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1. 发明授权

US07586013B2 Method for preparing hydroxystyrenes and acetylated derivatives thereof 失效
标题翻译：制备羟基苯乙烯及其乙酰化衍生物的方法
公开(公告)号：US07586013B2
公开(公告)日：2009-09-08
申请号：US11082258
申请日：2005-03-17
申请人： Keith Kunitsky , Mukesh C. Shah , Steven W. Shuey , Barry M. Trost , Mark Wagman
发明人： Keith Kunitsky , Mukesh C. Shah , Steven W. Shuey , Barry M. Trost , Mark Wagman
IPC分类号： C07C37/68
CPC分类号： C07C67/08 , C07C37/50 , C07C41/18 , C07C69/017 , C07C69/157 , C07C69/16 , C07C39/20 , C07C43/23
摘要： A method is provided for the thermal decarboxylation of a phenolic substrate in the presence of a non-amine basic catalyst to produce a vinyl monomer. The product of the decarboxylation reaction may additionally be acetylated in the presence of an acetylating agent in the same reaction vessel.
摘要翻译：在非胺碱性催化剂的存在下，提供酚底物的热脱羧以产生乙烯基单体的方法。在同一反应容器中，乙酰化剂的存在下，脱羧反应的产物可另外进行乙酰化。

2. 发明申请

US20050234266A1 Method for preparing para-(2-hydroxyalkyloxy) styrene monomers and oligomers 失效
标题翻译：对 - （2-羟基烷氧基）苯乙烯单体和低聚物的制备方法
公开(公告)号：US20050234266A1
公开(公告)日：2005-10-20
申请号：US11057589
申请日：2005-02-14
申请人： Samuel Arthur , Keith Kunitsky , Barry Trost , Mark Wagman
发明人： Samuel Arthur , Keith Kunitsky , Barry Trost , Mark Wagman
IPC分类号： C07C41/00 , C07C41/03 , C07C43/23
CPC分类号： C07C41/03 , C08F12/22 , C07C43/23
摘要： A method for preparing p-(2-hydroxyalkyloxy)styrene monomers and oligomers is described. The method comprises a base-catalyzed reaction of a styrene ester, a suitable alcohol and an alkylene oxide in a single vessel reaction. In this method, the reactive p-hydroxystyrene is generated in situ via the base-catalyzed transesterification reaction between the styrene ester and the alcohol in the presence of the base catalyst. The p-hydroxystyrene formed reacts with the alkylene oxide to form the p-(2-hydroxyalkyloxy)styrene monomer or oligomer.
摘要翻译：描述了制备对 - （2-羟基烷氧基）苯乙烯单体和低聚物的方法。该方法包括在单容器反应中苯乙烯酯，合适的醇和烯化氧的碱催化反应。在该方法中，在碱催化剂存在下，通过苯乙烯酯与醇之间的碱催化酯交换反应原位生成反应性对羟基苯乙烯。所形成的对羟基苯乙烯与烯化氧反应形成对 - （2-羟基烷氧基）苯乙烯单体或低聚物。

3. 发明申请

US20050228191A1 Method for preparing hydroxystyrenes and acetylated derivatives thereof 失效
标题翻译：制备羟基苯乙烯及其乙酰化衍生物的方法
公开(公告)号：US20050228191A1
公开(公告)日：2005-10-13
申请号：US11082258
申请日：2005-03-17
申请人： Keith Kunitsky , Mukesh Shah , Steven Shuey , Barry Trost , Mark Wagman
发明人： Keith Kunitsky , Mukesh Shah , Steven Shuey , Barry Trost , Mark Wagman
IPC分类号： C07C37/00 , C07C37/50 , C07C39/06 , C07C39/18 , C07C39/20 , C07C41/00 , C07C41/18 , C07C43/23 , C07C67/08 , C07C69/00 , C07C253/30 , C07C255/00
CPC分类号： C07C67/08 , C07C37/50 , C07C41/18 , C07C69/017 , C07C69/157 , C07C69/16 , C07C39/20 , C07C43/23
摘要： A method is provided for the thermal decarboxylation of a phenolic substrate in the presence of a non-amine basic catalyst to produce a vinyl monomer. The product of the decarboxylation reaction may additionally be acetylated in the presence of an acetylating agent in the same reaction vessel.
摘要翻译：在非胺碱性催化剂的存在下，提供酚底物的热脱羧以产生乙烯基单体的方法。在同一反应容器中，乙酰化剂的存在下，脱羧反应的产物可另外进行乙酰化。

