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    • 3. 发明授权
    • Thermoplastic polyester resin composition
    • 热塑性聚酯树脂组合物
    • US08796367B2
    • 2014-08-05
    • US13055407
    • 2009-07-22
    • Morio TsunodaOsamu TakiseYasushi Yamanaka
    • Morio TsunodaOsamu TakiseYasushi Yamanaka
    • C08K5/3492
    • C08L67/02C08G77/18C08G77/70C08K3/38C08K5/34928C08K5/5313C08L51/08C08L83/04C08L2666/02C08L83/00
    • A thermoplastic polyester resin composition comprising 100 parts by weight of a thermoplastic polyester resin (A), 5 to 40 parts by weight of a phosphinate (B), and an organosiloxane (X); wherein the phosphinate is a calcium salt or aluminum salt of phosphine acid having the anion part having a particular structure; which, as the organosiloxane (X), comprises 1.5 to 10 parts by weight of an organosiloxane compound (X-1) or 0.01 to 5 parts by weight of an organosiloxane polymer (X-2), relative to 100 parts by weight of the thermoplastic polyester resin (A); and wherein the organosiloxane compound (X-1) comprises organic groups bonding to a silicon atom directly or through an oxygen atom, and 40 mole % or more of the organic groups are an aryl group, and the organosiloxane polymer (X-2) is in the form of solid at 25° C.
    • 一种热塑性聚酯树脂组合物,其包含100重量份的热塑性聚酯树脂(A),5至40重量份的次膦酸盐(B)和有机硅氧烷(X); 其中次膦酸盐是具有具有特定结构的阴离子部分的膦酸的钙盐或铝盐; 作为有机硅氧烷(X),相对于100重量份的有机硅氧烷(X-1),作为有机硅氧烷(X),含有1.5〜10重量份的有机硅氧烷化合物(X-1)或0.01〜5重量份的有机硅氧烷聚合物 热塑性聚酯树脂(A); 其中有机硅氧烷化合物(X-1)包含直接或通过氧原子与硅原子键合的有机基团,有机基团的40摩尔%以上为芳基,有机硅氧烷聚合物(X-2)为 在25℃下为固体形式
    • 4. 发明申请
    • THERMOPLASTIC POLYESTER RESIN COMPOSITION
    • 热塑性聚酯树脂组合物
    • US20110201730A1
    • 2011-08-18
    • US13055407
    • 2009-07-22
    • Morio TsunodaOsamu TakiseYasushi Yamanaka
    • Morio TsunodaOsamu TakiseYasushi Yamanaka
    • C08K5/3492C08K5/52
    • C08L67/02C08G77/18C08G77/70C08K3/38C08K5/34928C08K5/5313C08L51/08C08L83/04C08L2666/02C08L83/00
    • A thermoplastic polyester resin composition comprising 100 parts by weight of a thermoplastic polyester resin (A), 5 to 40 parts by weight of a phosphinate (B), and an organosiloxane (X); wherein the phosphinate is a calcium salt or aluminium salt of phosphine acid having the anion part having a particular structure; which, as the organosiloxane (X), comprises 1.5 to 10 parts by weight of an organosiloxane compound (X-1) or 0.01 to 5 parts by weight of an organosiloxane polymer (X-2), relative to 100 parts by weight of the thermoplastic polyester resin (A); and wherein the organosiloxane compound (X-1) comprises organic groups bonding to a silicon atom directly or through an oxygen atom, and 40 mole % or more of the organic groups are an aryl group, and the organosiloxane polymer (X-2) is in the form of solid at 25° C.
    • 一种热塑性聚酯树脂组合物,其包含100重量份的热塑性聚酯树脂(A),5至40重量份的次膦酸盐(B)和有机硅氧烷(X); 其中次膦酸盐是具有具有特定结构的阴离子部分的膦酸的钙盐或铝盐; 作为有机硅氧烷(X),相对于100重量份的有机硅氧烷(X-1),作为有机硅氧烷(X),含有1.5〜10重量份的有机硅氧烷化合物(X-1)或0.01〜5重量份的有机硅氧烷聚合物 热塑性聚酯树脂(A); 其中有机硅氧烷化合物(X-1)包含直接或通过氧原子与硅原子键合的有机基团,有机基团的40摩尔%以上为芳基,有机硅氧烷聚合物(X-2)为 在25℃下为固体形式
    • 5. 发明申请
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • US20070117901A1
    • 2007-05-24
    • US11635798
    • 2006-12-08
    • Masami SuzukiMorio TsunodaHajime OhyamaMakoto NakamuraKiyoji Takagi
    • Masami SuzukiMorio TsunodaHajime OhyamaMakoto NakamuraKiyoji Takagi
    • C08K3/34
    • C08L77/02C08K3/34C08L23/0861C08L29/04C08L53/00C08L53/02C08L53/025C08L77/00C08L77/06C08L2205/02C08L2205/035C08L2666/02C08L2666/04C08L2666/24
    • The present invention relates to a thermoplastic resin composition which excels in impact resistance, dimension stability and rigidity, and also excels in appearance, fluidity and paint film adhesion property, and further which is very useful as manufacturing materials for exterior parts of automobile. A thermoplastic resin composition comprising component (A): a polyamide resin; component (B): a hydrogenated product of block copolymer comprising vinyl aromatic polymer block (a) and conjugated diene based polymer block (b), and/or ethylene-α-olefin based block copolymer; component (C): a modified hydrogenated product of block copolymer comprising the vinyl aromatic polymer block (a) and the conjugated diene based polymer block (b), which hydrogenated product is modified by addition of an unsaturated acid and/or derivative thereof; component (D): a plate-like and/or needle-like inorganic filler; and component (F): an ethylene-vinyl alcohol copolymer and/or a partial saponified product of ethylene-vinyl acetate copolymer.
