer precursor between a pair of substrates, each having an inside electrode, and irradiating a substrate surface with ultraviolet. The radiation causes a phase separation of the liquid crystal and the polymer precursor as well as polymerization and curing of the precursor. The method forms a polymer dispersion type liquid crystal having liquid crystal droplets dispersed and held in a continuous matrix phase or a three-dimensional network matrix. During the phase separation step, the irradiation time is controlled from the beginning of irradiation to the completion of phase separation to influence any of the degree of polymerization of the precursor in the solution, the rate of phase separation, and the generating density of the separated liquid crystal nuclei so that the dispersed liquid crystal droplets have even particle sizes.
    • 一种制备包括相分离步骤的聚合物分散型液晶显示元件的方法。 该方法要求将具有液晶和聚合物前体的液晶聚合物前体相容溶液放置在一对基板之间,每个基板具有内部电极,并用紫外线照射基板表面。 辐射导致液晶和聚合物前体的相分离以及前体的聚合和固化。 该方法形成具有分散并保持在连续矩阵相位或三维网络矩阵中的液晶小滴的聚合物分散型液晶。 在相分离步骤中,照射时间从照射开始到相分离完成进行控制,以影响前体在溶液中的任何聚合度,相分离速率和分离出的发生密度 液晶核,使得分散的液晶微滴具有均匀的粒径。
    • 8. 发明授权
    • Macromolecular dispersion type liquid crystal display element and method of manufacturing the same
    • 高分子分散型液晶显示元件及其制造方法
    • US06221443B1
    • 2001-04-24
    • US09386857
    • 1999-08-31
    • Hirofumi KubotaShinya KosakoKenji NakaoNoriko NaitoTsuyoshi UemuraMasao Yamamoto
    • Hirofumi KubotaShinya KosakoKenji NakaoNoriko NaitoTsuyoshi UemuraMasao Yamamoto
    • C09K1938
    • G02F1/1334C09K19/544C09K2019/546Y10T428/10
    • In a liquid crystal display element in which liquid crystal droplets are dispersed and held in polymer composition sandwiched between a pair of substrates each having an electrode at the inside thereof, the liquid crystal droplets are formed to have substantially the same shape and size with minimized variations in particle size so that the liquid crystal droplets can be stably kept in the bipolar-form orientation pattern within a wide temperature range, to minimize hysteresis of transmittance of light to a voltage applied across the electrodes. Similar effects can be produced by tilt angles of liquid crystal molecules in the vicinity of interface between the liquid crystal droplets and the polymer compound being minimized or by anchoring strength being increased, by adding an interfacial restrictive force controlling material to a liquid crystal polymer precursor compatible solution or raising a temperature under which polymerization of polymers and phase separation between the polymer and the liquid crystal are performed by irradiation of ultraviolet. Also, an improved response to electric field can be provided within a wide operation temperature range by allowing surface tension of liquid crystal material to be smaller than critical surface tension of an insulating film or surface tension of the polymer compound. Accordingly, the liquid crystal display element is available for forming displays, such as television sets and personal computers, capable of displaying moving pictures and the like within a wide operation temperature range.
    • 在将液晶微滴分散并保持在夹在其内部具有电极的一对基板的聚合物组合物中的液晶显示元件中,液晶微滴形成为具有基本相同的形状和尺寸,具有最小的变化 使得液晶小滴能够在宽温度范围内稳定地保持在双极型取向图案中,以使光的透射率滞后到施加在电极上的电压。 通过在液晶聚合物前体相容性中加入界面限制力控制材料,可以在液晶微滴与高分子化合物之间的界面附近的倾斜角度最小化或锚固强度提高时产生类似的效果 溶液或提高聚合物聚合和聚合物和液晶之间的相分离通过紫外线照射进行的温度。 此外,通过使液晶材料的表面张力小于绝缘膜的临界表面张力或高分子化合物的表面张力,能够在宽的工作温度范围内提供对电场的改善的响应。 因此,液晶显示元件可用于形成在宽的工作温度范围内能够显示运动图像等的显示器,例如电视机和个人计算机。
    • 9. 发明授权
    • Macromolecular dispersion type liquid crystal display element and method of manufacturing the same
    • 高分子分散型液晶显示元件及其制造方法
    • US06365239B1
    • 2002-04-02
    • US09712248
    • 2000-11-15
    • Hirofumi KubotaShinya KosakoKenji NakaoNoriko NaitoTsuyoshi UemuraMasao Yamamoto
    • Hirofumi KubotaShinya KosakoKenji NakaoNoriko NaitoTsuyoshi UemuraMasao Yamamoto
    • C09K1938
    • C09K19/544C09K2019/546G02F1/1334Y10T428/10Y10T428/2984
    • A polymer dispersion type liquid crystal display element having a polymer dispersion type liquid crystal sandwiched between a pair of substrates, each having an inside electrode, is disclosed. The liquid crystal has liquid crystal droplets dispersed and held in either a polymer compound-containing continuous phase matrix or a three dimensional network of such a matrix. In one embodiment, the capacitance hysteresis, defined as Chys=(C2−C1)/Cmax, does not exceed 1.5%. C1 is the capacitance for an applied voltage that is in the process of rising a voltage-capacitance characteristic; C2 is the capacitance of an applied voltage in the process of dropping; and C2 is the capacitance of a maximum applied voltage. In another embodiment, the Chys value does not exceed 0.6% when the optical hysteresis Thys is (P2−P1)/Pmax where P1 is the intensity of transmitted light of an applied rising voltage V, P2 is the intensity of transmitted light of an applied dropping voltage, and Pmax is the intensity of transmitted light of a maximum applied voltage.
    • 公开了一种聚合物分散型液晶显示元件,其具有夹在一对基板之间的聚合物分散型液晶,每个基板具有内部电极。 液晶具有分散并保持在含高分子化合物的连续相矩阵或这种基体的三维网络中的液晶小滴。 在一个实施例中,定义为Chys =(C2-C1)/ Cmax的电容滞后不超过1.5%。 C1是正在上升电压电容特性的施加电压的电容; C2是放电过程中施加电压的电容; C2是最大施加电压的电容。 在另一个实施例中,当光滞后Thys是(P2-P1)/ Pmax时,Chys值不超过0.6%,其中P1是施加的上升电压V的透射光的强度,P2是所施加的透射光的强度 降低电压,Pmax是最大施加电压的透射光强度。