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    • 2. 发明授权
    • Polymer material and method for producing same
    • 聚合物材料及其制造方法
    • US08796413B2
    • 2014-08-05
    • US13818553
    • 2011-08-04
    • Hironori TabataAkira NakasugaNorihiro Asai
    • Hironori TabataAkira NakasugaNorihiro Asai
    • C08G64/00B29C35/16B29C71/00B29C45/00B29C43/00C08F6/26B29C71/02C08G63/02B29C35/02B29C43/10B29C35/08
    • C08F6/26B29C35/0227B29C35/16B29C43/003B29C43/02B29C43/10B29C45/0001B29C71/0063B29C71/02B29C2035/0811B29C2043/5808B29C2071/027
    • Provided are a method for producing a polymer material having a high degree of crystallization, a small variability in degree of crystallization, and a three-dimensionally isotropic crystallinity to thus give high thermal resistance, high isotropy of resin physical properties, and a small variability in resin physical properties; and the polymer material. The method for producing a polymer material includes the steps of: heating a thermoplastic resin to or above a melting point determined from a melting peak measured by DSC into a thermoplastic resin melt; applying a pressure higher than atmospheric pressure to the thermoplastic resin melt; starting cooling the thermoplastic resin melt with a pressure higher than atmospheric pressure applied thereto; releasing the pressure on the thermoplastic resin melt after cooling the thermoplastic resin melt to a cooling-end-temperature lower than an upper limit of a crystallization temperature range, wherein during the cooling, the pressure on the thermoplastic resin melt is maintained at the pressure higher than atmospheric pressure or raised. The polymer material is one obtained by the above production method.
    • 本发明提供了具有高结晶度,结晶度变化小,三维各向同性结晶性的高分子材料的制造方法,从而得到高耐热性,树脂物性的各向异性高,变异性小 树脂物理性能; 和聚合物材料。 聚合物材料的制造方法包括以下步骤:将热塑性树脂加热到由DSC测定的熔融峰值确定的熔点以上的热塑性树脂熔融体; 将高于大气压的压力施加到热塑性树脂熔体; 以高于大气压的压力开始冷却热塑性树脂熔体; 在将热塑性树脂熔体冷却至低于结晶温度范围的上限的冷却终止温度之后,释放热塑性树脂熔体上的压力,其中在冷却期间,热塑性树脂熔体上的压力保持在更高的压力 比大气压或升高。 聚合物材料是通过上述制备方法得到的。
    • 3. 发明申请
    • POLYMER MATERIAL AND METHOD FOR PRODUCING SAME
    • 聚合物材料及其制造方法
    • US20130158224A1
    • 2013-06-20
    • US13818553
    • 2011-08-04
    • Hironori TabataAkira NakasugaNorihiro Asai
    • Hironori TabataAkira NakasugaNorihiro Asai
    • C08F6/26
    • C08F6/26B29C35/0227B29C35/16B29C43/003B29C43/02B29C43/10B29C45/0001B29C71/0063B29C71/02B29C2035/0811B29C2043/5808B29C2071/027
    • Provided are a method for producing a polymer material having a high degree of crystallization, a small variability in degree of crystallization, and a three-dimensionally isotropic crystallinity to thus give high thermal resistance, high isotropy of resin physical properties, and a small variability in resin physical properties; and the polymer material. The method for producing a polymer material includes the steps of: heating a thermoplastic resin to or above a melting point determined from a melting peak measured by DSC into a thermoplastic resin melt; applying a pressure higher than atmospheric pressure to the thermoplastic resin melt; starting cooling the thermoplastic resin melt with a pressure higher than atmospheric pressure applied thereto; releasing the pressure on the thermoplastic resin melt after cooling the thermoplastic resin melt to a cooling-end-temperature lower than an upper limit of a crystallization temperature range, wherein during the cooling, the pressure on the thermoplastic resin melt is maintained at the pressure higher than atmospheric pressure or raised. The polymer material is one obtained by the above production method.