    • 本发明涉及耐冲击性,尺寸稳定性和刚性优异的外观,流动性和漆膜附着性优异的热塑性树脂组合物,进一步作为汽车用外装件的制造材料非常有用。 一种热塑性树脂组合物,其包含组分(A):聚酰胺树脂; 组分(B):包含乙烯基芳族聚合物嵌段(a)和共轭二烯基聚合物嵌段(b)的嵌段共聚物的氢化产物和/或乙烯-α-烯烃基嵌段共聚物; 组分(C):包含乙烯基芳族聚合物嵌段(a)和共轭二烯基聚合物嵌段(b)的嵌段共聚物的改性氢化产物,该加氢产物通过加入不饱和酸和/或其衍生物进行改性; 组分(D):板状和/或针状无机填料; 和组分(F):乙烯 - 乙烯醇共聚物和/或乙烯 - 乙酸乙烯酯共聚物的部分皂化产物。
    • 7. 发明授权
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • US08193282B2
    • 2012-06-05
    • US11635798
    • 2006-12-08
    • Masami SuzukiMorio TsunodaHajime OhyamaMakoto NakamuraKiyoji Takagi
    • Masami SuzukiMorio TsunodaHajime OhyamaMakoto NakamuraKiyoji Takagi
    • C08K3/04C08K3/34C08L53/02C08L77/00
    • C08L77/02C08K3/34C08L23/0861C08L29/04C08L53/00C08L53/02C08L53/025C08L77/00C08L77/06C08L2205/02C08L2205/035C08L2666/02C08L2666/04C08L2666/24
    • The present invention relates to a thermoplastic resin composition which excels in impact resistance, dimension stability and rigidity, and also excels in appearance, fluidity and paint film adhesion property, and further which is very useful as manufacturing materials for exterior parts of automobile.A thermoplastic resin composition comprising component (A): a polyamide resin; component (B): a hydrogenated product of block copolymer comprising vinyl aromatic polymer block (a) and conjugated diene based polymer block (b), and/or ethylene-α-olefin based block copolymer; component (C): a modified hydrogenated product of block copolymer comprising the vinyl aromatic polymer block (a) and the conjugated diene based polymer block (b), which hydrogenated product is modified by addition of an unsaturated acid and/or derivative thereof; component (D): a plate-like and/or needle-like inorganic filler; and component (F): an ethylene-vinyl alcohol copolymer and/or a partial saponified product of ethylene-vinyl acetate copolymer.