4. 发明申请

US20070073003A1 Random copolymers of ethylene and 4-vinylphenyl esters and method for preparing the same 失效
标题翻译：乙烯和4-乙烯基苯基酯的无规共聚物及其制备方法
公开(公告)号：US20070073003A1
公开(公告)日：2007-03-29
申请号：US11235300
申请日：2005-09-26
申请人： Michael Sheehan , Mark Wagman
发明人： Michael Sheehan , Mark Wagman
IPC分类号： C08F226/06
CPC分类号： C08F6/001 , C08F210/02 , C08L23/08 , C08F4/32 , C08F2/00 , C08F218/12 , C08F2500/01 , C08F2500/12 , C08F2500/20 , C08F220/06
摘要： The invention discloses a composition consisting essentially of an E/X/M random copolymer wherein X is from 0.1 to 20 mol % of the E/X/M copolymer and is a 4-vinylphenyl ester, preferably 4-acetoxystyrene; M is from 0 to 40 mol % of the E/X/M copolymer and is one or more ethylenically unsaturated monomers; and E is ethylene. The invention further encompasses a high pressure radical polymerization process for providing the novel polymers; and a base catalyzed transesterification process for conversion of the E/X/M copolymer to an E/Y/M copolymer wherein Y is derived from 4-hydroxystyrene. Another embodiment of the invention is a composition consisting essentially of an E/Y/M random copolymer wherein Y is greater than 1.0 to about 20 mol % of the E/Y/M copolymer and is 4-hydroxystyrene; M is from 0 to 40 mol % of the E/Y/M copolymer and is one or more ethylenically unsaturated monomers; and E is ethylene.
摘要翻译：本发明公开了一种基本上由E / X / M无规共聚物组成的组合物，其中X为E / X / M共聚物的0.1-20摩尔％，是4-乙烯基苯基酯，优选4-乙酰氧基苯乙烯; M为E / X / M共聚物的0〜40摩尔％，为一种或多种烯属不饱和单体; E是乙烯。本发明还包括用于提供新型聚合物的高压自由基聚合方法; 以及用于将E / X / M共聚物转化成其中Y衍生自4-羟基苯乙烯的E / Y / M共聚物的碱催化酯交换方法。本发明的另一个实施方案是基本上由E / Y / M无规共聚物组成的组合物，其中Y大于E / Y / M共聚物的1.0至约20mol％且为4-羟基苯乙烯; M为0〜40摩尔％的E / Y / M共聚物，为一种或多种烯属不饱和单体; E是乙烯。

5. 发明申请

US20050267262A1 Method for making polyolefin graft polymers having improved adhesion properties 失效
标题翻译：制备具有改进的粘合性能的聚烯烃接枝聚合物的方法
公开(公告)号：US20050267262A1
公开(公告)日：2005-12-01
申请号：US11135861
申请日：2005-05-23
申请人： Mark Wagman , Barry Morris
发明人： Mark Wagman , Barry Morris
IPC分类号： C08F255/00 , C08F255/02 , C08L51/00
CPC分类号： C08F255/00 , C08F255/02 , C08F212/14 , C08F220/40
摘要： A solution grafting method for making polyolefin graft polymers by grafting a phenolic ester monomeric compound on olefinic polymers in the presence of a radical initiator in an organic solvent is described. The grafted polymers provide improved adhesion properties, particularly to metal and polyester substrates.
摘要翻译：描述了通过在自由基引发剂存在下在有机溶剂中将酚酯单体化合物接枝到烯烃聚合物上来制备聚烯烃接枝聚合物的溶液接枝方法。接枝聚合物提供改善的粘合性能，特别是金属和聚酯基材。

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