    • 本发明提供了具有高结晶度,结晶度变化小,三维各向同性结晶性的高分子材料的制造方法,从而得到高耐热性,树脂物性的各向异性高,变异性小 树脂物理性能; 和聚合物材料。 聚合物材料的制造方法包括以下步骤:将热塑性树脂加热到由DSC测定的熔融峰值确定的熔点以上的热塑性树脂熔融体; 将高于大气压的压力施加到热塑性树脂熔体; 以高于大气压的压力开始冷却热塑性树脂熔体; 在将热塑性树脂熔体冷却至低于结晶温度范围的上限的冷却终止温度之后,释放热塑性树脂熔体上的压力,其中在冷却期间,热塑性树脂熔体上的压力保持在更高的压力 比大气压或升高。 聚合物材料是通过上述制备方法得到的。
    • 4. 发明申请
    • METHOD FOR PRODUCING POLYMER MOLDED ARTICLE, AND POLYMER MOLDED ARTICLE
    • 聚合物成型制品的制造方法和聚合物成型品
    • US20130190440A1
    • 2013-07-25
    • US13877905
    • 2011-12-14
    • Hironori TabataAkira Nakasuga
    • Hironori TabataAkira Nakasuga
    • C08K3/18B05D7/02
    • C08K3/18B05D7/02C08J7/02C08J2323/02C08J2323/10
    • Provided are a method for producing a polymer molded article, which is capable of increasing crystallinity, heat resistance, and isotropic elastic modulus while maintaining the original shape of a polymer molded body and a polymer molded article obtained by the method and having a high crystallinity, high heat resistance, and a high isotropic elastic modulus. The method for producing a polymer molded article includes the steps of: preparing a polymer material mainly containing a crystalline polymer; and impregnating the polymer material with a first gas having solubility in the crystalline polymer in an atmosphere in which the pressure of the first gas is equal to or higher than atmospheric pressure at a temperature higher than (Tm−30)° C. but lower than (Tm−15)° C., where Tm represents the melting point of the crystalline polymer, to obtain a polymer molded article. The polymer molded article is obtained by such a production method.
    • 提供一种聚合物成型体的制造方法,其能够在保持聚合物成型体的原始形状和通过该方法获得的具有高结晶度的聚合物成型体的同时提高结晶性,耐热性和各向同性弹性模量, 高耐热性,高均相弹性模量。 聚合物成型体的制造方法包括以下步骤:制备主要含有结晶聚合物的聚合物材料; 并且在高于(Tm-30)℃但低于(Tm-30)℃的温度下,在第一气体的压力等于或高于大气压的气氛中,用具有溶解度的第一气体在结晶聚合物中浸渍聚合物材料 (Tm-15)℃,其中Tm表示结晶聚合物的熔点,得到聚合物成型体。 通过这样的制造方法得到聚合物成型品。
    • 5. 发明申请
    • POLYMER ARTICLE AND METHOD FOR PRODUCING POLYMER ARTICLE
    • 聚合物制品及其制备方法
    • US20130041124A1
    • 2013-02-14
    • US13643544
    • 2011-05-24
    • Hironori TabataHiroyuki HiranoKazuho UchidaAkira Nakasuga
    • Hironori TabataHiroyuki HiranoKazuho UchidaAkira Nakasuga
    • B29C43/00C08F110/06
    • B29C43/003B29C43/02B29C43/52B29C47/0019B29C47/003B29C47/0033B29C47/004C08J5/121C08J2323/12
    • Provided are a polymer article excellent in mechanical strength, toughness, and stretchability and a production method of the polymer article. The polymer article of the present invention is formed of a polymer material and is a polymer blank or a formed polymer body. The polymer article of the present invention has a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%. A method for producing a polymer article of the present invention includes: a heating step of heating the polymer material to a temperature of not lower than (Tm−70)° C. but lower than Tm(° C.) where Tm is the melting point (° C.) of the polymer material; and a compression step of cooling the polymer material heated in the heating step and compressing the polymer material in the course of the cooling to obtain a polymer article having a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%.
