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    • 3. 发明授权
    • Alkaline storage battery
    • 碱性蓄电池
    • US5389468A
    • 1995-02-14
    • US29525
    • 1993-03-11
    • Shozo FujiwaraYoichi IzumiYoshio MoriwakiIsao Matsumoto
    • Shozo FujiwaraYoichi IzumiYoshio MoriwakiIsao Matsumoto
    • C22C1/00B22F9/04C22C1/02H01M4/24H01M4/26H01M4/38H01M10/24H01M10/34H01M10/26H01M4/36
    • H01M4/383B22F9/04B22F2999/00Y10S420/90
    • A hydrogen storage alloy particles comprising base particles consisting of hydrogen storage alloy particles and fine particles consisting of at least one of metals, alloys, hydrophobic resins, catalyst materials, metal oxides having a particle size smaller than that of the base particles where the fine particles are very firmly bonded to the base particles are employed as negative electrodes for alkaline storage batteries. The bonding of the fine particles to the base particles is performed by a surface treatment so-called mechanofusion process (one of mechanochemical reaction process) where the base particles and the fine particles are subjected therebetween predominantly to a mechanical energy, practically those derived from the compression and attrition forces simultaneously to emboss the surfaces of the base particles and to allow the fine particles to be extended and bonded firmly under pressure onto the surfaces of the base particles, thereby coating at least a part of the surfaces of the base particles with the fine particles.
    • 一种储氢合金颗粒,其包含由储氢合金颗粒组成的基础颗粒和由金属,合金,疏水性树脂,催化剂材料,具有比基础颗粒小的颗粒的金属氧化物中的至少一种构成的细颗粒,其中细颗粒 非常牢固地结合到基础颗粒上用作碱性蓄电池的负极。 通过表面处理所谓的机械融合工艺(机械化学反应过程之一)进行表面处理,其中基体颗粒和细颗粒主要经受机械能,其实际上是从 压缩和磨损力同时压印基础颗粒的表面,并允许细颗粒在压力下被牢固地延伸和粘合到基础颗粒的表面上,从而将基体颗粒的至少一部分表面涂覆 细颗粒。
    • 6. 发明授权
    • Metal outer can for a battery and method of manufacturing same
    • 金属外罐用于电池及其制造方法
    • US06333124B1
    • 2001-12-25
    • US09254365
    • 1999-03-04
    • Yoshio MoriwakiAkira IwaseSusumu KitaokaIsao Matsumoto
    • Yoshio MoriwakiAkira IwaseSusumu KitaokaIsao Matsumoto
    • H01M202
    • H01M2/0272B21D22/28H01M2/0202H01M2/0217H01M2/0225H01M2/027H01M2/0275H01M2/0287Y10T29/49108
    • A battery has elements for electromotive-force accommodated in a metal outer can which has a bottom having a cylindrical, prismatic or similar shape. The ratio of the bottom thickness (TA) the side thickness (TB) is 1.5-7.0. The metal outer can contains primarily iron and a layer of nickel is provided on at least the inner face of the battery. Shallow grooves are formed on the nickel layer perpendicular to the bottom face. An iron-based metallic sheet formed with a nickel layer on at least one face is subjected to drawing forming into a tubular shape having a bottom, continuous ironing processing being performed such that the side of the can formed in the tubular shape has an ironing ratio in the range of 20% to 90% and a metal outer can is thereby manufactured having a ratio of a bottom thickness to its side thickness from 1.5 to 7.0, having a cylindrical shape, prismatic shape or shape similar thereto, and with shallow longitudinal grooves formed in a nickel layer provided on the battery inside face.