    • 本发明涉及耐冲击性,尺寸稳定性和刚性优异的外观,流动性和漆膜附着性优异的热塑性树脂组合物,进一步作为汽车外用部件的制造材料非常有用。 一种热塑性树脂组合物,其包含组分(A):聚酰胺树脂; 组分(B):包含乙烯基芳族聚合物嵌段(a)和共轭二烯基聚合物嵌段(b)的嵌段共聚物的氢化产物和/或乙烯-α-烯烃基嵌段共聚物; 组分(C):包含乙烯基芳族聚合物嵌段(a)和共轭二烯基聚合物嵌段(b)的嵌段共聚物的改性氢化产物,该加氢产物通过加入不饱和酸和/或其衍生物进行改性; 组分(D):板状和/或针状无机填料; 和组分(F):乙烯 - 乙烯醇共聚物和/或乙烯 - 乙酸乙烯酯共聚物的部分皂化产物。
    • 8. 发明申请
    • FLAME RETARDANT POLYAMIDE RESIN COMPOSITION AND MOLDED ARTICLE
    • 阻燃聚酰胺树脂组合物和成型品
    • US20090312468A1
    • 2009-12-17
    • US12293022
    • 2007-03-12
    • Morio TsunodaYasushi Yamanaka
    • Morio TsunodaYasushi Yamanaka
    • C08K5/5317C08K5/5313
    • C08L53/025C08K3/38C08K5/0091C08K5/34928C08K5/5313C08L51/003C08L51/06C08L71/12C08L71/126C08L77/00C08L77/02C08L77/06C08L2666/02C08L2666/14C08L2666/04C08L2666/20
    • A flame retardant polyamide resin composition having excellent extrudability and moldability, being free of generating a highly corrosive hydrogen halide gas upon combustion, exhibiting very high flame retardancy, having excellent mechanical properties and electrical properties and being suited for use in electrical and electronic parts and parts for automobile electrical equipments, and a molded article thereof are provided. A polyamide resin composition comprising 100 parts by weight of an aliphatic polyamide resin (A) having a viscosity number of 70 to 200 ml/g, 0.1 to 30 parts by weight of a polyphenylene ether-based resin (B), and 5 to 100 parts by weight of flame retardant agent (C) comprising at least the following components (a), (b) and (c); (a) a reaction product of a melamine and a phosphoric acid, (b) a phosphinic acid salt and/or a diphosphinic acid salt, and (c) a metal salt of boric acid, wherein a compounding weight ratio (a):(b):(c) of the flame retardant agent components is 1:(0.5 to 2.5):(0.01 to 1).
    • 一种具有优异的挤出性和成型性的阻燃性聚酰胺树脂组合物,其在燃烧时不产生高度腐蚀性的卤化氢气体,显示出非常高的阻燃性,具有优异的机械性能和电性能并且适用于电气和电子部件 用于汽车电气设备及其模塑制品。 一种聚酰胺树脂组合物,其包含100重量份的粘度为70〜200ml / g的脂肪族聚酰胺树脂(A),0.1〜30重量份的聚苯醚系树脂(B),5〜100重量份 至少包含以下组分(a),(b)和(c)的阻燃剂(C)的重量份; (a)三聚氰胺和磷酸的反应产物,(b)次膦酸盐和/或二次膦酸盐,和(c)硼酸金属盐,其中配混重量比(a):( b):( c)阻燃剂成分为1:(0.5〜2.5):(0.01〜1)。
    • 10. 发明授权
    • Flame retardant polyamide resin composition and molded article
    • 阻燃聚酰胺树脂组合物和模塑制品
    • US07968629B2
    • 2011-06-28
    • US12293022
    • 2007-03-12
    • Morio TsunodaYasushi Yamanaka
    • Morio TsunodaYasushi Yamanaka
    • C08K5/3492
    • C08L53/025C08K3/38C08K5/0091C08K5/34928C08K5/5313C08L51/003C08L51/06C08L71/12C08L71/126C08L77/00C08L77/02C08L77/06C08L2666/02C08L2666/14C08L2666/04C08L2666/20
    • A flame retardant polyamide resin composition having excellent extrudability and moldability, being free of generating a highly corrosive hydrogen halide gas upon combustion, exhibiting very high flame retardancy, having excellent mechanical properties and electrical properties and being suited for use in electrical and electronic parts and parts for automobile electrical equipments, and a molded article thereof are provided. A polyamide resin composition comprising 100 parts by weight of an aliphatic polyamide resin (A) having a viscosity number of 70 to 200 ml/g, 0.1 to 30 parts by weight of a polyphenylene ether-based resin (B), and 5 to 100 parts by weight of flame retardant agent (C) comprising at least the following components (a), (b) and (c); (a) a reaction product of a melamine and a phosphoric acid, (b) a phosphinic acid salt and/or a diphosphinic acid salt, and (c) a metal salt of boric acid, wherein a compounding weight ratio (a):(b):(c) of the flame retardant agent components is 1:(0.5 to 2.5):(0.01 to 1).
    • 一种具有优异的挤出性和成型性的阻燃性聚酰胺树脂组合物,其在燃烧时不产生高度腐蚀性的卤化氢气体,显示出非常高的阻燃性,具有优异的机械性能和电性能并且适用于电气和电子部件 用于汽车电气设备及其模塑制品。 一种聚酰胺树脂组合物,其包含100重量份的粘度为70〜200ml / g的脂肪族聚酰胺树脂(A),0.1〜30重量份的聚苯醚系树脂(B),5〜100重量份 至少包含以下组分(a),(b)和(c)的阻燃剂(C)的重量份; (a)三聚氰胺和磷酸的反应产物,(b)次膦酸盐和/或二次膦酸盐,和(c)硼酸金属盐,其中配混重量比(a):( b):( c)阻燃剂成分为1:(0.5〜2.5):(0.01〜1)。