    • 提供了机械强度,韧性和拉伸性优异的聚合物制品和聚合物制品的制造方法。 本发明的聚合物制品由聚合物材料形成,并且是聚合物坯料或形成的聚合物体。 本发明的聚合物制品的结晶度不小于50%但小于90%,断裂时的拉伸应变不小于60%。 本发明的聚合物制品的制造方法包括:将聚合物材料加热至不低于(Tm-70)℃但低于Tm(℃)的温度的加热步骤,其中Tm为熔融温度 点(℃); 以及冷却在加热步骤中加热并在冷却过程中压缩聚合物材料的聚合物材料的压缩步骤,以获得结晶度不小于50%但小于90%的聚合物制品和断裂时的拉伸应变 不低于60%。
    • 6. 发明授权
    • Polymer article and method for producing polymer article
    • 聚合物制品和聚合物制品的制造方法
    • US08986590B2
    • 2015-03-24
    • US13643544
    • 2011-05-24
    • Hironori TabataHiroyuki HiranoKazuho UchidaAkira Nakasuga
    • Hironori TabataHiroyuki HiranoKazuho UchidaAkira Nakasuga
    • B29C43/02B29C43/00B29C43/52B29C47/00
    • B29C43/003B29C43/02B29C43/52B29C47/0019B29C47/003B29C47/0033B29C47/004C08J5/121C08J2323/12
    • Provided are a polymer article excellent in mechanical strength, toughness, and stretchability and a production method of the polymer article. The polymer article of the present invention is formed of a polymer material and is a polymer blank or a formed polymer body. The polymer article of the present invention has a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%. A method for producing a polymer article of the present invention includes: a heating step of heating the polymer material to a temperature of not lower than (Tm−70)° C. but lower than Tm(° C.) where Tm is the melting point (° C.) of the polymer material; and a compression step of cooling the polymer material heated in the heating step and compressing the polymer material in the course of the cooling to obtain a polymer article having a crystallinity of not less than 50% but less than 90% and a tensile strain at fracture of not less than 60%.
    • 提供了机械强度,韧性和拉伸性优异的聚合物制品和聚合物制品的制造方法。 本发明的聚合物制品由聚合物材料形成,并且是聚合物坯料或形成的聚合物体。 本发明的聚合物制品的结晶度不小于50%但小于90%,断裂时的拉伸应变不小于60%。 本发明的聚合物制品的制造方法包括:将聚合物材料加热至不低于(Tm-70)℃但低于Tm(℃)的温度的加热步骤,其中Tm为熔融温度 点(℃); 以及冷却在加热步骤中加热并在冷却过程中压缩聚合物材料的聚合物材料的压缩步骤,以获得结晶度不小于50%但小于90%的聚合物制品和断裂时的拉伸应变 不低于60%。
    • 7. 发明授权
    • Method for producing polymer molded article, and polymer molded article
    • 聚合物成型体的制造方法和聚合物成型体
    • US08846795B2
    • 2014-09-30
    • US13877905
    • 2011-12-14
    • Hironori TabataAkira Nakasuga
    • Hironori TabataAkira Nakasuga
    • C08K3/00C08F210/00B05D7/02C08J7/02C08K3/18
    • C08K3/18B05D7/02C08J7/02C08J2323/02C08J2323/10
    • Provided are a method for producing a polymer molded article, which is capable of increasing crystallinity, heat resistance, and isotropic elastic modulus while maintaining the original shape of a polymer molded body and a polymer molded article obtained by the method and having a high crystallinity, high heat resistance, and a high isotropic elastic modulus. The method for producing a polymer molded article includes the steps of: preparing a polymer material mainly containing a crystalline polymer; and impregnating the polymer material with a first gas having solubility in the crystalline polymer in an atmosphere in which the pressure of the first gas is equal to or higher than atmospheric pressure at a temperature higher than (Tm−30)° C. but lower than (Tm−15)° C., where Tm represents the melting point of the crystalline polymer, to obtain a polymer molded article. The polymer molded article is obtained by such a production method.
    • 提供一种聚合物成型体的制造方法,其能够在保持聚合物成型体的原始形状和通过该方法获得的具有高结晶度的聚合物成型体的同时提高结晶性,耐热性和各向同性弹性模量, 高耐热性,高均相弹性模量。 聚合物成型体的制造方法包括以下步骤:制备主要含有结晶聚合物的聚合物材料; 并且在高于(Tm-30)℃但低于(Tm-30)℃的温度下,在第一气体的压力等于或高于大气压的气氛中,用具有溶解度的第一气体在结晶聚合物中浸渍聚合物材料 (Tm-15)℃,其中Tm表示结晶聚合物的熔点,得到聚合物成型体。 通过这样的制造方法得到聚合物成型品。