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    • 6. 发明授权
    • Poly(aryletherimides) for negative birefringent films for LCDs
    • 用于LCD的负双折射膜的聚(芳基酰亚胺)
    • US07820253B2
    • 2010-10-26
    • US11867372
    • 2007-10-04
    • Frank HarrisLimin SunDong ZhangStephen Z. D. Cheng
    • Frank HarrisLimin SunDong ZhangStephen Z. D. Cheng
    • G02F1/13363
    • C08G73/1039C08G73/1042C08G73/1067C08J5/18C08J2379/08G02B5/3083G02F1/133634Y10T428/1027Y10T428/1036Y10T428/1041Y10T428/31721
    • A negative birefringence film prepared from a poly(aryletherimide) which is the reaction product of a dianhydride and a diamine, where the dianhydride is 4,4′-[4,4′-(p-phenyleneoxy)isopropylidene]bis(phthalic anhydride) (BisADA), bis(3,4-dicarboxyphenyl)ether dianhydride (ODPA), 4,4′-bis(3,4-dicarboxyphenoxy)biphenyl dianhydride (BPEDA), 1,4-bis(3,4-dicarboxyphenyloxy)phenyl dianhydride (BPQDA), 3,3′,4,4′-tetracarboxylicbiphenyl dianhydride (BPDA), or 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride (6FDA), alone or a mixture with one or more of: 3,3′,4,4′-tetracarboxylicbiphenyl dianhydride (BPDA), 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride (6FDA); and where the diamine is 1,4-bis(2-trifluoromethyl-4-aminophenoxy)-2,5-di(t-butyl)benzene (BTBDA), 3,3′-dimethyl-4,4′-diamino biphenyl (OTOL), or mixtures thereof and wherein when a mixture of dianhydrides is present, they are present in a molar amount of between 99 to 1 (99:1) and 1 to 99 (1:99), and the film has a negative birefringence greater than 0.01, at a thickness of less than 15 μm, when the poly(aryletherimide) is solution cast or coated onto a substrate.
    • 由二酐与二酐反应产生的聚(芳基醚酰亚胺)制备的负双折射膜,其中二酐是4,4' - [4,4' - (对亚苯基氧)异亚丙基]双(邻苯二甲酸酐) (BisADA),双(3,4-二羧基苯基)醚二酐(ODPA),4,4'-双(3,4-二羧基苯氧基)联苯二酐(BPEDA),1,4-双(3,4-二羧基苯氧基)苯基 二酐(BPQDA),3,3',4,4'-四羧基联苯二酐(BPDA)或2,2-双(3,4-二羧基苯基)-1,1,1,3,3,3-六氟丙烷二酐( 6FDA),单独的或与以下的一种或多种的混合物:3,3',4,4'-四羧基联苯二酐(BPDA),2,2-双(3,4-二羧基苯基)-1,1,1,3, 3,3-六氟丙烷二酐(6FDA); 其中二胺为1,4-双(2-三氟甲基-4-氨基苯氧基)-2,5-二(叔丁基)苯(BTBDA),3,3'-二甲基-4,4'-二氨基联苯( OTOL)或其混合物,并且其中当存在二酸酐的混合物时,其存在的摩尔量为99至1(99:1)至1至99(1:99),并且该膜具有负双折射率 当聚(芳基醚酰亚胺)溶液浇铸或涂覆在基底上时,其厚度小于15μm。