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    • 3. 发明申请
    • LITHIUM COMPOSITE METAL OXIDE
    • 锂复合金属氧化物
    • US20090309062A1
    • 2009-12-17
    • US12307612
    • 2007-07-06
    • Yoshihiro KawakamiSho Kanesaka
    • Yoshihiro KawakamiSho Kanesaka
    • H01M4/88
    • H01M4/505C01D15/02C01G53/44C01P2002/74C01P2002/86C01P2006/12C01P2006/40H01M4/525H01M10/052
    • Provided is a lithium composite metal oxide containing Li, Ni and M (wherein, M is Mn and/or Co), characterized by exhibiting Signal B below in a spectrum at a rotational speed of 10 kHz among the solid-state nuclear magnetic resonance spectra of 7Li of a lithium composite metal oxide obtained by the nuclear magnetic resonance measuring method 1, A lithium composite metal oxide is rotated at each of rotational speeds of 10 kHz and 11 kHz by the magic angle-spinning method using a nuclear magnetic resonance apparatus with a magnetic field strength of 7.05 teslas, a solid-state nuclear magnetic resonance of 7Li of the lithium composite metal oxide is measured at each rotational speed, and a chemical shift of a central peak is evaluated from two resulting solid-state nuclear magnetic resonance spectra (wherein the chemical shift value is a value corrected by taking a position of a central peak of lithium chloride as 0 ppm using lithium chloride as an external standard substance); A signal having a central peak and its spinning side bands, wherein the central peak has a chemical shift in the range of +1100 to +1900 ppm and the largest peak has a chemical shift in the range of +2100 to +2600 ppm.
    • 提供了含有Li,Ni和M(其中,M是Mn和/或Co)的锂复合金属氧化物,其特征在于在固态核磁共振光谱中以10kHz的旋转速度在光谱中显示下面的信号B 通过核磁共振测定方法1得到的7Li的锂复合金属氧化物,<核磁共振测定法1>通过魔角旋转将锂复合金属氧化物以10kHz,11kHz的旋转速度旋转 使用磁场强度为7.05特斯拉的核磁共振装置的方法,在每个转速下测量锂复合金属氧化物的7Li的固态核磁共振,并从两个角度评估中心峰的化学位移 得到的固态核磁共振谱(其中化学位移值是使用氯化锂将氯化锂的中心峰位置为0ppm校正的值 ide作为外部标准物质); <信号B>具有中心峰及其旋转侧带的信号,其中中心峰在+ 1100〜+ 1900ppm的范围内具有化学位移,最大峰的化学位移在+ 2100〜+ 2600ppm。
    • 8. 发明授权
    • Lithium manganese composite oxide
    • 锂锰复合氧化物
    • US08501350B2
    • 2013-08-06
    • US11843927
    • 2007-08-23
    • Ryoji KannoMakoto YoshiokaYoshihiro Kawakami
    • Ryoji KannoMakoto YoshiokaYoshihiro Kawakami
    • H01M4/50H01M4/13
    • H01M4/505C01G45/1264C01P2002/54C01P2002/72C01P2006/40H01M4/131H01M4/485H01M10/052
    • To provide a lithium manganese composite oxide capable of improving the initial discharge capacity of secondary batteries by removing more Li ions than the conventional lithium manganese composite oxide does when used in the positive electrode used for secondary batteries. A lithium manganese composite oxide having a Li2MnO3 type crystal structure, wherein a part of Li and/or Mn in a lithium manganese oxide represented by a formula Li2MnO3 is substituted by one or more doping elements M selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Si, Ge, Sn, P, Sb and Bi. The above-described lithium manganese composite oxide, wherein the doping elements are P and/or Si. A positive electrode used for nonaqueous electrolyte secondary batteries, comprising the above-described lithium manganese composite oxide. A nonaqueous electrolyte secondary battery comprising the above-described positive electrode used for nonaqueous electrolyte secondary batteries.
    • 为了提供一种能够提高二次电池的初始放电容量的锂锰复合氧化物,其比当前用于二次电池的正极中常用的锂锰复合氧化物除去更多的Li离子。 具有Li 2 MnO 3型晶体结构的锂锰复合氧化物,其中由式Li 2 MnO 3表示的锂锰氧化物中的Li和/或Mn的一部分被一种或多种选自Ti,Zr, Hf,V,Nb,Ta,Si,Ge,Sn,P,Sb和Bi。 上述锂锰复合氧化物,其中掺杂元素是P和/或Si。 用于非水电解质二次电池的正极,其包含上述锂锰复合氧化物。 一种非水电解质二次电池,其包含上述用于非水电解质二次电池的正极。