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    • 10. 发明申请
    • METHOD OF MANUFACTURING POLYMER FILM
    • 制造聚合物膜的方法
    • US20110052821A1
    • 2011-03-03
    • US12868385
    • 2010-08-25
    • Kenichi ISHIZUKATaisei NISHIMI
    • Kenichi ISHIZUKATaisei NISHIMI
    • B05D3/02
    • B05D7/24B82Y10/00C08J5/18C08J2353/00C08J2387/00G11B5/82
    • A method of manufacturing a polymer film having a microphase-separated morphology includes a film-forming step in which a solution containing a block copolymer having two or more types of polymer chains which are mutually incompatible and are bonded to each other, a first solvent and a second solvent having a higher boiling point by at least 15° C. than the first solvent is applied onto a substrate and the first solvent is removed to form a film; a heating step in which the film is heated at a temperature which is higher than the boiling point of the first solvent but is lower than the boiling point of the second solvent to make the film formed have a microphase-separated morphology; and a solvent removal step in which the second solvent is removed from the film having the microphase-separated morphology to form the polymer film having the microphase-separated morphology.
    • 具有微相分离形态的聚合物膜的制造方法包括成膜步骤,其中含有具有两种或更多种彼此不相容并且彼此结合的聚合物链的嵌段共聚物的溶液,第一溶剂和 将具有比第一溶剂高沸点至少15℃的第二溶剂施加到基材上,并除去第一溶剂以形成膜; 加热步骤,其中所述膜在比所述第一溶剂的沸点高但低于所述第二溶剂的沸点的温度下加热以使所形成的膜具有微相分离的形态; 以及溶剂除去步骤,其中从具有微相分离形态的膜中除去第二溶剂以形成具有微相分离形态的聚合物膜。