    • 电池具有容纳在金属外罐中的电动势的元件,其具有圆柱形,棱柱形或类似形状的底部。 底部厚度(TA)与侧面厚度(TB)之比为1.5-7.0。 金属外壳主要包含铁,并且至少在电池的内表面上设置一层镍。 在垂直于底面的镍层上形成浅槽。 在至少一个面上形成有镍层的铁基金属片被拉伸成形为具有底部连续熨烫加工的管状,使得形成为管状的罐的侧面具有熨烫比 在20%至90%的范围内,并且由此制造具有底部厚度与其侧面厚度的比率为1.5至7.0的金属外罐,其具有圆柱形形状,棱柱形状或类似形状,并且具有浅纵向凹槽 形成在设置在电池内侧的镍层中。
    • 8. 发明授权
    • Alkaline storage battery
    • 碱性蓄电池
    • US06338917B1
    • 2002-01-15
    • US09201843
    • 1998-12-01
    • Akihiro MaedaHirokazu KimiyaYoshio MoriwakiIsao Matsumoto
    • Akihiro MaedaHirokazu KimiyaYoshio MoriwakiIsao Matsumoto
    • H01M432
    • H01M10/345H01M4/52H01M10/26Y02E60/124
    • A nickel positive electrode including an active material mixture mainly composed of a nickel oxide and an electrically conductive support, a metal and/or an oxide thereof including elements effective for increasing oxygen overvoltage, preferably at least one element selected from Ca, Ti, Nb, Cr, Y and Yb is contained in a conducting agent such as metallic Co and/or Co oxide added to supplement the electrical conductivity of the active material. By virtue of this construction, the decrease of charging efficiency caused by increase of battery temperature and decrease of the oxygen overvoltage with charging of the battery can be inhibited and the charging efficiency can be improved in a wide temperature atmosphere. Thus, a nickel-metal hydride storage battery of high capacity can be provided.
    • 包括主要由氧化镍和导电载体组成的活性物质混合物的镍正极,包含有效提高氧过电压的元素的金属和/或氧化物,优选选自Ca,Ti,Nb, Cr,Y和Yb包含在添加的金属Co和/或Co氧化物等导电剂中以补充活性物质的导电性。 通过这种结构,可以抑制由于电池温度升高引起的充电效率的降低和电池充电时的氧过电压的降低,并且可以在宽温度的气氛中提高充电效率。 因此,可以提供高容量的镍氢蓄电池。
    • 9. 发明授权
    • Method of producing hydrogen-storing alloy and electrode making use of
the alloy
    • 使用该合金制备储氢合金和电极的方法
    • US5281390A
    • 1994-01-25
    • US870224
    • 1992-04-20
    • Takaharu GamoYoshio MoriwakiTsutomu IwakiAkemi Shintani
    • Takaharu GamoYoshio MoriwakiTsutomu IwakiAkemi Shintani
    • C01B3/00C22C1/02H01M4/38C22C16/00C22C30/00
    • C01B3/0031C22C1/02H01M4/383Y02E60/327Y10S420/90
    • In the method of the present invention for producing a hydrogen-storing alloy, part or whole of single substance of Zr as a starting material is replaced with a ferrozirconium or a zircalloy. This method enables production of a hydrogen-storing alloy at reduced material and production costs and with high efficiency and safety of work. The alloy produced by this method has high homogeneity with no segregation. It is thus possible to obtain a hydrogen-storing alloy superior in hydrogen-storing characteristics such as hydrogen storage capacity, reaction speed, and electrode reaction efficiency in an electrolyte. It is also possible to obtain, by using this alloy, a nickel-hydrogen storage battery having a large storage capacity and capable of performing quick charging and discharging, while exhibiting longer life and higher economy.
    • PCT No.PCT / JP89 / 01319 Sec。 371日期1990年8月2日第 102(e)1990年8月2日PCT PCT 1989年12月28日PCT公布。 公开号WO90 / 07585 日本1990年7月12日。在本发明的制备储氢合金的方法中,作为起始原料的Zr的单一物质的一部分或全部被铁氟化锆或锆合金代替。 该方法能够以减少的材料和生产成本以及高效率和安全的工作生产储氢合金。 通过该方法制造的合金具有高均匀性,没有偏析。 因此,可以获得在电解液中的储氢能力,反应速度,电极反应效率等储氢特性优异的储氢合金。 通过使用这种合金,也可以获得具有大存储容量并能够进行快速充放电的镍氢蓄电池,同时具有更长的寿命和更高的经济性。